Engineering Science and Materials Commons^™

Preparation Of Poly (Bromophenol Blue) Modified Glassy Carbon Electrode And Its Electrocatalytic Activity, Wei Chen, Hong-Bin Luo, Xin-Hua Lin

Journal of Electrochemistry

A film of poly (bromophenol blue) was formed on a glassy carbon electrode by using cyclic voltammetry. A stable film could be obtained with a potential range from -1.0 V to +1.8 V (vs.Ag/AgCl). The experimental results showed that the poly (bromophenol blue) modified glassy carbon electrode could catalyse the oxidation of ascorbic acid. It decreased the oxidation potential by about 270mV but increased the peak current. Meanwhile, this electrode showed a good linear current response for the ascorbic acid range from 2.5 to 250 (g/mL).

Research On Phenol Wastewater Treatment By Electrochemical Oxidation, Tian-Cheng Li, Shen-Lin Zhu

Journal of Electrochemistry

Electrochemical oxidation is an effective technology for the phenol wastewater treatment, and the anode properties are important to the electrochemical oxidationefficiency. The over-potentials of oxygen evolution have been measured for thestainless steel, feasible graphite and SnO₂/Ti anode respectively. Moreover, the synthetic phenol wastewater was treated by the electrochemical oxidation with the stainless steel or feasible graphite anodes. The experimental results showed that the order of the over-potential is SnO₂/Ti > graphite > stainless steel; meanwhile, the COD values of purified water were approaching to or less than 100 mg·L^-1, and the phenol concentrations in the purified …

Calcium Zincate Prepared By Ball Mill Method, Sheng-Xian Li, Shuan-Bao Tian, Shao-Shan Zhu

Journal of Electrochemistry

Calcium zincate was prepared by ball milling method and the factors that influence its synthesis were investigated. The composition of the compound was Ca(OH)₂·2Zn(OH)_2^·2H₂O, which was verified by XRD and TG-DTA methods. The results of powder microelectrode and in simulated batteries showed that the material had excellent cyclic performance.

Influence Of Rare Earth Oxide On The Performance Of Secondary Zinc Electrodes, Xian-Ling Meng, Hua-Bin Yang, Jun-Hong Wang, Zuo-Xiang Zhou

Journal of Electrochemistry

Influence of La(OH)₃ or Ce(OH)₃ in secondary zinc electrode was investigated by the cyclic voltammetry, potentiodynamic polarizationand potentiostatic polarization tests and influence of La₂O₃ or CeO₂ in the charge/discharge performance of Zn/Ni battery was studied by galvanostatic charge/discharge experiment. The results showed that the film of rare earth hydroxide prevented the zincate species from transferring toward solution, enhanced hydrogen overpotential and decreased thecorrosion current density (i_corr), and therefore inhibited zinc corrosion. The potentiostatic polarization results at100mV overpotential showed that La(OH)₃ or Ce(OH)₃ oated on the zinc electrode effectively suppressed the …

The Fabrication And Electrochemical Studies On Carbon Nanotube Array Electrodes, Quan-Yong Gao, Jing Zhang, Yong Yang

Journal of Electrochemistry

An improved technique for fabrication of carbon nanotube array electrodes has been proposed in this work. Firstly, carbon nanotubes (CNs) array electrodes were prepared by combsination of Chemical Vapor Decomposition (CVD) method and sputtering techniques in anodized aluminum oxide (AAO) membrane. The CNs/AAO was immersed into HF solution to remove the barrier layer. Controlling the immersing time, the CNs array electrodes with different length contacted with electrolyte can be prepared. The morphology of CNs array electrodes was observed by SEM. The electrochemical properties of CNs array electrodes were investigated by cyclic voltammetry and electrochemical impedance spectroscopy. Cyclic voltammetric curves of …

Fabrication And Studies Of A Novel Ag/Agcl Reference Electrode In High Temperature Molten Chloride Salts, Pei Gao, Xian-Bo Jin, Di-Hua Wang, Xiao-Hong Hu, Zheng Chen

Journal of Electrochemistry

A new method for the easy fabrication of a stable and long life silver/silver chloride reference electrode in molten chloride salts is described in this paper. The method is based on the fact that simply placing the silica glass in molten NaCl or its vapour in the presence of oxygen resulted in satisfactory conductivity for sodium ion and possibly calcium ion in the material.The performance of such made electrode has been investigated in a few typical chloride systems at temperatures ranging from 400 to 900℃. Due to the wholly sealed construction, the reference electrode is stable, temperature-reversible, contamination free to …

Using Neural Networks To Identify The Effect Of Construction Factors On The Cost Of Reinforced Concrete Elements, Ahmed Aly El-Sotouhy

Archived Theses and Dissertations

No abstract provided.

Engineering Tools For Variable Stiffness Vibration Suppression And Isolation, Michael F. Winthrop

Theses and Dissertations

With the advent of smart materials, the concept of semi-active control or dynamic control of stiffness and/or damping for vibration control of structures has become practical and has seen limited use. Semi-active control has advantages over active and passive control methods, since it provides almost as much capability as active control while requiring much less power. Its main disadvantage is its inherent nonlinearity, greatly complicating engineering design. The purpose of this research is to extend semi-active control vibration isolation tools and methods considering space launch and on-orbit systems.

Me-Em 2005 Annual Report, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical and Aerospace Engineering Annual Reports

Table of Contents

• Overview, Mission, and Vision
• Comments on the Strategic Plan
• Enrollment and Expenditure Data
• Professional Advisory Committee
• Faculty & Staff
• Students
• Alumni
• Entrepreneurs
• Resources
• Graduates
• Publications

Medical Technology: Contexts And Content In Science And Technology, Michael A. De Miranda, Mark Doggett, Jane T. Evans

Architectural and Manufacturing Sciences Faculty Publications

No abstract provided.

Rf-Sputter Fabrication Of Magnetic Garnet Thin Films And Simulation Modeling For 1-D Magnetic Photonic Crystal Waveguide Devices, Haichun Yang

Dissertations, Master's Theses and Master's Reports - Open

One dimensional magnetic photonic crystals (1D-MPC) are promising structures for integrated optical isolator applications. Rare earth substituted garnet thin films with proper Faraday rotation are required to fabricate planar 1D-MPCs. In this thesis, flat-top response 1D-MPC was proposed and spectral responses and Faraday rotation were modeled. Bismuth substituted iron garnet films were fabricated by RF magnetron sputtering and structures, compositions, birefringence and magnetooptical properties were studied. Double layer structures for single mode propagation were also fabricated by sputtering for the first time.

Multilayer stacks with multiple defects (phase shift) composed of Ce-YIG and GGG quarter-wave plates were simulated by the …

Electronic Commerce Negotiation In A Supply Chain Via Constraint Evaluation, R. Wilhelm, B. Chu, R. Sun

Department of Mechanical and Materials Engineering: Faculty Publications

Negotiation is of critical importance in e-commerce applications where the supply chain is dynamic and reconfiguring. In this research supply chain negotiation problems are addressed as constraint-satisfaction problems. In general each negotiation is handled in the largest scope possible to avoid the suboptimality that can result from many local solutions. This global approach, however, must be balanced with time constraints that apply in e-commerce supply chain execution. In this paper, we describe a new approach for e-commerce supply chain negotiation via constraint evaluation. As well, results from prototype software, distributed across the internet, are discussed. Beyond the general formulation, we …

Managing The Transformation Of System Of Systems Engineering, Samuel F. Kovacic, Andres Sousa-Poza

Engineering Management & Systems Engineering Faculty Publications

SOSE methodologies exist that support engineering difficult and disparate systems with a technical solution. However, from literature it is apparent that there is a need for a formal methodology and methods that govern engineering of System of Systems (SOS) beyond the technical solution. This paper presents some of the current thinking being undertaken at NCSOSE (National Centers for Systems of Systems Engineering), on what is driving the development of SOSE, and a hypothesized solution to this problem. The purpose is to offer a different approach for resolving complexity within a situation. The paper concludes with an initial derivative of a …

Adaptive Voip Playout Scheduling: Assessing User Satisfaction, Miroslaw Narbutt, Andrew Kelly, Liam Murphy, Philip Perry

Articles

Delay and packet loss dramatically affect the quality of a voice-over-IP (VoIP) call and depend on the playout buffer scheme implemented at the receiver. The choice of playout algorithm can’t be based on statistical metrics without considering the perceived end-to-end conversational speech quality. The authors present a method for evaluating various playout algorithms that extends the Emodel concept by estimating user satisfaction from time-varying transmission impairments. This article evaluates several playout algorithms and shows a correspondence between their results and those obtained via statistical loss and delay metrics.

Managing The Transformation Of System Of Systems Engineering, Samuel F. Kovacic, Andres Sousa-Poza

Engineering Management & Systems Engineering Faculty Publications

SOSE methodologies exist that support engineering difficult and disparate systems with a technical solution. However, from literature it is apparent that there is a need for a formal methodology and methods that govern engineering of System of Systems (SOS) beyond the technical solution. This paper presents some of the current thinking being undertaken at NCSOSE (National Centers for Systems of Systems Engineering), on what is driving the development of SOSE, and a hypothesized solution to this problem. The purpose is to offer a different approach for resolving complexity within a situation. The paper concludes with an initial derivative of a …

A Tablet Pc Application For Construction Site Safety Inspection And Fatality Prevention, Prabhu Sunkara

LSU Master's Theses

Construction industry accounts for the largest number of occupational injuries and fatalities every year. Occupational Safety and Health Administration (OSHA) is an organization responsible for regulating and enforcing standards for various occupations to ensure safe working conditions including construction industry. As an OSHA requirement, every construction employer should employ a safety program that involves both training of the employees and frequent site inspections. OSHA has provided an online ‘construction eTool’ as a training tool which also aids in the development of safety inspection procedures. Traditionally, safety inspections are paper based and usually designed to address a specific work area or …

The Electrodeposition And Property Study Of Nickel-Rhenium Alloy, Shirong Wen

LSU Master's Theses

The electrodeposition of nickel-rhenium alloys from Ni(II) and Re(VII) solution was studies in an aqueous acidic solution. Different plating current density and pH have been carried out, and the effect of them on the composition of the deposited Ni-Re alloy was studied. Wavelength-dispersive spectrometer (WDS) was used to measure the composition of Ni-Re alloy. The thermal stability of nickel-rhenium alloy system has been investigated. Differential scanning calorimetry (DSC) tests have been conducted for the electroplated Ni-Re samples in order to find the possible heating initiated interactions at elevated temperatures. To investigate the thermal stability of Ni-Re alloys, the samples were …

Supercritical Fluid Extraction Of Rice Bran With Adsorption On Rice Hull Ash, Paresh Manilal Patel

LSU Doctoral Dissertations

Rice bran oil was extracted using environmentally-friendly supercritical carbon dioxide at varying conditions. Experimental treatments included pressure (27.6, 41.4 and 55.2 MPa), temperature (40 and 60 oC) and flow rates (25, 45 and 65 g/min) of supercritical carbon dioxide. Extracts collected at different time intervals during 4-hour extraction runs in a 3-L extractor were analyzed for oil yield and antioxidants. Normal-phase HPLC was used for analyzing the extract for important antioxidant compounds of oryzanol, tocopherols, tocotrienols. Silica rich rice hull ash adsorbent was also incorporated in combined extraction-adsorption experiments under similar supercritical fluid conditions. Supercritical extraction yields of rice bran …

Transport And Kinetics Of Aromatic Hydrocarbons Into Micron-Sized Liquid Droplets: With Applications To Atmospheric Chemistry, Suresh Raja

LSU Doctoral Dissertations

In the natural process of wet deposition, gas-water interfaces play an important role in the transport of chemical contaminants in the atmosphere via fog, rain and cloud drops. Evidences from several other works point out deviations in gas-liquid partitioning as predicted by Henry’s law. Uptake and mass transfer of benzene, naphthalene, and phenanthrene was chosen to study in a falling droplet train apparatus. Higher droplet-to-vapor partition constant (KDV) was noted for diameters less than 200ìm and was attributed to surface adsorption and accumulation. Mass transfer of phenanthrene was dependent on gas-phase diffusion and mass accommodation at the interface, while the …

Purification And Structural Characterization Of Caged Dna Oligonucleotides, Brendan Michael Mcadams

LSU Master's Theses

“Cage” molecules reversibly block the bioactivity of a target substrate molecule by a photolyzable covalent bond formed at a functional site of the target molecule. The attachment of cage molecules to DNA oligodeoxynucleotides (ODNs) to transiently block bioactivity, and site-specific restoration of bioactivity using targeted light exposure, would enable a new method of control for use in gene therapy, molecular/DNA computing, molecular biology, and drug delivery. The reaction of the cage molecule 1-(4,5-dimethoxy-2-nitrophenyl)diazoethane (DMNPE) with DNA ODNs in an batch reaction yields a mixture of products with varying degrees of caging. Purification and verification of the hypothesized site of DMNPE …

A Project Improvement System For Effective Management Of Construction Projects, Shahriyar Mojahed

LSU Doctoral Dissertations

The concept of construction productivity began in the early 20th century with a series of time and motion studies to improve bricklaying operations. A substantial number of subsequent studies focused on repetitive tasks and automation of the manufacturing operations and subsequently benefited manufacturing more than the construction industry. There has been a lack of studies for productivity improvement in the construction industry. Building upon the available body of knowledge as it related to productivity of manufacturing and construction industries, this study focused on developing a project improvement system for effective management of construction projects. Development of the system included a …

Evidence Of Neotectonic Activity In Southwest Louisiana, Jordan Oliver Heltz

LSU Master's Theses

A methodology that combines high-resolution topographic mapping, field observations, subsurface evaluation, and geodetic data analysis has successfully located several fault-related geomorphic steps in an area of southwestern Louisiana once thought to be relatively devoid of such features. Comparison of height differences of benchmarks straddling these suspected fault-related steps shows that vertical displacement rates on faults in the study area ranged from about 2 mm/yr to as much as 6 mm/yr during the 1960’s and 1970’s. However, leveling data obtained as recently as January 2005 reveals that the majority of these faults are currently moving at rates of less than 1 …

Development Of High Performance Hybrid Syntactic Foams: Structure And Material Property Characterization, Rahul R. Maharsia

LSU Doctoral Dissertations

Syntactic foams are light weight particulate composites that use hollow particles (microballoons) as reinforcement in a polymer resin matrix. High strength microballoons provide closed cell porosity which helps in reducing weight of the material. Due to their wide range of possible applications such as in aerospace and marine structures, it is desirable to modify the physical and mechanical properties of syntactic foams as per the requirements of an application. Various filler materials can be used to modify the foam microstructure to attain these desired properties. Compression tests have revealed that high density syntactic foams demonstrate poor damage tolerance and low …

Influence Of Composition And Heat-Treatment On The Charge Transport Properties Of Poly(3-Hexylthiophene) And [6,6]-Phenyl C61-Butyric Acid Methyl Ester Blends, Jinsong Huang, Gang Li, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C₆₁-butyric acid methyl ester (PCBM) blends have been demonstrated to form highly efficient polymer photovoltaic devices. In this letter, the time-of-flight technique is used to investigate the influence of composition and heat treatment on charge transport properties of P3HT and PCBM blends. The transport of electrons and holes both display a transition from dispersive to nondispersive and return to dispersive again as the percentage of PCBM increases. A balanced mobility of both electron and hole is obtained at a composition of 1:1 weight ratio, and it is nearly independent of the electrical field in …

Effect Of Microstructure And Alloying Elements On The Resistance Of Fastener Grade Steels To Hydrogen Assisted Cracking , Nicholas E. Nanninga

Dissertations, Master's Theses and Master's Reports - Open

Fastener grade steels with varying alloy contents and heat treatments were employed to measure changes in resistance to hydrogen assisted cracking. The testing procedure compared notched tension specimens fractured in air to threshold stress values obtained during hydrogen charging, utilizing a rising step load procedure. Bainitic structures improved resistance by 10-20% compared to tempered martensite structures. Dual phase steels with a tempered martensite matrix and 20% ferrite were more susceptible and notch sensitive. High strength, fully pearlitic structures showed an improvement in resistance. Carbon content, per se, had no effect on the resistance of steel to hydrogen assisted cracking. Chromium …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository, Dhanesh Chandra, Jaak J.K. Daemen, Jaime Gonzalez, Raymond Keeler, Amy J. Smiecinski

Publications (YM)

The objective of the proposed investigation is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. In critical areas, it is possible to use highly corrosion resistant steels for rock bolts at Yucca Mountain (YM) repository, as the steel rock bolts, as well as other materials such as Bernold type shields for tunnels at YM site [1-4]. In addition, there is propensity for stress corrosion cracking as well as hydrogen induced cracking in rock bolts likely to occur in YM repository emplacement under drift conditions. As corrosion of these materials for underground support …

Oxidation Of Titanium In Alpha-Calf Serum Solution, Ali Stait Ismailoglu

Masters Theses

Titanium and its alloys have been used extensively in orthopedic implants mainly because of its excellent biocompatibility. This biocompatibility is attributed to its surface oxide film (3-7 nm thickness) that forms immediately upon exposure of titanium to air. In the research, the oxidation of Ti-6Al-4V in alpha-calf serum solution was studied. Four different immersion times were tested. Characterization of surface topography and its chemical composition was examined using Atomic force microscopy (AFM), Fourier transform-infrared radiation (FT-IR), and X-ray photoelectron spectroscopy (XPS). The AFM results clearly show the gradual change that occurred in the samples topography which is associated with more-rounded …

Stress Corrosion Cracking Resistance Of Martensitic Stainless Steels For Transmutation Applications, Phani P. Gudipati

UNLV Theses, Dissertations, Professional Papers, and Capstones

The susceptibility of Alloy EP-823 to stress corrosion cracking has been evaluated using smooth and notched cylindrical specimens in neutral and acidic solutions at ambient and elevated temperatures using constant load and slow strain rate testing (SSR) techniques. C-ring and U-bend specimens have also been tested in the acidic solution. The effect of hydrogen on the cracking susceptibility has been evaluated under controlled cathodic potential. While no failures were observed with smooth specimens at constant load, the notched specimens showed failure. The SSR test results indicate that the true failure stress (o'_f), time to failure and ductility parameters …

Cfd Analysis Of 3-D Thermalhydraulics Flow Effects On Wall Concentration Gradient Profiles For Lbe Loop Fittings, Narain Armbya

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of the thesis is to study the effects of thermalhydraulics flows on the wall concentration gradient profiles in LBE loop fittings. To that end detailed models of the fittings have been constructed to study these effects. These fittings include sudden expansion, sudden contraction, t-joint and elbow. The typical flow rates chosen for these simulations are typical of design criteria chosen for the loop with Reynolds numbers expected around 200,000 and the usual axial temperature profiles which are being characterized in the DELTA loop at LANL. STAR-CD is the simulation package used to make these predictions, which include detailed …

Stress Corrosion Cracking And Hydrogen Embrittlement Of Martensitic Alloy Ep-823, Mohammad K. Hossain

UNLV Theses, Dissertations, Professional Papers, and Capstones

This investigation is focused on the evaluation of stress corrosion cracking (SCC), localized corrosion, and hydrogen embrittlement (HE) susceptibility of martensitic Alloy EP-823 in neutral and acidic solutions at ambient and elevated temperatures. While no failures were observed in smooth specimens in the neutral solution, failures were noticed in the 90°C acidic solution at constant-load (CL) leading to a threshold stress (O'_th) of 102 ksi. The presence of a notch reduced the O'_th value to 91 ksi in a similar environment. The ductility (%El and %RA), time-to-failure (TTF), and true failure stress (O'_r) were gradually …