Atmospheric Sciences Commons^™

Simulation Of Photochemical Effects On Air Quality, Grace Li

Chemical Engineering Undergraduate Honors Theses

Nitrogen dioxide (NO₂) and ozone (O₃) are both EPA criteria air pollutants in the troposphere, largely generated by combustion and therefore present in significant concentrations in urban areas. Sunlight facilitates chemical reactions between pollutants and ambient air. Aerosols modulate the amount of available energy required to drive such photochemical reactions, ultimately impacting air quality. Simulating photolysis rates with FastJX software is a resource-efficient strategy to study how these aerosols can affect air quality.

Investigation Of The Flow Field In The Jack Rabbit Ii Mock Urban Environment Field Tests Using A 1:50 Scale Wind Tunnel Model, Paulo Victor De Freitas Lopes

Graduate Theses and Dissertations

Accidental release of toxic chemicals can put workers and nearby populations at significant risk. Consequence assessment of accidents in urban environments is of particular interest. Urban geometries create wind channels between buildings, along with particularly dangerous areas downwind of buildings, where near-stagnant flow is present. Furthermore, recirculation zones can be formed between buildings, trapping high concentrations of toxic gases at ground level, particularly for denser-than-air gases. In 2015, the Department of Homeland Security conducted the Jack Rabbit II Field Test (JR-II) at Dugway Proving Ground, UT. During JR-II, chlorine was released at the center of a Mock Urban Environment (MUE) …

Changes Of Winter Severity In Arkansas During 1901-2100, Christian Garcia

Graduate Theses and Dissertations

The objective of this study was to quantify the winter severity in a way that was reproduceable and easy to understand. The Accumulated Winter Severity Seasonal Index (AWSSI) was chosen for this reason and was used to quantify winter severity by season across the state of Arkansas. The variables that go into the AWSSI calculation are maximum daily temperature, minimum daily temperature, daily snowfall, and daily snow depth. When the snowfall and snow depth were missing, they can be estimated using daily temperature and precipitation. Then the estimated snowfall and snow depth can be subsequently used to quantify the winter …

Assimilation Of Seasonal Moisture Variability In North America And Asia For The Last Millennium, Chang Liu

Graduate Theses and Dissertations

The seasonal tree-ring chronologies that recorded discrete moisture signal for warm and cool season have been used to reconstruct the North America Seasonal Precipitation Atlas (NASPA) by the point-by-point regression method, and the results indicated that they can fairly reproduce the seasonal precipitation variability in the past. Compared with reconstructions using only paleoclimate proxy data, the paleoclimate data assimilation (PDA) considers both proxy data and climate model output, so the PDA reconstructions are consistent with both the climate signals reflected by the proxy data and the physical mechanisms represented by climate models. Based on the tree rings with discrete seasonal …

Pan American Interactions Of Amazon Precipitation, Streamflow, And Tree Growth Extremes, D. W. Stahle, M. C. A. Torbenson, I. M. Howard, D. Granato-Souza, A. C. Barbosa, S. Feng, J. Schöngart, L. Lopez, R. Villalba, J. Villanueva, K. Fernandes

Geosciences Faculty Publications and Presentations

Rainfall and river levels in the Amazon are associated with significant precipitation anomalies of opposite sign in temperate North and South America, which is the dominant mode of precipitation variability in the Americas that often arises during extremes of the El Niño/Southern Oscillation (ENSO). This co-variability of precipitation extremes across the Americas is imprinted on tree growth and is detected when new tree-ring chronologies from the eastern equatorial Amazon are compared with hundreds of moisture-sensitive tree-ring chronologies in mid-latitude North and South America from 1759 to 2016. Pan-American co-variability exists even though the seasonality of precipitation and tree growth only …

Cool And Warm Season Climate Signals In Tree Rings From North America, Max Carl Arne Torbenson

Graduate Theses and Dissertations

Earlywood (EW) and latewood (LW) ring-width chronologies have become an increasingly important proxy in paleoclimate reconstructions. These subannual variables can provide estimates of past hydroclimate variability for seasonal windows that total ring-widths cannot resolve. The strength of the relationship between EW and LW series may influence what type of paleoclimate information is embedded within the tree-ring series. High correlations (> 0.70) between EW and LW are recorded for much of the continent but the magnitude of correlation varies greatly across space and species boundaries. Using four LW chronologies from shortleaf pine, the North American conifer species displaying the lowest EW-LW …

Daily To Seasonal Moisture Signals Present In Sub-Annual Tree-Ring Data, Ian Howard

Graduate Theses and Dissertations

In recent decades, there has been an increase in the development of sub-annual earlywood (EW) and latewood (LW) width tree-ring chronologies that have been used to make long-term inferences about discrete seasonal moisture variability for different regions of North America. This doctoral research developed a new network of EW, LW, and adjusted latewood (LWa) tree-ring chronologies from the western Great Plains. These chronologies were used to reconstruct 300+ years of spring and summer moisture variability over the northern and southern Plains. The reconstructions document new information about the long-term seasonal climate history of the Great Plains, including the unusual nature …

A Long-Term (2002 To 2017) Record Of Closed-Path And Open-Path Eddy Covariance Co2 Net Ecosystem Exchange Fluxes From The Siberian Arctic, David Holl, Christian Wille, Torsten Sachs, Peter Schreiber, Benjamin R. K. Runkle, Lutz Beckebanze, Moritz Langer, Julia Boike, Eva-Maria Pfeiffer, Irina Fedorova, Dimitry Y. Bolshianov, Mikhail N. Grigoriev, Lars Kutzbach

Biological and Agricultural Engineering Faculty Publications and Presentations

Ground-based observations of land–atmosphere fluxes are necessary to progressively improve global climate models. Observed data can be used for model evaluation and to develop or tune process models. In arctic permafrost regions, climate–carbon feedbacks are amplified. Therefore, increased efforts to better represent these regions in global climate models have been made in recent years. We present a multi-annual time series of land–atmosphere carbon dioxide fluxes measured in situ with the eddy covariance technique in the Siberian Arctic (72◦220 N, 126◦300 E). The site is part of the international network of eddy covariance flux observation stations (FLUXNET; site ID: Ru-Sam). The …

Methanogens, Plausible Extraterrestrial Life Forms On Mars, And Their Tolerance To Increasing Concentrations Of Illite Clay, Chandler Kern

Biological Sciences Undergraduate Honors Theses

Methanogens, some of Earth’s most primitive prokaryotic organisms, are candidates for possible life forms capable of inhabiting Mars. Specifically, four different species (Methanobacterium formicicum, Methanococcus maripaludis, Methanosarcina barkeri, Methanothermobacter wolfeii) were analyzed for their tolerance to the presence of illite clay. Illite is a crystalline mineral that has been identified from regions of Mars’s surface. Results indicated that all four species grew with some success in the illite at different concentrations. This experimentation with methanogens’ abilities to survive and reproduce in the presence of illite allows for a more accurate understanding of the potential capability of microbial …

Comparison Of Various Mean Field Formulations For Retrieving Refractive Indices Of Aerosol Particles Containing Inclusions, Kristin S. Dooley, Jessica Deyoung

Journal of the Arkansas Academy of Science

Application of effective medium approximation (EMA) methods to two-component systems are presented. Systems studied are composed of water, sulfate, soot, and dust as these are commonly encountered atmospheric aerosol components. Atmospheric models often employ EMAs to include internally mixed aerosols without the computational burden of exact theory. In the current work, several types of mixing rules (Maxwell-Garnet, Bruggeman, and coherent potential approximation) have been applied to various two-component internally mixed particles at 550 nm using volume fractions of the minor component below 0.1. As expected, results show that the formulations tested produce very similar effective refractive indices indicating that electric …

An Investigation Of Biological Carbon Sequestration At The Pea Ridge National Military Park, Dorine Reed Bower

Graduate Theses and Dissertations

The direct correlation between increasing levels of atmospheric CO2 and global temperatures is now irrefutable. A 50% increase in atmospheric CO2 levels from a pre-industrial level of 270 ppm to a present-day level of 405 ppm, has resulted in documented record temperatures and a concomitant rising of sea levels from melting ice caps.

The ability of biological/terrestrial ecological systems to store atmospheric carbon is a viable option in the effort to mitigate the climate impacts of rising anthropogenically-caused greenhouse gas emissions. Components of the vegetation and soils in the Pea Ridge National Military Park (the Park) were examined for carbon …

Variability In Methane Emissions From West Siberia's Shallow Boreal Lakes On A Regional Scale And Its Environmental Controls, Aleksandr F. Sabrekov, Benjamin R.K. Runkle, Mikhail V. Glagolev, Irina E. Terentieva, Victor M. Stephanenko, Oleg R. Kotsyurbenko, Shamil S. Maksyutov, Oleg S. Pokrovsky

Biological and Agricultural Engineering Faculty Publications and Presentations

Small lakes represent an important source of atmospheric CH4 from northern wetlands. However, spatiotemporal variations in flux magnitudes and the lack of knowledge about their main environmental controls contribute large uncertainty into the global CH4 budget. In this study, we measured methane fluxes from small lakes using chambers and bubble traps. Field investigations were carried out in July–August 2014 within the West Siberian middle and southern taiga zones. The average and median of measured methane chamber fluxes were 0.32 and 0.30 mgCH4 m−2 h−1 for middle taiga lakes and 8.6 and 4.1 mgCH4 m−2 h−1 for southern taiga lakes, respectively. …

Delta‐Flux: An Eddy Covariance Network For A Climate‐Smart Lower Mississippi Basin, Benjamin R. K. Runkle, James R. Rigby, Michele L. Reba, Saseendran S. Anapalli, Joydeep Bhattacharjee, Ken W. Krauss, Lu Liang, Martin A. Locke, Kimberly A. Novick, Ruixiu Sui, Kosana Suvocarev, Paul M. White Jr.

Biological and Agricultural Engineering Faculty Publications and Presentations

Networks of remotely monitored research sites are increasingly the tool used to study regional agricultural impacts on carbon and water fluxes. However, key national networks such as the National Ecological Observatory Network and AmeriFlux lack contributions from the Lower Mississippi River Basin (LMRB), a highly productive agricultural area with opportunities for soil carbon sequestration through conservation practices. The authors describe the rationale to create the new Delta‐Flux network, which will coordinate efforts to quantify carbon and water budgets at seventeen eddy covariance flux tower sites in the LMRB. The network structure will facilitate climate‐smart management strategies based on production‐scale and …

Upscaling Methane Emission Hotspots In Boreal Peatlands, Fabio Cresto Aleina, Benjamin R. K. Runkle, Tim Brucher, Thomas Kleinen, Victor Brovkin

Biological and Agricultural Engineering Faculty Publications and Presentations

Upscaling the properties and effects of small-scale surface heterogeneities to larger scales is a challenging issue in land surface modeling. We developed a novel approach to upscale local methane emissions in a boreal peatland from the micro-topographic scale to the landscape scale. We based this new parameterization on the analysis of the water table pattern generated by the Hummock–Hollow model, a microtopography resolving model for peatland hydrology. We introduce this parameterization of methane hotspots in a global model-like version of the Hummock–Hollow model that underestimates methane emissions. We tested the robustness of the parameterization by simulating methane emissions for the …

Modeling Micro-Topographic Controls On Boreal Peatland Hydrology And Methane Fluxes, F. Cresto Aleina, Benjamin R. K. Runkle, T. Kleinen, Lars Kutzbach, J. Schneider, V. Brovkin

Biological and Agricultural Engineering Faculty Publications and Presentations

Small-scale surface heterogeneities can influence land-atmosphere fluxes and therefore carbon, water and energy budgets on a larger scale. This effect is of particular relevance for high-latitude ecosystems, because of the great amount of carbon stored in their soils. We introduce a novel micro-topographic model, the Hummock-Hollow (HH) model, which explicitly represents small-scale surface elevation changes. By computing the water table at the small scale, and by coupling the model with a process-based model for soil methane processes, we are able to model the effects of micro-topography on hydrology and methane emissions in a typical boreal peatland. In order to assess …

Application Of High-Resolution Spectral Absorbance Measurements To Determine Dissolved Organic Carbon Concentration In Remote Areas, Armine Avagyan, Benjamin R. K. Runkle, Lars Kutzbach

Biological and Agricultural Engineering Faculty Publications and Presentations

Accurate quantification of dissolved organic carbon (DOC) in surface and soil pore waters is crucial for understanding changes in water resources under the influence of climate and land use changes. Sampling and laboratory analysis of DOC content at a sufficient temporal frequency are especially difficult to achieve for natural DOC sources like the extensive boreal and arctic mire landscapes due to their remoteness. Therefore, the goals of this paper are (1) to investigate the performance of a portable, high-resolution ultraviolet–visible light spectroscopic method for determining the DOC content of surface and soil pore water samples from a boreal mire complex …

Seasonal Variability As A Source Of Uncertainty In The West Siberian Regional Ch4 Flux Upscaling, A. F. Sabrekov, Benjamin R. K. Runkle, M. V. Glagolev, I E. Kleptsova, S. S. Maksyutov

Biological and Agricultural Engineering Faculty Publications and Presentations

This study compares seasonal and spatial variations in methane fluxes as sources of uncertainty in regional CH4 flux upscaling from the wetlands of West Siberia. The study examined variability in summertime CH4 emissions from boreal peatlands, with a focus on two subtaiga fen sites in the southern part of West Siberia (Novosibirskaya oblast). We measured CH4 flux, water table depth, air and peat temperature, pH and electric conductivity of peat water during three field campaigns in summer 2011 (9–12 July, 26–28 July and 20–21 August). Fluxes were measured with static chambers at sites chosen to represent two of the most …

The Surface Energy Balance And Its Drivers In A Boreal Peatland Fen Of Northwestern Russia, Benjamin R. K. Runkle, Christian Wille, Michal Gazovic, M. Wilmking, L. Kutzbach

Biological and Agricultural Engineering Faculty Publications and Presentations

Boreal peatland energy balances using the eddy covariance technique have previously been made in Alaska, Canada, Scandinavia, and Western Siberia, but not in the European portion of the Russian Federation. European Russia contains approximately 200,000 km2 of peatlands and has a boreal (subarctic), continental climate influencing the region’s energy balance. To help fill this research gap, the surface energy balance was determined for a boreal peatland fen in the Komi Republic of Russia for an 11-month period in 2008–2009 using the eddy covariance method. The total measurement period’s cumulative energy balance closure rate was 86%, with higher closure during the …

Bulk Partitioning The Growing Season Net Ecosystem Exchange Of Co2 In Siberian Tundra Reveals The Seasonality Of Its Carbon Sequestration Strength, Benjamin R. K. Runkle, T. Sachs, C. Wille, E.-M. Pfeiffer, L. Kutzbach

Biological and Agricultural Engineering Faculty Publications and Presentations

This paper evaluates the relative contribution of light and temperature on net ecosystem CO2 uptake during the 2006 growing season in a polygonal tundra ecosystem in the Lena River Delta in Northern Siberia (72°22´ N, 126°30´ E). The occurrence and frequency of warm periods may be an important determinant of the magnitude of the ecosystem's carbon sink function, as they drive temperature-induced changes in respiration. Hot spells during the early portion of the growing season, when the photosynthetic apparatus of vascular plants is not fully developed, are shown to be more influential in creating positive mid-day surface-to-atmosphere net ecosystem CO2 …