Physics Commons^™

Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers

Faculty Publications

High throughput (combinatorial) materials science methodology is a relatively new research paradigm that offers the promise of rapid and efficient materials screening, optimization, and discovery. The paradigm started in the pharmaceutical industry but was rapidly adopted to accelerate materials research in a wide variety of areas. High throughput experiments are characterized by synthesis of a “library” sample that contains the materials variation of interest (typically composition), and rapid and localized measurement schemes that result in massive data sets. Because the data are collected at the same time on the same “library” sample, they can be highly uniform with respect to …

Versatile Rb Vapor Cells With Long Lifetimes, John F. Hulbert, Matthieu Giraud-Carrier, Tom Wall, Aaron R. Hawkins, Scott D. Bergeson, Jennifer Black, Holger Schmidt

Faculty Publications

The authors report on an approach to the construction of long-lasting rubidium atomic vapor cells. The method uses pinch-off copper cold-welds, low temperature solders, and electroplated copper to create long-lasting hermetic seals between containment chambers of dissimilar geometries and materials. High temperature epoxy, eutectic lead/tin solder, and indium solder were considered as sealing materials. These seals were analyzed using accelerated lifetime testing techniques. Vapor cells with epoxy and bare metal solder seals had a decrease in the rubidium atomic density within days after being heated to elevated temperatures. They also exhibited broadened spectra as a result of rubidium reacting with …

Ace-Fts Version 3.0 Data Set: Validation And Data Processing Update, Claire Waymark, Kaley A. Walker, Chris D. Boone, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

No abstract provided.

The Roles Of Vertical Advection And Eddy Diffusion In The Equatorial Mesospheric Semi-Annual Oscillation (Msao), R. L. Gattinger, E. Kyrölä, C. D. Boone, W. F.J. Evans, K. A. Walker, I. C. Mcdade, P. F. Bernath, E. J. Llewellyn

Chemistry & Biochemistry Faculty Publications

Observations of the mesospheric semi-annual oscillation (MSAO) in the equatorial region have been reported dating back several decades. Seasonal variations in both species densities and airglow emissions are well documented. The extensive observations available offer an excellent case study for comparison with model simulations. A broad range of MSAO measurements is summarised with emphasis on the 80-100 km region. The objective here is not to address directly the complicated driving forces of the MSAO, but rather to employ a combination of observations and model simulations to estimate the limits of some of the underlying dynamical processes. Photochemical model simulations are …

Iupac Critical Evaluation Of The Rotational-Vibrational Spectra Of Water Vapor, Part Iii: Energy Levels And Transition Wavenumbers For H216o, Jonathan Tennyson, Peter F. Bernath, Linda R. Brown, Alain Campargue, Attila G. Csaszar, Ludovic Daumont, Robert R. Gamache, Joseph T. Hodges, Olga V. Naumenko, Oleg L. Polyansky

Chemistry & Biochemistry Faculty Publications

This is the third of a series of articles reporting critically evaluated rotational-vibrational line positions, transition intensities, and energy levels, with associated critically reviewed labels and uncertainties, for all the main isotopologues of water. This paper presents experimental line positions, experimental-quality energy levels, and validated labels for rotational-vibrational transitions of the most abundant isotopologue of water, H₂¹⁶O. The latest version of the MARVEL (Measured Active Rotational-Vibrational Energy Levels) line-inversion procedure is used to determine the rovibrational energy levels of the electronic ground state of H₂¹⁶O from experimentally measured lines, together with their self-consistent uncertainties, …

Capturing And Modeling A Three-Dimensional Stationary Noise Source Directivity Pattern With A Dynamic Array In The Near Field, Randy Mieskoski

Browse all Theses and Dissertations

The author has studied several legacy landmark methodologies to develop an original measurement technique. Spherical harmonics modeling practices were leveraged to accurately represent a source directivity pattern. In this thesis a lightweight microphone measurement array that was manually maneuvered around a static noise source was employed. The measurement technique consisted of inserting a head-tracker sensor onto the microphone array to allow the location of the captured acoustic Sound Pressure Level (SPL) to be investigated. By leveraging the historical methodologies the acoustic SPL and location data collected with this technique were processes to represent a directivity pattern of the compressor source …

Quantifying The Impact Of Various Radioactive Background Sources On Germanium-76 Zero-Neutrino-Double-Beta-Decay Experiments, Katarina Leila Mizouni

Theses and Dissertations

The goal of searching for 0vBB-decay is to probe an absolute neutrino mass scale suggested by the mass-splitting parameters observed by neutrino oscillation experiments. Furthermore, observation of 0vBB-decay is an explicit instance of lepton-number non-conservation. To detect the rare events such as 0vBB-decay, half-lives of the order of 10^25-10^27 years have to be probed. Using an active detector with a large volume, such as hundreds of kilograms of HPGe in the case of MAJORANA, and taking efficient measures to mitigate background of cosmic and primordial origins are necessary for the success of a sensitive 0vBB-decay experiment.

One focus of the …

Dipolar Interactions, Long Range Order And Random Fields In A Single Molecule Magnet, Mn12-Acetate, Bo Wen

Dissertations, Theses, and Capstone Projects

In this thesis, I will present an experimental study of two single molecule magnets, Mn₁₂-ac and Mn₁₂-ac-MeOH. I will show that in both systems, the temperature dependence of the inverse susceptibility yields a positive intercept on the temperature axis (a positive Weiss temperature), implying the existence of a ferromagnetic phase at low temperature.

Applying a magnetic field in the transverse direction moves the Weiss temperature downward towards zero. This implies that the transverse field triggers mechanisms in the system that compete with the dipolar interaction and suppress the long-range ordering.

I will then show that the …

Excitation Of Radiative Polaritons By Polarized Broadband Infrared Radiation In Thin Oxide Films Deposited By Atomic Layer Deposition, Anita J. Vincent-Johnson, Andrew E. Masters, Xiaofeng Hu, Giovanna Scarel

Department of Physics and Astronomy - Faculty Scholarship

This work contributes to the understanding of infrared radiation interaction with matter and its absorption for energy harvesting purposes. By exciting radiative polaritons in thin oxide filmswith polarized infrared radiation, a further evidence is collected that a link exists between radiative polaritons and the heat recovery mechanism hypothesized in previous research. In the voltage transient occurring when the infrared radiation is turned on, the observed time necessary to reach the maximum voltage and the voltage intensity versus angle of incidence exhibit a mismatch when generated by polarized and nonpolarized infrared radiation. The existence of collective charge oscillation modes in the …

Thermal Tuning Of Mid-Infrared Plasmonic Antenna Arrays Using A Phase Change Material, Mikhail A. Kats, Romain Blanchard, (...), M. M. Qazilbash, Et Al.

Arts & Sciences Articles

We demonstrate that the resonances of infrared plasmonic antennas can be tuned or switched on/off by taking advantage of the thermally driven insulator-to-metal phase transition in vanadium dioxide (VO2). Y-shaped antennas were fabricated on a 180 nm film of VO2 deposited on a sapphire substrate, and their resonances were shown to depend on the temperature of the VO2 film in proximity of its phase transition, in good agreement with full-wave simulations. We achieved tunability of the resonance wavelength of approximately 10% (>1 μm at λ ∼ 10 μm).

Active Optimal Control Strategies For Increasing The Efficiency Of Photovoltaic Cells, Sharif Aljoaba

Theses and Dissertations--Electrical and Computer Engineering

Energy consumption has increased drastically during the last century. Currently, the worldwide energy consumption is about 17.4 TW and is predicted to reach 25 TW by 2035. Solar energy has emerged as one of the potential renewable energy sources. Since its first physical recognition in 1887 by Adams and Day till nowadays, research in solar energy is continuously developing. This has lead to many achievements and milestones that introduced it as one of the most reliable and sustainable energy sources. Recently, the International Energy Agency declared that solar energy is predicted to be one of the major electricity production energy …

The Classical Limit Of Quantum Optics: Not What It Seems At First Sight, Yakir Aharonov, Alonso Botero, Shmuel Nussinov, Sandu Popescu, Jeff Tollaksen, Lev Vaidman

Mathematics, Physics, and Computer Science Faculty Articles and Research

What light is and how to describe it has always been a central subject in physics. As our understanding has increased, so have our theories changed: geometrical optics, wave optics and quantum optics are increasingly sophisticated descriptions, each referring to a larger class of phenomena than its predecessor. But how exactly are these theories related? How and when wave optics reduces to geometric optics is a rather simple problem. Similarly, how quantum optics reduces to wave optics has also been considered to be a very simple business. It is not so. As we show here the classical limit of quantum …

Towards A Formulation Of Quantum Theory As A Causally Neutral Theory Of Bayesian Inference, Matthew S. Leifer, Robert W. Spekkens

Mathematics, Physics, and Computer Science Faculty Articles and Research

Quantum theory can be viewed as a generalization of classical probability theory, but the analogy as it has been developed so far is not complete. Whereas themanner in which inferences aremade in classical probability theory is independent of the causal relation that holds between the conditioned variable and the conditioning variable, in the conventional quantum formalism, there is a significant difference between how one treats experiments involving two systems at a single time and those involving a single system at two times. In this article, we develop the formalism of quantum conditional states, which provides a unified description of …

Maximally Epistemic Interpretations Of The Quantum State And Contextuality, Matthew S. Leifer, O. J. E. Maroney

Mathematics, Physics, and Computer Science Faculty Articles and Research

We examine the relationship between quantum contextuality (in both the standard Kochen-Specker sense and in the generalized sense proposed by Spekkens) and models of quantum theory in which the quantum state is maximally epistemic.We find that preparation noncontextual models must be maximally epistemic, and these in turn must be Kochen-Specker noncontextual. This implies that the Kochen-Specker theorem is sufficient to establish both the impossibility of maximally epistemic models and the impossibility of preparation noncontextual models. The implication from preparation noncontextual to maximally epistemic then also yields a proof of Bell’s theorem from an Einstein-Podolsky-Rosen-like argument.

Visualizing And Understanding Tectonism And Volcanism On Earth And Other Terrestrial Bodies, Mladen M. Dordevic

Physics Theses & Dissertations

This dissertation presents new methods of visualizing, teaching, assessing, modeling, and understanding tectonics on Earth and other celestial bodies. Tectonics is the study of planetary lithospheres and includes impact, plate, plume, cryo- and gravitational mechanisms. This dissertation is concerned with plate tectonics and plate/mantle plume interactions. Plate tectonics describes the mainly horizontal motion of lithospheric plates over the asthenosphere. Lithosphere is created at ridges and consumed at subduction zones. In addition to the plate tectonic system, mantle plumes also contribute to mass motions in the subsurface Earth. Both plate tectonics and plume upwelling processes help shape the present form of …

Investigation Of Nbnx Thin Films And Nanoparticles Grown By Pulsed Laser Deposition And Thermal Diffusion, Ashraf Hassan Farha

Electrical & Computer Engineering Theses & Dissertations

Niobium nitride films (NbNx) were grown on Nb and Si (100) substrates using pulsed laser deposition (PLD), laser heating, and thermal diffusion methods. Niobium nitride films were deposited on Nb substrates using PLD with a Q-switched Nd: YAG laser (λ = 1064 nm, 40 ns pulse width, and 10 Hz repetition rate) at different laser fluences, different nitrogen background pressures and deposition temperatures. The effect of changing PLD parameters for films done by PLD was studied. The seen observations establish guidelines for adjusting the laser parameters to achieve the desired morphology and phase of the grown NbNx films.

When the …

Measurement Of Polarized Proton-Proton Elastic Scattering At The Relativistic Heavy Ion Collider (Rhic), Ivan Koralt

Physics Theses & Dissertations

Elastic proton-proton (pp) scattering is one of the most fundamental processes in nature and yet, it is one of the most difficult to describe. There are two interactions involved in this process: electromagnetic (Coulomb) and hadronic (strong) interactions. Underlying exchange mechanisms of these two interactions are the virtual photon and the Pomeron exchange, respectively. The difficulty of elastic pp scattering arises from the fact that the nature of the Pomeron and its exchange are not well understood and need a theoretical approach, which is still under development.

At the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Lab …

Aqueous Red-Emitting Silicon Nanoparticles For Cellular Imaging: Consequences Of Protecting Against Surface Passivation By Hydroxide And Water For Stable Red Emission, Sheng-Kuei Chiu, Beth Ann Manhat, William J.I. Debenedetti, Anna L. Brown, Katye Fichter, Tania Vu, Micah Eastman, Jun Jiao, Andrea Mitchell Goforth

Chemistry Faculty Publications and Presentations

Stable, aqueous, red-to-near infrared emission is critical for the use of silicon nanoparticles (Si NPs) in biological fluorescence assays, but such Si NPs have been difficult to attain. We report a synthesis and surface modification strategy that protects Si NPs and preserves red photoluminescence (PL) in water for more than 6 mo. The Si NPs were synthesized via high temperature reaction, liberated from an oxide matrix, and functionalized via hydrosilylation to yield hydrophobic particles. The hydrophobic Si NPs were phase transferred to water using the surfactant cetyltrimethylammonium bromide (CTAB) with retention of red PL. CTAB apparently serves a double role …

Effects Of Fluctuating Energy Input On The Small Scales In Turbulence, Greg Voth

Greg A. Voth

In the standard cascade picture of three-dimensional turbulent fluid flows, energy is input at a constant rate at large scales. Energy is then transferred to smaller scales by an intermittent process that has been the focus of a vast literature. However, the energy input at large scales is not constant in most real turbulent flows. We explore the signatures of these fluctuations of large-scale energy input on small-scale turbulence statistics. Measurements were made in a flow between oscillating grids, with Taylor Reynolds number up to 262, in which temporal variations in the large-scale energy input can be introduced by modulating …

A Lagrangian Which Mathematically Models Lambda Cdm Cosmology And Explains The Null Results Of Dark Astroparticle Searches., Hontas Farmer

Hontas F Farmer

Background: The Lambda CDM model or is the standard model of modern cosmology. It is named for dark energy and cold dark matter. This model contains a number of separate components with different mathematical formulations. Strong observational evidence for dark matter has been found by astronomy. At the same time astroparticle physics observations have not found solid evidence of dark matter. Purpose: The purpose of this paper is to reconcile observations of dark matter effects on the galactic and cosmological scales with the null results of astroparticle physics observations such as CDMS and ANTARES. This paper will also provide a …