Polymer Science Commons^™

Surface Immobilization Of Stimuli-Responsive Polymers Using A Network Of Aminopropyltriethoxysilane, Walter Bungard, Ryan Nixon

Williams Honors College, Honors Research Projects

The goal of this honors project is to develop a cost-effective and accessible method for entrapping stimuli-responsive polymers onto solid substrates using aminopropyltriethoxysilane (APTES). The entrapment network process will first be replicated on glass or silicon using APTES and poly(N-isopropylacrylamide), involving spin coating and thermal annealing to chemically bond the polymer to the substrate. Once validated, the method will be applied to other stimuli-responsive polymers, including thermo-responsive, electroactive, and pH-sensitive types, with APTES as a control. For each sample, film stability, responsiveness, and surface behavior will be evaluated using contact angles, optical microscopy, and spectroscopic analysis, followed by statistical evaluation. …

Ion-Imprinted Polymer-Based Sensors For Toxic Metal-Ion Detection In Water: Coordination Chemistry, Transduction Strategies, And Environmental Applications, Ghita Yammouri, Gymama Slaughter

Center for Bioelectronics Publications

Toxic metal contamination in aquatic environments remains a persistent threat to human health and ecosystems. Yet, the high cost, infrastructure demands, and centralized nature of conventional analytical methods constrain routine monitoring. Ion-imprinted polymers (IIPs), a subclass of molecularly imprinted polymers, have emerged as promising synthetic recognition materials for metal-ion sensing because they generate coordination-defined binding sites with high selectivity, chemical stability, low cost, and reusability. This review summarizes recent advances in Ion-imprinted polymer (IIP)-based sensing technologies for toxic metal-ion detection in water from 2016 to 2026. It examines the fundamental recognition chemistry of IIPs, major synthesis strategies used to generate …

Bio-Papcz: Corn Starch-Based Composite Bioplastic Reinforced With Pineapple Leaf Fiber (Palf), Zinc Oxide (Zno), And Polyvinyl Alcohol (Pva), Marvin C. Caya, Shervin Austin C. Huang, Jovar Khalel J. Maghari, Ruel M. Levida

Sinaya: A Philippine Journal for Senior High School Teachers and Students

Plastic pollution poses a serious global threat, as petroleum-based plastics persist for centuries, and their surging production of over 450 million tons overwhelms ecosystems (Ritchie et al., 2023). Using a quantitative experimental research design, the study examined the effects of varying concentrations of cornstarch-based bioplastic reinforced with pineapple leaf fiber (PALF), polyvinyl alcohol (PVA), and zinc oxide (ZnO) on the bioplastic’s tensile strength and soil degradability. Sample C2 (ZnO 3.0 %w/w; PVA 9.0 %w/w) demonstrated the optimal tensile properties with a tensile strength of 0.76 MPa and an elongation at break of 6.40%, which was attributed to the addition of …

Purifying Circular Rna Therapeutics, Karen Guillen-Cuevas

All Dissertations

Circular RNA (circRNA) has emerged as a promising therapeutic modality due to its enhanced stability and resistance to exonuclease degradation compared with linear mRNA. However, its stability and functionality depend strongly on achieving high purity, and current methods such as size-exclusion chromatography suffer from peak overlap, low yields, and poor scalability. This dissertation addresses these limitations by developing ultrafiltration-based strategies to purify circRNA directly from in vitro transcription (IVT) and self-splicing (circularization) reactions. First, the feasibility of ultrafiltration was demonstrated using polyethersulfone membranes, where sieving coefficients and critical flux values of circRNA, precursor RNA, and nicked RNA were measured to …

The Science And Economics Of 3d-Printed Filament Recycling, Michael Domingo, Dane Freund, John Mcswiggin, Adam Meadows

Sustainability Conference

In recent years, 3D printing has grown rapidly, both in homes and commercially. This has led to increased demand for plastic filaments, many of which contribute to plastic waste. This project explores the potential of recycling household plastics into 3D printing filament, promoting sustainability and creating a circular economy. Materials like PLA, PETG, ABS, and polypropylene can be recycled or even composted. Existing research has shown that recycled filaments can maintain comparable tensile strength to their virgin counterparts, depending on the recycling process. Furthermore, implementing circular economy practices for plastics could save billions annually by mitigating pollution and reducing landfill …

Effect Of Varying Chitosan Molecular Weights On The Morphology And Physical Characteristics Of Pva/Chitosan Composite Hydrogels, Yuan Alfinsyah Sihombing, Halida Rahmi Luthfianti, William Xaveriano Waresindo, Marathur Rodhiyah, Nur’Aini Nafisah, Dian Ahmad Hapidin, Dhewa Edikresnha, Khairurrijal Khairurrijal

Makara Journal of Science

We employed the innovative freeze–thaw method to investigate the effect of chitosan (CS) molecular weights incorporated into polyvinyl alcohol on the morphology and physical characteristics of the hydrogel. This study aimed to unravel the intricate relationships between CS molecular weight variations, CS concentration, and the number of freeze–thaw cycles (4 or 6 cycles) on hydrogel swelling degree and weight loss. Incorporating CS improved the hydrogel structure and enhanced its porosity, resulting in remarkable increases in swelling degree ranging from 2 to 6 times the initial weight. Higher molecular weight CS (310,000–375,000 Da) exhibited a lower swelling degree than medium molecular …

Superhydrophobic Cerium-Based Metal–Organic Frameworks/Polymer Nanofibers For Water Treatment, Samar A. Salim, Hani Nasser Abdelhamid,

Nanotechnology Research Centre

No abstract provided.

Polymer-Enhanced Nanopore Sensing, Eugene Gyasi Agyemang

Graduate Theses and Dissertations

The resistive pulse technique characterizes single analytes by detecting fluctuations in the ion current as they pass through a narrow orifice connecting two electrolyte-filled chambers, each containing a single electrode. The amplitude, shape, frequency, and duration of these fluctuations primarily provide information about the analyte’s size, shape, concentration, and net surface charge, respectively. One configuration for resistive pulse measurements is of an electrolyte-filled nanopipette immersed in a bath, where the nanopipette tip acts as the nanoscale orifice. It was previously shown that incorporating the large quantities polymer polyethylene glycol (PEG 8K, 50% w/v) into the external electrolyte bath dramatically enhanced …

Theoretical And Experimental Investigation Of Liquid-Liquid Phase Separation: Characterizing Elastin-Like-Polypeptides, Adam D. Quintana

Chemical and Biological Engineering ETDs

This dissertation develops and validates a semi-empirical Flory–Huggins-based interaction model, combined with Cahn–Hilliard simulations, for predicting multi-component liquid–liquid phase separation (LLPS) in elastin-like polypeptide (ELP) systems. Equilibrium droplet compositions, measured using a PDMS-based microfluidic device, enabled direct parameterization of interaction coefficients. The model was applied to generate phase diagrams and assess composition dependence in ternary mixtures. Cahn–Hilliard simulations were conducted to explore potential phase morphologies under different interfacial conditions. Multi-component Lattice Boltzmann simulations were implemented to model droplet morphology evolution under varying interfacial and diffusive parameters, reproducing experimentally relevant morphologies. A three-phase wetting study revealed conditions for selective wetting and …

Experimentally Driven Numerical Model Of Carbon/Polyaniline-Based Glucose Monitoring Sensors: An Evaluation Using A New Figure Of Merit, Ziad Khalifa, Kyrillos Selim, Amira Ali, Sameh Abdellatif

Chemical Engineering

This study presents an experimentally driven numerical model for evaluating carbon/polyaniline (PANI)- based glucose monitoring sensors (GMSs), focusing on innovative configurations using graphene-PANI and carbon nanotube (CNT)-PANI composites. We performed a thorough analysis of the morphological, electrophysical, and electrical properties of these materials, ultimately leading to the extraction of key electrical parameters for integration into a finite element model (FEM). This model simulates the entire sensor, enabling the estimation of critical performance metrics such as sensitivity, limit of detection (LOD), linearity, and power consumption. Our findings demonstrate that the CNT-PANI configuration significantly outperforms the laser-induced graphene (LIG)-PANI electrode, achieving a …

Removal Of Fluoroquinolones From Water Systems Employing Rice Husk Composited Sponges Via Nanoadsorption, Dalia Kanaa

Theses and Dissertations

A novel nanocomposite of polyvinyl alcohol formaldehyde (PVF) sponge loaded with green zinc oxide nanoparticles (ZnONP) and referred to as (NP-PVF) was fabricated as a potential adsorbent of ciprofloxacin from water. A simple mechanical foaming process was used to synthesize the adsorbent. Rice husk extract was used to synthesize zinc oxide nanoparticles (ZnONP) for its phytochemicals as reducing agents. A facile and low-energy-dependent extraction method was used that did not require the use of high-temperature annealing. The synthesized nanoparticles showed a maximum UV absorption at 347 nm, which corresponds to a 3.58 eV band gap energy. FTIR confirmed the successful …

Effect Of Household Oil Contamination And Agricultural Soil Contamination On Phyllosilicate Nanocatalyst Performance During Pyrolysis Of Polyolefins, Joey Velasquez

Master's Theses

The effect of household oil and agricultural soil contamination on catalyst performance during polyolefin pyrolysis was simulated on mixed virgin plastic pellets by evaluating contamination influence on mixed plastic degradation temperatures. Three phyllosilicate nanocatalysts including Fulcat435, Fulcat22F and Y-Zeolite were evaluated in this work based on a literature review of catalyzed plastic pyrolysis and these catalysts’ ability to lower plastic decomposition temperature by 50 °C – 100 °C. These findings were confirmed in this research through thermogravimetric analysis of a polyolefin mixture and further developed in furnace experiments containing household oil and agricultural contamination. Household oil contamination deactivated each of …

Chemical Recycling Of Pet Plastic Waste, Charlie Parker, Benjamin Puga, Jake Verschoor

Materials Engineering

The growing accumulation of plastic waste, specifically polyethylene terephthalate (PET), has driven the need for more efficient and scalable chemical recycling methods. This study investigated the methanolysis of PET using zinc oxide (ZnO) nanoparticles as a catalyst and tetrabutylammonium chloride (NBu₄Cl) as an ionic liquid, aiming to reduce methanol consumption while achieving high PET conversion efficiency. ZnO nanoparticles were synthesized via wet chemistry and characterized using Dynamic Light Scattering (DLS), which showed an average particle size of 13.5 nm with a polydispersity index of 0.1556, indicating a moderately-high monodisperse distribution of particles sufficient for reactions. The main conversion product, dimethyl …

Interfacial Phenomena Of Plastics: From Surface Modifications To Environmental Impacts, Kennedy Guillot

LSU Doctoral Dissertations

Plastic is a ubiquitous part of everyday life since its introduction in the previous century. Global production continues to exponentially increase, establishing plastics as one of the most dominant materials in modern manufacturing. Within the scope of academia, plastic is essential due to its low cost and sterility, particularly for minimizing contamination. Beyond the laboratory, plastic use spans numerous industries, and its use and disposal has since raised many environmental concerns. Once valued for its durability, plastics now pollute the environment in landfills and natural ecosystems. In recent decades, the consequences of this pollution have been investigated, yet the full …

Multifunctional Pvdf Ionogels With Magnetic Nanoparticles For Electroactive And Magnetic Actuation, Alfredo Carrillo Valverde

Chemical Engineering Undergraduate Honors Theses

The fast development of compact and multifunctional electronics has driven interest in smart materials capable of responding to multiple stimuli. Ionogels, polymers that have been swollen with ionic liquids (IL), offer several favorable electrochemical and thermal properties due to their intrinsic ion conductivity, wide electrochemical window, non-flammability, and high thermal stability. However, their poor mechanical properties (e.g., modulus and strength) limit their use in applications. In this work, multifunctional PVDF ionogel composites were made by blending magnetically responsive iron oxide nanoparticles (Fe₃O₄ MNPs) into the polymer matrix. The influence of MNP concentration (9-21 wt%) on composition, ionic …

Tuning The Morphology Of Triblock Copolymers Via Homopolymer Blending, John F. Searles

Honors Theses

Morphology plays an important role in the physical properties of block copolymer (BCP) materials. Depending on the type of morphology and chemical composition of the blocks, BCPs are used in applications ranging from soft biomaterials for biomedical devices to rigid materials for ballistics protection. Due to incompatibility between comonomers and required block weight ratios to achieve targeted morphologies, it is generally necessary to use complex, time-consuming, and expensive synthetic techniques to prepare BCPs. As a result, there is increased interest in the development of new processing methods to tailor block copolymer morphology without the need for additional synthesis. The morphological …

Mechanistic Insights Into Polymer-Assisted Graphene Exfoliation: The Roles Of Velocity, Adhesion, Cohesion, Temperature, Peeling Mode, And Edge Defect Via Coarse-Grained Molecular Dynamics, Linjiale Dai

All Theses

Graphene exfoliation is a critical step in the fabrication of high-quality graphene

layers. However, the underlying fracture mechanisms remain poorly understood. In this

work, I employed coarse-grained (CG) molecular dynamics (MD) simulations to

investigate how factors such as interfacial binding energy, substrate cohesion, temperature,

peeling mode, and edge defects influence the outcome of the exfoliation process. To model

polymer-assisted mechanical exfoliation, I used a finite-size system in which multilayer

graphene (MLG) is sandwiched between two thin polymer films. Leveraging the

spatiotemporal efficiency of the CG model, I performed fifty simulation iterations per

parameter set and analyzed the results from a …

Incorporating Recycled And Repurposed Plastic Into 100% Reclaimed Asphalt Pavement, Basant Bhatt

Graduate Theses and Dissertations (2019 - present)

The increasing awareness of sustainability in the asphalt industry has driven the use of recycled materials like reclaimed asphalt pavement (RAP) and waste plastic. This study examines the incorporation of recycled polypropylene (rPP), recycled high-density polyethylene (rHDPE), and recycled low-density polyethylene (rLDPE) at 0.3%, 0.6%, and 0.8% dosages into 100% RAP, along with the warm mix asphalt additive Evotherm® P25. Laboratory tests were conducted to evaluate the mechanical and durability performance of the modified asphalt mixtures while rutting and fatigue life were evaluated using mechanistic-empirical (ME) analysis in PerRoad software. Both plastic type and dosage had a statistically significant impact …

Design And Characterization Of Lignin-Based, Thermoresponsive Soft Composites With Improved Mechanical And Transport Properties, Missoury D. Wolff

All Dissertations

In an attempt to reduce reliance on petroleum-based polymers, lignin – an abundant biopolymer – has gained popularity as a sustainable alternative. However, research on lignin-containing soft composites – i.e., hydrogel (bio)composites – has largely been heuristic, providing limited insight into the fundamental structure-processing-property relationships that govern performance improvements in this emerging class of ‘green’ soft composites. As such, this dissertation presents a systematic investigation of how lignin molecular weight (MW), composite composition, and the concentrations of crosslinker and accelerator impact the mechanical and transport characteristics of soft composites composed of lignin, poly(N-isopropylacrylamide) (PNIPAm), and poly(vinyl alcohol) (PVA).

In the …

Enhancing Oil Recovery With Novel Nano-Particle-Infused Surfactant Biopolymer Composite: A Comprehensive Investigation, Attia Attia, Amira Shafaay Dr., Michael Sami Alfonse Eng., George Azmi Eng., Rania Ramadan

Petroleum Engineering and Gas

The oil industry worldwide is searching for a new way to increase oil recovery. Chemical flooding has been used worldwide to improve oil recovery. In this research, the study of Enhanced Oil Recovery was carried out by using an Egyptian oil of API 42◦; the experiments were done by using Xanthan biopolymer (XG) gum with sodium dodecylbenzene sulfonate (SDBS) as a composite for the EOR process and studying the impact of different composite concentrations on oil recovery. Design Expert software was used to determine the optimum concentrations of the composite. 500 ppm concentration of graphene cobalt samarium ferrite nanoparticles (NP) …