Digital Commons Network^™

Enhanced Photostability Through Rapid Exciton Decay In Desymmetrized Cyclopentannulated Acenes With Strong Face-To-Face Pi Stacking, Chad D. Cruz, Karl J. Thorley, Zachary J. Knepp, Jared Wahlstrand, Gil M. Repa, John C. Stephenson, Sean Parkin, Lisa A. Fredin, John E. Anthony, Emily G. Bittle

Chemistry Faculty Publications

The photophysics of organic semiconductors impacts their efficiency in optoelectronic devices where exciton transitions, including singlet fission, intersystem crossing and the formation of charge transfer states influence the ability to convert between bright and dark states and to dissociate into free charges. Unfortunately, photodegradation and spurious signals often confound the results of optical studies, especially of important triplet states. Here four asymmetric cyclopentannulated acenes are synthesized and studied. This system represents an extreme in photophysics achieved via molecular design to fully quench the photoluminescence and bypass triplet formation allowing for comparative studies with other highly absorbing acenes. Rapid molecular exciton …

How-To: Academic Job Interviews (In The United States), Erin K. Peck, Kendall Valentine, Serina S. Wittyngham, Jessie S. Turner

OES Faculty Publications

[Introduction] "I (EKP) bombed my first interview on the tenure-track academic market. After I entered the Zoom room filled with search committee volunteers, the chair performed a quick round of introductions, and I was told that I would have strictly five minutes to answer each question. I smiled nervously, wringing my hands under the desk, and waited to be asked to derive a diagenetic equation or defend the methods I used in my recent manuscript.

“We'll start with something easy. Tell us about yourself,” began the chair.

I opened my mouth. I closed my mouth. My mind went blank. “Um …

Diatom Community Response To High And Low Iron Upwelling Plumes In The California Current System, Sveinn V. Einarsson, Kimberly Powell, Claire Till, Tyler Coale, P. Dreux Chappell

OES Faculty Publications

Diatoms are important primary producers, accounting for most of the oceanic production and carbon export relative to other photosynthetic eukaryotes. There are important differences among diatom species that enable them to proliferate in different environments. Some have nutrient storage capabilities or lower nutrient quotas suited for oligotrophic oceans. Bloom-forming diatoms are typically found in nutrient-rich coastal waters where they respond quickly to nutrient pulses and can influence biogeochemical cycling in the ocean after blooms. As many physiological differences affect biomass and export, it is important to better understand how physical and chemical parameters influence diatom community composition, especially in dynamic …

Modeling Upper Ocean Ecosystem Dynamics In Response To Interannual Sea-Ice Variability In The Western Antarctic Peninsula, Catherine R. Czajka, Jessica S. Turner, Sharon Stammerjohn, Heather H. Kim, Oscar Schofield, Benjamin T. Saenz, Scott C. Doney

OES Faculty Publications

In the Western Antarctic Peninsula (WAP), marine plankton dynamics are tightly linked to the interannual variability in environmental conditions, including phenological shifts in sea-ice seasonality. To explore these linkages, we use a 1-dimensional vertical ocean-ice-ecosystem model (KPP-Eco-Ice, or KEI) that simulates physical and ecosystem conditions at a continental shelf mooring location in the Palmer Long Term Ecological Research program sampling grid. KEI allows for year-round examination of the ecosystem in a region where in situ observations on the shelf are limited to January. Comparisons are made between seasonal sea-ice retreat, mixed layer depth, primary productivity, and phytoplankton relative abundance, grazing, …

Autonomous Float Data Reveal Decoupled Trends In Chlorophyll And Stratification In The Indian Ocean, Marufa Ishaque, Sophie Clayton, John Klinck

OES Faculty Publications

Recent studies have shown that the Indian Ocean is warming significantly, but how this warming impacts primary production is largely unresolved due to a relative lack of depth-resolved biological observations. In this study, we have used Biogeochemical-Argo data from 2013 to 2022, comprising over 9,000 individual profiles, to examine regional patterns and trends in depth-integrated chlorophyll, depth-integrated net primary production and stratification in the northern and Equatorial Indian Ocean. Our analysis shows that water column stratification is increasing in the majority of the study area, with the highest rate of increase observed in the western Bay of Bengal. At the …

Aquatic Macrophytes As Nature-Based Solutions: Challenges And Opportunities Across Inland And Coastal Waters, Morgan Botrel, Roxane Maranger, Lindsay L. Trottier, Mathieu Cusson, Lars L. Iverson, Fanny Noisette, Christian Nozais, Katrine Turgeon, Andrea Bertolo, Thibaud André-Alphonse, Simon Bélanger, Arthur De Grandpré, Jean-Olivier Goyette, Sabine Hilt, Ladd Johnson, Valérie Langlois, Martin Laporte, Félix Lauzon, Brigitte Légaré, Anne Ola, Marie-Pomme Presne-Poissant, Matthieu Prugne, Caroline Susini, Richard Zimmerman

OES Faculty Publications

Macrophytes are foundation species whose use as nature-based solution (NbS) in aquatic ecosystems can help reduce climate change impacts while mitigating biodiversity loss. The discrepancy in research and application of macrophytes as NbS across inland and marine coastal ecosystems is an opportunity to expand the concept and learn from different approaches. We report on an initiative uniting marine and freshwater scientists that compared knowledge on macrophytes as NbS across realms, identified advances and gaps in their use, and synthesized challenges and opportunities for application. We conducted a bibliometric analysis and an expert participatory exercise around recent review papers. We reveal …

Mental Health And Art Adherence In A Multisite International Study: The Mediating Roles Of Social Support And Substance Use In People With Hiv, Joseph Awad, Wenxiu Sun, Diane Santa Maria, Rebecca Schnall, Panta Apiruknapanond, Tongyao Wang, Claudia Patricia Valencia, Christine Horvat Davey, Solymar Solis Baez, Sheila Shaibu

School of Nursing & Midwifery, East Africa

ART adherence, essential to preventing disease progression for people living with HIV (PLHIV), remains challenged by factors like poor mental health condition, insufficient social support, and substance use. This study investigates the roles of social support and substance use as mediators in the relationship between mental health and antiretroviral therapy (ART) adherence among PLHIV in a multisite, international context. Cross-sectional data from N = 1598 PLHIV across eight countries were analyzed using parallel mediation analyses in R. Results indicated that both social support and substance use independently mediated the relationship between mental health and ART adherence. Hallucinogens mediated the mental …

Formal And Informal Digital Health In Tanzania: Healthcare Workforce, Regulatory And Trust Implications Of E-Patients And Virtual Care And The Development Of The Trust Framework, Kahabi Isangula, Judith Keebisilo Leo, James Tumaini Kengia

School of Nursing & Midwifery, East Africa

Digital health and virtual care are increasingly reshaping how healthcare is organized, delivered, and experienced. In Tanzania, digital transformation is evident in national commitments to digital health governance, health information exchange, hospital information systems, digital referral and emergency transportation, telemedicine, and emerging diagnostic applications supported by artificial intelligence. At the same time, patients are increasingly using social media, mobile platforms, and other digital channels to seek health information, consultations, diagnoses, and medicines, creating new forms of digitally mediated care that often operate alongside formal healthcare systems. Using a narrative synthesis design informed by a practice-based perspective, this study reviewed policy …

Ai-Assisted Wheat Spike And Spikelet Detection And Density Mapping Using Multiscale Remote Sensing Data To Support Wheat Grain Yield Forecasting, Hillson Ghimire

Electronic Theses and Dissertations

Wheat grain yield is determined by the number of spikes per unit area, the number of grains per spike, and kernel weight. However, spike number and spikelets per spike are still measured predominantly through manual counting, a labor-intensive and subjective process that limits phenotyping throughput and selection intensity in modern wheat breeding programs. This thesis develops and evaluates a deep learning framework for automated, high-throughput phenotyping of wheat spike and spikelet traits across complementary imaging scales and implements the framework as a deployable platform. First, two large-scale benchmark datasets with oriented bounding box (OBB) annotations were established, comprising 48,521 spike …

Bridging Language And Game Worlds: Semantic Representations And Text-Driven Terrain Generation For Procedural Content, Zhongyu Xie

Electronic Theses and Dissertations

Procedural Content Generation (PCG) systems produce vast quantities of game levels, terrain, and environments, but lack semantic interfaces: no shared vocabulary exists between natural language, designer intent, and the structured representations generators operate on. This thesis addresses the language-content grounding gap in PCG through two complementary studies spanning semantic analysis and semantic synthesis. The first study introduces a group-supervised contrastive learning framework for semantic representation of symbolic PCG maps under many-to-one semantics, where visually distinct maps may share the same design intent. The framework combines parameter-guided semantic grouping, LLM-based caption augmentation, and a multi-positive contrastive objective that aligns language with …

Regenerative Farming Practices Effects On Invertebrates In Wheat Systems, Daniel J. Pecenka

Electronic Theses and Dissertations

The modern agricultural system is based upon the Green Revolutions principle of creating more food. However, this came at a cost of invertebrate declines through habitat loss, pollution, and the introduction of agrochemicals. Here I address knowledge gaps in biological inventory of invertebrates across north, northwestern, and central North America. These invertebrates were identified and given a size scale and a dietary guild. We also examined how regenerative and conventional agricultural practices can affect invertebrate populations within the same crop. We also examined whether regenerative management wheat fields fostered great invertebrate communities while limited pest presence. Invertebrate populations were negatively …

Development And Application Of Lc-Ms/Ms Methods For The Determination Of Environmental Contaminants, Mawuli Wilson-Cee Macdonald

Electronic Theses and Dissertations

Environmental contaminants such as neonicotinoids and bisphenols are increasingly detected at ultratrace concentrations in environmental and consumer matrices, necessitating sensitive and efficient analytical methodologies. This dissertation presents the development, validation, and application of liquid chromatography–tandem mass spectrometry (LC–MS/MS) methods coupled with simplified sample preparation techniques. In Chapter 2, a direct aqueous injection (DAI) LC–MS/MS method was developed for the analysis of five neonicotinoids in surface water, eliminating extensive sample preparation. The method demonstrated strong linearity (R² = 0.993–0.998), with limits of detection (LOD) ranging from 0.5 to 4 ng/L and lower limits of quantification (LLOQ) of 10–50 ng/L. Accuracy (80–120%) …

“None In Velvet Gowns”: Camp Followers And White Womanhood In Eighteenth-Century Anglo-American Warfare, Angelica Labren Torres

History Theses

For over two hundred years, women who followed American and European armies during the long eighteenth century were popularly stereotyped and denigrated as prostitutes, burdens, and generally individuals of ill repute by both contemporaries and subsequent generations of historians. While recent scholarship has largely debunked this long-standing characterization as simplistic and inaccurate, the question remains: why exactly were these women so mischaracterized in their own time, particularly by commissioned officers and other members of Anglo-American middling and elite classes, when ample evidence existed of their material usefulness and comparative marital fidelity? This thesis seeks to address the ideological and cultural …

Aging With A Chronic Illness: Symptom Burden, Everyday Challenges, And Quality Of Life Among Older Adults With Multiple Sclerosis, Swasati Handique

Social Work Dissertations

This three-article study examined the quality of life and everyday lived experience of older adults living with multiple sclerosis (MS). The first article is a scoping review of 14 peer-reviewed studies published between 2012 and 2025, conducted in accordance with Arksey and O’Malley’s five-stage framework and the PRISMA checklist. The second article is a cross-sectional study using the Aging Concerns, Challenges, and Everyday Solution Strategies (ACCESS) Phase II data set of 60 older adults living with MS. Multiple linear regression and moderation analysis was conducted to examine the association between physical symptom burden and quality of life, and whether participation …

All Games Have Equilibria, Arthur Paul Pedersen, M. Ali Khan, Maxwell B. Stinchcombe

Publications and Research

Research on Nash equilibrium existence for infinite games has grown into a patchwork of technical preconditions and counterexamples. This paper presents a unified program in equilibrium theory by revising the predominant model of mixed strategies based on countable additivity. A game is specified by a nonempty set of players and, for each player, a nonempty action set and a bounded von Neumann-Morgenstern utility function. Every such game is shown to admit a Nash equilibrium in finitely additive mixed strategies. In addition, the equilibrium correspondence for any such game is shown to be nonempty, compact-valued, and upper hemicontinuous, and the same …

Called To Lead: Leadership Journeys And Workplace Experiences Of Women Presidents In Seventh-Day Adventist Institutions, Gary Thurber

Dissertations

Problem

Although women constitute more than half of Seventh-day Adventist Church membership, they remain substantially underrepresented in senior leadership roles across North America. This disparity raises important questions about the historical, theological, organizational, and gender-related factors that shape women’s access to institutional leadership within the denomination. A growing body of scholarship has examined the life experiences of women clergy in the church; however, limited research has explored the experiences of women serving in presidential leadership roles within Seventh-day Adventist institutions.

Purpose

The purpose of this study was to understand and describe the experiences of women serving in presidential leadership roles …

The Financial Effects Of Clinically Significant Readmissions In Florida Hospitals, Brian Patrick Cotton

Doctor of Business Administration Dissertations

This study examines how the financial performance of hospitals in the state of Florida impacts the quality of care. This study used data from 2017-2019 to evaluate how the number of hospital readmissions – a proxy for care quality – are associated with and vary in relation to the stability of the financial resources held by the hospital. The Hospital Readmission Reduction Program (HRRP), a Medicare value-based purchasing program, uses a mandatory pay-for-performance process that was initiated to decrease the 30-day hospital readmission rate. Hospitals with high readmissions are held accountable and financially encouraged to increase their quality of care …

Overview Of The Ergonomic Model Of Soccer And The Training Process, James J. Collins, Shane Malone, Kieran Collins

Research Outputs: 2025-Present

Soccer is a complex sport with significant physical, physiological, psychological, technical, and tactical demands on players. This review presents an ergonomics-based model of soccer performance, emphasizing that no single component operates in isolation. Building on the foundational ergonomic framework, this review integrates contemporary evidence on training load monitoring, ecological dynamics, and cognitive-perceptual performance dimensions not systematically addressed in prior frameworks. Elite outfield players cover 9–14 km·h⁻¹ per match, with high-speed running (19.8–24.8 km·h⁻¹) making up about 20% of total distance and sprinting (>25 km·h⁻¹) around 2%. These outputs vary by playing position, tactical formation, …

Exploring The Prevalence Of Eating Disorders, Low Sex Drive, And Exercise Compulsion Among Professional And Non-Professional Elite Male Rugby Union Players, Gary Sweeney, Siobhain Mcardle, Danielle Logue, Nessan Costello, Kieran Collins

Research Outputs: 2025-Present

Rugby union exhibits large variations in the idealised player physical profiles across positions. The pursuit of physique ideals with limited professional support can influence eating disorder symptomology, exercise compulsion, and low sexual drive. The primary aims were to (1) explore the prevalence of elite male rugby union players who are at risk for eating disorders, low sex drive, and exercise compulsion, and (2) explore the relationship between risk and players’ professional status, weight, age, and playing position. A secondary aim was to explore the nutritional service support and dietary monitoring practices experienced by the players. Participants were recruited from four …

Am I Top Of The Pops? Does Feedback Of Live Gps Between Sets Of Hurling-Specific Small-Sided Games Improve Subsequent Running And Physiological Performance?, Shane Malone, John Keane, Tom Hargroves, Conor P. Clancy, John David Duggan, Damien Young, Kieran Collins

Research Outputs: 2025-Present

The investigation aimed to determine if live feedback of team- and player-specific global positioning system (GPS) running performance data between bouts of hurling small-sided games (SSGs) altered the physical and physiological responses during subsequent bouts of SSGs during a 6-week hurling pre-season period. Twenty-four (n = 24) hurling players (age 25.5 ± 3.2 years; height 177.9 ± 3.2 cm; body mass 83.5 ± 4.5 kg) received either feedback or no feedback during hurling-specific SSGs across a 6-week pre-season period. Teams were assigned to two specific groups, a) GPS live feedback or b) no GPS live feedback (control) for each session, …

Efficacious Anti-Cancer Drugs Targeting Nicotinamide N-Methyltransferase (Nnmt) In Cultured Human Oral Squamous Cell Carcinoma (Oscc), Brian Maloney, Martyna Kubisztal, Ziqian Ge, Yin Lu, Lisa Strotmann, Adrianna Budziňska, Mary F. Rooney, Marilena Karavyraki, Andrew Knox, Richard K. Porter

Research Outputs: 2025-Present

Background/Objectives: Oral squamous cell carcinoma (OSCC) is a major cause of human cancer. The enzyme, nicotinamide N-methyltransferase (NNMT), is overexpressed in a variety of human cancers, including OSCC. Our objective was to target NNMT with novel inhibitors and determine their anti-cancer efficacy while shedding light on their possible mechanism of action. Methods: We identified two small molecule inhibitors of NNMT (AG-670 and AO-022) based on a pharmacophore of the in silico nicotinamide binding site. These inhibitors were investigated for (i) potency to inhibit the activity of the isolated NNMT enzyme (EC₅₀ values), (ii) cytotoxicity (IC₅₀ values) against the …

Physique Development And Management Shape Experiences Of Low Energy Availability Risk In Elite Professional Male Rugby Union Players, Gary Sweeney, Siobhain Mcardle, Nessan Costello, Kieran Collins

Research Outputs: 2025-Present

This study aimed to explore elite male rugby union players’ perceptions and lived experiences of physique development and management in relation to low energy availability risk. Semi-structured interviews (29 ± 8 min) were conducted with 18 players (senior: n = 9; academy: n = 9; mean age: 23 ± 3) across four professional rugby union clubs in Ireland. Through reflexive thematic analysis, the following themes were constructed. Players had limited awareness of low energy availability, yet described experiences consistent with symptoms, including fatigue, low mood and reduced libido. A pervasive physique culture, characterised by body composition ‘ideals’ and weight or …

From Platelets To Particles: Optimizing Extracellular Vesicle Isolation In A National Blood Centre, Y. Chintala, A. Waters, F. Mcgrath, A. Lorusso, C. Wynne, S. Meaney

Research Outputs: 2025-Present

Background and Objectives: Platelet-derived extracellular vesicles (PEVs) are submicron, membrane-bound particles released upon platelet activation, with a recognized role in haemostasis, inflammation and immunoregulation. PEVs remain insufficiently characterized in blood products. This study compared four isolation methods to evaluate their impact on PEV yield, purity and characteristics, aiming to identify a practical approach for transfusion service workflows. Materials and Methods: PEVs were isolated from expired single-donor aphaeresis platelet concentrates (n = 12) using methods based on different isolation principles: ultracentrifugation (UC), size exclusion chromatography (SEC), mixed size/charge separation (hybrid) and an affinity-based spin column method (affinity). Size, number and biochemical …

Order Of The Coif Program, August 14, 2026, University Of South Carolina School Of Law Order Of The Coif

Order of the Coif Programs and Documents

No abstract provided.

Determining Knowledge Gaps In Natural Disaster Preparedness: An Exploratory Analysis Of Socioeconomic Variables And Response Quality, Michelle S. Repass

Theses and Dissertations

This exploratory study examines potential knowledge gaps in natural disaster preparedness across socioeconomic groups in Lee County, Alabama and identifies communication barriers affecting response behavior through the lens of the knowledge gap hypothesis. Survey data from 20 residents were analyzed using an objective socioeconomic status (OSES) score based on household income and highest level of education. Results indicate that while most respondents reported access to weather alerts and favorable behavioral responses that align with current guidelines from the National Weather Service, gaps are present in comprehension, response timing, and engagement in risky behavior that could delay protective action. Findings suggest …

Practicing Contemporary Documentation: An Analysis Of Historic Influences And Personal Inspirations, Zoee D. Rasso

Theses and Dissertations

For my Honors Thesis, I proposed and created a solo exhibition of my artwork, researching the inspiration behind this work to determine its place within in the context of contemporary art history. My work as an artist centers on stylized, psychologically charged portraits of birds. Looking at art history, birds as artistic subjects are historically rooted in documentation, from scientific illustrations and game paintings to ukiyo-e. Analyzing my own creative influences such as James Audubon, Walton Ford, and Safet Zec, this Thesis explores my artistic background and influences, examining how I have developed as an artist over my tenure at …

Representation In Black Media And How It Affects Generational Mental Health, Amiya Smith

Theses and Dissertations

This article examines how negative media portrayals of Black Americans have harmed their mental health. It traces the impact of persistent stereotypes and the lack of recognition for Black achievements in the media. Each chapter explores how media—from social media to movies—reinforces outdated stereotypes originating in the antebellum era and discusses how Black Americans have challenged these narratives to assert their identity. The article also highlights positive shifts in representation within the media industry, as well as research on how racial discrimination and media depictions influence the mental health and self-esteem of Black adolescents.

Exploring Secondary Stem Teachers’ Experiences In Online Learning Environments: A Directed Content Analysis Using The Community Of Inquiry Framework, Tiffany Janese Lester

Theses and Dissertations

This study is a directed qualitative content analysis of 21 peer-reviewed studies published between 2020 and May 2025 on secondary STEM teaching in online environments. Using the Community of Inquiry framework, I examined how teaching, social, and cognitive presence shaped instructional strategies, teacher experiences, and reported challenges. Coding with deductive and inductive methods identified recurring themes: teachers adapted to digital platforms, navigated uneven levels of digital fluency, and implemented intentional strategies to maintain social interaction. The studies also revealed persistent equity gaps in access and participation alongside innovative approaches to course and pedagogical design. These themes demonstrate how secondary STEM …

Album Production: A Pedagogical Tool In Collegiate Brass Performance, Alex Doolittle

Theses and Dissertations

This graduate research project investigates the value of musical album production within collegiate brass performance training and pedagogy. Within the collegiate sphere, brass pedagogy has long centered on live performance, such as juries, recitals, and ensemble participation as a primary performance tool; however, the 21st-century musical landscape is deeply rooted in technological and digital artistic dissemination. This study is used to push the boundaries of how technology can be interpreted in brass pedagogy by asking: How does album production function as a pedagogical tool in collegiate brass performance training?

In this project, I used an auto-ethnographic case study design, serving …

Literacy Intervention At The Middle Level: A Mixed-Methods Examination Of The Implementation Of Thinking Maps, Ashley Chantal Choice

Theses and Dissertations

This study examined the implementation of Thinking Maps® as a literacy instructional intervention for students in grades four and five. Using an explanatory sequential mixed-methods design, the study investigated the effect of Thinking Maps® on student achievement, changes in students’ literacy-related work products, and teachers’ perceptions of the strategy. The study was conducted at a rural Title I elementary school in the southeastern United States and included nine teachers and 150 students across English language arts, mathematics, science, and social studies during an eight-week intervention period. Quantitative data included unit pretest and posttest scores from standards-aligned assessments and teacher perception …