Biogeochemistry Commons^™

Utilizing Indicator Of Reduction In Soils Tubes To Affirm A Serpentinitic Hydric Soil On The California Central Coast, Jason Demoss

Natural Resources Management and Environmental Sciences

Wetlands are vital ecosystems that are crucial in maintaining the life of rare and unique soils, plants, and animals. These ecosystems are key players in water storage, water filtration, carbon storage, and harboring unique species. Since the intervention of human development on the Earth’s surface, almost 50% of the Earth’s original wetlands have either been damaged or destroyed. The identification and assessment of both new and old wetlands is crucial in the survival of these precious ecosystems and their conservation. A 3 month-long study was performed to confirm the hydric status of a soil derived from serpentinitic parent material. The …

Carbon And Nitrogen Dynamics From Slow Pools Of Soil Organic Matter In A Temperate Forest: Pyrogenic Organic Matter And And Root Litter, Fernanda Dos Santos

Dissertations, Theses, and Capstone Projects

Soil organic matter (SOM) is the dominant reservoir of organic carbon (OC) in terrestrial ecosystems, storing approximately three times the size of the C pool in the atmosphere. In temperate forests, a major fraction of the SOM consists of slowly decaying soil organic C (SOC) pools. While slowly cycling C pools constitute a large reservoir of stable C in soils, the dominant environmental factors controlling this C pool remain unresolved. This research investigates two significant, but poorly characterized slowly decaying C pools: fine root litter (< 2mm) and thermally altered plant biomass (pyrogenic organic matter, PyOM). Specifically, I used compound-specific stable isotope analysis (¹³C and ¹⁵N) as my main methodological approach to examine the (1) …

Carbon Losses From Pyrolysed And Original Wood In A Forest Soil Under Natural And Increased N Deposition, B. Maestrini, S. Abiven, N. Singh, J. Bird, M. W. I. Schmidt

Publications and Research

Pyrogenic organic matter (PyOM) plays an important role as a stable carbon (C) sink in the soils of terrestrial ecosystems. However, uncertainties remain about in situ turnover rates of fire-derived PyOM in soil, the main processes leading to PyOM-C and nitrogen (N) losses from the soil, and the role of N availability on PyOM cycling in soils. We measured PyOM and native soil organic carbon losses from the soil as carbon dioxide and dissolved organic carbon (DOC) using additions of highly 13C-labelled PyOM (2.03 atom %) and its precursor pinewood during 1 year in a temperate forest soil. The field …

Speleothem And Biofilm Formation In A Granite/Dolerite Cave, Northern Sweden, Therese Sallstedt, Magnus Ivarsson, Johannes Lundberg, Rabbe Sjöberg, Juan Ramón Vidal Romaní

International Journal of Speleology

Tjuv-Antes grotta (Tjuv-Ante's Cave) located in northern Sweden is a round-abraded sea cave ('tunnel cave'), about 30 m in length, formed by rock-water abrasion in a dolerite dyke in granite gneiss. Abundant speleothems are restricted to the inner, mafic parts of the cave and absent on granite parts. The speleothems are of two types: cylindrical (coralloid, popcorn-like), and flowstone (thin crusts). Coralloids correspond to terrestrial stromatolite speleothems in which layers of light calcite alternate with dark, silica-rich laminae. The dark laminae are also enriched in carbon and contain incorporated remains of microorganisms. Two types of microbial communities can be distinguished …

Investigation Of The Flow And Fate Of Nitrate In Epikarst At The Savoy Experimental Watershed, Northwest Arkansas, Jozef Laincz

Graduate Theses and Dissertations

Many karst aquifers are at high risk of nitrate contamination due to a combination of vulnerable geology characterized by thin soils and conduit flow, and excess inputs of nutrients from animal feeding operations. One zone that is present in many karst regions and could play an important role in nitrate attenuation due to properties such as increased residence time and matrix-water contact is the upper, weathered portion of karst, the epikarst. However, the understanding of this role is lacking, and the objective of this dissertation was to elucidate it. The fate of nitrate in the epikarst was traced along a …

Ice Caves On Extraterrestrial Bodies: What Are The Prospects For Speleogenesis And Detection?, Penelope J. Boston

The International Workshop on Ice Caves

Potential mechanisms for creating cavities in icy extraterrestrial bodies have been tentatively explored by several authors. On one hand we have examples of mechanisms that create caves in water ice here on Earth. In addition, there may be unique mechanisms on other Solar System objects that do not occur on Earth but might produce cavities, e.g. sublimation of comets upon perihelion passage. The methods of detecting such cavities depend upon the nature of the icy body in question, the potential for orbital or landed missions to visit those bodies in the future, and remote or landed methods for detecting the …

Characterization Of Rain And Stormwater Nitrogen Inputs To The Mississippi Sound: A Landscape Approach, Joshua Michael Allen

Master's Theses

Urbanization in coastal watersheds is becoming an increasingly important issue in the world. Increased impervious surface cover, a factor of urbanization, has drawn more attention to stormwater runoff as a source of contamination to receiving waters. In this study, nitrogen species from rain and stormwater were analyzed across three different landscape types along the Mississippi Sound (hardened, residential, and pristine), as well as from drainage pipes that flow directly into to the Mississippi Sound. Nitrogen stable isotopes were used to trace the stormwater nitrogen to the surface waters and biota within the Sound.

The objective of this study was to …

Integrating Microbial Physiology And Physio-Chemical Principles In Soils With The Microbial-Mineral Carbon Stabilization (Mimics) Model, William R. Wieder, A. Stuart Grandy, Cynthia M. Kallenbach, Gordon B. Bonan

Faculty Publications

A growing body of literature documents the pressing need to develop soil biogeochemistry models that more accurately reflect contemporary understanding of soil processes and better capture soil carbon (C) responses to environmental perturbations. Models that explicitly represent microbial activity offer inroads to improve representations of soil biogeochemical processes, but have yet to consider relationships between litter quality, functional differences in microbial physiology, and the physical protection of microbial byproducts in forming stable soil organic matter (SOM). To address these limitations, we introduce the MIcrobial-MIneral Carbon Stabilization (MIMICS) model, and evaluate it by comparing site-level soil C projections with observations from …

Land-Use Legacies Regulate Decomposition Dynamics Following Bioenergy Crop Conversion, Cynthia M. Kallenbach, A. Stuart Grandy

Faculty Publications

Land-use conversion into bioenergy crop production can alter litter decomposition processes tightly coupled to soil carbon and nutrient dynamics. Yet, litter decomposition has been poorly described in bioenergy production systems, especially following land-use conversion. Predicting decomposition dynamics in postconversion bioenergy production systems is challenging because of the combined influence of land-use legacies with current management and litter quality. To evaluate how land-use legacies interact with current bioenergy crop management to influence litter decomposition in different litter types, we conducted a landscape-scale litterbag decomposition experiment. We proposed land-use legacies regulate decomposition, but their effects are weakened under higher quality litter and …

Mass And Nutrient Loss In Decaying Hardwood Boles At Hubbard Brook, Chris E. Johnson

Civil and Environmental Engineering - All Scholarship

No abstract provided.

Organic Copper Binding Ligands And Thiol Compounds Produced By Bacteria And In The Elizabeth River, Virginia, Christina Louise Dryden

OES Theses and Dissertations

This dissertation presents work focusing on copper and organic copper binding ligands in laboratory cultures and the Elizabeth River, Virginia. Laboratory cultures of the marine bacterium Vibrio parahaemolyticus were used to demonstrate the influence of elevated copper concentrations on copper-complexing ligand and thiol production. Copper-complexing ligands similar in binding strength to the strongest natural ligands were detected in V. parahaemolyticus cultures (log K′_CuL = 11.8–13.2). A strong correlation (r² = 0.973) was found between total thiol and copper-complexing ligand concentrations at all copper concentrations examined.

A yearlong seasonal study was undertaken in a heavily polluted estuary to ascertain …

A Comprehensive Evaluation Of C25 Highly Branched Isoprenoid Alkenes Of Marine Diatoms As Proxies For Sea Ice Extent In The Arctic Ocean, Tetiana Muniak

OES Theses and Dissertations

Sea Ice extent is one of the major factors regulating carbon cycling and ecosystem function in the modern Arctic Ocean. It is an essential component of climate models and is crucial for the evaluation of various oceanographic processes that influence a particular region. Yet it is also one of the most difficult attributes of the ocean with respect to our ability for its accurate reconstruction from paleo records. The lack of the detailed records prior to satellite information has encouraged the development of new proxy records for the reconstruction of past

sea ice conditions. In recent years, a new monounsaturated …

Analysing The Spatio-Temporal Impacts Of The 2003 And 2010 Extreme Heatwaves On Plant Productivity In Europe, A. Bastos, C. M. Trigo, R. M. Trigo, Steven W. Running

Ecosystem and Conservation Sciences Faculty Publications

In the last decade, Europe has been stricken by two outstanding heatwaves, the 2003 event in western Europe and the 2010 episode over Russia. Both events were characterized by record-breaking temperatures and widespread socioeconomic impacts, including significant increments on human mortality, decreases in crop yields and in hydroelectric production. Previous works have shown that an extreme climatic event does not always imply an extreme response by ecosystems. This work attempts to assess how extreme was the vegetation response to the heatwaves during 2003 and 2010 in Europe, in order to quantify the impacts of the two events on carbon fluxes …

Changes In Tundra Plant And Soil Organic Geochemical Composition In Response To Long-Term Increased Winter Precipitation In N. Alaska, Olivia Miller

Open Access Theses

Tundra ecosystem soils store half of the global soil organic carbon (SOC) pool and have the potential to release large amounts of greenhouse gases, primarily CH₄ and CO₂. As climates warm and permafrost thaws, the emissions of these gases as organic matter decomposition rates increase may become increasingly important to the chemistry of the atmosphere. Increases in precipitation that accompany warming, may shift tundra vegetative composition from moss/graminoid- to shrub-dominated systems. These vegetation shifts may result in important feedback effects as altered plant and litter chemistry may affect SOC storage in soils. Questions investigated include: 1) How …

Implications Of Climate Change For Cyanobacteria Over The Western Florida Shelf In The Gulf Of Mexico, Ivy Mara Ozmon

OES Theses and Dissertations

Concentrations of atmospheric CO₂ are expected to double by year 2100 as a result of anthropogenic activities. Under elevated CO₂ conditions, cyanobacteria may reallocate energy from active accumulation and transport of dissolved inorganic carbon (C) required for photosynthesis to other growth processes. Stimulation of cyanobacterial production on the Western Florida Shelf in the Gulf of Mexico (GOM) could lead to improved nutritional status for the toxic, mixotrophic dinoflagellate Karenia brevis that utilizes newly fixed N₂ from co-occurring diazotrophic cyanobacteria and consumes unicellular cyanobacteria via grazing for growth. Culture studies performed by other researchers on the climate induced …

Carbon Sequestration In Tidal Salt Marshes And Mangrove Ecosystems, Carlos Eduardo Quintana-Alcantara

Master's Projects and Capstones

Wetlands are dynamic systems that provide support to vital environmental functions and services. Wetlands take part in the global carbon cycle by holding organic carbon in biomass, soils and sediments. In recent years, the wetland carbon sequestration capacity has been researched worldwide due to the increase of the concentrations of greenhouse gasses implicated in global warming and climate change. Although coastal wetlands release the greenhouse gasses carbon dioxide, methane and nitrous oxide, these ecosystems maintain high performance in offsetting significant amounts of atmospheric carbon. This paper investigated the carbon sequestration capacity of coastal wetland ecosystems summarizing the environmental conditions and …

Water Water Everywhere: Analyzing Long Island's Water Issues And Finding Solutions For A Sustainable Future, Anthony T. Becker

2014 Student Theses

Over three million people call Long Island their home. With access to beautiful landscapes, world-renowned beaches, and proximity to New York City, it is no wonder that so many proudly call this geographic stretch of glacial till their home. However, throughout the years our actions do not necessarily reflect this affection we have to our home. Years of sprawl and human infestation across the island have resulted in widespread environmental degradation. Specifically, the water we drink and the beaches we enjoy have become endangered. I plan on studying the urban ecology of how intensified population growth led to the eutrophication …

Searching For Biogeochemical Hot Spots In Three Dimensions: Soil C And N Cycling In Hydropedologic Settings In A Northern Hardwood Forest, Jennifer L. Morse, S F. Werner, Cody P. Gillin, Christine L. Goodale, Scott W. Bailey, Kevin J. Mcguire, Peter M. Groffman

Environmental Science and Management Faculty Publications and Presentations

Understanding and predicting the extent, location, and function of biogeochemical hot spots at the watershed scale is a frontier in environmental science. We applied a hydropedologic approach to identify (1) biogeochemical differences among morphologically distinct hydropedologic settings and (2) hot spots of microbial carbon (C) and nitrogen (N) cycling activity in a northern hardwood forest in Hubbard Brook Experimental Forest, New Hampshire, USA. We assessed variables related to C and N cycling in spodic hydropedologic settings (typical podzols, bimodal podzols, and Bh podzols) and groundwater seeps during August 2010. We found that soil horizons (Oi/Oe, Oa/A, and B) differed significantly …

Estimating Nitrogen Fixation Rates, Importance, And Short-Term Efficiency In Small, Temperate Reservoirs Using Delta15n Techniques, Bryant Christopher Baker

Graduate Theses and Dissertations

Nitrogen (N2) fixation can give certain species of cyanobacteria a competitive advantage in lake and reservoir phytoplankton. These species of cyanobacteria, along with others that cannot fix N2, can form toxic compounds that impair water quality when present in high concentrations. N2 fixation rates may be substantial in small (< 1.0 km2), temperate reservoirs since these systems experience thermal stratification and often nitrogen (N) limitation throughout a substantial proportion of the year. However, the effects of N2 fixation on N cycling, alleviation of short-term N limitation, and water quality are not well-understood. A mesocosm experiment and ecosystem-scale observational study were conducted to 1) determine the efficiency of N2 fixation under varying N relative to phosphorus (P) supply, 2) examine the effects of N2 fixation on autotrophic biomass accumulation and microcystin production, and 3) measure N2 fixation rates and importance to autotrophic N demand and zooplankton N assimilation. Results of the mesocosm experiment indicated that N2 fixation was increased at low N:P supply under high P. However, N2 fixation was inefficient at alleviating N limitation when fixed N was the primary source of N. Additionally, microcystin production occurred only at high N:P supply when N2 fixation was low, indicating that reducing external N inputs may have a positive effect on water quality. Results of whole-reservoir determination of N2 fixation using seston δ15N natural abundances indicated that N2 fixation rates throughout the warm season were substantial and influenced by water temperature. Annual N2 fixation rates ranged from 2.2 - 6.6 g N m-2 yr-1, and contributed up to 19% of the annual autotrophic N demand. Zooplankton were assimilating fixed N in most of the study reservoirs, representing a possible mechanism of ecosystem fixed N retention. Collectively, these results suggest that N2 fixation plays a substantial role in N cycling in small, temperate reservoirs, but likely cannot alleviate short-term N limitation.

Methane Emissions And Ammonia Volatilization From Drill-Seeded, Delayed-Flood Rice On A Silt-Loam Soil In Arkansas, Christopher Wade Rogers

Graduate Theses and Dissertations

The Environmental Protection Agency (EPA) currently uses a single methane (CH4) emissions factor of 160 kg CH4-C ha-1 for a primary rice (Oryza sativa L.) crop. The emissions factor is based on studies that do not adequately represent current management practices in Arkansas. Another concern is pre-flood fertilizer nitrogen (N) management, as the common N source, urea, is prone to loss via ammonia (NH3) volatilization. Thus, the objective of this research was to investigate trace gas emissions from rice on a silt-loam soil, including CH4 emissions as influenced by nitrogen (N) fertilization (i.e., optimal N and no N) in 2011, …