Engineering Science and Materials Commons^™

Assessing Change In Runoff Water Parameters Through Road Shoulder Vegetated Filter Strips: Experimental Comparison Of Soils And Engineered Infiltration Media, Andrew Corrado, Mohammad Shokri

The Pegasus Review: UCF Undergraduate Research Journal

Placement of Vegetated Filter Strips (VFS) along roadways may facilitate removal of nutrients from stormwater runoff. The objective of this research is to compare water quality performance of a VFS containing engineered media to that of typical Florida sandy soil. Storms of variable intensity were simulated over two 1:1 scale physical models of typical one- and two-lane roadway shoulders, one with engineered media (treatment), and one without (control). Simulated roadway runoff was introduced as sheet flow from the roadway and precipitation was applied with a rainfall simulator. Samples of runoff and infiltrate were tested for Dissolved Oxygen (DO) concentration and …

Nanoscale Spectroscopy In Energy And Catalytic Applications, Yi Ding

Electronic Theses and Dissertations

Emerging societal challenges such as the need for more sustainable energy and catalysis are requiring more sensitive and versatile measurements at the nanoscale. This is the case in the design and optimization of new materials for energy harvesting (solar cells) and energy storage devices (batteries and capacitors), or for the development of new catalysts for carbon sequestration or other reactions of interest. Hence, the ability to advance spectroscopy with nanoscale spatial resolution and high sensitivity holds great promises to meet the demands of deeper fundamental understanding to boost the development and deployment of nano-based devices for real applications. In this …

Analysis Of Residual Stress And Damage Mechanisms Of Thermal Barrier Coatings Deposited Via Ps-Pvd And Eb-Pvd, Linda Rossmann

Electronic Theses and Dissertations

Thermal barrier coatings (TBCs) are critical to gas turbine engines, as they protect the components in the hot section from the extreme temperatures of operation. The current industry standard method of applying TBCs for turbine blades in jet engines is electron-beam physical vapor deposition (EB-PVD), which results in a columnar structure that is valued for its high degree of strain tolerance. An emerging deposition method is plasma-spray physical vapor deposition (PS-PVD), capable of producing a variety of customizable microstructures as well as non-line-of-sight deposition, which allows more complex geometries to be coated, or even multiple parts at once. The pseudo-columnar …

Lithium Polysulfide Battery With Improved Capacity And Cycle Performance Using Carbon Black Coated Free-Standing Carbon Cloth, Zhen Wei

Electronic Theses and Dissertations

Lithium ion batteries (LIBs) have been used in various applications such as portable electronics, grid storages, and electric vehicles (EVs). Despite its commercial success, further advancement of the battery is necessary to satisfy the increasing demands for low-cost and high- performance energy storage devices as LIB is reaching its theoretical limits. Lithium sulfur battery (LSB) is one of the promising candidates for the next generation energy storage technologies. LSB uses sulfur cathode which is a low-cost and earth abundant material with an extremely high theoretical capacity of 2600 Wh kg-1. Although there have been numerous researches aiming to establish the …

Interfacial Behavior In Polymer Derived Ceramics And Salt Water Purification Via 2d Mos2, Hao Li

Electronic Theses and Dissertations

In the present dissertation, the behavior of the internal potential barrier in a polymer-derived amorphous SiAlCN ceramic was studied by measuring its complex impedance spectra at various dc bias as well as different testing and annealing temperatures. The complex impedance spectra of the polymer-derived a-SiAlCN were measured under various dc bias voltages in a temperature range between 50 and 150°C, as well as different annealing temperatures (1100-1400 °C). All spectra, regardless of temperature and bias, consist of two semi-circular arcs, corresponding to the free-carbon phase and the interface, respectively. The impedance of the free-carbon phase is independent of the bias, …

Fabrication And Characterization Of Nonlinear Optical Ceramics For Random Quasi-Phase-Matching, Xuan Chen

Electronic Theses and Dissertations

A number of technologies rely on the conversion of short laser pulses from one spectral domain to another. Efficient frequency conversion is currently obtained in ordered nonlinear optical materials and requires a periodic spatial modulation of their nonlinear coefficient which results in a narrow bandwidth. One can trade off efficiency for more spectral bandwidth by relaxing the strict phase-matching conditions and achieve nonlinear interaction in carefully engineered disordered crystalline aggregates, in a so-called random quasi-phase-matching (rQPM) process. In this dissertation, we examine appropriate fabrication pathways for (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-PT) and ZnSe transparent ceramics for applications in the mid-IR. The main challenge …

Development Of S-Nitroso-N-Acetylpenicillamine (Snap) Impregnated Medical Grade Polyvinyl Chloride For Antimicrobial Medical Device Interfaces, Corbin Feit

Electronic Theses and Dissertations

In the clinical setting, polyvinyl chloride (PVC) accounts for 25% of all polymers used in medical device applications. However, medical devices fabricated with PVC, such as endotracheal tubes, extracorporeal circuits (ECCs), or intravenous catheters suffer from thrombosis and infection. Mortality associated with hospital associated infections (HAIs) exceed 100,000 deaths each year. One method to overcome these challenges is to develop bioactive polymers with nitric oxide (NO) release. Nitric oxide exhibits many physiological roles including, antibacterial, antithrombic, anti-inflammatory activity. In this study, Tygon® PVC tubing was impregnated with a NO donor molecule, S-nitroso-N-acetylpenicillamine (SNAP), via a simple solvent-swelling-impregnation method, where polymer …

Development Of In Vitro Point Of Care Diagnostics (Ivpcd) Based On Aptamers Integrated Biosensors, Nileshi Saraf

Electronic Theses and Dissertations

The global market for the medical diagnostic industry is worth 25 billion dollars in the United States and is expected to grow exponentially each year. Presently available methods for biodetection, such as immunoassays, chemiluminescence and fluorescent based assays are expensive, time consuming and require skilled labor with high-end instruments. Therefore, development of novel, passive colorimetric sensors and diagnostic technologies for detection and surveillance is of utmost importance especially in resource constrained communities. The present work focusses on developing novel and advanced in vitro biodiagnostic tools based on aptamer integrated biosensors for an early detection of specific viral proteins or small …

The Subject Librarian Newsletter, Engineering And Computer Science, Fall 2017, Buenaventura "Ven" Basco

Libraries' Newsletters

No abstract provided.

The Study Of Physiochemical Properties Of Cerium Oxide Nanoparticles And Its Application In Biosensors, Swetha Barkam

Electronic Theses and Dissertations

Biosensors continue to get smaller and faster with the advancement in nanotechnology through the use of nanomaterials to achieve high sensitivity and selectivity. However, the continued reliance on biomolecules or enzymes in the biosensor assembly poses the problem of reproducibility, storage and complexity. This dissertation research address some of the challenges by investigating the physiochemical properties of nanoparticles to understand its interaction with biological systems and develop enzyme free biosensors. In this study, we have demonstrated a novel strategy to integrate cerium oxide nanoparticles (CNPs) as an efficient transducer through rigorous screening for developing enzyme/label free biosensors for detecting analytes …

Redox-Active Solid State Materials And Its Biomedical And Biosensing Applications, Ankur Gupta

Electronic Theses and Dissertations

Reactive oxygen species (ROS) are byproducts of physiological processes in human body, and strengthened production of ROS is known to cause acute conditions such as inflammation, aging, Alzheimer's disease, melanoma and ovarian cancer, fibrosis and multiple sclerosis. Therefore, early detection of ROS at nanomolar concentration (at cellular level) and developing more potent antioxidants is essential for regular health monitoring. As an example, ROS are also responsible for inflammation reactions at orthopedic implants-tissue interface triggered by wear debris. Inflammation induced by ROS results in revision surgery. Coatings of redox-active materials exhibiting antioxidant properties on implants have potential to mitigate the inflammation …

Polyelectrolyte And Hydrogel Stabilized Liquid Crystal Droplets For The Detection Of Bile Acids, Jinan Deng

Electronic Theses and Dissertations

Liquid crystal (LC) droplets show great potential as an optical probe for sensor applications due to their large surface areas and stimuli-response director configurations. Bile acids with amphipathic properties, which are formed in liver and secreted into the small intestine, play an important role in the digestion of fats and fat-soluble vitamins. After the digestion process, most of bile acids are recycled back to the liver and ready for the next digestion. Only a few of them are excreted into body fluids. However, there is significant increases in the concentration level of bile acids in body fluids for patients with …

Developing An Insider Threat Experimental Environment, Eric Ortiz

Electronic Theses and Dissertations

Simulated, 3D gaming environments have been used for a wide-range of applications including training, entertainment, and experimentation in an assortment of domains for some time. This can be attributed to their unique ability to emulate multifaceted situations that may be difficult to control, while affording participants the opportunity to operate in a relatively safe environment. In cybersecurity research, investigation of insider threat behavior is an endeavor that has received little attention in terms of available environments and resources for experimental manipulation. This research effort aimed to close this gap. A simulated, 3D gaming environment and accompanying scenarios were developed for …

Anisotropy Evolution Due To Surface Treatment On 3d-Printed Fused Deposition Modeling (Fdm) Of Acrylonitrile Butadiene Styrene (Abs), Blake E. Lozinski

Honors Undergraduate Theses

Purpose: This paper will present insight to the methodology and results of the experimental characterization of Acrylonitrile Butadiene Styrene (ABS) using Fused Deposition Modeling (FDM). The work in this research explored the effects of print orientation, surface treatment, and ultraviolet (UV) light degradation with the utilization of Digital Image Correlation (DIC) on ABS tensile specimens.

Design/methodology: ABS specimens were printed at three build orientations (flat (0 degrees), 45 degrees, and up-right (90 degrees)). Each of these specimens were treated with three different surface treatments including a control (acrylic paint, Cyanoacrylate, and Diglycidyl Bisphenol A) followed by exposure to UV light …

Quantification Of The Effect Of Degassing On The Microstructure, Chemistry And Estimated Strength Of Nanocrystalline Aa5083 Powder, Clara Hofmeister

Electronic Theses and Dissertations

Degassing is a critical heat treatment process in aluminum powder metallurgy, where powders are subjected to high temperature in vacuum to remove volatile gaseous species absorbed in and adsorbed on powders. For cryomilled aluminum alloy powders with nanoscale features, degassing can cause accelerated microstructural and chemical changes including removal of volatiles, grain growth, dislocation annihilation, and formation of dispersoids. These changes can significantly alter the mechanical behavior of consolidated components based on their contributions to strength. In this study, cryomilled AA5083 (0.4 wt.% Mn; 4.5 wt.% Mg; minor Si, Fe, Cu, Cr, Zn, Ti; balance Al) powders were degassed at …

Development Of Enzyme-Free Hydrogen Peroxide Biosensor Using Cerium Oxide And Mechanistic Study Using In-Situ Spectro-Electrochemistry, Shashank Saraf

Electronic Theses and Dissertations

During recent development, it has been demonstrated that cerium oxide nanoparticles (CNPs) have exhibited catalytic activity which mimics naturally existing enzymes such as superoxide dismutase (SOD) and catalase. The underlying mechanism is attributed to the modulation of oxygen vacancies on CNPs lattice by dynamic switching of the oxidation states between Ce3+ and Ce4+ due to the electron transfer resulting from the redox reaction between CNPs and reactive oxygen species such as hydrogen peroxide (H2O2). Thereby the redox potential of CNPs is dependent on the surface chemistry i.e. the surface concentration of Ce3+ and Ce4+ Currently, the ratio of Ce3+/ Ce4+ …

Advanced Metrology And Diagnostic Loss Analytics For Crystalline Silicon Photovoltaics., Eric Schneller

Electronic Theses and Dissertations

Characterization plays a key role in developing a comprehensive understanding of the structure and performance of photovoltaic devices. High quality characterization methods enable researchers to assess material choices and processing steps, ultimately giving way to improved device performance and reduced manufacturing costs. In this work, several aspects of advanced metrology for crystalline silicon photovoltaic are investigated including in-line applications for manufacturing, off-line applications for research and development, and module/system level applications to evaluate long-term reliability. A frame work was developed to assess the cost and potential value of metrology within a manufacturing line. This framework has been published to an …

Design Of Surface Chemical Reactivity And Optical Properties In Glasses, Antoine Lepicard

Electronic Theses and Dissertations

Thermal poling is a technique which involves the application of a strong DC electric field to a glass substrate heated below its glass transition temperature (Tg). Following the treatment, a static electric field is frozen inside the glass matrix, effectively breaking its centrosymmetry. Historically, this treatment has been used as a way to gain access to second order non-linear optical properties in glasses. However, recent efforts have shown that the treatment was responsible for structural changes as well as surface property modifications. Our study was focused on using this technique to tailor surface properties in oxide (borosilicate and niobium borophosphate) …

Improved Interpolation In Sph In Cases Of Less Smooth Flow, Oddny Brun

Electronic Theses and Dissertations

We introduced a method presented in Information Field Theory (IFT) [Abramovich et al., 2007] to improve interpolation in Smoothed Particle Hydrodynamics (SPH) in cases of less smooth flow. The method makes use of wavelet theory combined with B-splines for interpolation. The idea is to identify any jumps a function may have and then reconstruct the smoother segments between the jumps. The results of our work demonstrated superior capability when compared to a particular challenging SPH application, to better conserve jumps and more accurately interpolate the smoother segments of the function. The results of our work also demonstrated increased computational efficiency …

Effects Of Thermo-Mechanical Loading From In-Situ Studies Of Eb-Pvd Thermal Barrier Coatings, Melan N. Jansz

Electronic Theses and Dissertations

The thermo-mechanical effects on the strain evolution within an EB-PVD thermal barrier coating (TBC) is presented in this work using in-situ characterization. Synchrotron X-ray diffraction at sector 1-ID at the Argonne National Laboratory provided both qualitative and quantitative in-situ data on the strain evolution under a thermal cycle with mechanical loading. The results show that at a critical combination of temperature and load, the stress in the thermally grown oxide (TGO) layer in the TBC reaches a tensile region. These significant findings enhance existing literature showing purely compressive strains within the TGO where mechanical loads have been neglected. The results …

Calibration Of Alumina-Epoxy Nanocomposites Using Piezospectroscopy For The Development Of Stress-Sensing Adhesives, Amanda L. Stevenson

Electronic Theses and Dissertations

A non-invasive method to quantify the stress distribution in polymer-based materials is presented through the piezospectroscopic calibration of alumina-epoxy nanocomposites. Three different alumina volume fraction nanocomposites were created and loaded under uniaxial compression in order to determine the relationship between applied stress and the frequency shift of the R-lines produced by alumina under excitation. Quantitative values for six piezospectroscopic coefficients were obtained which represent the stress-sensing property of the nanocomposites. The results were applied to an alumina-filled adhesive in a single lap shear configuration demonstrating the capability of the technique to monitor R-line peak positions with high spatial resolution and …

Design Of Sea Water Heat Exchanger For Miniature Vapor Compression Cycle, James Hughes

Electronic Theses and Dissertations

Recent advances in the development of miniature vapor compression cycle components have created unique opportunities for heating and cooling applications, specifically to human physiological requirements that arise in extreme environments. Diving in very cold water between 1.7 and 5°C requires active heating because passive thermal insulation has proven inadequate for long durations. To maintain diver mobility and cognitive performance, it is desirable to provide 250 to 300 W of heat from an untethered power source. The use of a miniature vapor compression cycle reduces the amount of power (batteries or fuel cell) that the diver must carry by 2.5 times …

Effect Of Sodium And Absorber Thickness On Cigs2 Thin Film Solar Cells, Parag Vasekar

Electronic Theses and Dissertations

Chalcopyrites are important contenders among solar cell technologies due to direct band gap and higher absorption coefficient. CuIn1-xGaxS2 (CIGS2) thin-film solar cells are of interest for space power applications because of near optimum bandgap of 1.5 eV for AM0 solar radiation outside the earth's atmosphere. The record efficiency of 11.99% has been achieved on a 2.7 µm CIGS2 thin film prepared by sulfurization at FSEC PV Materials Laboratory. Since CIGS2 films are typically grown in copper-rich regime, excess cuprous sulfide which helps in the formation of CIGS2 is etched away. This makes CIGS2 nearly stoichiometric. However, it is difficult to …

Droplet Flows In Microchannels Using Lattice Boltzmann Method, Amit Gupta

Electronic Theses and Dissertations

Microelectromechanical systems (MEMS) have widespread applications in medical, electronical and mechanical devices. These devices are characterized by the smallest dimension which is at least one micrometer and utmost one millimeter. Rapid progress in the manufacture and utilization of these microdevices has been achieved in the last decade. Current manufacturing techniques of such devices and channels include surface silicon micromachining; bulk silicon micromachining; lithography; electrodeposition and plastic molding; and electrodischarge machining (EDM). In recent years, electrostatic, magnetic, electromagnetic and thermal actuators, valves, gears and diaphragms of dimensions of hundred microns or less have been fabricated successfully. Sensors have been manufactured that …

Study Of The Effects Of Sodium And Absorber Microstructure For The Development Of Cuin1-Xgaxse2-Ysy Thin Film Solar Cell Using An Alternative Selenium Precursor, Vinaykumar Hadagali

Electronic Theses and Dissertations

Thin film solar cells have the potential to be an important contributor to the world energy demand in the 21st century. CuInGaSe2 thin film solar cells have achieved the highest efficiency among all the thin film technologies. A steady progress has been made in the research and development of CuInSe2 based thin film solar cells. However, there are many issues that need to be addressed for the development of CuInSe2 based thin films solar cells. High price of PV modules has been a biggest factor impeding the growth of photovoltaic modules for terrestrial application. This thesis tries to address the …

Study Of Low Speed Transitional Regime Gas Flows In Microchannels Using Information Preservation (Ip) Method, Umit Kursun

Electronic Theses and Dissertations

Proper design of thermal management solutions for future nano-scale electronics or photonics will require knowledge of flow and transport through micron-scale ducts. As in the macro-scale conventional counterparts, such micron-scale flow systems would require robust simulation tools for early-stage design iterations. It can be envisioned that an ideal Nanoscale thermal management (NSTM) solution will involve two-phase flow, liquid flow and gas flow. This study focuses on numerical simulation gas flow in microchannels as a fundamental thermal management technique in any future NSTM solution. A wellknown particle-based method, Direct Simulation Monte Carlo (DSMC) is selected as the simulation tool. Unlike continuum …

Design And Performance Evaluation Of An Integrated Miniature Single Stage Centrifugal Compressor And Permanent Magnet Synchronous Motor, Dipjyoti Acharya

Electronic Theses and Dissertations

An attempt has been made in this present work to design, fabricate and performance evaluate an integrated single stage centrifugal compressor and permanent magnet synchronous motor which is a key component of the reverse brayton cycle cryocooler. An off the shelf compressor – the driven and electric motor – the driver was not available commercially to suffice the requirements of the reverse brayton cryocooler. The integrated compressor-motor system was designed and tested with air as the working fluid at mass flow rate of 7.3 grams per sec, with a compression ratio of 1.58 and driven by a 2 KW permanent …

Commissioning Of A Dynamic Mechanical Analyzerfor The Characterization Of Low Temperature Nitife Shape Memory Alloys, Maruthi Diwakar Nandiraju

Electronic Theses and Dissertations

NiTiFe shape memory alloys can undergo transformations between cubic, trigonal and monoclinic phases at low temperatures. The low hysteresis associated with the trigonal R-phase transformation make them candidates for actuator applications at low temperatures. However, the literature available on these alloys is limited and there is a need to establish processing structure-property correlations. This study was undertaken with the objective of determining and understanding such correlations in a Ni46.8Ti50Fe3.2 alloy. First, a dynamic mechanical analyzer (DMA) was successfully commissioned to facilitate mechanical testing between -150 and 600ºC. The experiments performed over selected ranges of stress and temperature probed a range …

Investigations Of Inertia Effects On An Infinite Solid Cylinder Due To Thermal Shock, Roland Vanderbilt Williams

Retrospective Theses and Dissertations

In this paper the effects of inertia are explored for the case of a thermal excitation applied on the surface of an infinitely long, solid circular cylinder. The linear uncoupled field equations for a homogeneous, isotropic, thermoelastic medium are used to derive the desired field equations of stress and displacement. The solution procedure included, first, the determination of the thermal boundary value problem from the energy equation which is identically satisfied for the uncoupled condition. Secondly, substitution of the strain-displacement relationships and the previously obtained thermal relation into the equilibrium equation containing inertial effects. The equilibrium equation is the only …