Atmospheric Sciences Commons^™

The Effects Of Downdraft And Radial Ventilation In Hurricanes Earl (2010) And Edouard (2014), Jacob Vile

Electronic Theses & Dissertations (2024 - present)

Tropical cyclone (TC) intensity change in moderate vertical wind shear (VWS) is difficult to predict. Specifically, ventilation, the intrusion of dry and/or cool (i.e., low equivalent potential temperature (theta-e) air inside the TC, can have differing effects on TCs. Downdraft ventilation is the downward transport of below-mean  theta-e air by downdrafts, and radial ventilation is the inward transport of below-mean theta-e air by storm-relative radial winds. If this low theta-e air is able to get ingested by updrafts, it can result in a reduction of convection in the TC, thereby reducing intensity. Although most studies of ventilation have been conducted …

Twenty-One Years Of Global Atmospheric Chlorine Inventories From Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Measurements, N. Raymond, P. Bernath, C. Boone, M. P. Chipperfield

Chemistry & Biochemistry Faculty Publications

We present atmospheric chlorine inventories over 21 years (2004-2024) and five latitude bands (82-60°N, 60-30°N, 30°N-30°S, 30-60°S, 60-82°S) across altitudes from the surface up to 61 km. These inventories were calculated using the Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS) version 5.3 retrievals of the volume mixing ratios (VMRs) of 13 chlorine-containing species. Of these, five are product gases: HCl, HOCl, ClONO₂, COClF, COCl₂, and eight are source gases: CCl₄, CH₃Cl, CFC-11 (CCl₃F), CFC-12 ( CCl₂F₂), CFC-113 (CClF₂CCl₂F}), HCFC-22 (CHF₂Cl), HCFC-141b ( C₂H₃Cl₂F), and HCFC-142b (C₂H₃}Cl₂F). Where necessary, ACE-FTS data were supplemented with data from the TOMCAT 3-D chemical transport model, …

Twenty Years Of Global Stratospheric Fluorine Inventories From Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Measurements, N. Raymond, P. Bernath, C. Boone, M. Chipperfield

Chemistry & Biochemistry Faculty Publications

We present fluorine inventories calculated for twenty years (2004–2023) and five latitude bands (82°–60°N, 60°–30°N, 30°N–30°S, 30°–60°S, and 60°–82°S) at altitudes from the surface up to 55 km. The inventories were calculated using the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE‐FTS) version 5.2 retrievals of the volume mixing ratios (VMRs) of 15 fluorine‐containing species. Of these 15 species, 3 are product gases: HF, COF₂, COCIF, and 12 are source gases: SF₆, PFC-14 (CF₄), CFC-11 (CCl₃F), CFC-12 (CCl₂F₂), CFC-113 (CCIF₂CCl₂F), HCFC-22 (CHF₂CL), HCFC-141b(C₂H₃Cl₂F), HCFC-142b ( …

Trends In Atmospheric Composition Between 2004-2023 Using Version 5 Ace-Fts Data, Matthew Schmidt, Peter Bernath, Chris Boone, Michael Lecours, Johnathan Steffen

Chemistry & Biochemistry Faculty Publications

The Atmospheric Chemistry Experiment (ACE) is a satellite mission that has been in orbit since 2003. The primary instrument on ACE is a Fourier transform spectrometer (FTS) that records infrared atmospheric transmittance spectra in the limb geometry using the Sun as a light source. Version 5 of ACE-FTS data processing contains improved volume mixing ratio (VMR) profiles for 46 molecules and 24 isotopologues, including HFC-32 (CH₂F₂) and HOCl as new routine data products. VMR trends for each of the 46 molecules are reported for regions of atmospheric interest. Specifically, the longevity of the ACE mission has …

Understanding The Relationship Between Urban Areas And The Boundary Layer Using Remote Sensing Methods, Gabriel A. Rios

Dissertations and Theses

The atmospheric boundary layer is crucial to the exchange in energy between the Earth's surface and the atmosphere. Within this layer, the majority of human activities are carried out, which makes understanding the boundary layer especially important for many of our interests. A key component of this energy exchange is found at the surface, was surface properties are the interface through which momentum, heat, moisture, and other fluxes are transferred between media. Not only does the surface act as an interface, but as an actor that influences the exchange efficiency and rates. This concept is the crux of atmospheric boundary …

Toward Closing The Urban Surface Energy Balance Using Satellite Remote Sensing, Joshua Hrisko

Dissertations and Theses

The energy exchanges at the Earth’s surface are responsible for many of the processes that govern weather, climate, human health, and energy use. This exchange, commonly known as the surface energy balance (SEB), determines the near-surface thermodynamic state by partitioning the available energy into surface fluxes. The net all-wave radiation is often the primary energy source, while the heat storage and sensible and latent heat fluxes account for the majority of energy distributed elsewhere. While the SEB of various natural environments(trees, crops, soils) has been well-observed and modeled, the urban surface energy balance remains elusive. This is due to the …

Stratospheric Ozone And Hcl Trends (2000-2016): How Significant Is Recent Growth In Chlorinated Very Short-Lived Substances, Ryan Hossaini, Martyn Chipperfield, Peter Bernath, Anton Fernando, Sandip Dhomse, Wuhu Feng

Chemistry & Biochemistry Faculty Publications

[Introduction] Chlorinated very short-lived substances (VSLS), such as dichloromethane (CH₂CL₂), chloroform (CHCl₃₎ and perchloroethylene (C₂Cl₄) constitute a small, but growing source of stratospheric chlorine (e.g. WMO, 2014). High-altitude aircraft observations provide some constraint on the stratospheric source gas injection of chlorine from these compounds, though product gas injection - from VSLS-derived phosgene and HCl produced in the troposphere - is uncertain. Furthermore, in addition to an overall paucity of atmospheric VSLS observations, the impact of VSLS growth on stratospheric composition trends in the recent past (e.g. ozone, HCl) remains poorly constrained.

Observations Of Greenhouse Gas Isotopologues With Ace-Fts And Waccm, Eric Michael Buzan

Chemistry & Biochemistry Theses & Dissertations

Increases in greenhouse gas concentrations in the atmosphere are the major driver of climate change. Quantifying the sources and sinks of these gases is a major focus of research. Measuring isotopologues, or molecules that differ in isotopic composition, is one useful way of constraining the budget of a molecule as they are highly sensitive to different sources and sinks. However, measurements above the surface have been restricted to a few locations and have only reached the lower stratosphere. Satellite-based remote sensing can achieve nearly global measurement coverage, but so far no satellites have measured isotopologues.

Presented here are measurements of …

Modeling Gross Primary Production Of Midwest Maize And Soybean Croplands With Satellite And Gridded Weather Data, Gunnar Malek-Madani

Department of Geography: Dissertations, Theses, and Student Research

The gross primary production (GPP) metric is useful in determining trends in the terrestrial carbon cycle. Models that determine GPP utilizing the light use efficiency (LUE) approach in conjunction with biophysical parameters that account for local weather conditions and crop specific factors are beneficial in that they combine the accuracy of the biophysical model with the versatility of the LUE model. One such model developed using in situ data was adapted to operate with remote sensing derived leaf area index (LAI) data and gridded weather datasets. The model, known as the Light Use Efficiency GPP Model (EGM), uses a four …

Measuring Landfill Methane Emissions Using Satellite And Ground Data, Madjid Delkash, Bowen Zhou, Ramesh P. Singh

Mathematics, Physics, and Computer Science Faculty Articles and Research

Landfill methane emissions (LME) vary in short periods depending upon the meteorological and atmospheric conditions. In this paper, coupling the Atmospheric InfraRed Sounder (AIRS) with the tracer dilution method (TDM) is proposed during unmeasured emission days to have a better annual estimation of the LME. Some assumptions were made to develop this proposed model. The atmospheric model Advanced Regional Prediction System (ARPS) was employed to evaluate assumptions made during emission estimation using the proposed technique. Methane emissions of a landfill for 13 days during 2011–2013 were measured by the TDM and filtered to remove unreliable data. Then, the filtered data …

Modeling And Satellite Remote Sensing Of The Meteorological Impacts Of Irrigation During The 2012 Central Plains Drought, Clint Aegerter

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

As irrigation is increasingly needed for agricultural production, it is becoming progressively more important to understand not only how irrigation impacts water availability, but how the introduction of this water into the soil impacts weather and climate through land-atmosphere interactions. In the summer of 2012, the Central Plains of the United States experienced one of its most severe droughts on record. This study examines the meteorological impacts of irrigation during this drought through observations and model simulations using the Community Land Model (CLM) coupled to the Weather Research and Forecasting (WRF) model. A simple parameterization of irrigation processes is added …

The Use Of Remote Sensing Technologies And Models To Study Pollutants In Pdn Region, Suhail Mahmud

Open Access Theses & Dissertations

Using a suite of modeling techniques and instrumentation we study the atmospheric pollutants in the PdN Region. The first objective of this work was to measure hemi-spherically integrated, spectrally resolved solar photon flux (actinic flux) between the wavelengths 300 and 700 nm, and use the measured actinic flux to improve air quality simulations. Actinic flux was measured in the PdN region in order to calculate photolysis rate coefficients for different pollutants. The improved photolysis rate coefficients were then integrated into a photochemical air quality model (CAMx) in order to improve air quality forecasting. We present the simulations performed for a …

The Tropical Cyclone Diurnal Cycle, Jason Paul Dunion

Legacy Theses & Dissertations (2009 - 2024)

The research presented in this thesis explores a phenomenon referred to as the tropical cyclone (TC) diurnal cycle (TCDC) and presents satellite, numerical modeling, and observational perspectives pertaining to how it can be monitored, its evolution in time and space, its relevance to TC structure and intensity, and how it manifests in numerical simulations of TCs. Infrared satellite imagery was developed and used to investigate diurnal oscillations in TCs and finds a diurnal pulsing pattern that occurs with notable regularity through a relatively deep layer from the inner core to the surrounding environment. A combination of satellite, numerical model simulations, …

Global Stratospheric Measurements Of The Isotopologues Of Methane From The Atmospheric Chemistry Experiment Fourier Transform Spectrometer, Eric M. Buzan, Chris A. Beale, Chris. D. Boone, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

This paper presents an analysis of observations of methane and its two major isotopologues, CH₃D and ¹³CH₄, from the Atmospheric Chemistry Experiment (ACE) satellite between 2004 and 2013. Additionally, atmospheric methane chemistry is modeled using the Whole Atmospheric Community Climate Model (WACCM). ACE retrievals of methane extend from 6 km for all isotopologues to 75 km for ¹²CH₄, 35 km for CH₃D, and 50 km for ¹³CH₄. While total methane concentrations retrieved from ACE agree well with the model, values of δD-CH₄ and δ¹³C-CH …

Retrieval And Validation Of Carbon Dioxide, Methane, And Water Vapor For The Canary Islands Ir-Laser Occultation Experiment, V. Proschek, G. Kirchengast, S. Schweitzer, J.S. A. Brooke, P. F. Bernath, C. B. Thomas, J. G. Wang, K. A. Tereszchuk, G. González Abad, R. J. Hargreaves, C. A. Beale, J. J. Harrison, P. A. Martin, V. L. Kasyutich, C. Gerbig, O. Kolle, A. Loescher

Chemistry & Biochemistry Faculty Publications

The first ground-based experiment to prove the concept of a novel space-based observation technique for microwave and infrared-laser occultation between low-Earthorbit satellites was performed in the Canary Islands between La Palma and Tenerife. For two nights from 21 to 22 July 2011 the experiment delivered the infrared-laser differential transmission principle for the measurement of greenhouse gases (GHGs) in the free atmosphere. Such global and long-term stable measurements of GHGs, accompanied also by measurements of thermodynamic parameters and line-of-sight wind in a self-calibrating way, have become very important for climate change monitoring. The experiment delivered promising initial data for demonstrating the …

Assessment Of Water Vapor Isotopologue Measurements By Ace-Fts And Odin-Smr, Ralf Bauer, Patrick Sheese, Kaley Walker, Joachim Urban, Donal Murtagh, Chris Boone, Peter Bernath, Gloria Manney

Chemistry & Biochemistry Faculty Publications

[Introduction] Knowing the isotopic composition of trace gases can improve our understanding of processes in the Earth's atmosphere causing isotopic fractionation. In many studies, isotopologue (molecules of identical chemical but different isotopic composition) amounts are primarily discussed as δ values, which are defined relative to a standard, e.g.:

Ace-Fts And Haloe Observations Of Hydrogen Fluoride (Hf) And Their Comparison With Slimcat Chemical Transport Model Calculations, Jeremy Harrison, Martyn Chipperfield, Chris Boone, Peter Bernath, Lucien Froidevaux, John Anderson, James Russell Iii

Chemistry & Biochemistry Faculty Publications

The majority of fluorine in the atmosphere has resulted from the anthropogenic emission of chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), and hydrofluorocarbons (HFCs). Most tropospheric fluorine is present in its emitted 'organic' form due to the molecules having long lifetimes (up to a decade or longer). Thus they are able to reach the stratosphere where they are broken down, liberating fluorine. The principal degradation products are carbonyl fluoride (COF2), carbonyl chloride fluoride (COClF), and hydrogen fluoride (HF); of these HF is the most abundant. In fact at the top of the stratosphere most of the fluorine is present as HF, which, due …

Retrievals Of Carbonyl Fluoride (Cof₂) From Ace-Fts And Mipas Spectra And Their Comparison With Slimcat Ctm Calculations, Jeremy Harrison, Shaomin Cai, Anu Dudhia, Martyn Chipperfield, Chris Boone, Peter Bernath

Chemistry & Biochemistry Faculty Publications

The majority of fluorine in the atmosphere has resulted from the anthropogenic emission of chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), and hydrofluorocarbons (HFCs). Most tropospheric fluorine is present in its emitted 'organic' form due to the molecules having long lifetimes. At the top of the stratosphere most of the fluorine is present as the 'inorganic' product HF, which, due to its extreme stability, is an almost permanent reservoir of stratospheric fluorine. The second most abundant stratospheric 'inorganic' fluorine reservoir is carbonyl fluoride (COF₂). The major sources of COF₂ are from the atmospheric degradation of CFC-12 (CCl₂F₂), which is now banned under the …

Environmental Analysis Of Goes-R Proving Ground Convection Initiation Forecasting Algorithms, Jason M. Apke

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The enhanced temporal and spatial resolution of the GOES-R series will allow for the use of cloud top cooling based convection initiation (CI) forecasting algorithms. Two such algorithms have been created on the current generation of GOES satellites: theUniversityofWisconsincloud top cooling algorithm (UWCTC) and the University of Alabama-Huntsville’s satellite convection analysis and tracking algorithm (SATCAST). Preliminary analysis of algorithm products has led to speculation over pre-convective environmental effects on algorithm performance, which this study aims to examine. CI indications are used with objective segmentation tools to identify and cluster radar objects over theGreat Plainsbased on reflectivity quantitative and spatial thresholds. …

Retrieval Of Sub-Pixel-Based Fire Intensity And Its Application For Characterizing Smoke Injection Heights And Fire Weather In North America, David Peterson

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

For over two decades, satellite sensors have provided the locations of global fire activity with ever-increasing accuracy. However, the ability to measure fire intensity, know as fire radiative power (FRP), and its potential relationships to meteorology and smoke plume injection heights, are currently limited by the pixel resolution. This dissertation describes the development of a new, sub-pixel-based FRP calculation (FRP_f) for fire pixels detected by the MODerate Resolution Imaging Spectroradiometer (MODIS) fire detection algorithm (Collection 5), which is subsequently applied to several large wildfire events in North America. The methodology inherits an earlier bi-spectral algorithm for retrieving sub-pixel …

Accuracy Assessment Of Aqua-Modis Aerosol Optical Depth Over Coastal Regions: Importance Of Quality Flag And Sea Surface Wind Speed, Jacob Anderson

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Using data collected from 62 coastal stations worldwide from the Aerosol Robotic Network (AERONET) from 2002-2011, accuracy assessments are made for coastal aerosol optical depth (AOD) retrieved from MODIS aboard the Aqua satellite. It is found that coastal AODs (at 550 nm) characterized respectively by the MODIS Dark Land (Land) surface algorithm, the Open Ocean (Ocean) algorithm, and AERONET all exhibit a log-normal distribution. After filtering by quality flags, the coastal MODIS AODs retrieved from the Land and Ocean algorithms are highly correlated with AERONET (with R²≈0.8), but only the Land algorithm AODs fall within the expected error …

Effects Of Lightning And Other Meteorological Factors On Fire Activity In The North American Boreal Forest: Implications For Fire Weather Forecasting, David Peterson, Jun Wang, Charles Ichoku, Lorraine Remer

Department of Earth and Atmospheric Sciences: Faculty Publications

The effects of lightning and other meteorological factors on wildfire activity in the North American boreal forest are statistically analyzed during the fire seasons of 2000–2006 through an integration of the following data sets: the MODerate Resolution Imaging Spectroradiometer (MODIS) level 2 fire products, the 3-hourly 32-km gridded meteorological data from North American Regional Reanalysis (NARR), and the lightning data collected by the Canadian Lightning Detection Network (CLDN) and the Alaska Lightning Detection Network (ALDN). Positive anomalies of the 500 hPa geopotential height field, convective available potential energy (CAPE), number of cloud-to-ground lightning strikes, and the number of consecutive dry …

Impacts Of Meteorological Factors On Modis-Observed Fire Activity In The North American Boreal Forest: The Role Of Lightning, David A. Peterson

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The meteorological impact on wildfire activity in the North American boreal forest during the fire seasons of 2000 – 2006 is statistically analyzed through an integration of the following data sets: the MODerate Resolution Imaging Spectroradiometer (MODIS) level 2 fire products, the 3-hourly 32-km gridded meteorological data from North American Regional Reanalysis (NARR), the instantaneous lightning data collected by the Canadian Lightning Detection Network (CLDN), and the Alaska Lightning Detection Network (ALDN). Positive anomalies of the 500 hpa geopotential height field, convective available potential energy (CAPE), number of cloud-to-ground lightning strikes, and the number of consecutive dry days are found …

Analytic Forms Of Bidirectional Reflectance Functions For Application To Earth Radiation Budget Studies, N. Manalo-Smith, G. L. Smith, S. N. Tiwari, W. F. Staylor

Mechanical & Aerospace Engineering Faculty Publications

Analytic expressions for the bidirectional reflectance functions are formulated and fit to the Earth Radiation Budget Experiment (ERBE) operational models, which were developed using Nimbus 7 ERB data. The analytic bidirectional reflectance distribution functions (BRDFs) are based on theoretical considerations and are functions of viewing geometry and scene type. The models consist of a Rayleigh scattering term and a term for scattering due to clouds and surface. The darkness of the ocean permits the empirical determination of the Rayleigh component of scattering from the atmosphere. The models have the advantage that they are smooth in terms of view and solar …

Earth Observing System, Volume Iia: Data And Information System, Report Of The Eos Data Panel, Raymond Arvidson, Frederick Billingsley, Robert Chase, Pat Chavez Jr., Michael Devirian, Frederick Mosher, Et Al.

Publications

The purpose of this report is to provide NASA with a rationale and recommendations for planning, implementing, and operating an Earth Observing System data and information system that can evolve to meet the Earth Observing System's needs in the 1990s. The Earth Observing System (EOS), defined by the EOS Science and Mission Requirements Working Group, consists of a suite of instruments in low Earth orbit acquiring measurements of the Earth's atmosphere, surface, and interior; an information system to support scientific research; and a vigorous program of scientific research, stressing study of global-scale processes that shape and influence the Earth as …