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2004

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Articles 1 - 30 of 89

Full-Text Articles in Engineering Science and Materials

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository, Dhanesh Chandra, Jaak J.K. Daemen, Jaime Gonzalez, Raymond Keeler, Amy J. Smiecinski Dec 2004

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository, Dhanesh Chandra, Jaak J.K. Daemen, Jaime Gonzalez, Raymond Keeler, Amy J. Smiecinski

Publications (YM)

The objective of the proposed investigation is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. In critical areas, it is possible to use highly corrosion resistant steels for rock bolts at Yucca Mountain (YM) repository, as the steel rock bolts, as well as other materials such as Bernold type shields for tunnels at YM site [1-4]. In addition, there is propensity for stress corrosion cracking as well as hydrogen induced cracking in rock bolts likely to occur in YM repository emplacement under drift conditions. As corrosion of these materials for underground support …

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Oxidation Of Titanium In Alpha-Calf Serum Solution, Ali Stait Ismailoglu Dec 2004

Oxidation Of Titanium In Alpha-Calf Serum Solution, Ali Stait Ismailoglu

Masters Theses

Titanium and its alloys have been used extensively in orthopedic implants mainly because of its excellent biocompatibility. This biocompatibility is attributed to its surface oxide film (3-7 nm thickness) that forms immediately upon exposure of titanium to air. In the research, the oxidation of Ti-6Al-4V in alpha-calf serum solution was studied. Four different immersion times were tested. Characterization of surface topography and its chemical composition was examined using Atomic force microscopy (AFM), Fourier transform-infrared radiation (FT-IR), and X-ray photoelectron spectroscopy (XPS). The AFM results clearly show the gradual change that occurred in the samples topography which is associated with more-rounded …

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Stress Corrosion Cracking Resistance Of Martensitic Stainless Steels For Transmutation Applications, Phani P. Gudipati Dec 2004

Stress Corrosion Cracking Resistance Of Martensitic Stainless Steels For Transmutation Applications, Phani P. Gudipati

UNLV Theses, Dissertations, Professional Papers, and Capstones

The susceptibility of Alloy EP-823 to stress corrosion cracking has been evaluated using smooth and notched cylindrical specimens in neutral and acidic solutions at ambient and elevated temperatures using constant load and slow strain rate testing (SSR) techniques. C-ring and U-bend specimens have also been tested in the acidic solution. The effect of hydrogen on the cracking susceptibility has been evaluated under controlled cathodic potential. While no failures were observed with smooth specimens at constant load, the notched specimens showed failure. The SSR test results indicate that the true failure stress (o'f), time to failure and ductility parameters …

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Cfd Analysis Of 3-D Thermalhydraulics Flow Effects On Wall Concentration Gradient Profiles For Lbe Loop Fittings, Narain Armbya Dec 2004

Cfd Analysis Of 3-D Thermalhydraulics Flow Effects On Wall Concentration Gradient Profiles For Lbe Loop Fittings, Narain Armbya

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of the thesis is to study the effects of thermalhydraulics flows on the wall concentration gradient profiles in LBE loop fittings. To that end detailed models of the fittings have been constructed to study these effects. These fittings include sudden expansion, sudden contraction, t-joint and elbow. The typical flow rates chosen for these simulations are typical of design criteria chosen for the loop with Reynolds numbers expected around 200,000 and the usual axial temperature profiles which are being characterized in the DELTA loop at LANL. STAR-CD is the simulation package used to make these predictions, which include detailed …

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Stress Corrosion Cracking And Hydrogen Embrittlement Of Martensitic Alloy Ep-823, Mohammad K. Hossain Dec 2004

Stress Corrosion Cracking And Hydrogen Embrittlement Of Martensitic Alloy Ep-823, Mohammad K. Hossain

UNLV Theses, Dissertations, Professional Papers, and Capstones

This investigation is focused on the evaluation of stress corrosion cracking (SCC), localized corrosion, and hydrogen embrittlement (HE) susceptibility of martensitic Alloy EP-823 in neutral and acidic solutions at ambient and elevated temperatures. While no failures were observed in smooth specimens in the neutral solution, failures were noticed in the 90°C acidic solution at constant-load (CL) leading to a threshold stress (O'th) of 102 ksi. The presence of a notch reduced the O'th value to 91 ksi in a similar environment. The ductility (%El and %RA), time-to-failure (TTF), and true failure stress (O'r) were gradually …

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Electrochemical Behaviours Of Hemoglobin-Ddab-Modified Powder Microelectrode And The Application Of The Powder Microelectrode In Determination Of Nitric Oxide, Zhi-Mou Guo, Huan Liu, Jian Chen, Wen-Ting Zhang Nov 2004

Electrochemical Behaviours Of Hemoglobin-Ddab-Modified Powder Microelectrode And The Application Of The Powder Microelectrode In Determination Of Nitric Oxide, Zhi-Mou Guo, Huan Liu, Jian Chen, Wen-Ting Zhang

Journal of Electrochemistry

The electrochemical behaviours of DDAB-Hb-PME were studied in this paper. The (apparent) surface concentration of Hb was enhanced greatly by using the powder microelectrode (technique). NO reacts with Hb and absorbs on the surface of the modified carbon powder. Therefore, the output of the electrode was enhanced greatly by employing PME with higher reaction surface (area). The sensitivity of DDAB-Hb-PME is 3.1 mA/μmol·L-1·cm2, which is much larger than the values obtained with the traditional electrodes. The detection limit is 9 nmol·L-1 and the linear response range is 9～100 nmol·L-1.

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Improvement And Its Mechanism Of Storage Performance Of Ni-Mh Battery, Xiao-Feng Li, Li-Ping Ma, Yu-Wan Lou, Feng Li, Bao-Jia Xia Nov 2004

Improvement And Its Mechanism Of Storage Performance Of Ni-Mh Battery, Xiao-Feng Li, Li-Ping Ma, Yu-Wan Lou, Feng Li, Bao-Jia Xia

Journal of Electrochemistry

The storage performance of nickel-metal-hydride (Ni-MH) battery was studied by using galvanostatic charge-discharge and cyclic voltammetry. The experimental results indicated that CoOOH could not be completely restored after its being thoroughly reduced at lower potential, which might weaken electric conduction network in the positive electrode and result in fading of electrochemical properties of Ni-MH battery. Addition of nickel powder as a conductive agent into the positive electrode was beneficial to the capacity recovery after storage.

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Preparation And Electrochemical Magnesium Insertion Behaviors Of Mgv2O6, Hua-Tang Yuan, Li-Fang Jiao, Jian-Sheng Cao, Xiu-Sheng Liu, Ming Zhao, Yong-Mei Wang Nov 2004

Preparation And Electrochemical Magnesium Insertion Behaviors Of Mgv2O6, Hua-Tang Yuan, Li-Fang Jiao, Jian-Sheng Cao, Xiu-Sheng Liu, Ming Zhao, Yong-Mei Wang

Journal of Electrochemistry

MgV2O6 was synthesized by conventional solid-state reaction from MgO and V2O5 as starting materials. X-Ray diffraction analysis showed that the prepared sample belongs to the monoclinic structure. Electrochemical magnesium insertion from aprotic electrolytes such as organomagnesium halides into this host was found possible and exhibited charge/discharge circulation.

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Study On Mass Transport In Liquid Layer Adjacent To The Electrode Through Transmission Vop-Spectroellipsometry, Wei Zhu, Yu-Ru Yang, Zong-Qing Huang Nov 2004

Study On Mass Transport In Liquid Layer Adjacent To The Electrode Through Transmission Vop-Spectroellipsometry, Wei Zhu, Yu-Ru Yang, Zong-Qing Huang

Journal of Electrochemistry

In electrochemical system, the mass transport process in liquid layer adjacent to electrode is studied through theoretical analysis only.The diffusion process can be analyzed theoretically by Fick's law for homogeneous media. Up to now, none of satisfied experimental method has been reported for studying mass transport of a whole process in liquid media yet. This paper described the experimental approach to explore mass transport in electrochemical system by transmission Vop-spectroellipsometry briefly.

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Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma Nov 2004

Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma

Journal of Electrochemistry

The air electrodes with different mass ratio of Pt/active carbon or carbon nanotube as catalyst layer material have been prepared. The electrocatalytic performances for oxygen reduction were evaluated by means of polarization curve and electrochemical impedance spectroscopy (EIS). The results disclosed that carbon nanotubes dealt with nitric acid in the catalyst layer had been improved obviously on the electrocatalytic activity. After the surface of carbon nanotube was oxygenated and aggraded with platinum, the catalyst had obviously effects on the electrocatalytic activity. The air electrode with the mass ratio of active carbon to Pt/carbon nanotube in 4∶1 showed better electrocatalytic activity, …

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The Investigation Of Bafesi/C Alloy Composite As Anode Materials For Li-Ion Battery, Rui-Xiang Feng, Hua Dong, Xin-Ping Ai, Han-Xi Yang Nov 2004

The Investigation Of Bafesi/C Alloy Composite As Anode Materials For Li-Ion Battery, Rui-Xiang Feng, Hua Dong, Xin-Ping Ai, Han-Xi Yang

Journal of Electrochemistry

A novel BaFeSi/C composite was prepared by mechanical ball milling, and lithium insertion reactions on the composite electrode were investigated by cyclic voltammetry , charge-discharge measurements, XRD and XPS spectroscopy. It is demonstrated that the capacity retention with indiscernible capacity decas during charge-discharge cycling. The improved cycling ability of the composite is suggested from a cooperative action by inactive FeSi2 and BaSi2 matrix and outer graphite shell, which both buffer the volumetric changes of the active Si phase and provide a good connection for electronic and ionic conduction during lithium insertion and extraction processes.

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Electrochemical Investigations On Pitting Susceptibility Of Iron-Based Alloy, Wei-Shan Li, Hong-Yu Chen, Zhong-Zhi Yuan, Hong Li, Qi-Ming Huang, Dong-Sheng Lv Nov 2004

Electrochemical Investigations On Pitting Susceptibility Of Iron-Based Alloy, Wei-Shan Li, Hong-Yu Chen, Zhong-Zhi Yuan, Hong Li, Qi-Ming Huang, Dong-Sheng Lv

Journal of Electrochemistry

The formation process of passive film on iron and electronic properties and pitting susceptibility of an iron-based alloy are investigated by using linear potential sweep, alternative current impedance and electrochemical nose technologies. The relationship between reciprocal square capacitance and potential following the Mott-Schottky behavior is limited at a narrow rang of low potentials. At higher potentials, linear relationship between reciprocal capacitance and potential is obtained, which is ascribed to the increasing thickness of the passive film with potential. The donor density of the passive film is influenced by the formation potential of the film, passivator and microstructure. The decrease in …

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LicoXNi1-XO2 Cathode Materials Prepared By Electrolysis Of Co And Ni, Jin-Ping Wei, Xin Sun, Xiao-Yu Wang, Xi-Kui Bian, Jin-Ling Zhai, Yan-Jie Yan-Jie Nov 2004

LicoXNi1-XO2 Cathode Materials Prepared By Electrolysis Of Co And Ni, Jin-Ping Wei, Xin Sun, Xiao-Yu Wang, Xi-Kui Bian, Jin-Ling Zhai, Yan-Jie Yan-Jie

Journal of Electrochemistry

A new electrolytic method was developed to prepare LiCoxNi1-xO2 as a cathode material of lithium-ion battery. Contrary to the traditional method, electrolytic method is a potential method with simple process to industrialization and no pollution. Metal cobalt and nickel were electrolysed in parallel to prepare the precursor of CoxNi1- x(OH)2.Different compositional precursors could be conveniently prepared by changing electrolytic current. The LiCo0.3Ni0.7O2 cathode prepared by this method was found favorable charge-discharge and cycle properties. For the LiCo0.3Ni0.7O2 cathode material, …

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Applications Of New Activated Carbon Meterials In The Electric Double-Layer Capacitor, Jian-Jun Zhang, Hua Jiang, Jian-Hui Fang, Li-Yi Shi, Ren-He Yin, Yi Wen, Ji-Quan Liu Nov 2004

Applications Of New Activated Carbon Meterials In The Electric Double-Layer Capacitor, Jian-Jun Zhang, Hua Jiang, Jian-Hui Fang, Li-Yi Shi, Ren-He Yin, Yi Wen, Ji-Quan Liu

Journal of Electrochemistry

A new type activated carbon whose precursor was coconut shell could be obtained using specific physics-chemistry activation, and the activated carbon was applied as the material of electrode in EDLC (electrical double-layer capacitor),which had a large specific capacitance, and could charge and discharged in some large currents. Carbon dioxide and acid were used to modify carbon,and the effects of post-treatment on surface area and pore volume were investigated. A moulding method which has influence on some properties of carbon electrode with PTFE additive was researched in the paper.

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Effect Of Fe3+ Dopen Of Titanium Dioxide Film On Absorption Spectra And Photo Catalysis, Mei-Qun Xiao, Jia-Nian Shen, Moucheng Li, Peng-Fei Wu, Dong Liu, Yu-Juan Zhang Nov 2004

Effect Of Fe3+ Dopen Of Titanium Dioxide Film On Absorption Spectra And Photo Catalysis, Mei-Qun Xiao, Jia-Nian Shen, Moucheng Li, Peng-Fei Wu, Dong Liu, Yu-Juan Zhang

Journal of Electrochemistry

Photo-catalytic titanium dioxide film in nano crystalline has been prepared by electrochemical oxidation process and adding different amount of ferric ion into the electrolyte during the anodic oxidation.The effects of Fe3+ dopen on absorption spectra and photo-catalytic of the titanium dioxide films have been studied. It shows that the Fe3+ dopen caused the red shife of the absorption edge for the incoming light and exhibited the improved photocatalytic reactivity.

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Studies On The Electrochemical Preparation And Electrochemical Properties Of Conducting Polymers——Brief Introduction To The Research Work Of Electrochemistry Of Conducting Polymers In Cas Key Laboratory Of Organic Solids(I), Yong-Fang Li Nov 2004

Studies On The Electrochemical Preparation And Electrochemical Properties Of Conducting Polymers——Brief Introduction To The Research Work Of Electrochemistry Of Conducting Polymers In Cas Key Laboratory Of Organic Solids(I), Yong-Fang Li

Journal of Electrochemistry

Conducting polymers have drawn much attention since the discovery of conducting polyacetylene in 1977, due to the novelty and curiosity of their structure and properties as well as their promising applications in many aspects. Among the studies of conducting polymers, the electrochemical preparation and electrochemical properties of conducting polymers are of special importance, because the electropolymerization is a main method for preparing conducting polymer films and the electrochemical properties are the basis for their applications in the fields of electrode materials for batteries, electrocatalysis, electrochromic display, etc. We are one of the earliest research groups in the world to perform …

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Preparation And Photo-Catalyst Properties Of The α-Fe2O3-Tio2 Films On Sodium Alginate Polymer, Li-Qin Chen, Huai-Zhen Zhong, Ri-Yao Chen, Xi Zheng, Zhen Chen Nov 2004

Preparation And Photo-Catalyst Properties Of The α-Fe2O3-Tio2 Films On Sodium Alginate Polymer, Li-Qin Chen, Huai-Zhen Zhong, Ri-Yao Chen, Xi Zheng, Zhen Chen

Journal of Electrochemistry

Three new nano thin films of α-Fe2O3, TiO2 and α-Fe2O3-TiO2 by doping their powder with sodium alginate polymer were prepared. Surface structure and catalytic activities of the films were characterized by FTIR, XRD, PL, TEM and I-V techniques. The results of UV-visible absorption showed that the methylene blue was mineralized in aqueous of α-Fe2O3/SA, TiO2/SA and (α-(Fe2O3))-TiO2 /SA upon radiation with ultra violet light. α-Fe2O3 enhanced their photo-decolorized-activities by doping 15% TiO2.

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Environmental Effects On Corrosion Properties Of Alloy 22, K. S. Raja, L. G. Mcmillion, Shantanu A. Namjoshi, Paige Russel, Raymond E. Keeler, Amy J. Smiecinski Nov 2004

Environmental Effects On Corrosion Properties Of Alloy 22, K. S. Raja, L. G. Mcmillion, Shantanu A. Namjoshi, Paige Russel, Raymond E. Keeler, Amy J. Smiecinski

Publications (YM)

During the regulatory life of the Yucca Mountain High Level Nuclear Waste (HLNW) repository the primary engineered barrier that is to prevent release of radioactive material into the environment is proposed to be a Corrosion-Resistant Material (CRM) outer shell covering the Waste Package (WP) container. The current selection for the CRM is Alloy 22 (UNS N06022), a Ni-Cr-Mo-W-Fe alloy. Alloy 22 forms a defective chromic oxide passive film which results in excellent corrosion resistance; the presence of molybdenum in Alloy 22 offers corrosion resistance in reducing environments as well as oxidizing environments.

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Phase Stability And Segregation In Alloy 22 Base Metal And Weldments, Jeffrey Lacombe, Shantanu A. Namjoshi, Paige Russel, Raymond E. Keeler, Amy J. Smiecinski Oct 2004

Phase Stability And Segregation In Alloy 22 Base Metal And Weldments, Jeffrey Lacombe, Shantanu A. Namjoshi, Paige Russel, Raymond E. Keeler, Amy J. Smiecinski

Publications (YM)

The current design of the waste disposal containers relies heavily on encasement in a multi-layered container, featuring a corrosion barrier of Alloy 22, a Ni-Cr-Mo-W based alloy with excellent corrosion resistance over a wide range of conditions. The fundamental concern from the perspective of the Yucca Mountain Project, however, is the inherent uncertainty in the (very) long-term stability of the base metal and welds. Should the properties of the selected materials change over the long service life of the waste packages, it is conceivable that the desired performance characteristics (such as corrosion reistance) will become compromised, leading to premature failure …

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Long-Term Mechanical Behavior Of Yucca Mountain Tuffs, And Its Variability, Jaak J.K. Daemen, George Danko, Jaime Gonzalez, Amy J. Smiecinski, Raymond E. Keeler Oct 2004

Long-Term Mechanical Behavior Of Yucca Mountain Tuffs, And Its Variability, Jaak J.K. Daemen, George Danko, Jaime Gonzalez, Amy J. Smiecinski, Raymond E. Keeler

Publications (YM)

We propose to continue the investigation of the long term strength of Yucca Mountain tuffs, with particular emphasis on tuffs from and near the emplacement horizon. We propose to also continue and expand the investigation of the spatial variability of rock strength and stiffness. An intrinsic component of this planned rock testing is the testing of rock joints. Although the emphasis is on tests aimed at determining long term strength, as part of the testing measurements of stiffness also are collected, and will be collected, reported, and analyzed.

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Swing-Up And Balancing Nonlinear Control For A Rotational Inverted Pendulum, Jiang Wang Oct 2004

Swing-Up And Balancing Nonlinear Control For A Rotational Inverted Pendulum, Jiang Wang

Mechanical & Aerospace Engineering Theses & Dissertations

In this thesis, nonlinear controllers are designed for the swing-up and balance modes of a rotational inverted pendulum, which is a pendulum hinged on a horizontally rotating link. The proposed control algorithms are designed by partial feedback linearization and sliding mode control techniques, for swing-up and balancing respectively. First a mathematical model of the pendulum dynamics is derived, followed by experimental verification. Then the system model is partially linearized, which makes it possible for the system to track a simple desired trajectory with "pump energy" function. Then a swing-up controller is designed. For an under-actuated mechanical system, like the inverted …

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Science For Stewardship: Multidisciplinary Research On Uss Arizona, Matthew A. Russell, Larry E. Murphy, Donald L. Johnson, Timothy J. Foecke, Pamela J. Morris, Raphy Mitchell Oct 2004

Science For Stewardship: Multidisciplinary Research On Uss Arizona, Matthew A. Russell, Larry E. Murphy, Donald L. Johnson, Timothy J. Foecke, Pamela J. Morris, Raphy Mitchell

Department of Mechanical and Materials Engineering: Faculty Publications

The National Park Service’s Submerged Resources Center and USS Arizona Memorial are conducting and coordinating research directed at understanding the nature and rate of natural processes affecting the deterioration of the USS Arizona in Pearl Harbor, Hawaii. The USS Arizona Preservation Project is designed to be multi-year, interdisciplinary and cumulative, with each element contributing to developing an overall management strategy designed to minimize environmental hazard from fuel oil release and provide the basic research required to make informed management decisions for long-term preservation. The primary project focus is toward acquiring requisite data for understanding the complex corrosion and deterioration processes …

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The Physical Understanding Of The Use Of Coatings To Mitigate Hypervelocity Gouging Considering Real Test Sled Dimensions, Andrew G. Szmerekovsky Sep 2004

The Physical Understanding Of The Use Of Coatings To Mitigate Hypervelocity Gouging Considering Real Test Sled Dimensions, Andrew G. Szmerekovsky

Theses and Dissertations

A dimensional analysis with accompanying numerical investigation is conducted. A simplified model of the real test sled is created that allows test sled dimensions to be converted to a numerical model for analysis. The dimensional analysis is used as a means of directly applying the numerical results to real test sled conditions. Similarity principles are studied and tested by comparing the results from scaled numerical models. Strain rate and other time dependent parameters are not scaled, but the effect of these parameters may be quantified and studied further. The dimensional analysis also provides a comprehensive approach to the test sled …

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Role Of Plasticity On Fretting Fatigue Behavior Of Ti-6al-4v, Kisu Shin Sep 2004

Role Of Plasticity On Fretting Fatigue Behavior Of Ti-6al-4v, Kisu Shin

Theses and Dissertations

Fretting fatigue generally leads to the degradation of the fatigue strength of a material due to cyclic micro-slip between two contacting materials. Fretting fatigue is regarded as an important issue in designing aerospace structures. While many studies have evaluated fretting fatigue behavior under elastic deformation conditions, few studies have focused on fretting fatigue behavior under elastic-plastic deformation conditions. The primary goal of this study was to characterize the fretting fatigue crack initiation behavior in the presence of plasticity. Experimental tests were performed using pad configurations involving elastic-plastic deformations. In order to calculate stress distributions under elastic-plastic fretting fatigue conditions, FEA …

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Stochastic Bifurcation In A Driven Laser System: Experiment And Theory, Lora Billings, Ira Schwartz, David Morgan, Erik Bollt, Riccardo Meucci, Enrico Allaria Aug 2004

Stochastic Bifurcation In A Driven Laser System: Experiment And Theory, Lora Billings, Ira Schwartz, David Morgan, Erik Bollt, Riccardo Meucci, Enrico Allaria

Department of Mathematics Faculty Scholarship and Creative Works

We analyze the effects of stochastic perturbations in a physical example occurring as a higher-dimensional dynamical system. The physical model is that of a class-B laser, which is perturbed stochastically with finite noise. The effect of the noise perturbations on the dynamics is shown to change the qualitative nature of the dynamics experimentally from a stochastic periodic attractor to one of chaoslike behavior, or noise-induced chaos. To analyze the qualitative change, we apply the technique of the stochastic Frobenius-Perron operator [L. Billings et al., Phys. Rev. Lett. 88, 234101 (2002)] to a model of the experimental system. Our main result …

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Effects Of Barium On The Performance Of Secondary Alkaline Zinc Electrode, Yi Zheng, Jian-Ming Wang, Hua Chen, Hai-Bo Shao, Jian-Qing Zhang Aug 2004

Effects Of Barium On The Performance Of Secondary Alkaline Zinc Electrode, Yi Zheng, Jian-Ming Wang, Hua Chen, Hai-Bo Shao, Jian-Qing Zhang

Journal of Electrochemistry

The active material of secondary alkaline zinc electrode with barium additives was prepared by a chemical reaction method and characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The electrochemical performance of various pasted Zn electrodes was investigated by cyclic voltammetry, charge/discharge method and electrochemical impedance spectra (EIS) technology. The addition of barium can synthesize a compound barium zincate with the molecular structure of BaZn(OH)4·xH2O and improve the discharge performance. The EIS of the various Zn electrodes showed two time constants besides diffusion impedance, including a state variable representing the covering degree of discharge products …

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The Electrochemical Behavior And Determination Of Gsh At The Powder Microelectrode, Jian Chen, Zhong-Yu He, Chuansin Cha, Huan Liu Aug 2004

The Electrochemical Behavior And Determination Of Gsh At The Powder Microelectrode, Jian Chen, Zhong-Yu He, Chuansin Cha, Huan Liu

Journal of Electrochemistry

In this paper, the electrochemical behavior of GSH at the surface of platinum(Pt) electrode, glass carbon(GC) electrode and acetylene black packed powder microelectrode (AB-PME) was studied. It was found that the electrochemical oxidations of GSH at both Pt and GC electrode were highly irreversible. No current peak or current plateau could be observed from the CV curves. The direct electro-oxidation of GSH at carbon surface was achieved by using the PME technique.In this case, the apparent reversibility of GSH oxidation was enhanced significatly .The overpotential of GSH oxidation was reduced to 0.5 V at the surface of AB-PME compared with …

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Electrochemical Reduction Of Nitrobenzene On The Wc Electrode In Acidic Solution, Chun-An Ma, You-Qun Chu, Ying-Hong Zhu, Zhi-Hua Xu Aug 2004

Electrochemical Reduction Of Nitrobenzene On The Wc Electrode In Acidic Solution, Chun-An Ma, You-Qun Chu, Ying-Hong Zhu, Zhi-Hua Xu

Journal of Electrochemistry

The tungsten carbide (WC) electrode was constructed by using polyterafluoroethylene as binder. The electrochemical behavior of nitrobenzene on the WC electrode in acidic solution was investigated by cyclic voltammetry, linear scan method and chronoamperometry. Experimental results showed that WC electrode had good activity for the electrochemical reduction of nitrobenzene, and the electrode process was controlled by diffusion and electrochemical stepssimultaneously. The apparent active energy of the electrode process is 23.7kJ⋅mol-1, while the active energy of the electrochemicalstep is 10.91kJ⋅mol-1.

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Synthesis Of (S)-3-Phenylpropane-2-Tert-Butoxycarbonylamino-1-Thiol And Its Electrochemical Behavior Self-Assembled On Gold, Ru Sun, Jian-Feng Ge, Mei Wang, Ren-Ao Gu Aug 2004

Synthesis Of (S)-3-Phenylpropane-2-Tert-Butoxycarbonylamino-1-Thiol And Its Electrochemical Behavior Self-Assembled On Gold, Ru Sun, Jian-Feng Ge, Mei Wang, Ren-Ao Gu

Journal of Electrochemistry

The synthesis of (S)-3-Phenylpropane-2-tert-butoxycarbonylamino-1-thiol(N-Boc-APT) from L-phenylalanine was reported. L-Phenylalanine was reduced to the corresponding amino alcohol, protection of the amino group using tert-butyl pyrocarbonate gave (S)-2-tert-butoxycarbonylamino-3-phenylpropane-1-ol, which was then O-mesylated and treated with potassium thioacetate in DMF to give 3-phenylpropane-2-tert- butoxycarbonylamino-1-etylmercapto. After the acetyl group was removed with ammonia in alcohol, the desired target molecular was obtained. The structure of intermediate and target molecular was conformed by IR and 1HNMR. We made N-Boc-APT self-assemble-modificated gold electrode and investigated its electrochemical behavior. The CV results of methylene blue on nano-Au/N-Boc-APT SAM/Au electrode showed that nano-Au could speed this electron transfer …

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Solid State Synthesis And Electrocatalysis Of Pt/Moo3 For The Oxidation Of Methanol, Qing Wang, Yi-Ming Zhou, Yang Shao, Yi-Gang Ji, Juan Xu, Ya-Wen Tang, Tian-Hong Lu, Tao Shen Aug 2004

Solid State Synthesis And Electrocatalysis Of Pt/Moo3 For The Oxidation Of Methanol, Qing Wang, Yi-Ming Zhou, Yang Shao, Yi-Gang Ji, Juan Xu, Ya-Wen Tang, Tian-Hong Lu, Tao Shen

Journal of Electrochemistry

The electrocatalyst, Pt/MoO3 synthesized by solid state reaction, was used for the oxidation of methanol in direct methanol fuel cells. The X-Ray diffraction and cyclic voltammetry were employed to investigate the performance of the material. It was shown that the typical diffraction peaks for Pt appeared in XRD. And a good electrocatalysis for methanol oxidation was observed. The peak potential of the methanol oxidation appeared at ca. 0.63V(vs.SCE) and the peak current density for the oxidation was 78.1 mA⋅cm-2.

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