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Ab Initio Simulations For Oxidation Of An Ultra-High Temperature Ceramic (Hfb2), Wesley I. Black
Ab Initio Simulations For Oxidation Of An Ultra-High Temperature Ceramic (Hfb2), Wesley I. Black
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Ultra-High Temperature Ceramics are a class of ceramics that possess high strength and melting points in excess of 3000°C. These ceramics are promising for aerospace applications, where materials need to endure high-temperature and high-stress environments. Utilizing ab initio simulations, this thesis research focuses on the atomistic details of oxidation for a typical ultra-high temperature ceramic material, namely hafnium diboride. The simulations provide energy barriers for transition from the initial to final structures via transition states on the (0 0 0 1) surface. These result in estimates for reaction rates and other thermodynamic features that are essential for assessing applicability under …
Study Of Fiber-Loaded Slurries For Ceramic Matrix Composite Fabrication By Additive Manufacturing, Gaspard Matondo
Study Of Fiber-Loaded Slurries For Ceramic Matrix Composite Fabrication By Additive Manufacturing, Gaspard Matondo
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We studied the additive manufacturing of an alumina-matrix composite reinforced with alumina fibers using the Admatec Admaflex 3D printer, which utilizes digital light processing technology. Oxide-oxide composites are composite materials in which both the matrix and the reinforcing element are ceramic oxides. Monolithic alumina ceramic exhibits a good combination of thermal and mechanical properties, including thermal shock resistance, high melting point, thermal oxidation resistance, good thermal conductivity, hardness, and mechanical strength. However, it is very brittle. Introducing alumina fiber as a reinforcing material into the alumina matrix is expected to enhance mechanical properties, particularly toughness, making the ceramic matrix composite …
Production Of Cerium Oxide And Zinc Sulfide Composites, Ted Autore
Production Of Cerium Oxide And Zinc Sulfide Composites, Ted Autore
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Zinc sulfide has an infrared cutoff in the LWIR, but its low hardness makes it susceptible to rain erosion and abrasion. A composite of cerium oxide and zinc sulfide that retains an infrared cutoff in the LWIR, and with hardness higher than pure zinc sulfide is a potential solution to the rain erosion and abrasion issue. Several different processes were undertaken in this project to produce such a composite. The different reactions between ZnS and CeO2 were researched, along with the effects of different processing parameters. Composite samples were made that had a better hardness than zinc sulfide but did …
Fabricating And Analyzing Liquid And Polymer Electrolytes For Sodium Ion Batteries, Kekule Augustine
Fabricating And Analyzing Liquid And Polymer Electrolytes For Sodium Ion Batteries, Kekule Augustine
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The abundance and the cost-effectiveness of sodium resources have made sodium-ion batteries (SIBs) viable alternatives to lithium-ion batteries. Developing low-cost and high-performance electrolytes is one of the key areas for the advancement of SIB technology. The highly conductive liquid or solid electrolytes have the potential for practical sodium-ion battery applications. Long-term stability, alternative polymers, and full-cell integrations are other avenues that need further research to improve scalability and performance for SIBs. This research covers preparing and evaluating liquid and polymer electrolytes, with a focus on ionic conductivities. Liquid electrolytes were prepared by the dissolution of different sodium salts including NaCl, …
Direct Ink Write Processing Of Signal Crossovers Using Aerosol Jet Printing Method, Lucas A. Clark
Direct Ink Write Processing Of Signal Crossovers Using Aerosol Jet Printing Method, Lucas A. Clark
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Electronics in different applications, such as in medical imaging devices, radar systems, communication transmitters, and optical drives, often require various power and signal lines to be integrated at board level. In such cases, different lines may cross over one another in three-dimensional space for efficient electronic integration. Crossovers are usually achieved by adding additional layers to a PCB. However, these additional layers increase the cost, weight, and complexity of the component. By creating a process and structure to offer board-level heterogenous integration, these factors may be reduced. RF-DC crossovers were designed and additively manufactured using an aerosol jet printer. Benzocyclobutene …
Processing And Characterization Of Inkjet Printed Batio3/Su-8 Nanocomposite Dielectrics, Mustapha A. Muhammad
Processing And Characterization Of Inkjet Printed Batio3/Su-8 Nanocomposite Dielectrics, Mustapha A. Muhammad
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The persistent demand for flexible and wearable electronic components in healthcare, aerospace, media, and transit applications has led to a significant shift from traditional electronics processes to printed electronics. Printed electronics are anticipated to establish itself as the industry's dominant force due to their enhanced flexibility, rapid prototyping capabilities, and seamless integration with everyday objects. They are cost-effective and have the scalable option for large-scale production because additive manufacturing techniques are used. Among the various printing methods available, inkjet printing has recently gained popularity for printing electronics, especially capacitors that require precise and complex structures on different substrates. Inkjet printing …
Rheological Modeling And Inkjet Printability Of Electrode Ink Formulation For Miniature And Interdigital Lithium-Ion Batteries, Habib Temitope-Adebayo Ajose
Rheological Modeling And Inkjet Printability Of Electrode Ink Formulation For Miniature And Interdigital Lithium-Ion Batteries, Habib Temitope-Adebayo Ajose
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The rapid advancement of technology has resulted in a greater need for effective energy storage systems to meet the demands of the transportation and electronics industries. Among various energy storage systems, batteries are the most widely used, primarily because of their ability to store significant amounts of energy. In addition, lithium-ion batteries are prevalent for powering portable electronic devices due to their long cycle life, high energy density, and high operating voltage. The traditional doctor-blade approach has been used over the years for producing batteries. Currently, research is being directed to additively manufacture Li-ion batteries via Drop-on-Demand Inkjet Printing with …
Comparative Study Of Mof's In Phosphate Adsorption, Eniya Karunamurthy
Comparative Study Of Mof's In Phosphate Adsorption, Eniya Karunamurthy
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High concentrations of phosphate are known to adversely affect the environment. Excess phosphate can lead to eutrophication that eventually fosters uncontrollable growth of aquatic plants and algae. This can result in depletion of oxygen content which adversely impacts underwater organism’s survival rates. Metal organic frameworks (MOFs) consist of organic linkers in conjunction with metal ions or clusters arranged within a crystalline structure. They are highly porous and have larger surface area due to their ability to possess extensive void spaces while remaining bulky in nature. MOFs can absorb phosphate from aqueous solutions. We have investigated the use of commercially available …
Characterization Of Aerosol Jet Printed Silver Thin Films Sintered By A Scanning Laser, William A. Metzger
Characterization Of Aerosol Jet Printed Silver Thin Films Sintered By A Scanning Laser, William A. Metzger
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Direct write printing, which is part of additive manufacturing (AM) technology, offers unique capabilities that can complement traditional methods of electronics fabrication. Printing of electrical interconnects via aerosolization is one of the areas in AM that is very important in electronics fabrication. Post-print sintering is a critical step in printed electrical interconnects because it strongly influences the electrical resistivity of the interconnects. Interconnects require the lowest possible resistivity to achieve better performance. Thermal sintering is the most common technique employed in printed interconnects. However, it is limited to substrates that can handle the high temperature requirement for sintering. For polymers …
Influence Of Fill Percentage And Baking Parameters On The Feedability Of Metal-Cored Arc Welding Wires, Angelica Marie Black
Influence Of Fill Percentage And Baking Parameters On The Feedability Of Metal-Cored Arc Welding Wires, Angelica Marie Black
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Adequate feedability is essential for GMAW processes to ensure efficiency. The feedability of a wire refers to the wire’s ability to feed continuously through the contact tip. While there are several known causes of feedability difficulties when using cored welding wires, there are many variables that have yet to be explored thoroughly. Three factors are investigated in this research to determine their effects on feedability of cored wires: fill percentage, baking time, and baking temperature. A set of metal-cored arc welding wires were created with various fill percentages, baking times, and baking temperatures. Tension testing, microhardness testing, microstructural characterization, and …
Effect Of Build Geometry And Build Parameters On Microstructure, Fatigue Life, And Tensile Properties Of Additively Manufactured Alloy 718, Anna Dunn
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Additive Manufacturing (AM), particularly laser powder bed fusion, is being studied for use in critical component applications. Tensile and fatigue testing shows differences when built using different laser powers. However, when fabricated in an as-printed geometry, the gauge sections of the two specimens are different and experience different thermal behavior. This work explores microhardness, microstructure size, Niobium segregation, and porosity from samples made with varying laser power and different build geometry sizes representative of the gauge sections in the tensile and fatigue bars. Results show that microhardness varies spatially across the sample. Smaller diameter metallographic coupons (fatigue diameter) have a …
Ab Initio Methylammonium Orientation And Monolayer Effects In Hybrid Perovskite Solar Cells, Jacob M. Artz
Ab Initio Methylammonium Orientation And Monolayer Effects In Hybrid Perovskite Solar Cells, Jacob M. Artz
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Methylammonium lead triiodide (MAPbI3) has garnered attention due to their high solar cell efficiencies and low cost to manufacture, but commercialization is not yet possible owing to poor environmental stability. Thus, researchers seek ways which optimize the performance of the MAPbI3 solar cell by modifying the architecture and through interfacial engineering of the charge transport layers. Difficulties in understanding these devices arise from ion migration, charge separation and recombination, and metastable, thermally active precessions of the methylammonium (MA) moiety in the lead iodide framework. In this work, focus is given to the perovskite and an adsorbed monolayer, 2,3,4,5,6-pentafluorothiophenol (C6F5SH), which …
Ab Initio Methylammonium Orientation And Monolayer Effects In Hybrid Perovskite Solar Cells, Jacob M. Artz
Ab Initio Methylammonium Orientation And Monolayer Effects In Hybrid Perovskite Solar Cells, Jacob M. Artz
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Methylammonium lead triiodide (MAPbI3) has garnered attention due to their high solar cell efficiencies and low cost to manufacture, but commercialization is not yet possible owing to poor environmental stability. Thus, researchers seek ways which optimize the performance of the MAPbI3 solar cell by modifying the architecture and through interfacial engineering of the charge transport layers. Difficulties in understanding these devices arise from ion migration, charge separation and recombination, and metastable, thermally active precessions of the methylammonium (MA) moiety in the lead iodide framework. In this work, focus is given to the perovskite and an adsorbed monolayer, 2,3,4,5,6-pentafluorothiophenol (C6F5SH), which …
Functionalizing Ceramic Matrix Composites By The Integration Of A Metallic Substructure With Comparable Feature Size, Elizabeth Pierce Heckman
Functionalizing Ceramic Matrix Composites By The Integration Of A Metallic Substructure With Comparable Feature Size, Elizabeth Pierce Heckman
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A metallic network has been embedded in a silicon carbide fiber– silicon carbide (SiC) matrix ceramic composite (CMC) in order to combine the functional properties of the metal and the structural properties of the CMC. The processing of the composite involves iterative pre-ceramic polymer infiltration and heating to temperatures at 1100°C. The metallic structure embedded in the CMC must retain its unique properties during processing and cannot convert to a silicide or carbide resulting from diffusion of Si and C species from the SiC matrix. To gain an understanding of the diffusion process, a fully processed CMC with tungsten, tantalum, …
Fabrication And Analysis Of High-Performance Thermochemically Densified Wood, Victor Arulappan Pushparaj
Fabrication And Analysis Of High-Performance Thermochemically Densified Wood, Victor Arulappan Pushparaj
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While wood construction may be as ancient as humanity itself, wood remains one of the most utilized structural materials because of it’s availability, low cost, durability, surprisingly high specific mechanical properties, and renewability. Recent research into wood-based materials has focused on strategies for enhancing the strength and stiffness of as-grown materials. We fabricated densified wood by thermochemically treating raw white oak wood in Na2SO3 and NaOH solutions, followed by compressing the treated wood at 5MPa at high temperature. Treating the raw wood in NaOH and Na2SO3 cleaves the alpha-O-4 ether bond and beta-O-4 ether bonds, thus dissolving most of the …
Aqueous Fabrication Of Pristine And Oxide Coated Znse Nanoparticles, Nicholas L. Van Zandt
Aqueous Fabrication Of Pristine And Oxide Coated Znse Nanoparticles, Nicholas L. Van Zandt
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Semiconducting nanoparticles have received significant attention due to their unique optoelectronic properties. Quantum dots (QDs), a class of spherical nanoparticles, possess a size-dependent bandgap and photoluminescence at visible wavelengths. QDs have many applications including biological labelling, solar cells, chemical impurity detection, and optical glasses. Doping QDs into optical glasses is highly desirable. High-quality QDs can be synthesized via liquid solution methods. However, solution-synthesized QDs often degrade over time and they cannot survive incorporation into a glass melt without protection. In this work, the aqueous synthesis of ZnSe QDs and coating with nanometer silica and alumina protective shells are investigated. The …
The Thermal And Mechanical Characteristics Of Lithiated Peo Lagp Composite Electrolytes, Jacob Michael Denney
The Thermal And Mechanical Characteristics Of Lithiated Peo Lagp Composite Electrolytes, Jacob Michael Denney
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Lithium-ion batteries are part of a multibillion-dollar industry that strives to meet the demands for an increasingly advanced technological future. Flexible batteries can be easily adapted from emerging novel wearable electronics to electrical vehicles and advanced solar panels. Solid-state batteries can greatly reduce the risk of fire or leaking hazardous materials due to puncture. For the development of solid-state flexible lithium based batteries polymer-ceramic composites are attractive electrolyte candidates because of their combined properties, such as electrical, thermal and mechanical properties, that not only overcome limitations from the base materials but may also render some enhanced performances resulting from the …
Ab Initio Modeling Of An Electron Transport Layer Interface In Hybrid Perovskite Solar Cells, Krantikumar Subhash Pawar
Ab Initio Modeling Of An Electron Transport Layer Interface In Hybrid Perovskite Solar Cells, Krantikumar Subhash Pawar
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Hybrid organic-inorganic perovskite solar cell is an emerging technology which has shown the fastest advancement in power conversion efficiency within a few years since introduction, thus making it one of the clean energy breakthroughs. These cells are based on thin-film technology which makes them suitable to manufacture using low-cost solution processing methods. As these types of cells are easily tunable with the selection of different materials, interfacial engineering is an important approach to increasing their efficiency. One of the main hurdles in this regard is the loss caused by the recombination of separated charges. An approach to tackle these issues …
Metal Coupon Testing In An Axial Rotating Detonation Engine For Wear Characterization, Gary S. North
Metal Coupon Testing In An Axial Rotating Detonation Engine For Wear Characterization, Gary S. North
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Rotating Detonation Engines (RDE) are being explored as a possible way to get better fuel efficiency for turbine engines than is otherwise possible. The walls of the RDE are subjected to cyclic thermal and mechanical shock loading at rates of approximately 3 KHz, with gas temperatures as high as 2976 K. This project performed testing with Inconel 625 and 304 stainless steel coupons in an RDE outer body to attempt to measure material ablation rates. Significant microstructural changes were observed to include grain growth in both alloys, carbide formation and grain boundary melting in Inconel, and formation of delta ferrite …
Stabilization Of Β-Cristobalite In The Sio2-Alpo4-Bpo4 System, Kathryn Doyle
Stabilization Of Β-Cristobalite In The Sio2-Alpo4-Bpo4 System, Kathryn Doyle
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Fused silica (silica glass) is transparent in the optical and near-infrared and has a low dielectric constant, making it suitable as a window material for radio frequency radiation. However, at high temperatures (>1100C), fused silica will easily creep and lose dimensional stability. Crystallized silica is much more creep resistant than fused silica. Silica crystallizes to many different structures including quartz, tridymite, and α- and β cristobalite. The only cubic polymorph, which is suitable for both optical and radio frequency transmission in polycrystalline form, is β -cristobalite. Unfortunately, this polymorph transforms to α-cristobalite at ~300C, and the volume change during …
Growth Of Two-Dimensional Molybdenum Disulfide Via Chemical Vapor Deposition, Zachary Durnell Ganger
Growth Of Two-Dimensional Molybdenum Disulfide Via Chemical Vapor Deposition, Zachary Durnell Ganger
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Graphene has successfully been a 2D material applied in various fields, but it is not the most appropriate candidate for many electronic devices unless its bandgap structure is tuned through functionalization. Among all other 2D material families, transition metal dichalcogenides (TMDs), represented by molybdenum disulfide (MoS2), are promising and emerging in power electronics due to their large direct bandgap and other electronic properties. 2D MoS2 has been fabricated through different approaches such as mechanical exfoliation, chemical etching, and chemical vapor deposition (CVD). The current major challenge in fabricating 2D MoS2 films is to produce a high-quality large-area monolayer film at …
Hierarchical Carbon Structures With Vertically- Aligned Nanotube Carpets For Oil-Water Separation Under Different Conditions, Kimia Kiaei
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The primary purpose of this study is to investigate the role of surface nano-structuring in fluid separation. It is hypothesized that hierarchical carbon structures consisting of aligned carbon nanotube arrays strongly adhered to the surface of porous carbon solids such as fabric and foam, can be used for separation of polar and non-polar fluids by selective wettability of one fluid and rejection of another. The vertically-aligned carbon nanotube arrays, as synthesized, possess super hydrophobicity demonstrated by high water contact angle on their surfaces. On the other hand, they are incredibly oleophilic, showing a high affinity to adsorb oil. These properties …
Multi-Sensor Approach To Determine The Effect Of Geometry On Microstructure In Additive Manufacturing, Joseph R. Walker
Multi-Sensor Approach To Determine The Effect Of Geometry On Microstructure In Additive Manufacturing, Joseph R. Walker
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Laser powder bed fusion (LPBF) is an additive manufacturing technique used for making complex parts through a layer-by-layer process with fine feature resolution. However, the layer-by-layer process, with complex scanning patterns within each layer, introduces variability in thermal behavior leading to inconsistent microstructure and defects. The in- situ process monitoring approach in this work uses sensors including a high-speed visible camera, thermal camera, and spectrometer to evaluate each location in the LPBF process. Each sensor focuses on a different process phenomenon such as the melt pool or thermal behavior. An experimental study, using metallographic analysis and collection of sensor data, …
Deposition Of Nanoparticles Or Thin Films Via Magnetron Sputtering Towards Graphene Surface Functionalization And Device Fabrication, Bridget Jul Larson
Deposition Of Nanoparticles Or Thin Films Via Magnetron Sputtering Towards Graphene Surface Functionalization And Device Fabrication, Bridget Jul Larson
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Graphene, a 2-dimensional single layer of carbon, has high carrier mobility, strength and electrical conductivity. Due to the absence of a band gap and chemical reactivity, pristine graphene has less competitiveness in semiconductors and sensors. Functionalizing graphene is imperative in the development of advanced applications. Among various wet chemical or physical vapor deposition, magnetron sputtering is cost-effective, minimum maintenance, user-friendly, and can be used to rapidly deposit nano-particulates or thin films with less contaminations on any substrates surface. This study is to investigate the morphology evolution of the deposited films using magnetron sputtering and to find appropriate conditions for nanoparticulate …
Preparation And Characterization Of Porous Pdms For Printed Electronics, Eyad Khalid M. Balbaid
Preparation And Characterization Of Porous Pdms For Printed Electronics, Eyad Khalid M. Balbaid
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Fabricating an elastomeric substrate with internal features could provide a novel structure with distinctive mechanical properties that allow them to stretch, bend and absorb the impact force. To date, polydimethylsiloxane (PDMS) is a great candidate as a substrate for flexible electronic applications, due to easy fabrication, high stability and low cost. In the current thesis, porous PDMS samples are fabricated and characterized based on the particle size and the fusion of salt and sugar treated micro-regions. The liquid PDMS is prepared by mixing the silicon elastomer base (Sylgard 184) and elastomer curing agent using volume ration 10:1. The salt and …
Electronic And Crystalline Characteristics Of Mixed Metal Halide Perovskite Semiconductor Films, Patrick Joseph Cleaver
Electronic And Crystalline Characteristics Of Mixed Metal Halide Perovskite Semiconductor Films, Patrick Joseph Cleaver
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Solar technology has a long history of incremental improvements in cost, reliability and efficiency. However, solar cells based on lead halide perovskite films have made more rapid leaps forward in the past 10 years, making it the fastest growing solar technology in terms of efficiency. Leaders in academia and industry continue to find success in overcoming manufacturability and stability issues, but have not yet discovered a high-efficiency perovskite film without the use of toxic lead. Probing less toxic analogs to the highly efficient lead halide, a series of thin films with perovskite structures, i.e. A2BB’X6 where A = Cs or …
Microstructural Characterization Of LensTm Ti-6al-4v: Investigating The Effects Of Process Variables Across Multiple Deposit Geometries, Laura Christine Davidson
Microstructural Characterization Of LensTm Ti-6al-4v: Investigating The Effects Of Process Variables Across Multiple Deposit Geometries, Laura Christine Davidson
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Laser based additive manufacturing of Ti-6Al-4V components is under consideration for aerospace applications. The mechanical properties of the finished components depend on their microstructure. Process mapping compares process variables such as heat source power, heat source travel speed, material feed rate, part preheat temperature and feature geometry to process outcomes such as microstructure, melt pool geometry and residual stresses. In this work, the microstructure of two-dimensional pads, multilayer pads, thin walls, and structural components at the steady state location was observed. A method for measuring β grain widths that allows for the calculation of standard deviations, confidence intervals, and variances …
Defect Engineering: Novel Strengthening Mechanism For Low- Dimensional Zinc Oxide Nanostructures, Seyed Emad Rezaei
Defect Engineering: Novel Strengthening Mechanism For Low- Dimensional Zinc Oxide Nanostructures, Seyed Emad Rezaei
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The advent of nanomaterials has opened a new avenue for designing and fabricating materials with unique properties, e.g., superior mechanical properties. Based on a common notion, the perfect structures are assumed to exhibit better mechanical properties, such as higher yield strength and Young's modulus. Therefore, researchers have devoted an extensive amount of time to decrease defect concentration by fabricating materials with the micro/nanoscale, e.g., nanowires (NWs) and nanobelts (NBs), to enhance the mechanical characteristics of the system. However, defects are a part of the fabrication process and precise control over synthesizing procedure is needed to eliminate them from the material. …
Functionalization And Characterization Of Chemical Vapor Deposited Graphene Sheets Towards Application In Chemical Vapor Sensing, Nicholas Alexander Engel
Functionalization And Characterization Of Chemical Vapor Deposited Graphene Sheets Towards Application In Chemical Vapor Sensing, Nicholas Alexander Engel
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Chemical/biological sensors serve many purposes in protecting machinery, the environment, and human life/wellness. Graphene, a two-dimensional (2-D) material made up of carbon atoms in a honeycomb-like lattice, is promising for applications to chemical/biological sensing due to its unique properties. Functionalization of graphene by surface decorating with nanoparticles and increasing interior adsorption sites can tailor its catalytic activity and electrical properties, and hence, important for detecting and distinguishing trace hazardous gases. This research introduces two different approaches to functionalize graphene towards enhanced sensitivity and selectivity of graphene-based sensors. The morphologies, structures, and electrical properties of the functionalized graphene are systematically characterized. …
Friction Stir Welding Between Similar And Dissimilar Materials, Khaled Yousif Ali
Friction Stir Welding Between Similar And Dissimilar Materials, Khaled Yousif Ali
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This thesis focuses on the friction stir welding (FSW) between similar and dissimilar alloys. FSW is a solid state joining process that welds the work-pieces through a combination of heat generated by friction and mechanical stirring of the metals in the region of the joint. Being a solid state process, FSW can be used to weld alloys with significantly different melting points. This provides a significant benefit over traditional fusion welding process in a variety of applications in automotive, biomedical, aerospace, nuclear and petroleum industries. Two materials - an aluminum alloy (6061-T6, m.p. 582 - 652°C) and a steel (SAE …