Atmospheric Sciences Commons^™

Twenty-One Years Of Global Atmospheric Chlorine Inventories From Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Measurements, N. Raymond, P. Bernath, C. Boone, M. P. Chipperfield

Chemistry & Biochemistry Faculty Publications

We present atmospheric chlorine inventories over 21 years (2004-2024) and five latitude bands (82-60°N, 60-30°N, 30°N-30°S, 30-60°S, 60-82°S) across altitudes from the surface up to 61 km. These inventories were calculated using the Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS) version 5.3 retrievals of the volume mixing ratios (VMRs) of 13 chlorine-containing species. Of these, five are product gases: HCl, HOCl, ClONO₂, COClF, COCl₂, and eight are source gases: CCl₄, CH₃Cl, CFC-11 (CCl₃F), CFC-12 ( CCl₂F₂), CFC-113 (CClF₂CCl₂F}), HCFC-22 (CHF₂Cl), HCFC-141b ( C₂H₃Cl₂F), and HCFC-142b (C₂H₃}Cl₂F). Where necessary, ACE-FTS data were supplemented with data from the TOMCAT 3-D chemical transport model, …

Global Characterization Of Stratospheric Sulfate Aerosols By The Atmospheric Chemistry Experiment (Ace), Peter Bernath, Manish Bhusal, Michael Lecours, Chris Boone

Chemistry & Biochemistry Faculty Publications

Stratospheric sulfate aerosol (SSA) is an important part of the Earth's climate system. SSA climate impact is determined in part by particle composition, which has been measured from orbit. The weight percent of sulfuric acid in SSA has been determined from atmospheric infrared transmittance spectra recorded with the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) in limb geometry using the Sun as a light source (solar occultation). The global average SSA composition varies from about 50 to 80 percent with lowest values during the Antarctic winter. Atmospheric extinction at a wavelength of 1 μm was included in the analysis to …

Stratospheric Variability And Its Relationship To Cold Air Outbreaks In The United States, Paul T. Panhans

Electronic Theses & Dissertations (2024 - present)

Only since the early 2000s, has there been a growing body of work linking extreme winter temperature anomalies to the variability of the Northern Hemisphere stratospheric polar vortex (SPV). However, the understanding behind stratosphere-troposphere coupling and cold air outbreaks (CAOs) remain occasionally contradictory in the literature, making it difficult to properly articulate societal risks. Studies often focused on broad stratospheric influences, but this research directly compared stratospheric variability according to their respective tropospheric impacts. This dissertation filled a knowledge gap, as there has yet to be a comprehensive analysis to quantify the differences in stratospheric variability with and without CAOs …

High-Altitude Balloon-Launched Uncrewed Aircraft System Measurements Of Atmospheric Turbulence And Qualitative Comparison With Infrasound Microphone Response, Anisa Haghighi

Theses and Dissertations--Mechanical and Aerospace Engineering

This study explores the use of a balloon-launched uncrewed aircraft system (UAS) to measure atmospheric turbulence in the troposphere and lower stratosphere using both wind velocity measurements and infrasonic acoustic energy. The UAS, a glider configured for autonomous descent along a predefined trajectory, had on board, in situ sensors to capture thermodynamic and kinematic atmospheric parameters. Additionally, it carried an infrasonic microphone to evaluate its potential for remotely detecting clear-air turbulence by capturing infrasonic waves. The system’s performance was assessed over the course of three test flights conducted in New Mexico, USA, in 2021. The descent enabled high-resolution profiling, with …

Co₂ Isotopologues From The Ace Satellite, D. English, P. Bernath, C. Boone

Chemistry & Biochemistry Faculty Publications

Carbon dioxide isotopologues have been studied thoroughly in the troposphere. In the stratosphere, the minor oxygen CO₂ isotopologues have anomalous abundances due to their exchange reactions with isotopically fractionated ozone, differentiating them from tropospheric CO₂. Previously a model predicted that this anomalous isotopic abundance continues into the mesosphere but lacked verification from experimental observations. Here we use the Atmospheric Chemistry Experiment Fourier Transform Spectrometer which records infrared transmittance spectra of the Earth's limb from low Earth orbit using solar occultation. These infrared spectra provide measurements of global CO₂ isotopologue volume mixing ratios (VMRs) from the upper troposphere to the lower …

Twenty Years Of Global Stratospheric Fluorine Inventories From Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Measurements, N. Raymond, P. Bernath, C. Boone, M. Chipperfield

Chemistry & Biochemistry Faculty Publications

We present fluorine inventories calculated for twenty years (2004–2023) and five latitude bands (82°–60°N, 60°–30°N, 30°N–30°S, 30°–60°S, and 60°–82°S) at altitudes from the surface up to 55 km. The inventories were calculated using the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE‐FTS) version 5.2 retrievals of the volume mixing ratios (VMRs) of 15 fluorine‐containing species. Of these 15 species, 3 are product gases: HF, COF₂, COCIF, and 12 are source gases: SF₆, PFC-14 (CF₄), CFC-11 (CCl₃F), CFC-12 (CCl₂F₂), CFC-113 (CCIF₂CCl₂F), HCFC-22 (CHF₂CL), HCFC-141b(C₂H₃Cl₂F), HCFC-142b ( …

Stratospheric Glider Measurements Of Atmospheric Parameters, Anisa Haghighi

Theses and Dissertations--Mechanical and Aerospace Engineering

In June 2021 a series of high altitude flights were conducted in Spaceport America, NM, using a balloon launched Uncrewed Aircraft System (UAS) to assess its capability to conduct measurements of various atmospheric properties and study turbulence in the troposphere and lower stratosphere. This UAS descends using an automated flight trajectory. The instruments aboard included a NASA-developed infrasonic microphone to evaluate its remote turbulence detection capabilities and a five-hole probe capable of measuring the in situ wind vector. Also on board were temperature, humidity and wind profile sensors. This document focuses on the atmospheric properties measured at high altitudes, the …

Examining The Impact Of Stratospheric Vortex Variability On Us Surface Temperature, Elena M. Fernandez

Legacy Theses & Dissertations (2009 - 2024)

Variability in high-latitude stratospheric flow, including major sudden stratospheric warming (SSW) or strong polar vortex events, can modulate tropospheric circulation and have meteorological implications on surface temperature and weather. The largest tropospheric impacts from Northern Hemisphere stratospheric variability – and the regions of focus in the literature – are observed in the North Atlantic, Europe and Asia. Impacts on North America occur but have received less research attention. The goal of this thesis research is to identify and quantify the relationship between high-latitude stratospheric variability and North American wintertime temperature.Using the ERA-Interim and ERA-5 reanalysis for the period of 1999/2000–2018/19, …

Eastward-Propagating Planetary Waves In The Middle Atmosphere During Major Sudden Stratospheric Warming Events, Christian Todd Rhodes

Electronic Theses and Dissertations

No abstract provided.

Examining The Impact Of Synoptic-Scale Waves On Stratospheric Polar Vortex Variability From An Ensemble Forecast Perspective, Michael E. Main

Legacy Theses & Dissertations (2009 - 2024)

Major Sudden Stratospheric Warming (SSW) events are characterized by rapid warming of the polar regions at 10 hPa and are accompanied by a reversal of the 10-hPa zonal-mean zonal wind at 60˚N from westerly to easterly. Following an SSW event, stratospheric thermal and momentum anomalies can progress downward and linger near the tropopause for up to 60 days. These anomalies have major impacts on tropospheric sensible weather including increased likelihood of cold air outbreaks and heavy precipitation events. SSW events are largely forced by upward propagation of planetary-scale Rossby waves from the troposphere to the stratosphere. Synoptic-scale waves can contribute …

Volcanic Impact On Stratospheric Chlorine Chemistry And Perchlorate Formation: Evidence From Ice Cores, Joshua Andrew Kennedy

Electronic Theses and Dissertations

Perchlorate, suspected to be chemically formed in both the troposphere and stratosphere, has been recently measured in Arctic snow and ice cores. These comprise both discontinuous snow and ice cores from the Canadian Arctic and a continuous record of perchlorate was compiled from an analysis of Greenland ice cores. While the background perchlorate concentration typically is very low, a few spikes in concentration coinciding with deposition of volcanic sulfate were observed in the Greenland record, suggesting that perchlorate levels in the atmosphere may be impacted by volcanic eruptions. As of yet, no work has been done to investigate the connection …

Nrlmsis 2.0: A Whole-Atmosphere Empirical Model Of Temperature And Neutral Species Densities, J. T. Emmert, D. P. Drob, J. M. Picone, D. E. Siskind, M. Jones Jr., M. G. Mlynczak, Peter F. Bernath, X. Chu, E. Doornbos, B. Funke, L. P. Goncharenko, M. E. Hervig, M. J. Schwartz, P. E. Sheese, F. Vargas, B. P. Williams, T. Yuan

Chemistry & Biochemistry Faculty Publications

NRLMSIS® 2.0 is an empirical atmospheric model that extends from the ground to the exobase and describes the average observed behavior of temperature, eight species densities, and mass density via a parametric analytic formulation. The model inputs are location, day of year, time of day, solar activity, and geomagnetic activity. NRLMSIS 2.0 is a major, reformulated upgrade of the previous version, NRLMSISE-00. The model now couples thermospheric species densities to the entire column, via an effective mass profile that transitions each species from the fully mixed region below ~70 km altitude to the diffusively separated region above ~200 km. Other …

Design And Performance Of A Communications System For A Low-Cost High Altitude Balloon Platform For Troposphere And Stratosphere Research, Noemí Miguélez Gómez

Doctoral Dissertations and Master's Theses

AFOSR Multidisciplinary University Research Initiative (MURI), "Integrated Measurement and Modeling Characterization of Stratospheric Turbulence", is a 5-year effort to resolve significant operational issues concerning hypersonic vehicle aerothermodynamics, boundary layer stability, and aero-optical propagation. In situ turbulence measurements along with modeling will quantify spatiotemporal statistics and the dependence of stratospheric turbulence on underlying meteorology to a degree not previously possible. Data from high altitude balloons sampling up to kHz is required to characterize turbulence to the inner-scale, or smaller, over paltitudes from 20 km to 35+ km.

This thesis presents the development of a standard balloon bus, based on reliable COTS …

Recent Trends In Stratospheric Chlorine From Very Short‐Lived Substances, Ryan Hossaini, Elliot Atlas, Sandip S. Dhomse, Martyn P. Chipperfield, Peter F. Bernath, Anton M. Fernando, Jens Mühle, Amber A. Leeson, Stephen A. Montzka, Wuhu Feng

Chemistry & Biochemistry Faculty Publications

Very short‐lived substances (VSLS), including dichloromethane (CH₂Cl₂), chloroform (CHCl₃), perchloroethylene (C₂Cl₄), and 1,2‐dichloroethane (C₂H₄Cl₂), are a stratospheric chlorine source and therefore contribute to ozone depletion. We quantify stratospheric chlorine trends from these VSLS (VSLCl_tot) using a chemical transport model and atmospheric measurements, including novel high‐altitude aircraft data from the NASA VIRGAS (2015) and POSIDON (2016) missions. We estimate VSLCl_tot increased from 69 (±14) parts per trillion (ppt) Cl in 2000 to 111 (±22) ppt Cl in 2017, with >80% delivered to …

The Relationship Between Tropospheric Synoptic-Scale Events, Vertical Wave Activity Flux, And Sudden Stratospheric Warmings In The Boreal Winter, Hannah Elizabeth Attard

Legacy Theses & Dissertations (2009 - 2024)

Rapid breakdowns of the climatological mid-winter stratospheric polar vortex [i.e., sudden stratospheric warmings (SSWs)] are often preceded by tropospheric blocks. While some studies suggest that blocks can induce the upward wave activity flux (WAF) through the tropopause region that is necessary to trigger an SSW, other studies show no statistical relationship between tropospheric blocks and SSWs. One objective of this dissertation is to elucidate the dynamical relationship between tropospheric blocks and SSWs by exploring the relationship between blocks and tropopause-level upward WAF. Along with analyzing blocks, this dissertation also explores rapidly deepening extratropical cyclones (i.e., bombs) and tropical cyclones that …

Examining Variability In Model Skill During The 7 January 2013 Sudden Stratospheric Warming Event, Jonathan Lee Blufer

Legacy Theses & Dissertations (2009 - 2024)

Recent analyses of numerical weather prediction models have shown that stratospheric regime changes (e.g. strong and weak vortex events) are not skillfully predicted at medium-range lead times. Motivated by these recent analyses, this thesis investigates the sources of variability in stratospheric forecast skill amongst several operational models initiated at different lead times prior to the 7 January 2013 sudden stratospheric warming (SSW). This study extends upon a previous analysis by the Stratospheric Network for the Assessment of Predictability (SNAP), which concluded that a change in forecast lead-time from 15 to 10 days increased model skill in predicting the 2013 SSW …

Quantifying Carbonyl Sulfide And Other Sulfur-Containing Compounds Over The Santa Barbara Channel, Julia Black

Scripps Senior Theses

Carbonyl sulfide (OCS) is emitted to the atmosphere through the outgassing of ocean surface waters. OCS is also the primary source of sulfur-containing compounds in the stratosphere and contributes to the formation of the stratospheric sulfate layer, an essential controller of the radiative balance of the atmosphere. During the 2016 Student Airborne Research Program (SARP), 15 whole air samples were collected on the NASA DC-8 aircraft over the Santa Barbara Channel. Five additional surface samples were taken at various locations along the Santa Barbara Channel. The samples were analyzed using gas chromatography in the Rowland-Blake lab at UC Irvine, and …

Version 1.3 Aim Sofie Measured Methane (Ch4): Validation And Seasonal Climatology, P. P. Rong, J. M. Russell Iii, B. T. Marshall, D. E. Siskind, M. E. Hervig, L. L. Gordley, P. F. Bernath, K. A. Walker

Chemistry & Biochemistry Faculty Publications

The V1.3 methane (CH₄) measured by the Aeronomy of Ice in the Mesosphere (AIM) Solar Occultation for Ice Experiment (SOFIE) instrument is validated in the vertical range of ~25–70 km. The random error for SOFIE CH₄ is ~0.1–1% up to ~50 km and degrades to ~9% at ∼ 70 km. The systematic error remains at ~4% throughout the stratosphere and lower mesosphere. Comparisons with CH₄ data taken by the SCISAT Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS) and the Envisat Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) show an agreement within ~15% in the altitude range ~30–60 …

Growth In Stratospheric Chlorine From Short-Lived Chemicals Not Controlled By The Montreal Protocol, R. Hossaoni, M. P. Chipperfield, A. Saiz-Lopez, J. J. Harrison, R. Von Glasow, R. Sommariva, E. Atlas, M. Navarro, S. A. Montzka, W. Feng, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

We have developed a chemical mechanism describing the tropospheric degradation of chlorine containing very short-lived substances (VSLS). The scheme was included in a global atmospheric model and used to quantify the stratospheric injection of chlorine from anthropogenic VSLS (Cl_y^VSLS) between 2005 and 2013. By constraining the model with surface measurements of chloroform (CHCl₃), dichloromethane (CH₂Cl₂), tetrachloroethene (C₂Cl₄), trichloroethene (C₂HCl₃), and 1,2-dichloroethane (CH₂ClCH₂Cl), we infer a 2013 Cl_y^VSLS mixing ratio of 123 parts per trillion (ppt). Stratospheric injection …

Global Stratospheric Fluorine Inventory For 2004-2009 From Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Measurements And Slimcat Model Simulations, A. T. Brown, M. P. Chipperfield, N. A. D. Richards, C. Boone, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Fluorine-containing species can be extremely effective atmospheric greenhouse gases. We present fluorine budgets using organic and inorganic species retrieved by the ACE-FTS satellite instrument supplemented with output from the SLIMCAT 3-D chemical transport model. The budgets are calculated between 2004 and 2009 for a number of latitude bands: 70-30 °N, 30-00 °N, 00 °N-30 °S, and 30-70°S. At lower altitudes total fluorine profiles are dominated by the contribution from CFC-12, up to an altitude of 20 km in the extra-tropics and 29 km in the tropics; above these altitudes the profiles are dominated by hydrogen fluoride (HF). Our data show …

Ground-Based Observations With A Rayleigh-Mie-Raman Lidar From 15-120 Km, Leda Sox, Vincent B. Wickwar, Joshua P. Herron, David L. Barton, Matthew T. Emerick

Graduate Student Posters

Rayleigh lidar systems have historically made ground-based observations of the upper atmosphere (stratosphere and mesosphere) from 35-90 km. This technology has helped fill the data collection gap between the troposphere and space. Recently our Rayleigh lidar group at the Atmospheric Lidar Observatory on the campus of Utah State University (42° N, 112° W) upgraded the original lidar system in order to extend the measurement range for neutral densities and temperatures to higher altitudes and has increased the upper limit, so far, from 90 to 110 km. Next, we will extend the lower altitude limit downward to 15 km. This will …

On The Lack Of Stratospheric Dynamical Variability In Low‐Top Versions Of The Cmip5 Models, Andrew J. Charlton-Perez, Mark P. Baldwin, Thomas Birner, Robert X. Black, Amy H. Butler, Natalia Calvo, Nicholas A. Davis, Edwin P. Gerber, Nathan Gillett, Steven Hardiman, Junsu Kim, Kirsten Krüger, Yun-Young Lee, Elisa Manzini, Brent A. Mcdaniel, Lorenzo Polvani, Thomas Reichler, Tiffany A. Shaw, Michael Sigmond, Seok-Woo Son, Matthew Toohey, Laura Wilcox, Shigeo Yoden, Bo Christiansen, François Lott, Drew Shindell, Seiji Yukimoto, Shingo Watanabe

Faculty Articles

We describe the main differences in simulations of stratospheric climate and variability by models within the fifth Coupled Model Intercomparison Project (CMIP5) that have a model top above the stratopause and relatively fine stratospheric vertical resolution (high-top), and those that have a model top below the stratopause (low-top). Although the simulation of mean stratospheric climate by the two model ensembles is similar, the low-top model ensemble has very weak stratospheric variability on daily and interannual time scales. The frequency of major sudden stratospheric warming events is strongly underestimated by the low-top models with less than half the frequency of events …

The Relation Between Atmospheric Humidity And Temperature Trends For Stratospheric Water, S. Fueglistaler, Y. S. Liu, T. J. Flannaghan, P. H. Haynes, D. P. Dee, W. J. Read, E. E. Remsberg, L. W. Thomason, D. F. Hurst, J. R. Lanzante, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

We analyze the relation between atmospheric temperature and water vapor-a fundamental component of the global climate system-for stratospheric water vapor (SWV). We compare measurements of SWV (and methane where available) over the period 1980-2011 from NOAA balloon-borne frostpoint hygrometer (NOAA-FPH), SAGE II, Halogen Occultation Experiment (HALOE), Microwave Limb Sounder (MLS)/Aura, and Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) to model predictions based on troposphere-to-stratosphere transport from ERA-Interim, and temperatures from ERA-Interim, Modern Era Retrospective- Analysis (MERRA), Climate Forecast System Reanalysis (CFSR), Radiosonde Atmospheric Temperature Products for Assessing Climate (RATPAC), HadAT2, and RICHv1.5. All model predictions are dry biased. The interannual …

Identification And Classification Of Stratospheric Sudden Warming Events, Thomas S. Ehrmann

Doctoral Dissertations and Master's Theses

Analysis of northern hemisphere stratospheric data from 1978-2011 is used to identify and classify Stratospheric Sudden Warming events. A total of 41 events are identified during this 33 year period, resulting in an average occurrence rate of 1.24 events/year. No significant variation in the rate is observed during the period analyzed. The average temperature increase during an SSW event is 12 K and the average duration is 32 days. Each identified event is classified as either a vortex displacement or split event and the ratio of displacement to split events is found to be 0.86.

Technical Note: A Trace Gas Climatology Derived From The Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Data Set, A. Jones, K. A. Walker, J. J. Jin, J. R. Taylor, C. D. Boone, P. F. Bernath, S. Brohede, G. L. Manney, S. Mcleod, R. Hughes, W. H. Daffer

Chemistry & Biochemistry Faculty Publications

The Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS) aboard the Canadian satellite SCISAT (launched in August 2003) was designed to investigate the composition of the upper troposphere, stratosphere, and mesosphere. ACE-FTS utilizes solar occultation to measure temperature and pressure as well as vertical profiles of over thirty chemical species including O₃, H₂O, CH₄, N₂O, CO, NO, NO₂, N₂O₅, HNO₃, HCl, ClONO₂, CCl₃F, CCl₂F₂, and HF. Global coverage for each species is obtained approximately over a three month …

Analysis Of Iasi Tropospheric O₃ Data Over The Arctic During Polarcat Campaigns In 2008, M. Pommier, C. Clerbaux, K. S. Law, G. Ancellet, P. Bernath, P.-F. Coheur, J. Hadji-Lazaro, D. Hurtmans, P. Nédélec, J.-D. Paris, F. Ravetta, T. B. Ryerson, H. Schlager, A. J. Weinheimer

Chemistry & Biochemistry Faculty Publications

Ozone data retrieved in the Arctic region from infrared radiance spectra recorded by the Infrared Atmospheric Sounding Interferometer (IASI) on board the MetOp-A European satellite are presented. They are compared with in situ and lidar observations obtained during a series of aircraft measurement campaigns as part of the International Polar Year POLARCAT activities in spring and summer 2008. Different air masses were sampled during the campaigns including clean air, polluted plumes originating from anthropogenic sources, forest fire plumes from the three northern continents, and stratospheric-influenced air masses. The comparison between IASI O₃ [0–8 km], [0–12 km] partial columns and …

Chemistry–Climate Model Simulations Of Twenty-First Century Stratospheric Climate And Circulation Changes, Neal Butchart, I. Cionni, V. Eyring, T. G. Shepherd, D. W. Waugh, H. Akiyoshi, J. Austin, C. Brühl, M. P. Chipperfield, Eugene C. Cordero, M. Dameris, R. Deckert, S. Dhomse, S. M. Frith, R. R. Garcia, A. Gettelman, M. A. Giorgetta, D. E. Kinnison, F. Li, E. Mancini, S. Pawson, G. Pitari, D. A. Plummer, E. Rozanov, F. Sassi, J. F. Scinocca, K. Shibata, B. Steil, W. Tian

Faculty Publications, Meteorology and Climate Science

The response of stratospheric climate and circulation to increasing amounts of greenhouse gases (GHGs) and ozone recovery in the twenty-first century is analyzed in simulations of 11 chemistry–climate models using near-identical forcings and experimental setup. In addition to an overall global cooling of the stratosphere in the simulations (0.59 ± 0.07 K decade⁻¹ at 10 hPa), ozone recovery causes a warming of the Southern Hemisphere polar lower stratosphere in summer with enhanced cooling above. The rate of warming correlates with the rate of ozone recovery projected by the models and, on average, changes from 0.8 to 0.48 K decade …

Verification Of The Mountain Wave Forecast Model's Stratospheric Turbulence Forecasts Using Sounding Data And Pilot Reports, Scott M. Miller

Theses and Dissertations

Since stratospheric turbulence (Stratoturb) is becoming an increased concern to the Air Force, the threat of damage to aircraft must be addressed. Therefore, the Air Force Weather Agency (AFWA) requests an accurate Stratoturb forecast model. In 2002, The Mountain Wave Forecast Model (MWFM) was modified in order to develop a Stratoturb forecast tool. Turbulence forecasts generated twice daily by the MWFM for locations over East Asia over a period of thirty days were compared to output from the Rawindsonde Observation (RAOB) program to determine if the model agreed with the program output. Although the results were promising, verification by aircraft …