Atomic, Molecular and Optical Physics Commons^™

Strontium Monoxide Measurements In Methane-Air Flames, Bobby J. Wimberly

Masters Theses

The spectroscopy of alkaline earth metal compounds has been an area of active research for several decades. This is at least in part stimulated by the application of these compounds to practical areas ranging from technology to medicine. The use of these compounds in the field of pyrotechnics was the motivation for a series of flame emission spectroscopy (FES) experiments with strontium containing compounds. Specifically, strontium monoxide (SrO) is studied as a candidate radiator for the diagnostic of methane-air flames.

SrO emissions have been observed in flames with temperatures in the range of 1200-1600-K for two compounds: strontium hydroxide and …

Hohenberg-Kohn Theorems In Electrostatic And Uniform Magnetostatic Fields, Xiao-Yin Pan, Viraht Sahni

Publications and Research

The Hohenberg-Kohn (HK) theorems of bijectivity between the external scalar potential and the gauge invariant nondegenerate ground state density, and the consequent Euler variational principle for the density, are proved for arbitrary electrostatic field and the constraint of fixed electron number. The HK theorems are generalized for spinless electrons to the added presence of an external uniform magnetostatic field by introducing the new constraint of fixed canonical orbital angular momentum. Thereby, a bijective relationship between the external scalar and vector potentials, and the gauge invariant nondegenerate ground state density and physical current density, is proved. A corresponding Euler variational principle …

Effect Of Sm Content On Energy Product Of Rapidly Quenched And Oriented Smco5 Ribbons, Wenyong Zhang, Xingzhong Li, Shah R. Valloppilly

Nebraska Center for Materials and Nanoscience: Faculty Publications

The Sm-content dependence of phase composition, anisotropy, and other magnetic properties of Sm_1+δCo₅ (δ ≤ 0.12) ribbons melt spun at 10 m/s has been studied. The samples consist of hexagonal SmCo₅ grains whose c axes are preferentially aligned along the long direction of the ribbon. The lattice parameter a and the cell volume (V) increase with increasing Sm content δ, whereas c decreases. Sm addition appears to improve the degree of the preferred orientation of the c-axis and to increase the mean grain size, which weakens the effective intergranular exchange …

Two-Neutron Sequential Decay Of 24o, M. D. Jones, N. Frank, T. Baumann, J. Brett, J. Bullaro, P. A. Deyoung, J.E. Finck, K. Hammerton, J. Hinnefeld, Z. Kohley, A. N. Kuchera, J. Pereira, A. Rabeh, W. F. Rogers, J. K. Smith, A. Spyrou, Sharon L. Stephenson, K. Stiefel, M. Tuttle-Timm, R. G.T. Zegers, M. Thoennessen

Physics and Astronomy Faculty Publications

A two-neutron unbound excited state of 24O was populated through a (d,d ) reaction at 83.4 MeV/nucleon. A state at E = 715 ± 110 (stat) ± 45 (sys) keV with a width of < 2 MeV was observed above the two-neutron separation energy placing it at 7.65 ± 0.2 MeV with respect to the ground state. Three-body correlations for the decay of 24O → 22O + 2n show clear evidence of a sequential decay through an intermediate state in 23O. Neither a di-neutron nor phase-space model for the three-body breakup were able to describe these correlations.

Distributions Of Long-Lived Radioactive Nuclei Provided By Star-Forming Environments, Marco Fatuzzo, Fred Adams

Faculty Scholarship

Radioactive nuclei play an important role in planetary evolution by providing an internal heat source, which affects planetary structure and helps facilitate plate tectonics. A minimum level of nuclear activity is thought to be necessary—but not sufficient—for planets to be habitable. Extending previous work that focused on short-lived nuclei, this paper considers the delivery of long-lived radioactive nuclei to circumstellar disks in star forming regions. Although the long-lived nuclear species are always present, their abundances can be enhanced through multiple mechanisms. Most stars form in embedded cluster environments, so that disks can be enriched directly by intercepting ejecta from supernovae …

Population Of 13be In A Nucleon Exchange Reaction, B. R. Marks, P. A. Deyoung, J. K. Smith, T. Baumann, J. Brown, N. Frank, J. Hinnefeld, M. Hoffman, M. D. Jones, Z. Kohley, A. N. Kuchera, B. Luther, A. Spyrou, Sharon L. Stephenson, C. Sullivan, M. Thoennessen, N. Viscariello, S. J. Williams

Physics and Astronomy Faculty Publications

The neutron-unbound nucleus Be13 was populated with a nucleon exchange reaction from a 71 MeV/u secondary B13 beam. The decay-energy spectrum was reconstructed using invariant mass spectroscopy based on Be12 fragments in coincidence with neutrons. The data could be described with an s-wave resonance at Er=0.73(9)MeV with a width of Γr=1.98(34)MeVand a d-wave resonance at Er=2.56(13)MeV with a width of Γr=2.29(73)MeV. The observed spectral shape is consistent with previous one-proton removal reaction measurements from B14.

Energy-Efficient Computational Chemistry: Comparison Of X86 And Arm Systems, Kristopher Keipert, Gaurav Mitra, Vaibhav Sunriyal, Sarom S. Leang, Masha Sosonkina, Alistair P. Rendell, Mark S. Gordon

Computational Modeling & Simulation Engineering Faculty Publications

The computational efficiency and energy-to-solution of several applications using the GAMESS quantum chemistry suite of codes is evaluated for 32-bit and 64-bit ARM-based computers, and compared to an x86 machine. The x86 system completes all benchmark computations more quickly than either ARM system and is the best choice to minimize time to solution. The ARM64 and ARM32 computational performances are similar to each other for Hartree-Fock and density functional theory energy calculations. However, for memory-intensive second-order perturbation theory energy and gradient computations the lower ARM32 read/write memory bandwidth results in computation times as much as 86% longer than on the …

Magnetic-Field-Induced Alignment-To-Orientation Conversion In Sodium, G. Schinn, Xianming Han

Xianming Han

We report a detailed investigation of excited-state alignment-to-orientation conversion in the presence of an external magnetic field. This counterintuitive phenomenon occurs under intermediate-coupling conditions. A weak, linearly polarized, cw laser beam was used to excite and align the Na 3P3/2 state in an atomic beam along the z direction. The degree of circular polarization of the resulting fluorescence was detected along the z direction as a function of magnetic-field strength. The spectrally integrated transitions originating from individual F levels of the 3S1/2 state yield a maximum circular-polarization fraction of ∼40%; integrating the circular polarization over all the allowed 3S1/2-3P3/2 transitions …

Differential, Partial Cross Sections For Electron Excitation Of The Sodium 3p State, Xianming Han, G. W. Schwinn, A. Gallagher

Xianming Han

Using a powerful laser-based experimental method, the cross section for electron excitation of Na(3S) atoms to the Na(3P) state has been decomposed into partial components with respect to changes in the spin and angular momentum of the atomic electron, and these partial cross sections are further reduced to their differential character with respect to the electron scattering angle. Partial, differential cross sections are reported for electron collision energies from threshold 2.1 to 3.6 eV, and compared to available calculations.

Collision Induced Superfluorescence, A. Kumarakrishnan, Siddharaj Chudasama, Xianming Han

Xianming Han

We have studied superfluorescence (SF) in Ca vapor evolving on the 3d4s3DJ-4s4p3PJ−1 transitions at 1.9 mm by exciting the 4s21S0-4s4p1P1 with a pulsed dye laser. SF is generated following population transfer by spinchanging collisions with an inert gas Ar from the 4s4p1P1 and 3d4s1D2 levels. We show for the first time to our knowledge that the time delay for SF evolution follows the 1/ÎN dependence expected for the case of uniform excitation of the vapor column by collisional transfer. Here, N is the number of participating atoms that was measured directly from the photon yield. The measured photon yield for …

Superfluorescence Polarization: Signature Of Collisional Redistribution, A. Kumarakrishnan, S. Chudasama, Xianming Han

Xianming Han

We have studied effects of magnetic sublevel degeneracy on the polarization of superfluorescent pulses generated on the Ca 4s4p1P1–3d4s1D2 transition at 5.5μm. These pulses were generated from a cell of length 50 cm by optically pumping calcium vapor on the 4s21S0–4s4p1P1 transition in the presence of Ar gas. The axis of ellipticity of superfluorescence (SF) polarization is oriented parallel to the axis of the pump-laser polarization at large detunings, and undergoes an abrupt rotation through 90° for detunings close to resonance. The distribution of populations in the magnetic sublevels of the 1P1 state can be estimated using a simple model …

Diamond Growth Reactor Chemistry And Film Nucleation Enhancement Using Chlorinated Hydrocarbons, James Chenault, Charles Feigerle, Xianming Han, Robert Shaw

Xianming Han

The chemistry of diamond film growth from chlorinated hydrocarbons has been investigated using a hot filament reactor coupled to an orifice sampling mass spectrometer. The relative concentrations of the species present near the growth surface have been determined as a function of filament temperature for dilute mixtures of CH4, CH3Cl, CH2Cl2 and CHCl3 in H2. Mass spectral analysis indicated that chlorinated hydrocarbons are sequentially dechlorinated in the presence of hydrogen at moderate reactor temperatures. A dark film was deposited on all surfaces of the reactor during studies of this dechlorination of CHCl3. Raman analysis indicated that these deposits are small …

Fine‐Structure Mixing Within The Zn(43pj) Multiplet By Collisions With The Noble Gases, Xianming Han, J. F. Kelly

Xianming Han

Measurements of rate coefficients for intramultiplet state transfer of Zn(4 ³ P ₁→4 ³ P _J’) by collisions with the rare gases are presented. The state‐to‐state binary rate coefficients are derived from least‐squares fittings of the time‐resolved triexponential behavior of the 4 ³ P ₁fluorescence. These rate coefficients were studied systematically over a temperature range of 690–1100 K in order to characterize the velocity dependence of the collisional coupling. The systematic behavior of the rate coefficients with varying temperature and noble gas species is qualitatively consistent with a nearly adiabatic coupling limit for noncrossing levels.

Collisional Dynamics Of The First Excited States Of Neon In The 590-670 Nm Region Using Laser Optogalvanic Spectroscopy, Xianming Han, M. Su, C. Haridass, P. Misra

Xianming Han

A mathematical rate equation model, incorporating the various processes contributing to the generation of optogalvanic signals in a discharge plasma, has been used to analyze the time-resolved waveforms of neon in the wavelength region 590–670 nm. Amplitudes, decay rates and the appropriate instrumental time constant have been determined using a non-linear least-squares fit of the observed time-resolved optogalvanic waveforms.

Spin-Exchange Cross Section For Electron Excitation Of Na 3s 3p Determined By A Novel Spectroscopic Technique, Xianming Han, G. W. Schwinn, A. Gallagher

Xianming Han

An experimental technique is described which enables determination of the partial cross sections for electron excitation of atoms as a function of changes in spin and orbital angular momentum. This method provides a good signal-to-noise ratio in the energy region near threshold, and could be used to study long- or short-lived excited states of many atomic systems. Measurements for Na 3S−3P, near-threshold excitation are reported here. The results are generally in good agreement with the close-coupling calculations of D. L. Moores and D. W. Norcross [J. Phys. B 5, 1482 (1972)] for the largest ΔmS and ΔmL components of the …

Superfluorescence From Optically Trapped Calcium Atoms, Xianming Han

Xianming Han

We have studied superfluorescence (SF) under highly unfavorable conditions of rapid collisional and radiative distribution in a Doppler-broadened medium. Nanosecond SF pulses at 5.5 μm were generated on the Ca 4s4p1P1–3d4s1D2 transition from a column of calcium vapor buffered with Ar by optically pumping the 4s21S0–4s4p1P1 transition. The Rabi frequency associated with the intense pump pulse prevents the occurrence of SF while the pump laser is on. As a result, the predicted scaling laws that describe the properties of SF in a transversely excited system, such as peak heights, pulse widths, and delay times, are shown to apply in our …

Investigations Of Superfluorescent Cascades, A. Kumarakrishnan, Xianming Han

Xianming Han

We report our studies of superfluorescent cascades in atomic calcium which result from two-photon excitation of several levels reasonably close to the ionization limit. We have observed significant conversion efficiencies for some of these transitions which result in subnanosecond pulses particularly in the visible wavelengths. We report the discovery of a novel two-photon scattering mechanism which could prove to be a useful method for determining collisional broadening rates. In addition, a hyper Raman transition near 17 μm is discovered which appears to be a promising candidate for a tunable source.

Production And Diagnosis Of A Highly Spin-Polarized Na Beam, G. Schinn, Xianming Han, A. Gallagher

Xianming Han

We describe optically pumping a beam of sodium atoms to >96% mS and >92% mS, mI state selection. (We have accurately measured the population of every mS, mI state in the optically pumped beam.) For the optical pumping both ground hyperfine states are pumped, using single-mode cw dye-laser radiation tuned to the 3S1/2–3P1/2 transition that is phase modulated in a LiTaO3 crystal to produce first-order sidebands at approximately the 1772-MHz hyperfine splitting of the ground state. The z-directed optical pumping is performed in a z-directed magnetic field of ~5 G. The state-selected atoms then move, in ~1 cm, into an …

Hohenberg-Kohn Theorems In Electrostatic And Uniform Magnetostatic Fields, Xiao-Yin Pan, Viraht Sahni

Publications and Research

The Hohenberg-Kohn (HK) theorems of bijectivity between the external scalar potential and the gauge invariant nondegenerate ground state density, and the consequent Euler variational principle for the density, are proved for arbitrary electrostatic field and the constraint of fixed electron number. The HK theorems are generalized for spinless electrons to the added presence of an external uniform magnetostatic field by introducing the new constraint of fixed canonical orbital angular momentum. Thereby a bijective relationship between the external scalar and vector potentials, and the gauge invariant nondegenerate ground state density and physical current density, is proved. A corresponding Euler variational principle …

Hyperpolarized 129xe Magnetic Resonance Imaging Of Radiation-Induced Lung Injury, Ozkan Doganay

Electronic Thesis and Dissertation Repository

Lung cancer is the largest contributor to cancer-related mortality worldwide. Only 20% of stage III non-small cell lung cancer patients survive after 5-years post radiation therapy (RT). Although RT is an important treatment modality for lung cancer, it is limited by Radiation-Induced Lung Injury (RILI). RILI develops in two phases: (i) the early phase (days-weeks) referred to radiation pneumonitis (RP), and (ii) the late phase (months). There is a strong interest in early detection of RP using imaging to improve outcomes of RT for lung cancer. This thesis describes a promising approach based on ¹²⁹Xe gas as a contrast …