Atmospheric Sciences Commons^™

Atmospheric Remote Sensing Using X-Band Radar In The Marine Atmospheric Surface Layer, Daniel P. Greenway

Electronic Theses and Dissertations

Atmospheric remote sensors have always offered promising technological advancements for measuring atmospheric properties over large spatial areas at high spatiotemporal resolution – a feat not currently possible with present atmospheric measurement technologies. However, remote sensors do not measure these atmospheric properties directly; they rely on robust calibrations or conversions, complex mathematical inversion methods, and/or machine learning to retrieve these properties. These inverse methods rely on the selection of an objective function, a machine learning technique, and an accurate parameterization for atmospheric property estimation. By leveraging inverse methods to improve the characterization of properties measured by remote sensors, this work enables …

Photochemistry Of Quinones And Combustion-Derived Particles, Desiree J. Sarmiento

Electronic Theses and Dissertations

Quinones are ubiquitous species that can be produced from the photochemical aging of combustion-derived particles (CDPs). Polycyclic aromatic hydrocarbons (PAHs) are a major component of CDPs and are precursors to quinones and other oxidized products (OPAHs). My work first expanded on the PAH and OPAH photochemistry research of Dr. John Haynes, who showed that anthracene (ANT) oxidizes into 1,4-naphthoquinone (1,4-NAPQ), 1,4-anthraquinone (1,4-ANTQ), and 9,10-anthraquinone (9,10-ANTQ), and of Dr. Heather Runberg, who demonstrated the ability of ANT and these quinones to generate reactive oxygen species (ROS). Then at the Pacific Northwest National Laboratory (PNNL), I was given the opportunity to investigate …

The Effects Of Temperature, Flooding, And Goose Feces Addition On Greenhouse Gas Emissions And Ammonification In Four High-Latitude Soils From Western Alaska, Jenna M. Ross

Electronic Theses and Dissertations

The large carbon (C) stock of wetlands is vulnerable to climate change, especially in high latitudes that are warming at a disproportional rate. Likewise, low-elevation Arctic coastal areas will flood more frequently under climate change and sea-level rise, which may alter goose herbivory and fecal deposition patterns if geese move inland. While temperature, flooding, and feces impact soil C emissions, their interactive effects have been rarely studied. Here, I explore the impact of these interactions on CO2 and CH4 emissions and nitrogen (N) mineralization (ammonification) in soils collected from four plant communities in the Yukon-Kuskokwim (Y-K) Delta, a high latitude …

Characteristics Of Refractivity And Sea State In The Marine Atmospheric Surface Layer And Their Influence On X-Band Propagation, Douglas Matthew Pastore

Electronic Theses and Dissertations

Predictions of environmental conditions within the marine atmospheric surface layer (MASL) are important to X-band radar system performance. Anomalous propagation occurs in conditions of non-standard atmospheric refractivity, driven by the virtually permanent presence of evaporation ducts (ED) in marine environments. Evaporation ducts are commonly characterized by the evaporation duct height (EDH), evaporation duct strength, and the gradients below the EDH, known as the evaporation duct curvature. Refractivity, and subsequent features, are estimated in the MASL primarily using four methods: in-situ measurements, numerical weather and surface layer modeling, boundary layer theory, and inversion methods.

The existing refractivity estimation techniques often assume …

Arctic Sea Ice Loss In The Pacific Sector And Its Impacts On Sudden Stratospheric Warming Events, Jiarong Zhang

Electronic Theses and Dissertations

The Arctic sea ice is a critical indicator of climate change. The extent of sea ice coverage over the Arctic Ocean has dramatically declined over the past few decades. The impact has been extensively studied through observations suggesting a linkage between the anomalously warm Arctic surface associated with the Arctic sea ice loss and the mid-latitude surface cooling in the subsequent boreal winter. This linkage could involve the wintertime stratospheric circulation by enhancing the upward planetary wave activity and weakening the polar vortex. With recent advances in climate model, more relevant studies relied on numerical simulations and some suggested that …

Improving Near Surface Refractivity Estimates In Marine Environments, Sarah Evelyn Wessinger

Electronic Theses and Dissertations

This study utilizes in-situ measurements and numerical weather prediction datasets collected during the Coupled Air-Sea Processes Electromagnetic Ducting Research East field campaign to assess how thermodynamic properties in the marine atmospheric surface layer influence evaporation duct shape and to develop a simple near-surface modified refractivity estimation method. This study utilizes a logarithmic linear parametric model, which describes evaporation ducts via three main parameters: evaporation duct height, evaporation duct curvature, and mixed layer slope. Notably, most studies utilizing this type of model assume the curvature, C0, to be a theoretical value derived assuming neutral atmospheric stability; a thermodynamic regime that is …

A Mesonet-Based Analysis Of Severe Convective Winds In West Texas., Quint Long

Electronic Theses and Dissertations

Multiple studies have investigated the occurrence of severe convective-related winds and have increased our understanding of the forces driving severe winds and their spatial and temporal patterns. Data for these studies have come from airport stations maintained by the National Weather Service. Their standardization across the United States makes them ideal for research, but they are limited in their distribution. This study aims to create a similar climatology of severe surface level winds using a mesoscale network (“mesonet”). Like their ASOS (Automated Surface Observing System) and AWOS (Automated Weather Observing System) counterparts, these stations are standardized and well maintained. This …

The Impact Of Sea-Level Rise In Numerically Modeled Landfalling Hurricanes: Katrina And The Gulf Coast., Serenity Nadirah Mercuri

Electronic Theses and Dissertations

With climate change, landfalling hurricanes become an increasing threat to coastal regions. However, the interactions between the coastal landscape and landfalling hurricanes are often overlooked when addressing sea-level rise outside of inundation and independent of sea surface temperature. This study analyzed the potential impacts regarding structure and intensity as a result of sea-level rise in the Gulf of Mexico using the WRF-ARW numerical model coupled with a 1D ocean model. Analysis showed that 10 m windspeed from landfall forward was higher in modified coastlines, and minimum sea-level pressure post-landfall was consistently lower for modified runs where storms maintain a higher …

Eastward-Propagating Planetary Waves In The Middle Atmosphere During Major Sudden Stratospheric Warming Events, Christian Todd Rhodes

Electronic Theses and Dissertations

No abstract provided.

Radiosonde High Altitude Measurements Of Radiation Levels And Cosmic Ray Events, Ayodeji Opeyemi Akinuliola

Electronic Theses and Dissertations

Just above us, cosmic rays are hurtling in from space. These fast moving particles crash uncontrollably into molecules in the atmosphere, causing spontaneous decays of these particles. Despite the fact that we are broadly shielded from this radiation on earth, these particles can still disturb humans and electronics alike. Therefore, this research focuses on expanding the use of long-range radio transmitters such as radiosondes to transmit valuable data such as cosmic ray flux, geographical position, atmospheric temperature, pressure, etc. This can improve real-time radiation monitoring for aviation industry crew and passengers working in potentially higher radiation environments. On March 11, …

The Effect Of Initial Conditions On The Weather Research And Forecasting Model, Aaron D. Baker

Electronic Theses and Dissertations

Modeling our atmosphere and determining forecasts using numerical methods has been a challenge since the early 20th Century. Most models use a complex dynamical system of equations that prove difficult to solve by hand as they are chaotic by nature. When computer systems became more widely adopted and available, approximating the solution of these equations, numerically, became easier as computational power increased. This advancement in computing has caused numerous weather models to be created and implemented across the world. However a challenge of approximating these solutions accurately still exists as each model have varying set of equations and variables to …

Parametric Model Development For Heterogeneous Atmospheric Conditions, Daniel Paul Greenway

Electronic Theses and Dissertations

No abstract provided.

A Comprehensive Study Of The Short-Term Variability Of The Migrating Diurnal Tide In The Mesosphere And Lower Thermosphere., Lokupatabendige Ashan Shivantha Vitharana

Electronic Theses and Dissertations

Our ability to understand and predict space weather has become vital due to its significant societal impacts on communication, transportation, and national defense. One of the most exciting discoveries in the last decade has been the realization that tropospheric weather can strongly influence space weather. It is now recognized that the atmospheric waves (gravity waves, atmospheric tides, and planetary waves) play a key role in coupling the lower and upper atmosphere. The focus of this dissertation is to study atmospheric tides. While the climatology of tides has been extensively studied, little is known about the tidal weather (tidal variability

Volcanic Impact On Stratospheric Chlorine Chemistry And Perchlorate Formation: Evidence From Ice Cores, Joshua Andrew Kennedy

Electronic Theses and Dissertations

Perchlorate, suspected to be chemically formed in both the troposphere and stratosphere, has been recently measured in Arctic snow and ice cores. These comprise both discontinuous snow and ice cores from the Canadian Arctic and a continuous record of perchlorate was compiled from an analysis of Greenland ice cores. While the background perchlorate concentration typically is very low, a few spikes in concentration coinciding with deposition of volcanic sulfate were observed in the Greenland record, suggesting that perchlorate levels in the atmosphere may be impacted by volcanic eruptions. As of yet, no work has been done to investigate the connection …

Impact Of Data Selection On The Accuracy Of Atmospheric Refractivity Inversions Performed Over Marine Surfaces, Ian Joseph Matsko

Electronic Theses and Dissertations

Within the Earth’s atmosphere there is a planetary boundary layer that extends from the surface to roughly 1 km above the surface. Within this planetary boundary layer exists the marine atmospheric boundary layer, which is a complex turbulent surface layer that extends from the sea surface to roughly 100 m in altitude. The turbulent nature of this layer combined with the interactions across the air-sea interface cause ever changing environmental conditions within it, including atmospheric properties that affect the index of refraction, or atmospheric refractivity. Variations in atmospheric refractivity lead to many types of anomalous propagation phenomena of electromagnetic (EM) …

Biomass Burning In The Conterminous United States: A Comparison And Fusion Of Active Fire Observations From Polar-Orbiting And Geostationary Satellites For Emissions Estimation, Fangjun Li

Electronic Theses and Dissertations

Biomass burning is an important source of atmospheric greenhouse gases and aerosol emissions that significantly influence climate and air quality. Estimation of biomassburning emissions (BBE) has been limited to the conventional method in which parameters (i.e., burned area and fuel load) can be challenging to quantify accurately. Recent studies have demonstrated that the rate of biomass combustion is a linear function of fire radiative power (FRP), the instantaneous radiative energy released from actively burning fires, which provides a novel pathway to estimate BBE. To obtain accurate and timely BBE estimates for near real-time applications (i.e., air quality forecast), the satellite …

Improved Characterization And Analysis Strategies For Uv-Lif Bioaerosol Instrumentation: Lab And Field Application, Nicole Justine Savage

Electronic Theses and Dissertations

Atmospheric particles of biological origin, also referred to as bioaerosols or primary biological aerosol particles (PBAP), are important to various human health and environmental systems. There has been a recent steep increase in the frequency of published studies utilizing commercial instrumentation based on ultraviolet laser/light-induced fluorescence (UV-LIF), such as the WIBS (wideband integrated bioaerosol sensor), for bioaerosol detection both outdoors and in the built environment. Significant work over several decades supported the development of these technologies, but efforts to systematically characterize the operation of new commercial sensors has remained lacking. Specifically, there are gaps in the understanding of how different …

Quantification Of Airborne Fungal Spores Comparing Molecular Tracers Via Ion Chromatography And Uv-Lif Methods, Marie Ila Gosselin

Electronic Theses and Dissertations

Fungal spores represent an understudied subcategory of bioaerosols that can impact human health as pathogenic and allergenic particles. Fungal spores also have been shown to act as effective ice nuclei and giant cloud condensation nuclei in some cases. This has implications on the hydrological cycle on local and regional scales by impacting the formation and evolution of clouds and precipitation. The quantification of fungal spores has been limited in the past due to methods that were costly and that suffered from poor time resolution. The most commonly applied methods for airborne fungal spore analysis have traditionally included microscopy and culturing, …

New Particle Formation In The Mid-Latitude Upper Troposphere, Duncan Axisa

Electronic Theses and Dissertations

Primary aerosol production due to new particle formation (NPF) in the upper troposphere and the impact that this might have on cloud condensation nuclei (CCN) concentration can be of sufficient magnitude to contribute to the uncertainty in radiative forcing. This uncertainty affects our ability to estimate how sensitive the climate is to greenhouse gas emissions. Therefore, new particle formation must be accurately defined, parametrized and accounted for in models.

This research involved the deployment of instruments, data analysis and interpretation of particle formation events during the Mid-latitude Airborne Cirrus Properties Experiment (MACPEX) campaign. The approach combined field measurements and observations …

Investigating The Atmospheric Production Of Perchlorate: Inference From Polar Ice Cores, Thomas S. Cox

Electronic Theses and Dissertations

Perchlorate (ClO₄) in the environment is of concern, because of potential health risks to humans, among other reasons. Evidence suggests that the majority of environmental perchlorate is formed in the atmosphere (likely in the stratosphere), in chemical processes involving ozone and stratospheric chlorine. A lack of knowledge in regards to the processes has resulted in a limited understanding of the environmental conditions and variables that influence perchlorate production and consequently perchlorate prevalence and variability in the environment. In this study, perchlorate was measured, using an established ion chromatography-­‐electrospray ionization-­‐tandem mass spectrometry (IC-­‐ESI-­‐ MS/MS) technique, in over 1,600 snowpit …

Tornado Density And Return Periods In The Southeastern United States: Communicating Risk And Vulnerability At The Regional And State Levels, Michelle Bradburn

Electronic Theses and Dissertations

Tornado intensity and impacts vary drastically across space, thus spatial and statistical analyses were used to identify patterns of tornado severity in the Southeastern United States and to assess the vulnerability and estimated recurrence of tornadic activity. Records from the Storm Prediction Center's tornado database (1950-2014) were used to estimate kernel density to identify areas of high and low tornado frequency at both the regional- and state-scales. Return periods (2-year, 5-year, 10-year, 25-year, 50-year, and 100-year) were calculated at both scales as well using a composite score that included EF-scale magnitude, injury counts, and fatality counts. Results showed that the …

Source Apportionment Of Atmospheric Particulate Matter In Developing Countries Using Trace Elements And Stable Metal Isotope Ratios, Nitika Dewan

Electronic Theses and Dissertations

The work presented herein details the source apportionment of atmospheric particulate matter in developing countries (Kyrgyzstan in Central Asia, metropolitan cities in Northern India, and Shenzhen in China) using trace elements and stable metal isotope ratios. The first study focused on the development of a novel method for the concomitant separation of rare-earth elements in environmental samples of any geological origin. The separation procedure is based on three extraction chromatographic materials, referred to as Sr.Spec, TRU.Spec, and Ln.Spec. This triple column arrangement enables the simultaneous isolation of pure Sr and Nd fractions in less than one day and with great …

Description Of Coherent Structures In The Atmospheric Boundary Layer By Model Reduction Of The Surface Pressure, Gregory William Lyons

Electronic Theses and Dissertations

The flow of coherent turbulent structures into a wind turbine is associated with vibrational blade excitation. Successful forecasting of such turbulent events for control system input would increase the lifetime of turbine components. The coherence of these features suggests description by model reduction. To this end, an array of pressure transducers was deployed on the ground at Reese Technology Center in Lubbock, Texas, and the pressure fluctuations were recorded over nearly two diurnal cycles. A program for computation of the dynamic mode decomposition was developed with special consideration for the case of a non-stationary, nonlinear system. A simulated surface-pressure perturbation …