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Carbonate Chemistry And Carbon Sequestation Driven By Inorganic Carbon Outwelling From Mangroves And Saltmarshes, Gloria M. S. Reithmaier, Alex Cabral, Anirban Akhand, Matthew J. Bogard, Alberto V. Borges, Steven Bouillon, David J. Burdige, Mitchell Call, Nengwang Chen, Xiaogang Chen, Luiz C. Cotovicz Jr., Meagan J. Eagle, Erik Kristensen, Kevin D. Kroeger, Zeyang Lu, Damien T. Maher, J. Lucas Pérez-Lloréns, Raghab Ray, Pierre Taillardat, Joseph J. Tamborski, Rob C. Upstill-Goddard, Faming Wang, Zhaohui Aleck Wang, Kai Xiao, Yvonne Y.Y. Yau, Isaac R. Santos 2023 University of Gothenburg

Carbonate Chemistry And Carbon Sequestation Driven By Inorganic Carbon Outwelling From Mangroves And Saltmarshes, Gloria M. S. Reithmaier, Alex Cabral, Anirban Akhand, Matthew J. Bogard, Alberto V. Borges, Steven Bouillon, David J. Burdige, Mitchell Call, Nengwang Chen, Xiaogang Chen, Luiz C. Cotovicz Jr., Meagan J. Eagle, Erik Kristensen, Kevin D. Kroeger, Zeyang Lu, Damien T. Maher, J. Lucas Pérez-Lloréns, Raghab Ray, Pierre Taillardat, Joseph J. Tamborski, Rob C. Upstill-Goddard, Faming Wang, Zhaohui Aleck Wang, Kai Xiao, Yvonne Y.Y. Yau, Isaac R. Santos

OES Faculty Publications

Mangroves and saltmarshes are biogeochemical hotspots storing carbon in sediments and in the ocean following lateral carbon export (outwelling). Coastal seawater pH is modified by both uptake of anthropogenic carbon dioxide and natural biogeochemical processes, e.g., wetland inputs. Here, we investigate how mangroves and saltmarshes influence coastal carbonate chemistry and quantify the contribution of alkalinity and dissolved inorganic carbon (DIC) outwelling to blue carbon budgets. Observations from 45 mangroves and 16 saltmarshes worldwide revealed that >70% of intertidal wetlands export more DIC than alkalinity, potentially decreasing the pH of coastal waters. Porewater-derived DIC outwelling (81 ± 47 mmol m−2 …


Beaver Dam Analogs (Bdas) Alter Carbon Pools, Fluxes, And Concentrations Of Intermountain Headwater Streams, Hilary Schultz 2023 University of Montana, Missoula

Beaver Dam Analogs (Bdas) Alter Carbon Pools, Fluxes, And Concentrations Of Intermountain Headwater Streams, Hilary Schultz

Graduate Student Theses, Dissertations, & Professional Papers

Beaver dam analogs (BDAs) have emerged as a climate adaptation and restoration strategy for water resource management in the drought-prone Western U.S., yet the focus has been on their influence on water quantity, overlooking effects on broader ecological components. By increasing water residence time and facilitating sediment retention, BDAs have the potential to influence carbon pools, fluxes, and concentrations. To examine the influence of BDAs on instream and riparian organic C and trace gases, we studied three intermountain headwater streams restored with BDAs two years after restoration during the summer of 2021. We found that there were subtle differences in …


Rapid Bacterial And Fungal Successional Dynamics In First Year After Chaparral Wildfire, M. Fabiola Pulido-Chavez, James W. J. Randolph, Cassandra A. Zalman, Loralee Larios, Peter M. Homyak, Sydney I. Glassman 2022 University of California, Riverside

Rapid Bacterial And Fungal Successional Dynamics In First Year After Chaparral Wildfire, M. Fabiola Pulido-Chavez, James W. J. Randolph, Cassandra A. Zalman, Loralee Larios, Peter M. Homyak, Sydney I. Glassman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The rise in wildfire frequency and severity across the globe has increased interest in secondary succession. However, despite the role of soil microbial communities in controlling biogeochemical cycling and their role in the regeneration of post-fire vegetation, the lack of measurements immediately post-fire and at high temporal resolution has limited understanding of microbial secondary succession. To fill this knowledge gap, we sampled soils at 17, 25, 34, 67, 95, 131, 187, 286, and 376 days after a southern California wildfire in fire-adapted chaparral shrublands. We assessed bacterial and fungal biomass with qPCR of 16S and 18S and richness and composition …


Diversifying And Perennializing Plants In Agroecosystems Alters Retention Of New C And N From Crop Residues, Marshall D. McDaniel, Jeffrey A. Bird, Jennifer Pett-Ridge, Erika Marin-Spiotta, Tom M. Schmidt, A. Stuart Grandy 2022 Iowa State University

Diversifying And Perennializing Plants In Agroecosystems Alters Retention Of New C And N From Crop Residues, Marshall D. Mcdaniel, Jeffrey A. Bird, Jennifer Pett-Ridge, Erika Marin-Spiotta, Tom M. Schmidt, A. Stuart Grandy

Faculty Publications

Managing soils to retain new plant inputs is key to moving toward a sustainable and regenerative agriculture. Management practices, like diversifying and perennializing agroecosystems, may affect the decomposer organisms that regulate how new residue is converted to persistent soil organic matter. Here we tested whether 12 years of diversifying/perennializing plants in agroecosystems through extended rotations or grassland restoration would decrease losses of new plant residue inputs and, thus, increase retention of carbon (C) and nitrogen (N) in soil. We tracked dual-labeled (13C and 15N), isotopically enriched wheat (Triticum aestivum) residue in situ for 2 years as it decomposed in three …


Larval Ecology Of Atlantic Bluefin Tuna (Thunnus Thynnus): New Insights From Otolith Microstructure, Biotic, And Abiotic Analyses From The Gulf Of Mexico And Mediterranean Sea, Estrella Malca 2022 Nova Southeastern University

Larval Ecology Of Atlantic Bluefin Tuna (Thunnus Thynnus): New Insights From Otolith Microstructure, Biotic, And Abiotic Analyses From The Gulf Of Mexico And Mediterranean Sea, Estrella Malca

All HCAS Student Capstones, Theses, and Dissertations

Atlantic bluefin tuna (ABT), Thunnus thynnus, spawn in the Gulf of Mexico (GoM) and the Mediterranean Sea (MED). Spawning occurs within narrow temporal and environmental parameters. Efforts to characterize growth of ABT in wild conditions revealed a wide range of growth variability during the early life stages. This series of studies examined potential biotic and abiotic influences of larval growth from seven ABT cohorts, and identified several key drivers of growth for this commercially valuable species. A detailed investigation of larval dynamics using otolith microstructure was conducted as follows. First, companion growth curves and stable isotope analysis from the same …


Us Scientific Leadership Addressing Energy, Ecosystems, Climate, And Sustainable Prosperity: Report In Brief From The Berac Subcommittee On International Benchmarking, Maureen McCann, Patrick Reed, Ana Alonso, Ludmilla Aristilde, Massie S. Ballon, Crysten Blaby, Allison A. Campbell, Kenneth James Davis, Brian H. Davison, Ben Evans, Robert F. Fischetti, Serita D. Frey, Ann M. Fridlind, Efi Foufoula-Georgiou, Ramon Gonzalez, Michael N. Gooseff, Nathan Hillson, Janet Jansson, Klaus Keller, Markus Kleber, Costas Maranas, Gerald A. Meehl, Himadri Pakrasi, Jennifer Pett-Ridge, Kristala Prather, Johannes Quaas, G. Philip Robertson, Alistair Rogers, Tim Scheibe, Thomas R. Schneider, Gary Stacey, Margaret S. Torn, Kerstin Kleese van Dam, Detlef Vuuren, John Weyant, Stan Wullschleger, Shaocheng Xie, Seung Yon (Sue) Rhee, Huimin Zhao 2022 National Renewable Energy Lab

Us Scientific Leadership Addressing Energy, Ecosystems, Climate, And Sustainable Prosperity: Report In Brief From The Berac Subcommittee On International Benchmarking, Maureen Mccann, Patrick Reed, Ana Alonso, Ludmilla Aristilde, Massie S. Ballon, Crysten Blaby, Allison A. Campbell, Kenneth James Davis, Brian H. Davison, Ben Evans, Robert F. Fischetti, Serita D. Frey, Ann M. Fridlind, Efi Foufoula-Georgiou, Ramon Gonzalez, Michael N. Gooseff, Nathan Hillson, Janet Jansson, Klaus Keller, Markus Kleber, Costas Maranas, Gerald A. Meehl, Himadri Pakrasi, Jennifer Pett-Ridge, Kristala Prather, Johannes Quaas, G. Philip Robertson, Alistair Rogers, Tim Scheibe, Thomas R. Schneider, Gary Stacey, Margaret S. Torn, Kerstin Kleese Van Dam, Detlef Vuuren, John Weyant, Stan Wullschleger, Shaocheng Xie, Seung Yon (Sue) Rhee, Huimin Zhao

Faculty Publications

This document presents the subcommittee’s overarching and domain-specific findings and recommendations for the next decade, identified by consensus across the full BERAC subcommittee and experts interviewed for this assessment.


The Binding Of The Micronutrient Transition Metals To The Alkylation Products Of Chemical Warfare Agent, Sulfur Mustard, And Thiols, Potentially Giving New Understanding To Physiological Effects Of Exposure And Increased Toxicity, Colin O'Donnell 2022 University of Arkansas, Fayetteville

The Binding Of The Micronutrient Transition Metals To The Alkylation Products Of Chemical Warfare Agent, Sulfur Mustard, And Thiols, Potentially Giving New Understanding To Physiological Effects Of Exposure And Increased Toxicity, Colin O'Donnell

Graduate Theses and Dissertations

Model compounds, 3,6,9-trithaiundecane-1,11-dicarboxylic acid (TTDPA), 2,5,8-trithianonane-1,9-dicarboxylic acid (TTDAA), and 1,11-diamide-3,6,9-trithiaundecane (TTDAce), closely related to the adducts formed by cysteine alkylation of the chemical weapon, sulfur mustard, were synthesized. It is shown that TTDPA forms complexes with key metal micronutrients: copper, nickel, cobalt, manganese, and zinc. Though the strength of binding to TTDPA varies, the complexes in many cases precipitate from solution. All metals produced a visible precipitate upon interaction with TTDPA under the conditions tested, however only Cu2+, Mn2+, and Zn2+ produced enough to be measured. The mass of formed precipitate seemed to peak at an equimolar ratio of TTDPA …


Substrate Availability And Not Thermal Acclimation Controls Microbial Temperature Sensitivity Response To Long-Term Warming, Luiz A. Domeignoz-Horta, Grace Pold, Hailey Erb, David Sebag, Eric Verrecchia, Trent Northen, Katherine Louie, Emiley Eloe-Fadrosh, Christa Pennacchio, Melissa A. Knorr, Serita D. Frey, Jerry M. Melillo, Kristen M. DeAngelis 2022 University of Massachusetts, Amherst

Substrate Availability And Not Thermal Acclimation Controls Microbial Temperature Sensitivity Response To Long-Term Warming, Luiz A. Domeignoz-Horta, Grace Pold, Hailey Erb, David Sebag, Eric Verrecchia, Trent Northen, Katherine Louie, Emiley Eloe-Fadrosh, Christa Pennacchio, Melissa A. Knorr, Serita D. Frey, Jerry M. Melillo, Kristen M. Deangelis

Faculty Publications

Microbes are responsible for cycling carbon (C) through soils, and predicted changes in soil C stocks under climate change are highly sensitive to shifts in the mechanisms assumed to control the microbial physiological response to warming. Two mechanisms have been suggested to explain the long-term warming impact on microbial physiology: microbial thermal acclimation and changes in the quantity and quality of substrates available for microbial metabolism. Yet studies disentangling these two mechanisms are lacking. To resolve the drivers of changes in microbial physiology in response to long-term warming, we sampled soils from 13- and 28-year-old soil warming experiments in different …


Soil Microbial Communities Vary In Composition And Functional Strategy Across Soil Aggregate Size Class Regardless Of Tillage, Lukas T. Bernhardt, Richard G. Smith, Andrew S. Grandy, Jessica E. Mackay, Nicholas D. Warren, Kevin M. Geyer, Jessica G. Ernakovich 2022 University of New Hampshire, Durham

Soil Microbial Communities Vary In Composition And Functional Strategy Across Soil Aggregate Size Class Regardless Of Tillage, Lukas T. Bernhardt, Richard G. Smith, Andrew S. Grandy, Jessica E. Mackay, Nicholas D. Warren, Kevin M. Geyer, Jessica G. Ernakovich

Faculty Publications

The physicochemical environment within aggregates controls the distribution of carbon and microbial communities in soils. Agricultural management, such as tillage, can disrupt aggregates and the microscale habitat provided to microorganisms, thus altering microbial community dynamics. Categorizing microbial communities into life history strategies with shared functional traits—as has been done to understand plant community structure for decades—can illuminate how the soil physicochemical environment constrains the membership and activity of microbial communities. We conducted an aggregate scale survey of microbial community composition and function through the lens of the yield–acquisition–stress (Y–A–S) tolerator life history framework. Soils collected from a 7-year tillage experiment …


The Nitrogen Dynamics Of Deer Cave, Sarawak, And The Role Of Bat Caves As Biogeochemical Sinks In Tropical Moist Forests., Joyce Lundberg, Donald A. McFarlane, Guy Van Rentergem 2022 Carleton University, Canada

The Nitrogen Dynamics Of Deer Cave, Sarawak, And The Role Of Bat Caves As Biogeochemical Sinks In Tropical Moist Forests., Joyce Lundberg, Donald A. Mcfarlane, Guy Van Rentergem

International Journal of Speleology

A better understanding of the role of bat caves as nitrogen sinks in tropical moist forest ecosystems can be expected to shed light on regional and spatial variability in nutrient recycling studies. We measured the nitrogen flux (in air and water) associated with a very large Chaerephon plicata bat colony in Deer Cave, Borneo, in the process generating a new, quantitative, estimate of the total bat population (774,828 ±48,320), and the first detailed modelling of an ammonia plume in a cave. Long-term storage of N does not occur in this wet cave. Our final budget numbers indicate that, of the …


Environmental Controls On Carbon Biogeochemistry In Aquatic Systems, Lee Potter 2022 Louisiana State University and Agricultural and Mechanical College

Environmental Controls On Carbon Biogeochemistry In Aquatic Systems, Lee Potter

LSU Master's Theses

Carbon dioxide (CO2) outgassing from inland waters is a small but critical component of the global carbon cycle that is currently not well constrained. This thesis is composed of three interrelated studies with an overarching goal to further determine environmental factors impacting carbon dynamics in rivers and lakes. These studies utilized water samples and in situ measurements of pCO2 and ambient water parameters from the Lower Mississippi River at Baton Rouge and University Lake in Baton Rouge Louisiana, USA collected between January 2021 and August 2022. Additional Meteorological and hydrological data were download from public sources. Results …


Concentration Of Heavy Metals In Three Distinct Algae Families From Humboldt County, California, Kodiak E. Miller, Caleb J. Strait, Jacob I. Begorre, Brittney L. Mitchell, Claire P. Till 2022 Cal Poly Humboldt

Concentration Of Heavy Metals In Three Distinct Algae Families From Humboldt County, California, Kodiak E. Miller, Caleb J. Strait, Jacob I. Begorre, Brittney L. Mitchell, Claire P. Till

IdeaFest: Interdisciplinary Journal of Creative Works and Research from Cal Poly Humboldt

Anthropogenic impacts on marine environments can impact metal fluxes and concentrations available to marine species. Monitoring these impacts is necessary to better understand the interactions between the biotic and abiotic components of these ecosystems and mitigate the risk posed by harmful toxins introduced by human activities. Biomoniters, like macroscopic algae, are useful indicators that illuminate the bioaccumulation of toxins commonly introduced from anthropogenic activity. With this in mind, the concentrations of heavy metals zinc (Zn), nickel (Ni), and copper (Cu) were analyzed via the assessment of algae (Representatives from Ulva, Mastocarpus, Fucus) in two sites in Humboldt County: …


Permafrost And Climate Change: Carbon Cycle Feedbacks From The Warming Arctic, Edward A. G. Schuur, Benjamin W. Abbott, Roisin Commane, Jessica G. Ernakovich, Eugenie Euskirchen, Gustaf Hugelius, Guido Grosse, Miriam Jones, Charlie Koven, Victor Leshyk, David Lawrence, Michael M. Loranty, Marguerite Mauritz, David Olefeldt, Susan Natali, Heidi Rodenhizer, Verity Salmon, Christina Schadel, Jens Strauss, Claire C. Treat, Merritt Turetsky 2022 Northern Arizona University

Permafrost And Climate Change: Carbon Cycle Feedbacks From The Warming Arctic, Edward A. G. Schuur, Benjamin W. Abbott, Roisin Commane, Jessica G. Ernakovich, Eugenie Euskirchen, Gustaf Hugelius, Guido Grosse, Miriam Jones, Charlie Koven, Victor Leshyk, David Lawrence, Michael M. Loranty, Marguerite Mauritz, David Olefeldt, Susan Natali, Heidi Rodenhizer, Verity Salmon, Christina Schadel, Jens Strauss, Claire C. Treat, Merritt Turetsky

Faculty Publications

Rapid Arctic environmental change affects the entire Earth system as thawing permafrost ecosystems release greenhouse gases to the atmosphere. Understanding how much permafrost carbon will be released, over what time frame, and what the relative emissions of carbon dioxide and methane will be is key for understanding the impact on global climate. In addition, the response of vegetation in a warming climate has the potential to offset at least some of the accelerating feedback to the climate from permafrost carbon. Temperature, organic carbon, and ground ice are key regulators for determining the impact of permafrost ecosystems on the global carbon …


Evaluating The Impact Of Submarine Groundwater Discharge On Nutrients And Trace Elements In Coastal Systems: The Examples Of The Tuckean Swamp (Australia) And The Mississippi Sound (Usa), Amy Moody 2022 The University of Southern Mississippi

Evaluating The Impact Of Submarine Groundwater Discharge On Nutrients And Trace Elements In Coastal Systems: The Examples Of The Tuckean Swamp (Australia) And The Mississippi Sound (Usa), Amy Moody

Dissertations

Submarine groundwater discharge (SGD) is the advective flow of both fresh terrestrial groundwater and recirculating seawater through aquifer sediments, which is released into the coastal ocean. In this dissertation, I evaluated the impact of SGD on the distributions and input of trace metals and nutrients. In the Tuckean Swamp, an estuary in Australia dominated by coastal acid sulfate soils, I determined the impact of groundwater on Ba and U during the flood season, when the local aquifer is flushed out after a rapid increase in water table elevation. For Ba and U, groundwater contributed up to 18 and 66 % …


Nutrient Dynamics And Ecosystem Development Of Urban Forests, Gisselle A. Mejía 2022 CUNY Graduate Center

Nutrient Dynamics And Ecosystem Development Of Urban Forests, Gisselle A. Mejía

Dissertations, Theses, and Capstone Projects

Urban growth and expansion are a major component of global environmental change, with impacts on climate, air and water quality, biodiversity, and human well-being. Forests embedded in urban landscapes are critical in mitigating these impacts at local, regional, and continental scales. However, assessing urban forests is difficult because cities are heterogenous in physical, chemical, biological, and social dimensions. This heterogeneity has constrained how urban forests are defined, and therefore, how they are studied. The objective of this dissertation is to determine how these biophysical and social factors drive ecological processes in urban forests and will address three outstanding challenges in …


The Interaction Of Different Primary Producers And Physical And Chemical Dynamics Of An Urban Shallow Lake, Majid Sahin 2022 CUNY Graduate Center

The Interaction Of Different Primary Producers And Physical And Chemical Dynamics Of An Urban Shallow Lake, Majid Sahin

Dissertations, Theses, and Capstone Projects

An artificial urban shallow lake, Prospect Park Lake (PPL), is situated on a terminal moraine in Brooklyn New York, and supplied with municipal water treated with ortho-phosphates. The constant input of the phosphate nutrient is the primary source of eutrophication in the lake. The numerous pools along the water course houses various aquatic phototrophs, which influence the water quality and the state of the system, driving conditions into favoring the survival of their species. In the first half of the dissertation, the focus of the project is on analyzing how the different primary producers in different regions of PPL affect …


Determining The Effects Of Elevated Carbon Dioxide On Soil Acidification, Cation Depletion, And Soil Inorganic Carbon And Mapping Soil Carbons Using Artificial Intelligence, Jannatul Ferdush 2022 Mississippi State University

Determining The Effects Of Elevated Carbon Dioxide On Soil Acidification, Cation Depletion, And Soil Inorganic Carbon And Mapping Soil Carbons Using Artificial Intelligence, Jannatul Ferdush

Theses and Dissertations

Soil carbon is the largest sink and source of the global carbon cycle and is disturbed by several natural, anthropogenic, and environmental factors. The global increase of atmospheric CO2 affects soil carbon cycling through varied biogeochemical processes. The first chapter is a compilation of current information on potential factors triggering soil acidification and weathering mechanisms under elevated CO2 and their consequences on soil inorganic carbon (SIC) pool and quality. Soil water content and precipitation were critical factors influencing elevated CO2 effects on the SIC pool. The second chapter examines a detailed column experiment in which six soils …


Microtopography Matters: Belowground Ch4 Cycling Regulated By Differing Microbial Processes In Peatland Hummocks And Lawns, Clarice R. Perryman, Carmody K. McCalley, Jessica G. Ernakovich, Louis J. Lamit, Joanne H. Shorter, Erik Lilleskov, Ruth K. Varner 2022 University of New Hampshire, Durham

Microtopography Matters: Belowground Ch4 Cycling Regulated By Differing Microbial Processes In Peatland Hummocks And Lawns, Clarice R. Perryman, Carmody K. Mccalley, Jessica G. Ernakovich, Louis J. Lamit, Joanne H. Shorter, Erik Lilleskov, Ruth K. Varner

Faculty Publications

Water table depth and vegetation are key controls of methane (CH4) emissions from peatlands. Microtopography integrates these factors into features called microforms. Microforms often differ in CH4 emissions, but microform-dependent patterns of belowground CH4 cycling remain less clearly resolved. To investigate the impact of microtopography on belowground CH4 cycling, we characterized depth profiles of the community composition and activity of CH4-cycling microbes using 16S rRNA amplicon sequencing, incubations, and measurements of porewater CH4 concentration and isotopic composition from hummocks and lawns at Sallie's Fen in NH, USA. Geochemical proxies of methanogenesis and methanotrophy indicated that microforms differ in dominant microbial …


The Paleoecology Of High-Elevation Bison In The Greater Yellowstone Ecosystem And Implications For Modern Bison Conservation, Darian Bouvier 2022 East Tennessee State University

The Paleoecology Of High-Elevation Bison In The Greater Yellowstone Ecosystem And Implications For Modern Bison Conservation, Darian Bouvier

Electronic Theses and Dissertations

The national mammal of the United States, the American Bison (Bison bison) was once nearly extinct. Populations have recovered to the degree that thousands roam the Great Plains today. Due to their large numbers and body size, this species has an oversized impact on the ecological communities where it lives and is considered a keystone herbivore in modern North American grasslands. This study explores the detailed, seasonally resolved, paleoecology of seven bison from the Greater Yellowstone Ecosystem during the Late Holocene through stable isotope analyses and species niche modeling. Isotopic analyses of δ13C, δ15N, …


Wetland Soil Development Along Salinity And Hydrogeomorphic Gradients In Active And Inactive Deltaic Basins Of Coastal Louisiana, Amanda Fontenot 2022 Louisiana State University and Agricultural and Mechanical College

Wetland Soil Development Along Salinity And Hydrogeomorphic Gradients In Active And Inactive Deltaic Basins Of Coastal Louisiana, Amanda Fontenot

LSU Master's Theses

Coastal wetlands provide an abundance of ecosystem services that benefit society, such as essential habitat for commercial species, storm protection, nutrient cycling, and carbon storage. Louisiana faces rapid rates of relative sea level rise (natural subsidence and eustatic sea levels) that threaten wetland survival, which are amplified by a reduction of riverine sediment input. An important determining factor of marsh survival is the formation of wetland platform elevation, known as vertical accretion, which is determined by several processes including sediment deposition & erosion, below ground biomass (BGB) productivity, decomposition of organic matter, shallow & deep subsidence, and soil compaction. Feldspar …


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