Atmospheric Sciences Commons^™

Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are converted into the respective phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(•)). Further processing of the latter species by HO(•) decreases their vapor pressure as a second hydroxyl group is incorporated to accelerate their oxidative aging at interfaces and in aqueous particles. This work shows how catechol, pyrogallol, 3-methylcatechol, 4-methylcatechol, and 3-methoxycatechol (all proxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasing O3(g) during τc ≈ 1 μs contact time and contrasts their …

Modeling Gross Primary Production Of Midwest Maize And Soybean Croplands With Satellite And Gridded Weather Data, Gunnar Malek-Madani

Department of Geography: Dissertations, Theses, and Student Research

The gross primary production (GPP) metric is useful in determining trends in the terrestrial carbon cycle. Models that determine GPP utilizing the light use efficiency (LUE) approach in conjunction with biophysical parameters that account for local weather conditions and crop specific factors are beneficial in that they combine the accuracy of the biophysical model with the versatility of the LUE model. One such model developed using in situ data was adapted to operate with remote sensing derived leaf area index (LAI) data and gridded weather datasets. The model, known as the Light Use Efficiency GPP Model (EGM), uses a four …

Droughtscape, Spring 2017, National Drought Mitigation Center

DroughtScape: Quarterly Newsletter of the National Drought Mitigation Center (2007–2023)

Contents

Drought center helps islands reduce drought vulnerability

2017 sees above-average precipitation, warmer temps

California pulls out of drought

After tech transfer, training Tunisia launches first drought map

Drought center releases 2016 annual report

Book chapter focuses on drought and health

U2U wraps up, brings useful tools to farmers

Survey finds drought info leads to better decisions

A Predictor Analysis Framework For Surface Radiation Budget Reprocessing Using Design Of Experiments, Patricia Allison Quigley

Engineering Management & Systems Engineering Theses & Dissertations

Earth’s Radiation Budget (ERB) is an accounting of all incoming energy from the sun and outgoing energy reflected and radiated to space by earth’s surface and atmosphere. The National Aeronautics and Space Administration (NASA)/Global Energy and Water Cycle Experiment (GEWEX) Surface Radiation Budget (SRB) project produces and archives long-term datasets representative of this energy exchange system on a global scale. The data are comprised of the longwave and shortwave radiative components of the system and is algorithmically derived from satellite and atmospheric assimilation products, and acquired atmospheric data. It is stored as 3-hourly, daily, monthly/3-hourly, and monthly averages of 1°x1° …

Reactivity Of Ketyl And Acetyl Radicals From Direct Solar Actinic Photolysis Of Aqueous Pyruvic Acid, Alexis J. Eugene, Marcelo I. Guzman

Chemistry Faculty Publications

The variable composition of secondary organic aerosols (SOA) contributes to the large uncertainty for predicting radiative forcing. A better understanding of the reaction mechanisms leading to aerosol formation such as for the photochemical reaction of aqueous pyruvic acid (PA) at λ ≥ 305 nm can contribute to constrain these uncertainties. Herein, the photochemistry of aqueous PA (5-300 mM) continuously sparged with air is re-examined in the laboratory under comparable irradiance at 38° N at noon on a summer day. Several analytical methods are employed to monitor the time series of the reaction, including (1) the derivatization of carbonyl (C═O) functional …

Latitudinal Position And Trends Of The Intertropical Convergence Zone (Itcz) And Its Relationship With Upwelling In The Southern Caribbean Sea And Global Climate Indices, Kaitlyn E. Colna

USF Tampa Graduate Theses and Dissertations

The Intertropical Convergence Zone (ITCZ) is a feature that results from the ocean-atmosphere interactions in the tropics around the world. The ITCZ is characterized by surface wind convergence, tall storm clouds, and it forms a belt of high time-averaged precipitation around the globe. The ITCZ undergoes seasonal migrations between 5°S and 15°N roughly following the subsolar point on Earth with the seasons, with a mean annual position located slightly above the Equator, between 2° and 5°N.

This study tested the hypothesis that there was a northward shift in the median position of the ITCZ in the first decade of the …

Simultaneous Upward And Downward Propagating Inertia-Gravity Waves In The Mlt Observed At Andes Lidar Observatory, Kai Ming Hung, Alan Z. Liu, Shao Dong Zhang, Fan Yi, Chun Ming Huang, Yun Gong, Quan Gan, Et Al.

Publications

Based on the temperature and zonal and meridional winds observed with an Na lidar at Andes Lidar Observatory (30.3°S, 70.7°W) on the night of 20–21 July 2015, we report simultaneous upward and downward propagating inertia-gravity waves (IGWs) in the mesosphere/lower stratosphere (MLT). The ground-based periods of the upward and downward IGWs are about 5.4 h and 4.8 h, respectively. The horizontal and vertical wavelengths are about 935 km and 10.9 km for the 5.4 h IGW and about 1248 km and 22 km for the 4.8 h IGW, respectively. Hodograph analyses indicate that the 5.4 h IGW propagates in the …

Data From: Optical Depth And Size Characteristics Of Small Coastal Florida Cumuli From Surface-Based Lidar And Radiometer Measurements, Rodrigo Delgadillo

Supplementary Data and Tools

Data in this collection is from micro-pulse lidar (MPL) and near field of view (NFOV) radiometer from 20 Dec 2014 to 1 March 2015. The instruments are co-located and zenith-aligned. Measurements were recorded at the CAROb site (http://carob.rsmas.miami.edu/) located in the University of Miami Rosenstiel School of Marine & Atmospheric Science. The data in this collection is categorized as MPL and zenith radiometer data.

P07. Characterizing The Purple Crow Lidar To Investigate Potential Sources Of Wet Bias, Jeffrey Vankerkhove, Robert J. Sica, Robin Wing, Steve Argall

Western Research Forum

The Purple Crow Lidar is a large aperture lidar, capable of retrieving water vapor profiles into the stratosphere. Water vapor in the upper Troposphere-Lower Stratosphere (UTLS) region is of particular importance in understanding Earth's radiative budget and atmospheric dynamics, making accurate UTLS measurements crucial. A comparison campaign with the NASA/GSFC ALVICE mobile lidar in the spring of 2012 showed PCL water vapor measurements were consistently larger than those of ALVICE in the lower stratosphere, prompting an investigation to characterize the system. The investigation looks into how changes to the data processing approach, as well as applying additional instrumental corrections, would …

P16. Ralmo Rotational Raman Temperature Retrieval: First Steps Towards The Application Of Optimal Estimation Method (Oem), Shayamila N. Mahagammulla Gamage, Robert Sica, Alexander Haefele

Western Research Forum

Background:

Temperature is an important atmospheric parameter that plays an extensive role in the fields of atmospheric dynamics, climatology, meteorology, and chemistry. Light detection and ranging (lidar), is a remote sensing technology that can be used for atmospheric temperature profiling. A lidar transmits short laser pulses into the atmosphere and the light scattered by the particles in the atmosphere is collected and measured using a telescope. The atmospheric temperatures can be retrieved by analysing the Pure Rotational Raman (PRR) scatter measurements from the nitrogen and oxygen molecules in the atmosphere.

Methods:

In this study use the Optimal Estimation Method (OEM) …

Umphlett Qci March 2017, Natalie Umphlett

High Plains Regional Climate Center: Staff Publications

Highlights for the Basin

Temperature and Precipitation Anomalies

Mountain Snowpack

Christmas Day Storm

Heavy Fuels Increase Fire Risk

Early Warmth Causes Concerns

3-Month Precipitation and Temperature Outlooks

NOAA Spring Flood Outlook

Assessment Of An Atmospheric Transport Model For Annual Inverse Estimates Of California Greenhouse Gas Emissions, Justin Bagley, Seongeun Jeong, Xinguang Cui, Sally Newman, Jingsong Zhang, Chad Priest, Mixtli Campos-Pineda, Arlyn Andrews, Laura Bianco, Matthew Lloyd, Neil Lareau, Craig Clements, Marc Fischer

Faculty Publications, Meteorology and Climate Science

Atmospheric inverse estimates of gas emissions depend on transport model predictions, hence driving a need to assess uncertainties in the transport model. In this study we assess the uncertainty in WRF-STILT (Weather Research and Forecasting and Stochastic Time-Inverted Lagrangian Transport) model predictions using a combination of meteorological and carbon monoxide (CO) measurements. WRF configurations were selected to minimize meteorological biases using meteorological measurements of winds and boundary layer depths from surface stations and radar wind profiler sites across California. We compare model predictions with CO measurements from four tower sites in California from June 2013 through May 2014 to assess …

Nitrate Radicals And Biogenic Volatile Organic Compounds: Oxidation, Mechanisms And Organic Aerosol, Nga Lee Ng, Steven S. Brown, Alexander T. Archibald, Elliot Atlas, Ronald C. Cohen, John N. Crowley, Douglas A. Day, Neil M. Donahue, Juliane L. Fry, Hendrik Fuchs, Robert J. Griffin, Marcelo I. Guzman, Hartmut Hermann, Alma Hodzic, Yoshiteru Iinuma, José L. Jimenez, Astrid Kiendler-Scharr, Ben H. Lee, Deborah J. Luecken, Jingqiu Mao, Robert Mclaren, Anke Mutzel, Hans D. Osthoff, Bin Ouyang, Benedicte Picquet-Varrault, Ulrich Platt, Havala O. T. Pye, Yinon Rudich, Rebecca H. Schwantes, Manabu Shiraiwa, Jochen Stutz, Joel A. Thornton, Andreas Tilgner, Brent J. Williams, Rahul A. Zaveri

Chemistry Faculty Publications

Oxidation of biogenic volatile organic compounds (BVOC) by the nitrate radical (NO₃) represents one of the important interactions between anthropogenic emissions related to combustion and natural emissions from the biosphere. This interaction has been recognized for more than 3 decades, during which time a large body of research has emerged from laboratory, field, and modeling studies. NO₃-BVOC reactions influence air quality, climate and visibility through regional and global budgets for reactive nitrogen (particularly organic nitrates), ozone, and organic aerosol. Despite its long history of research and the significance of this topic in atmospheric chemistry, a number …

Nonlinear Ionospheric Responses To Large-Amplitude Infrasonic-Acoustic Waves Generated By Undersea Earthquakes, M. D. Zettergren, J. B. Snively, A. Komjathy, O. P. Verkhoglyadova

Publications

Numerical models of ionospheric coupling with the neutral atmosphere are used to investigate perturbations of plasma density, vertically integrated total electron content (TEC), neutral velocity, and neutral temperature associated with large-amplitude acoustic waves generated by the initial ocean surface displacements from strong undersea earthquakes. A simplified source model for the 2011 Tohoku earthquake is constructed from estimates of initial ocean surface responses to approximate the vertical motions over realistic spatial and temporal scales. Resulting TEC perturbations from modeling case studies appear consistent with observational data, reproducing pronounced TEC depletions which are shown to be a consequence of the impacts of …

Contributions Of Wood Smoke And Vehicle Emissions To Ambient Concentrations Of Volatile Organic Compounds And Particulate Matter During The Yakima Wintertime Nitrate Study, Graham Vanderschelden, Benjamin De Foy, Courtney Herring, Susan D. Kaspari, Tim Vanreken, Bertram Jobson

All Faculty Scholarship for the College of the Sciences

A multiple linear regression (MLR) chemical mass balance model was applied to data collected during an air quality field experiment in Yakima, WA, during January 2013 to determine the relative contribution of residential wood combustion (RWC) and vehicle emissions to ambient pollutant levels. Acetonitrile was used as a chemical tracer for wood burning and nitrogen oxides (NOx) as a chemical tracer for mobile sources. RWC was found to be a substantial source of gas phase air toxics in wintertime. The MLR model found RWC primarily responsible for emissions of formaldehyde (73%), acetaldehyde (69%), and black carbon (55%) and mobile sources …

Delta‐Flux: An Eddy Covariance Network For A Climate‐Smart Lower Mississippi Basin, Benjamin R. K. Runkle, James R. Rigby, Michele L. Reba, Saseendran S. Anapalli, Joydeep Bhattacharjee, Ken W. Krauss, Lu Liang, Martin A. Locke, Kimberly A. Novick, Ruixiu Sui, Kosana Suvocarev, Paul M. White Jr.

Biological and Agricultural Engineering Faculty Publications and Presentations

Networks of remotely monitored research sites are increasingly the tool used to study regional agricultural impacts on carbon and water fluxes. However, key national networks such as the National Ecological Observatory Network and AmeriFlux lack contributions from the Lower Mississippi River Basin (LMRB), a highly productive agricultural area with opportunities for soil carbon sequestration through conservation practices. The authors describe the rationale to create the new Delta‐Flux network, which will coordinate efforts to quantify carbon and water budgets at seventeen eddy covariance flux tower sites in the LMRB. The network structure will facilitate climate‐smart management strategies based on production‐scale and …

Ozone Depletion, A Big Threat To Climate Change: What Can Be Done?, Sumera Aziz Ali, Savera Aziz Ali, Nadir Suhail

Community Health Sciences

Ozone in the stratosphere is very important as it acts as a safeguard for the earth and protects life from harmful ultraviolet radiations coming from the sun. Depletion of stratospheric ozone, resulting from atmospheric pollution has led to increased ultraviolet radiation at the earth’s surface as well as spectral shifts to the more biologically damaging shorter wavelengths. A decrease in the concentration of stratospheric ozone enhances the solar ultraviolet (UV) radiation, which is harmful to the growth of the plant and various other metabolic processes of the organisms and might cause changes in pigment concentrations, nucleic acids, and proteins. Multiple …

Multiple Metabolisms Constrain The Anaerobic Nitrite Budget In The Eastern Tropical South Pacific, Andrew R. Babbin, Brian D. Peters, Calvin W. Mordy, Brittany Widner, Karen L. Casciotti, Bess B. Ward

OES Faculty Publications

The Eastern Tropical South Pacific is one of the three major oxygen deficient zones (ODZs) in the global ocean and is responsible for approximately one third of marine water column nitrogen loss. It is the best studied of the ODZs and, like the others, features a broad nitrite maximum across the low oxygen layer. How the microbial processes that produce and consume nitrite in anoxic waters interact to sustain this feature is unknown. Here we used ¹⁵N-tracer experiments to disentangle five of the biologically mediated processes that control the nitrite pool, including a high-resolution profile of nitrogen loss rates. …

Numerical Modeling Of A Multiscale Gravity Wave Event And Its Airglow Signatures Over Mount Cook, New Zealand, During The Deepwave Campaign, C. J. Heale, K. Bossert, J. B. Snively, D. C. Fritts, P. -D. Pautet, M. J. Taylor

Publications

A 2-D nonlinear compressible model is used to simulate a large-amplitude, multiscale mountain wave event over Mount Cook, NZ, observed as part of the Deep Propagating Gravity Wave Experiment (DEEPWAVE) campaign and to investigate its observable signatures in the hydroxyl (OH) layer. The campaign observed the presence of a �x = 200 km mountain wave as part of the 22nd research flight with amplitudes of >20 K in the upper stratosphere that decayed rapidly at airglow heights. Advanced Mesospheric Temperature Mapper (AMTM) showed the presence of small-scale (25–28 km) waves within the warm phase of the large mountain wave. The …

Estimating Methane Emissions From Biological And Fossil-Fuel Sources In The San Francisco Bay Area, Seongeun Jeong, Xinguang Cui, Donald Blake, Ben Miller, Stephen Montzka, Arlyn Andrews, Abhinav Guha, Philip Martien, Ray Bambha, Brian Lafranchi, Hope Michelsen, Craig Clements, Pierre Glaize, Marc Fischer

Faculty Publications, Meteorology and Climate Science

We present the first sector-specific analysis of methane (CH4) emissions from the San Francisco Bay Area (SFBA) using CH4 and volatile organic compound (VOC) measurements from six sites during September – December 2015. We apply a hierarchical Bayesian inversion to separate the biological from fossil-fuel (natural gas and petroleum) sources using the measurements of CH4 and selected VOCs, a source-specific 1 km CH4 emission model, and an atmospheric transport model. We estimate that SFBA CH4 emissions are 166–289 Gg CH4/yr (at 95% confidence), 1.3–2.3 times higher than a recent inventory with much of the underestimation from landfill. Including the VOCs, …

Application Of Recurrent Neural Networks For Drought Projections In California, J. A. Le, Hesham El-Askary, Mohamed Allali, Daniele C. Struppa

Mathematics, Physics, and Computer Science Faculty Articles and Research

We use recurrent neural networks (RNNs) to investigate the complex interactions between the long-term trend in dryness and a projected, short but intense, period of wetness due to the 2015-2016 El Niño. Although it was forecasted that this El Niño season would bring significant rainfall to the region, our long-term projections of the Palmer Z Index (PZI) showed a continuing drought trend, contrasting with the 1998-1999 El Niño event. RNN training considered PZI data during 1896-2006 that was validated against the 2006-2015 period to evaluate the potential of extreme precipitation forecast. We achieved a statistically significant correlation of 0.610 between …

Anisotropic Fluid Modeling Of Ionospheric Upflow: Effects Of Low‐Altitude Anisotropy And Thermospheric Winds, M. R. Burleigh, M. Zettergren

Publications

A new anisotropic fluid model is developed to describe ionospheric upflow responses to magnetospheric forcing by electric fields and broadband ELF waves at altitudes of 90–2500 km. This model is based on a bi‐Maxwellian ion distribution and solves time‐dependent, nonlinear equations of conservation of mass, momentum, parallel energy, and perpendicular energy for six ion species important to E, F, and topside ionospheric regions. It includes chemical and collisional interactions with the neutral atmosphere, photoionization, and electron impact ionization. This model is used to examine differences between isotropic and anisotropic descriptions of ionospheric upflow driven by DC electric fields, …

Data From: Observing System Simulation Experiments For An Array Of Autonomous Biogeochemical Profiling Floats In The Southern Ocean, Igor Kamenkovich, Angelique Haza, Alison R. Gray, Carolina O. Dufour, Zulema Garraffo

Supplementary Data and Tools

Data in this collection is from Observation System Simulation Experiments (OSSEs) that were carried in support of the SOCCOM program. Synthetic profiles were extracted from model-simulated dissolved oxygen and inorganic carbon. Full maps were then reconstructed from these sparse datasets, using objective mapping. For description of the model and reconstruction method please see Kamenkovich, I., A. Haza, A. Gray, C. Dufour, and Z. Garraffo: "Observing System Simulation Experiments for an array of autonomous biogeochemical profiling floats in the Southern Ocean", Journal of Geophysical Research, DOI: 10.1002/2017JC012819

Improved Characterization And Analysis Strategies For Uv-Lif Bioaerosol Instrumentation: Lab And Field Application, Nicole Justine Savage

Electronic Theses and Dissertations

Atmospheric particles of biological origin, also referred to as bioaerosols or primary biological aerosol particles (PBAP), are important to various human health and environmental systems. There has been a recent steep increase in the frequency of published studies utilizing commercial instrumentation based on ultraviolet laser/light-induced fluorescence (UV-LIF), such as the WIBS (wideband integrated bioaerosol sensor), for bioaerosol detection both outdoors and in the built environment. Significant work over several decades supported the development of these technologies, but efforts to systematically characterize the operation of new commercial sensors has remained lacking. Specifically, there are gaps in the understanding of how different …

Quantification Of Airborne Fungal Spores Comparing Molecular Tracers Via Ion Chromatography And Uv-Lif Methods, Marie Ila Gosselin

Electronic Theses and Dissertations

Fungal spores represent an understudied subcategory of bioaerosols that can impact human health as pathogenic and allergenic particles. Fungal spores also have been shown to act as effective ice nuclei and giant cloud condensation nuclei in some cases. This has implications on the hydrological cycle on local and regional scales by impacting the formation and evolution of clouds and precipitation. The quantification of fungal spores has been limited in the past due to methods that were costly and that suffered from poor time resolution. The most commonly applied methods for airborne fungal spore analysis have traditionally included microscopy and culturing, …

New Particle Formation In The Mid-Latitude Upper Troposphere, Duncan Axisa

Electronic Theses and Dissertations

Primary aerosol production due to new particle formation (NPF) in the upper troposphere and the impact that this might have on cloud condensation nuclei (CCN) concentration can be of sufficient magnitude to contribute to the uncertainty in radiative forcing. This uncertainty affects our ability to estimate how sensitive the climate is to greenhouse gas emissions. Therefore, new particle formation must be accurately defined, parametrized and accounted for in models.

This research involved the deployment of instruments, data analysis and interpretation of particle formation events during the Mid-latitude Airborne Cirrus Properties Experiment (MACPEX) campaign. The approach combined field measurements and observations …

High Plains Regional Climate Center (Poster)

High Plains Regional Climate Center: Staff Publications

The HPRCC provides the public with several ways to access climate data and information. Whether via direct contact, website access, or through a subscription to one of HPRCC’s online services, users can acquire a variety of climate data products, such as: • Near Real-Time and Historical Climate Data • National and Regional Climate Data Maps • Agricultural Climate Products • Monthly, Quarterly, and Annual Regional Climate Summaries

Light-Induced Protein Nitration And Degradation With Hono Emission, Hannah Meusel, Yasin Elshorbany, Uwe Kuhn, Thorsten Bartels-Rausch, Kathrin Reinmuth, Christopher J. Kampf, Yafang Cheng

USF St. Petersburg Campus Faculty Publications

Proteins can be nitrated by air pollutants (NO2), enhancing their allergenic potential. This work provides insight into protein nitration and subsequent decomposition in the presence of solar radiation. We also investigated light-induced formation of nitrous acid (HONO) from protein surfaces that were nitrated either online with instantaneous gas-phase exposure to NO2 or offline by an efficient nitration agent (tetranitromethane, TNM). Bovine serum albumin (BSA) and ovalbumin (OVA) were used as model substances for proteins. Nitration degrees of about 1% were derived applying NO2 concentrations of 100 ppb under VIS=UV illuminated conditions, while simultaneous decomposition of (nitrated) proteins was also found …

Comparing Cmaq Forecasts With A Neural Network Forecast Model For Pm2.5 In New York, Samuel D. Lightstone, Fred Moshary, Barry Gross

Publications and Research

Human health is strongly affected by the concentration of fine particulate matter (PM2.5). The need to forecast unhealthy conditions has driven the development of Chemical Transport Models such as Community Multi-Scale Air Quality (CMAQ). These models attempt to simulate the complex dynamics of chemical transport by combined meteorology, emission inventories (EI’s), and gas/particle chemistry and dynamics. Ultimately, the goal is to establish useful forecasts that could provide vulnerable members of the population with warnings. In the simplest utilization, any forecast should focus on next day pollution levels, and should be provided by the end of the business day (5 p.m. …

A Model-Based Assessment Of Potential Impacts Of Man-Made Reservoirs On Precipitation, Jesse Winchester, Rezaul Mahmood, William Rodgers, Faisal Hossain, Eric Rappin, Joshua D. Durkee, Themis Chronis

High Plains Regional Climate Center: Staff Publications

Land-use land-cover change (LULCC) plays an important role in weather and climate systems. Human modifications of land cover include building reservoirs and thus creating artificial lakes for multipurpose use. In this research, the authors have completed a Weather Research and Forecasting (WRF) Model–based assessment of impacts of two large parallel lakes on precipitation. This area is located in the western part of the states of Kentucky and Tennessee and known as the Land between the Lakes (LBL). To determine the impacts, this study has replaced the lakes with grass, deciduous forests, and bare soil and conducted model simulations for three …