Atmospheric Sciences Commons^™

Validation Of Stratospheric And Mesospheric Ozone Observed By Smiles From International Space Station, Y. Kasai, H. Sagawa, D. Kreyling, E. Dupuy, P. Baron, J. Mendrok, K Suzuki, T. O. Sato, T. Nishibori, S. Mizobuchi, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

We observed ozone O₃ in the vertical region between 250 and 0.0005 hPa (~ 12-96 km) using the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on the Japanese Experiment Module (JEM) of the International Space Station (ISS) between 12 October 2009 and 21 April 2010. The new 4K superconducting heterodyne receiver technology of SMILES allowed us to obtain a one order of magnitude better signal-to-noise ratio for the O₃ line observation compared to past spaceborne microwave instruments. The non-sun-synchronous orbit of the ISS allowed us to observe O₃ at various local times. We assessed the quality of the vertical …

The Relation Between Atmospheric Humidity And Temperature Trends For Stratospheric Water, S. Fueglistaler, Y. S. Liu, T. J. Flannaghan, P. H. Haynes, D. P. Dee, W. J. Read, E. E. Remsberg, L. W. Thomason, D. F. Hurst, J. R. Lanzante, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

We analyze the relation between atmospheric temperature and water vapor-a fundamental component of the global climate system-for stratospheric water vapor (SWV). We compare measurements of SWV (and methane where available) over the period 1980-2011 from NOAA balloon-borne frostpoint hygrometer (NOAA-FPH), SAGE II, Halogen Occultation Experiment (HALOE), Microwave Limb Sounder (MLS)/Aura, and Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) to model predictions based on troposphere-to-stratosphere transport from ERA-Interim, and temperatures from ERA-Interim, Modern Era Retrospective- Analysis (MERRA), Climate Forecast System Reanalysis (CFSR), Radiosonde Atmospheric Temperature Products for Assessing Climate (RATPAC), HadAT2, and RICHv1.5. All model predictions are dry biased. The interannual …

Hydrocarbons In The Upper Troposphere And Lower Stratosphere Observed From Ace-Fts And Comparisons With Waccm, Mijeong Park, William J. Randel, Douglas E. Kinnison, Louisa K. Emmons, Peter F. Bernath, Kaley A. Walker, Chris D. Boone, Nathaniel J. Livesey

Chemistry & Biochemistry Faculty Publications

Satellite measurements from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) are used to examine the global, seasonal variations of several hydrocarbons, including carbon monoxide (CO), ethane (C₂H₆), acetylene (C₂H₂), and hydrogen cyanide (HCN). We focus on quantifying large-scale seasonal behavior from the middle troposphere to the stratosphere, particularly in the tropics, and furthermore make detailed comparisons with the Whole Atmosphere Community Climate Model (WACCM) chemistry climate model (incorporating tropospheric photochemistry, time-varying hydrocarbon emissions, and meteorological fields nudged from reanalysis). Comparisons with Microwave Limb Sounder (MLS) measurements of CO are also included …

Water Vapor And The Equatorial Mesospheric Semi-Annual Oscillation (Msao), R. L. Gattinger, E. Kyröla, C. D. Boone, W. F. J. Evans, K. A. Walker, I. C. Mcdade, P. F. Bernath, E. J. Llewellyn

Chemistry & Biochemistry Faculty Publications

Observations of the mesospheric semi-annual oscillation (MSAO) in the equatorial region have been reported dating back several decades. Seasonal variations in both species densities and airglow emissions are well documented. The extensive observations available offer an excellent case study for comparison with model simulations. The broad range of measurements is summarised with emphasis on the 80 to 100 km region. Photochemical model simulations are described for near-equinox and near solstice conditions, the two lines with notable differences in the observed MSAO parameters. Diurnal tides are included in order to facilitate comparisons of observations made at different local times. The roles …

Modeling Visibility In The El Paso Del Norte (Pdn) Region, Richard Medina Calderon

Open Access Theses & Dissertations

Poor visibility is a subject of growing public concern throughout the U.S, and an active area of research. Its societal impacts on air quality, aviation transport and traffic are significant. Aerosols play a fundamental role in the attenuation of solar radiation, and also affect visibility. The scattering and extinction coefficients of aerosol particles in the Paso del Norte Region have been calculated using the T- matrix model in conjunction with a laser particle counter. Inter-comparison of the model's results of the scattering and absorption coefficients against the corresponding data from a Photoacustic extinctiometer instrument (which measures in-situ absorption and scattering …

Evaluation Of Emission Control Strategies To Reduce Ozone Pollution In The Paso Del Norte Region Using A Photochemical Air Quality Modeling System, Victor Hugo Valenzuela

Open Access Theses & Dissertations

Air pollution emissions control strategies to reduce ozone precursor pollutants are analyzed by applying a photochemical modeling system. Simulations of air quality conditions during an ozone episode which occurred in June, 2006 are undertaken by increasing or reducing area source emissions in Ciudad Juárez, Chihuahua, Mexico.

Two air pollutants are primary drivers in the formation of tropospheric ozone. Oxides of nitrogen (NOx) and volatile organic compounds (VOC) undergo multiple chemical reactions under favorable meteorological conditions to form ozone, which is a secondary pollutant that irritates respiratory systems in sensitive individuals especially the elderly and young children.

The U.S. Environmental Protection …

Implementation And Model To Model Intercomparison Of 12 Heat Stress Metrics, Jonathan Robert Buzan

Open Access Theses

Earth system models simulate the dynamics of the most complex systems on our planet with some success. Despite the overwhelming sophistication of these models, which include dynamical interactions of ocean, atmosphere, vegetation, ice, and land-surface properties, they fail to include the most important element. People. Humans are also a complex physical-biological system and coupling of human physiology within an Earth Systems Modeling framework is challenging. This thesis presents results that tackle one particular component of human physiological climate interaction--a representation of heat stress on human physiology. Twelve different metrics were implemented and analyzed. These metrics represent a variety of philosophical …

Chemical Consequences Of Chicxulub Impact Ejecta Reentry, Devon Donald Parkos

Open Access Theses

The Chicxulub impact 66.0 million years ago initiated the second biggest extinction in the Phanerozoic Eon. The global reentry of material ejected by the impact generated a strong pulse of thermal radiation that wiped out much of the terrestrial biota. The cause of the marine extinction, however, has remained elusive. This report shows that reentering ejecta produces enough NOx to acidify the upper ocean and cause a massive marine extinction. Using non-equilibrium chemically reacting flow simulations coupled with atmospheric transport modeling, it is determined that enough NOx reached the stratosphere and precipitated to overpower the carbonate buffer and acidify the …

Annual Patterns Of Atmospheric Pollutions And Episodes Over Cairo Egypt, Y. Aboel Fetouh, Hesham El-Askary, Mohamed El Raey, Mohamed Allali, W. A. Sprigg, Menas Kafatos

Mathematics, Physics, and Computer Science Faculty Articles and Research

The Nile Delta major cities, particularly Cairo, experienced stagnant air pollution episodes, known as Black Cloud, every year over the past decade during autumn. Low-elevated thermal inversion layers play a crucial role in intensifying pollution impacts. Carbon monoxide, ozone, atmospheric temperature, water vapor, and methane measurements from the tropospheric emission spectrometer (TES) on board the Aura have been used to assess the dominant component below the inversion layer. In this study, time series analysis, autocorrelations, and cross correlations are performed to gain a better understanding of the connections between those parameters and their local effect. Satellite-based data were obtained for …

Analyzing Experimental Data And Model Parameters: Implications For Predictions Of Soa Using Chemical Transport Models, Kelley Barsanti, Annmarie G. Carlton, Serena H. Chung

Civil and Environmental Engineering Faculty Publications and Presentations

Despite critical importance for air quality and climate predictions, accurate representation of secondary organic aerosol (SOA) formation remains elusive. An essential addition to the ongoing discussion of improving model predictions is an acknowledgement of the linkages between experimental conditions, parameter optimization and model output, as well as the linkage between empirically-derived partitioning parameters and the physicochemical properties of SOA they represent in models. In this work, a "best available" set of SOA modeling parameters is selected by comparing predicted SOA yields and mass concentrations with observed yields and mass concentrations from a comprehensive list of published smog chamber studies. Evaluated …

Turbulent Collision-Coalescence In Maritime Shallow Convection, A. A. Wyszogrodzki, W.W. Grabowski, L. P. Wang, Orlando Ayala

Engineering Technology Faculty Publications

This paper discusses cloud simulations aiming at quantitative assessment of the effects of cloud turbulence on rain development in shallow ice-free convective clouds. Cloud fields from large-eddy simulations (LES) applying bin microphysics with the collection kernel enhanced by cloud turbulence are compared to those with the standard gravitational collection kernel. Simulations for a range of cloud condensation nuclei (CCN) concentrations are contrasted. Details on how the parameterized turbulent collection kernel is used in LES simulations are presented. Because of the disparity in spatial scales between the bottom-up numerical studies guiding the turbulent kernel development and the top-down LES simulations of …

Terpene And Terpenoid Emissions And Secondary Organic Aerosol Production, Rosa M. Flores

Dissertations, Master's Theses and Master's Reports - Open

Approximately 90% of fine aerosol in the Midwestern United States has a regional component with a sizable fraction attributed to secondary production of organic aerosol (SOA). The Ozark Forest is an important source of biogenic SOA precursors like isoprene (> 150 mg m^-2 d^-1), monoterpenes (10-40 mg m^-2 d^-1), and sesquiterpenes (10-40 mg m^-2d^-1). Anthropogenic sources include secondary sulfate and nitrate and biomass burning (51-60%), vehicle emissions (17-26%), and industrial emissions (16-18%). Vehicle emissions are an important source of volatile and vapor-phase, semivolatile aliphatic and aromatic hydrocarbons that are important …

Investigations Of Cloud Microphysical Response To Mixing Using Digital Holography, Matthew Jacob Beals

Dissertations, Master's Theses and Master's Reports - Open

Cloud edge mixing plays an important role in the life cycle and development of clouds. Entrainment of subsaturated air affects the cloud at the microscale, altering the number density and size distribution of its droplets. The resulting effect is determined by two timescales: the time required for the mixing event to complete, and the time required for the droplets to adjust to their new environment. If mixing is rapid, evaporation of droplets is uniform and said to be homogeneous in nature. In contrast, slow mixing (compared to the adjustment timescale) results in the droplets adjusting to the transient state of …

Metr 200: Weather And Climate—A Peer Review Of Teaching Project Benchmark Portfolio, Matthew S. Van Den Broeke

UNL Faculty Course Portfolios

This benchmark portfolio is meant to be an assessment of how well the objectives of METR 200 (Weather and Climate) are being attained by students in several classifications of academic major. Students from a wide range of backgrounds enroll in this course as a general science elective, and for many, it will be the only science course taken in college. Thus, it is important that course material be sufficiently accessible for all students, while providing meaningful information which will be applicable by students of all backgrounds once they leave the course. In this portfolio, an analysis will be presented showing …

Metr 323: Physical Meteorology—A Peer Review Of Teaching Project Benchmark Portfolio, Jun Wang

UNL Faculty Course Portfolios

Hands-on out-door activities are added into a course that is designed to teach students atmospheric physics ranging form solar light transfer to cloud and precipitation formation in the atmosphere. Statistical analysis and anonymous survey are conducted to benchmark the improvement in students' learning. Results show that these hands-on activities increase the student's interest and understanding in the course materials, and also improve the overall students' satisfaction for the course.

Uncertainties In Modelling Heterogeneous Chemistry And Arctic Ozone Depletion In The Winter 2009/2010, I. Wohltmann, T. Wegner, R. Müller, R. Lehmann, M. Rex, G. L. Manney, M. L. Santee, P. Bernath, O. Suminska-Ebersoldt

Chemistry & Biochemistry Faculty Publications

Stratospheric chemistry and denitrification are simulated for the Arctic winter 2009/2010 with the Lagrangian Chemistry and Transport Model ATLAS. A number of sensitivity runs is used to explore the impact of uncertainties in chlorine activation and denitrification on the model results. In particular, the efficiency of chlorine activation on different types of liquid aerosol versus activation on nitric acid trihydrate clouds is examined. Additionally, the impact of changes in reaction rate coefficients, in the particle number density of polar stratospheric clouds, in supersaturation, temperature or the extent of denitrification is investigated. Results are compared to satellite measurements of MLS and …

Cave Ventilation Is Influenced By Variations In The Co2-Dependent Virtual Temperature, Enrique P. Sánchez-Cañete, Penélope Serrano-Ortiz, Francisco Domingo, Andrew S. Kowalski

International Journal of Speleology

Dynamics and drivers of ventilation in caves are of growing interest for different fields of science. Accumulated CO₂ in caves can be exchanged with the atmosphere, modifying the internal CO₂ content, affecting stalagmite growth rates, deteriorating rupestrian paintings or creating new minerals. Current estimates of cave ventilation neglect the role of high CO₂ concentrations in determining air density – approximated via the virtual temperature (T_v) –, affecting buoyancy and therefore the release or storage of CO₂. Here we try to improve knowledge and understanding of cave ventilation through the use of T …

Spatial And Temporal Trends Of Snowfall In Central New York - A Lake Effect Dominated Region, Justin Joseph Hartnett

USF Tampa Graduate Theses and Dissertations

Central New York is located in one of the snowiest regions in the United States, with the city of Syracuse, New York the snowiest metropolis in the nation. Snowfall in the region generally begins in mid-November and lasts until late-March. Snow accumulation occurs from a multitude of conditions: frontal systems, mid-latitude cyclones, Nor'easters, and most notably lake-effect storms. Lake effect snowfall (LES) is a difficult parameter to forecast due to the isolated and highly variable nature of the storm. Consequently, studies have attempted to determine changes in snowfall for lake-effect dominated regions. Annual snowfall patterns are of particular concern as …

A Modeling Investigation Of Human Exposure To Select Traffic-Related Air Pollutants In The Tampa Area: Spatiotemporal Distributions Of Concentrations, Social Distributions Of Exposures, And Impacts Of Urban Design On Both, Haofei Yu

USF Tampa Graduate Theses and Dissertations

Increasing vehicle dependence in the United States has resulted in substantial emissions of traffic-related air pollutants that contribute to the deterioration of urban air quality. Exposure to urban air pollutants trigger a number of public health concerns, including the potential of inequality of exposures and health effects among population subgroups. To better understand the impact of traffic-related pollutants on air quality, exposure, and exposure inequality, modeling methods that can appropriately characterize the spatiotemporally resolved concentration distributions of traffic-related pollutants need to be improved. These modeling methods can then be used to investigate the impacts of urban design and transportation management …

Multi-Instrument Comparisons Of D-Region Plasma Measurements, M. Friedrich, K. M. Torkar, U. P. Hoppe, T. A. Bekkeng, A. Barjatya, M. Rapp

Publications

The ECOMA (Existence and Charge state Of Meteoric dust grains in the middle Atmosphere) series of sounding rocket flights consisted of nine flights with almost identical payload design and flight characteristics. All flights carried a radio wave propagation experiment together with a variety of plasma probes. Three of these measured electron densities, two ion densities. The rockets were all launched from the Andøya Rocket Range, Norway, in four campaigns between 2006 and 2010. Emphasis is on the final three flights from 2010 where the payloads were equipped with four instruments capable of measuring plasma densities in situ, among them a …

Elevated Electron Temperatures Around Twin Sporadic E Layers At Low Latitude: Observations And The Case For A Plausible Link To Currents Parallel To The Geomagnetic Field, A. Barjatya, J. P. St. Maurice, C. M. Swenson

Publications

We present data from nighttime sounding rocket flights in the low latitude E region. The payloads carried a sweeping Langmuir probe, a plasma impedance probe, and electric field probes. A detailed examination of the plasma density, temperature, and electric field measurements show two strong sporadic E (Es) layers with very high electron temperatures (∼1000 K) on each side of the upper layer. The lower layer was consistent with the presence of a strong zonal neutral wind shear. The upper layer was strongly influenced by the presence of a strongly negative vertical electric field, with zonal winds and …

First Temperature Observations With The Usu Very Large Rayleigh Lidar: An Examination Of Mesopause Temperatures, Leda Sox, Vincent B. Wickwar, Joshua P. Herron, Marcus J. Bingham, Lance W. Petersen, Matthew T. Emerick

Posters

As the impetus for extended observational measurements throughout the middle atmosphere has increased1 , the limits of previous instrumentation need to be pushed. The Rayleigh lidar group at the Atmospheric Lidar Observatory (ALO) at Utah State University has pushed such limits on existing Rayleigh scatter lidar technology and, through major upgrades to the previous lidar system, has been able to gather temperature measurements in the upper mesosphere and lower thermosphere from approximately 70P109 km. A data campaign with the new system was conducted around the annual temperature minimum, centered on late June 2012, in this region. The temperatures from this …

Multiple Peaks In Saber Mesospheric Oh Emission Altitude Profiles, Jordan Rozum, Gene A. Ware, Doran J. Baker, Martin G. Wlynczak, James M. Russell

Browse All Undergraduate research

No abstract provided.

Identification And Classification Of Stratospheric Sudden Warming Events, Thomas S. Ehrmann

Doctoral Dissertations and Master's Theses

Analysis of northern hemisphere stratospheric data from 1978-2011 is used to identify and classify Stratospheric Sudden Warming events. A total of 41 events are identified during this 33 year period, resulting in an average occurrence rate of 1.24 events/year. No significant variation in the rate is observed during the period analyzed. The average temperature increase during an SSW event is 12 K and the average duration is 32 days. Each identified event is classified as either a vortex displacement or split event and the ratio of displacement to split events is found to be 0.86.

2000 Year Moisture Source Record From A Central Nevada Speleothem, Paul Pribyl

UNLV Theses, Dissertations, Professional Papers, and Capstones

The goal of this study was to determine the moisture source of winter precipitation in the central Great Basin for the past 2000 years, and to elucidate the role of Pacific Ocean and North American climate variability modes in driving observed droughts of the region around the Medieval Climatic Anomaly (MCA, ~900-1300 CE). Here a high resolution (~2-4 year) precisely dated moisture source reconstruction is presented from the δ18O values of speleothem LC-1 collected from Leviathan Cave in central Nevada, which reveals significant δ18O variability. I attribute the δ18O variability to changes in winter-season moisture circulation over the past 2000 …

An Intense Traveling Airglow Front In The Upper Mesosphere–Lower Thermosphere With Characteristics Of A Bore Observed Over Alice Springs, Australia, During A Strong 2 Day Wave Episode, R. L. Walterscheid, J. H. Hecht, L. J. Galinas, Michael P. Hickey Ph.D., I. M. Reid

Publications

The Aerospace Corporation’s Nightglow Imager observed a large step function change in airglow in the form of a traveling front in the OH Meinel (OHM) and O2 atmospheric (O2A) airglow emissions over Alice Springs, Australia, on 2 February 2003. The front exhibited nearly a factor of 2 stepwise increase in the OHM brightness and a stepwise decrease in the O2A brightness. There was significant (~25 K) cooling behind the airglow fronts. The OHM airglow brightness behind the front was among the brightest for Alice Springs that we have measured in 7 years of observations. The event was associated with a …

Climate Change Up Close And Personal: Impacts On Hampton Roads Region, Russell De Young

November 16, 2012: Best Practices for Adapting to Sea Level Rise and Flooding

No abstract provided.

Overview Of The 2007 And 2008 Campaigns Conducted As Part Of The Greenland Summit Halogen-HoX Experiment (Gshox), J L. Thomas, Jack E. Dibb, J Stutz, R Von Glasow, Steve Brooks, L Gregory Huey, Barry Lefer

Earth Sciences

From 10 May through 17 June 2007 and 6 June through 9 July 2008 intensive sampling campaigns at Summit, Greenland confirmed that active bromine chemistry is occurring in and above the snow pack at the highest part of the Greenland ice sheet (72°36´ N, 38°25´ W and 3.2 km above sea level). Direct measurements found BrO and soluble gas phase Br⁻ mixing ratios in the low pptv range on many days (maxima < 10 pptv). Conversion of up to 200 pg m⁻³ of gaseous elemental mercury (GEM) to reactive gaseous mercury (RGM) and enhanced OH relative to HO₂ plus RO₂ confirm that active bromine chemistry is …

Spectral Absorption Of Biomass Burning Aerosol Determined From Retrieved Single Scattering Albedo During Arctas, C A. Corr, S R. Hall, B E. Anderson, Kirk Ullman, A J. Beyersdorf, Kenn L. Thornhill, Michael J. Cubison, Jose L. Jimenez, Armin Wisthaler, Jack E. Dibb

Earth Sciences

Actinic flux, as well as aerosol chemical and optical properties, were measured aboard the NASA DC-8 aircraft during the ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites) mission in Spring and Summer 2008. These measurements were used in a radiative transfer code to retrieve spectral (350-550 nm) aerosol single scattering albedo (SSA) for biomass burning plumes encountered on 17 April and 29 June. Retrieved SSA values were subsequently used to calculate the absorption Angstrom exponent (AAE) over the 350-500 nm range. Both plumes exhibited enhanced spectral absorption with AAE values that exceeded 1 (6.78 ± …

An Analysis Of Deep Convection Initiation Environments, Noah Lock

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Initiation is the part of the convective life cycle which is currently least understood and least well forecast. The inability to properly forecast the timing and/or location of deep convection initiation degrades forecast skill, especially during the warm season. The goals of this research are examine the spatiotemporal distribution of thunderstorm initiation points and to determine which atmospheric parameters (and ultimately processes) are most important for the initiation of thunderstorms. The spatiotemporal distribution of thunderstorm initiation points shows the expected peaks during summer and during the afternoon. The warm season also produces significant concentrations of initiation points near mountains, mainly …