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Nmr Characterization Of Novel Materials For Battery Electrolyte Applications, Sahana Bhattacharyya 2022 The Graduate Center, City University of New York

Nmr Characterization Of Novel Materials For Battery Electrolyte Applications, Sahana Bhattacharyya

Dissertations, Theses, and Capstone Projects

The extensive application of renewable and non-renewable energy storage devices in commercial products and services and the global warming have created significant motivations to accelerate research in battery technology. In addition, the risk factors generated by the high heat generation and flammability of the batteries are being addressed by inventing new renewable or non-renewable energy resources that do not release greenhouse gases into the atmosphere. This thesis discusses the applications of Nuclear Magnetic Resonance (NMR) Spectroscopy in characterizing and understanding novel battery materials as potential battery electrolytes. Works discussed include: the variable temperature characterization of water-based solid polymer electrolyte for …


Diagnostics Of Energy Release In Solar Flares With Radio Dynamic Imaging Spectroscopy, Yingjie Luo 2022 New Jersey Institute of Technology

Diagnostics Of Energy Release In Solar Flares With Radio Dynamic Imaging Spectroscopy, Yingjie Luo

Dissertations

Studies of the magnetic energy release and conversion process lie at the core of solar flare physics. Radio observations serve as a unique diagnostic method. In this dissertation, taking advantage of broadband radio dynamic imaging spectroscopy observations made by the Karl G. Jansky Very Large Array (VLA), studies are carried out on the flare energy release processes using different types of radio emissions.

The VLA is a general-purpose radio observatory located in New Mexico, which provides high-quality radio dynamic imaging spectroscopic observations with an ultra-fast time cadence. In the first study, stochastic decimetric radio spike bursts are observed by the …


Perovskite Solar Cells, Liqiu Zheng Dr., Tyler Hurst, Zhongrui Li 2022 Albany State University

Perovskite Solar Cells, Liqiu Zheng Dr., Tyler Hurst, Zhongrui Li

Georgia Journal of Science

The semiconductor perovskite CsPbBr2I was doped with Mn2+ to modulate its optical and photovoltaic performance. The Mn2+-doped CsPb0.9Mn0.1Br2I exhibited improved crystalline quality. Ultraviolet and visible spectroscopy of Mn2+-doped CsPb0.9Mn0.1Br2I revealed enhanced absorption capacity. Although the efficiency was not as good as desired, the enhanced light absorption of CsPb0.9Mn0.1Br2I still boosted the photovoltaic performance when it was utilized as a light absorber in perovskite solar cells, along with a low-cost carbon electrode. Compared with its counterpart …


A Comparison Of Uniaxial Compressive Response And Inelastic Deformation Mechanisms In Freeze Cast Alumina-Epoxy Composites Without And With Rigid Confinement, Tareq Aljuhari 2022 Old Dominion University

A Comparison Of Uniaxial Compressive Response And Inelastic Deformation Mechanisms In Freeze Cast Alumina-Epoxy Composites Without And With Rigid Confinement, Tareq Aljuhari

Mechanical & Aerospace Engineering Theses & Dissertations

Cellular ceramics have an array of improved mechanical properties that make them incredibly desired for different applications such as armor systems, aircraft structures, automobiles bumpers, and biomedical implants. It is also desirable that porous architecture could be shaped into bulk complicated shapes and easy to scale-up with low manufacturing cost. Despite several efficient techniques to fabricate cellular ceramics, some limitations are preventing us from meeting the high demand of the after mentioned applications. For that, freeze casting, also called ice-templating, is technique of solidifying an aqueous ceramic suspension under the effect of unidirectional temperature gradient. In this study, Ice-templated porous …


Developing A Software Defined Radio Based Faraday Receiver, Alvaro J. Guerra 2022 Clemson University

Developing A Software Defined Radio Based Faraday Receiver, Alvaro J. Guerra

All Theses

The ionosphere can be approximated as a magnetized plasma. This results in wave- particle interactions driving a large quantity of ionospheric phenomena. To understand these phenomena, it is important to quantify and measure certain key plasma parameters. One such parameter is electron density. The Faraday Experiment was developed for the purpose of measuring electron density in the D-region of the ionosphere. This experiment was made popular by Martin Friedrich in the 1970s and is currently one of the only ways to provide high resolution measurements of electron density in the D-region without actively disturbing the surrounding plasma. This thesis aims …


Weakness Of Weak Values: Incompatibility Of Anomalous Pulse-Spectrum Amplification And Optical Frequency Combs, John C. Howell 2022 Chapman University

Weakness Of Weak Values: Incompatibility Of Anomalous Pulse-Spectrum Amplification And Optical Frequency Combs, John C. Howell

Mathematics, Physics, and Computer Science Faculty Articles and Research

We probe the use of optical frequency combs to place lower bounds on anomalous amplification of a weak-value-measured pulse delay, potentially reaching a theoretical temporal resolution of better than 10−34 s. Owing to the interferometric behavior of weak values, we show that anomalous weak value amplification of a time delay is not equivalent to a temporal linear phase ramp. We show that the anomalous weak value is a rearrangement of amplitudes that generates an apparent shift that can be measured in direct detection, but does not change the actual frequency offset of a spectral distribution measurable in coherent detection. …


Magnetic Resonance Systems Development For Point-Of-Care Mri Platforms, Eric J. Lessard 2022 The University of Western Ontario

Magnetic Resonance Systems Development For Point-Of-Care Mri Platforms, Eric J. Lessard

Electronic Thesis and Dissertation Repository

Magnetic resonance imaging utilizes electromagnets to produce anatomical images in both clinical and research settings. In the race towards increasing performance head-optimized scanners have begun playing a significant role in providing high quality imaging of the head. However, they are implemented using smaller geometries and as such fail to allow entrance of the patient past their shoulders. This is overcome by designing asymmetric gradient coils which have their imaging region located towards one end of the gradient coil, as opposed to the geometric center, allowing brain imaging. There exists interest in compact configurations which allow imaging further into the cervical …


Ultra-High Carrier Mobilities In Ferroelectric Domain Wall Corbino Cones At Room Temperature, Conor J. McCluskey, Matthew G. Colbear, James P.V. McConville, Shane J. McCartan, Jesi R. Maguire, Michele Conroy, Kalani Moore, Alan Harvey, Felix Trier, Ursel Bangert, Alexei Gruverman, Manuel Bibes, Amit Kumar, Raymong G.P. McQuaid, J. Marty Gregg 2022 Queen’s University Belfast

Ultra-High Carrier Mobilities In Ferroelectric Domain Wall Corbino Cones At Room Temperature, Conor J. Mccluskey, Matthew G. Colbear, James P.V. Mcconville, Shane J. Mccartan, Jesi R. Maguire, Michele Conroy, Kalani Moore, Alan Harvey, Felix Trier, Ursel Bangert, Alexei Gruverman, Manuel Bibes, Amit Kumar, Raymong G.P. Mcquaid, J. Marty Gregg

Alexei Gruverman Publications

Recently, electrically conducting heterointerfaces between dissimilar band-insulators (such as lanthanum aluminate and strontium titanate) have attracted considerable research interest. Charge transport has been thoroughly explored and fundamental aspects of conduction firmly established. Perhaps surprisingly, similar insights into conceptually much simpler conducting homointerfaces, such as the domain walls that separate regions of different orientations of electrical polarisation within the same ferroelectric band-insulator, are not nearly so well-developed. Addressing this disparity, we herein report magnetoresistance in approximately conical 180° charged domain walls, which occur in partially switched ferroelectric thin film single crystal lithium niobate. This system is ideal for such measurements: firstly, …


Aerospace Components Made By Polymer Material, Minal Babar Graduate Engineer, Priyansh Saxena Graduate Engineer, Nilesh Vilash Thube Graduate Engineer, GOKUL RAJ S Engineering Graduate 2022 Department of Aerospace Engineering, Sandip University, MH, INDIA

Aerospace Components Made By Polymer Material, Minal Babar Graduate Engineer, Priyansh Saxena Graduate Engineer, Nilesh Vilash Thube Graduate Engineer, Gokul Raj S Engineering Graduate

Graduate Research in Engineering and Technology (GRET)

The aerospace and aviation industry have fasted growing industries on a global scale. Reliable aircraft demands many top rubber components. These rubber components must-have high performance and endurance properties, since they will be exposed to a range of extreme weather conditions, such as excessively hot or cold temperatures, and different types of oils and gases. Rubber products are becoming more famous because of their durability under extreme environmental conditions and cost-effectiveness. The rubber used for aircraft must be of high quality, and this factor is most important in the production of the necessary parts. To study the effect of all …


Shadows Of A Schwarzschild Black Hole Surrounded By A Spherically Symmetric Dark Matter, Ahmad Ibrahim 2022 American University in Cairo

Shadows Of A Schwarzschild Black Hole Surrounded By A Spherically Symmetric Dark Matter, Ahmad Ibrahim

Theses and Dissertations

In this thesis, using general relativity, the null geodesics and black hole shadow of a spherically symmetric configuration of a black hole (surrounded by a dark matter shell) are studied. First, the standard

results of the photon sphere of Schwarzschild de-Sitter black hole is revisited and analyzed more carefully. Secondly, using an ansatz (piecewise metric function) commonly used in the literature to describe the mass distribution of the spherically symmetric black hole - dark matter configuration, the null geodesics through vacuum and dark matter are analyzed. Assuming an observer located at a finite distance from the black hole outside the …


Investigating The Thermodynamics And Seismic Profile Of The Europan Hydrosphere Through Pure-Water Modeling And Saltwater Experiments, Samantha Rosenfeld 2022 Union College - Schenectady, NY

Investigating The Thermodynamics And Seismic Profile Of The Europan Hydrosphere Through Pure-Water Modeling And Saltwater Experiments, Samantha Rosenfeld

Honors Theses

We explore the properties of the hydrosphere on Europa involving both a modeling technique and experimental methods. We perform a computational analysis of the thermodynamic properties for an ideal, pure-water Europan ice shell using a Python programming framework called SeaFreeze. We create four models assuming surface temperatures of either 50 K or 140 K and ice shell thicknesses of either 3 km or 30 km. We observe mostly linear trends for the density and seismic wave velocities with respect to depth and find that surface temperature has the greatest effect on the models. Simultaneously, we experimentally investigate the phase diagram …


Using Differential Equations To Model A Cockatoo On A Spinning Wheel As Part Of The Scudem V Modeling Challenge, Miles Pophal, Chenming Zhen, Henry Bae 2022 Florida Institute of Technology

Using Differential Equations To Model A Cockatoo On A Spinning Wheel As Part Of The Scudem V Modeling Challenge, Miles Pophal, Chenming Zhen, Henry Bae

Rose-Hulman Undergraduate Mathematics Journal

For the SCUDEM V 2020 virtual challenge, we received an outstanding distinction for modeling a bird perched on a bicycle wheel utilizing the appropriate physical equations of rotational motion. Our model includes both theoretical calculations and numerical results from applying the Heaviside function for the swing motion of the bird. We provide a discussion on: our model and its numerical results, the overall limitations and future work of the model we constructed, and the experience we had participating in SCUDEM V 2020.


Waves And Oscillations In A Sunspot: Observations And Modeling Of Noaa Ar 12470, Yi Chai 2022 New Jersey Institute of Technology

Waves And Oscillations In A Sunspot: Observations And Modeling Of Noaa Ar 12470, Yi Chai

Dissertations

Waves and oscillations are important solar phenomena not only because they can propagate and dissipate energy in the chromosphere, but also because they carry information about the structure of the atmosphere in which they propagate. Among these phenomena, the one of the most interesting ones occurs in the sunspot umbra. In this area, continuously propagating magnetohydrodynamic (MHD) waves generated from below the photosphere create the famous 3-minute sunspot umbral oscillations that affect the line profile of spectral lines due to temperature, density, and velocity changes of the plasma in the region. In the past decades, numerous observations and models have …


Nondestructive Evaluation Of 3d Printed, Extruded, And Natural Polymer Structures Using Terahertz Spectroscopy And Imaging, Alexander T. Clark 2022 New Jersey Institute of Technology

Nondestructive Evaluation Of 3d Printed, Extruded, And Natural Polymer Structures Using Terahertz Spectroscopy And Imaging, Alexander T. Clark

Dissertations

Terahertz (THz) spectroscopy and imaging are considered for the nondestructive evaluation (NDE) of various three-dimensional (3D) printed, extruded, and natural polymer structures. THz radiation is the prime candidate for many NDE challenges due to the added benefits of safety, increased contrast and depth resolution, and optical characteristic visualization when compared to other techniques. THz imaging, using a wide bandwidth pulse-based system, can evaluate the external and internal structure of most nonconductive and nonpolar materials without any permanent effects. NDE images can be created based on THz pulse attributes or a material’s spectroscopic characteristics such as refractive index, attenuation coefficient, or …


Periodic Fast Multipole Method, Ruqi Pei 2022 New Jersey Institute of Technology

Periodic Fast Multipole Method, Ruqi Pei

Dissertations

Applications in electrostatics, magnetostatics, fluid mechanics, and elasticity often involve sources contained in a unit cell C, centered at the origin, on which periodic boundary condition are imposed. The free-space Green’s functions for many classical partial differential equations (PDE), such as the modified Helmholtz equation, are well-known. Among the existing schemes for imposing the periodicity, three common approaches are: direct discretization of the governing PDE including boundary conditions to yield a large sparse linear system of equations, spectral methods which solve the governing PDE using Fourier analysis, and the method of images based on tiling the plane with copies of …


Developing A Natural Language Processing Approach For Analyzing Student Ideas In Calculus-Based Introductory Physics, Jon M. Geiger, Lisa M. Goodhew, Tor Ole B. Odden 2022 Seattle Pacific University

Developing A Natural Language Processing Approach For Analyzing Student Ideas In Calculus-Based Introductory Physics, Jon M. Geiger, Lisa M. Goodhew, Tor Ole B. Odden

Honors Projects

Research characterizing common student ideas about particular physics topics has made a significant impact on university-level physics teaching by providing knowledge that supports instructors to target their instruction and by informing curriculum development. This work utilizes a Natural Language Processing algorithm (Latent Dirichlet Allocation, or LDA) to categorize student ideas, with the goal of significantly expediting the process of categorizing student ideas. We preliminarily test the LDA approach by applying the algorithm to a collection of introductory physics student responses to a conceptual question about circuits, specifically attending to whether it is useful for characterizing conceptual resources, or student ideas …


In-Phantom Film Measurements Of Two Treatment Planning Systems For Single-Fraction Spine Sbrt, Michael J. Taylor 2022 Louisiana State University and Agricultural and Mechanical College

In-Phantom Film Measurements Of Two Treatment Planning Systems For Single-Fraction Spine Sbrt, Michael J. Taylor

LSU Master's Theses

Purpose: Treatment planning accuracy for spine stereotactic body radiation therapy (SBRT) varies depending on the dose calculation algorithm utilized in the treatment planning system (TPS). This project compared the end-to-end accuracy between spine SBRT plans calculated in a convolution-superposition based TPS (TPSCS) and Monte Carlo based TPS (TPSMC) with radiochromic film measurements. The hypothesis was that TPSMC would calculate the dose gradient in the critical region between the vertebral body and the spinal cord more accurately than TPSCS.

Methods: Single-fraction spine SBRT treatments following RTOG 0631 and local institutional guidelines were planned in …


A Molecular Dynamics Study Of Polymer Chains In Shear Flows And Nanocomposites, Venkat Bala 2022 The University of Western Ontario

A Molecular Dynamics Study Of Polymer Chains In Shear Flows And Nanocomposites, Venkat Bala

Electronic Thesis and Dissertation Repository

In this work we study single chain polymers in shear flows and nanocomposite polymer melts extensively through the use of large scale molecular dynamics simulations through LAMMPS. In the single polymer chain shear flow study, we use the Lattice Boltzmann method to simulate fluid dynamics and also include thermal noise as per the \emph{fluctuation-dissipation} theorem in the system. When simulating the nanocomposite polymer melts, we simply use a Langevin thermostat to mimic a heat bath. In the single polymer in shear flow study we investigated the margination of a single chain towards solid surfaces and how strongly the shear flow …


Transistion Metal Chalcogenides And Phosphides For Energy Storage And Conversion Through Water Splitting, Kelsey Thompson 2022 Pittsburg State University

Transistion Metal Chalcogenides And Phosphides For Energy Storage And Conversion Through Water Splitting, Kelsey Thompson

Electronic Theses & Dissertations

In contemporary society, there are many different ways that energy is used in daily life. From applications that require a high energy density to long-term storage in a stable manner, the requirements for energy usage are diverse. Therefore, the greater the number of uses a designed material exhibits, the more practical it may be for wide-scale manufacture. Two areas of particular interest for energy applications are fuel cells (to generate energy) and supercapacitors (to store energy). To provide cheaper and more durable alternatives for energy storage, electrodes containing CoMoO4, NiMoO4, CoMoS4, NiMoS4, …


Control And Calibration Strategies For Quantum Simulation, Paul M. Kairys 2022 University of Tennessee, Knoxville

Control And Calibration Strategies For Quantum Simulation, Paul M. Kairys

Doctoral Dissertations

The modeling and prediction of quantum mechanical phenomena is key to the continued development of chemical, material, and information sciences. However, classical computers are fundamentally limited in their ability to model most quantum effects. An alternative route is through quantum simulation, where a programmable quantum device is used to emulate the phenomena of an otherwise distinct physical system. Unfortunately, there are a number of challenges preventing the widespread application of quantum simulation arising from the imperfect construction and operation of quantum simulators. Mitigating or eliminating deleterious effects is critical for using quantum simulation for scientific discovery. This dissertation develops strategies …


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