Induction Vacuum Swing Adsorption Over Magnetic Sorbent Monoliths And Extrudates For Ethylene/Ethane Separation,
2024
Missouri University of Science and Technology
Induction Vacuum Swing Adsorption Over Magnetic Sorbent Monoliths And Extrudates For Ethylene/Ethane Separation, Khaled Baamran, Usman Shareef, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Electrification of adsorption processes is emerging as an adaptable solution for future gas separations. This study develops magnetic sorbent structures for use in induction vacuum swing adsorption (IVSA) process specifically designed for olefin/paraffin separation. Two sorbents, namely Fe3O4/ZIF-7 (ethane-selective) and Fe3O4/13X (ethylene-selective) were developed and formulated into extrudates (Fe20/ZIF-7-P) and monoliths (Fe20/13X-M), and tested under different regeneration scenarios, including simultaneous and subsequent induction-evacuation, induction only, and evacuation only. The dynamic adsorption results demonstrated that regeneration under subsequent induction-evacuation improves desorption rate and capability. Under this regeneration scenario, Fe …
Emulsion Liquid Membrane (Elm) Enhanced By Nanoparticles And Ionic Liquid For Extracting Vanadium Ions From Wastewater,
2024
Missouri University of Science and Technology
Emulsion Liquid Membrane (Elm) Enhanced By Nanoparticles And Ionic Liquid For Extracting Vanadium Ions From Wastewater, Qusay Al-Obaidi, Nora Yehia Selem, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Emulsion liquid membrane (ELM) stands out as an extraction process that has drawn much attention due to its promising prospects in industrial wastewater treatment technology. Nevertheless, the pivotal challenge is to reach high membrane stability to overcome the obstacle of applying ELM at the industrial scale. In this study, ELM was boosted by using nanoparticles (superparamagnetic iron oxide (Fe2O3)) in the stripping phase (W1) and ionic liquid (1-methyl-3-octyl-imidazolium-hexafluorophosphate [OMIM][PF6) in the oil phase (O) for recovering/extracting vanadium from synthetic wastewater to near completion and at the same time enhancing emulsion stability to be appropriate for industrial …
Response To Replication Stress And Maintenance Of Genome Stability By Wrn, The Werner Syndrome Protein,
2024
University of Kentucky
Response To Replication Stress And Maintenance Of Genome Stability By Wrn, The Werner Syndrome Protein, David K. Orren, Amrita Machwe
Markey Cancer Center Faculty Publications
Werner syndrome (WS) is an autosomal recessive disease caused by loss of function of WRN. WS is a segmental progeroid disease and shows early onset or increased frequency of many characteristics of normal aging. WRN possesses helicase, annealing, strand exchange, and exonuclease activities and acts on a variety of DNA substrates, even complex replication and re- combination intermediates. Here, we review the genetics, biochemistry, and probably physiological functions of the WRN protein. Although its precise role is unclear, evidence suggests WRN plays a role in pathways that respond to replication stress and maintain genome stability particularly in telomeric regions.
Exploring Shape Dependency Of Catalysts For Chemical Reactions,
2024
University of South Carolina
Exploring Shape Dependency Of Catalysts For Chemical Reactions, Kaveh Shariati
Theses and Dissertations
Recent advancements in the synthesis of nanoparticles, particularly one-dimensional (1D) nanoparticles, have significantly enhanced the catalytic activity of various processes by enabling precise control over their morphologies and exposing unique crystallographic facets. The shape of nanoparticles is closely linked to their chemical, physical, electrical, optical, magnetic, and catalytic properties. This dissertation investigates the impact of 1D nanoparticle catalysts on two distinct and well-known chemical reactions. In the first part of the study, we explore the catalytic activity and selectivity of silver catalysts in the ethylene epoxidation reaction, which are intrinsically linked to their faceting. Silver nanowire catalysts representing Ag(100) and …
Simulation Of A Passive Osmosis-Integrated Electrolyzer For Seawater Electrolysis,
2024
University of South Carolina
Simulation Of A Passive Osmosis-Integrated Electrolyzer For Seawater Electrolysis, Masoomeh Ghasemi
Theses and Dissertations
Efforts to develop direct seawater electrolysis technology have been ongoing due to the need for pure water in electrolysis and the abundance of seawater. However, progress has been hampered by several issues, including competition with the chlorine evolution reaction, higher membrane resistance, corrosion of electrodes, and scaling from multivalent cations [1]. To avoid these issues, our project has proposed a new reactor that integrates passive osmosis (extracting fresh water from seawater) with electrolysis. In this thesis, we will discuss the operation of the osmosis-integrated electrolyzer and show theoretical predictions of the osmotic pressure differential and water flux/velocity profiles under different …
Machine Learning Approaches To The Exploration Of Ammonia Synthesis Catalysts Utilizing Experimental Data,
2024
University of South Carolina
Machine Learning Approaches To The Exploration Of Ammonia Synthesis Catalysts Utilizing Experimental Data, Rasika Jayarathna
Theses and Dissertations
Traditional heterogeneous catalyst discovery process relies upon human expert-guided experiments based on domain knowledge and human intuition supported by catalyst characterization. However, this process is time and resource-consuming and suffers from human bias. Machine learning (ML) models trained on experimental data have the potential to significantly accelerate this discovery process by guiding experiments to optimize the catalyst performance and increase the understanding of the catalysts. Ammonia synthesis catalysts are a class of catalysts widely investigated in the literature, which has generated decades of experimental data. Moreover, ammonia has been gaining attention since it can be used as a carbon-free next-generation …
Applications Of Catalytic Ammonia Chemistry: From Low-Pressure Ammonia Synthesis To The Decomposition Of Tritiated Ammonia As A By-Product Of Magnetically Confined Nuclear Fusion,
2024
University of South Carolina
Applications Of Catalytic Ammonia Chemistry: From Low-Pressure Ammonia Synthesis To The Decomposition Of Tritiated Ammonia As A By-Product Of Magnetically Confined Nuclear Fusion, Jennifer Kules Naglic
Theses and Dissertations
Ammonia is the 2nd most produced chemical in the world with vital importance for its use in fertilizer as the global population has grown in accordance with the industrialization of NH3. While 80% of NH3 produced goes to fertilizer, it has gained attention recently as a hydrogen storage and transportation vessel. Industrially, NH3 is produced at high temperatures and pressures which in turn require high electrical input. Turning to a green NH3 cycle with low temperature and pressure membrane reactors for both NH3 synthesis and decomposition would allow for much lower energy input as well as a renewable energy to …
Characteristics Of Pyrolysis Products Of California Chaparral And Their Potential Effect On Wildland Fires,
2024
Brigham Young University - Provo
Characteristics Of Pyrolysis Products Of California Chaparral And Their Potential Effect On Wildland Fires, Mahsa Alizadeh, David R. Weise, Thomas H. Fletcher
Faculty Publications
The aim of this study was to investigate the pyrolysis of selected California foliage and estimate the energy content of the released volatiles to show the significance of the pyrolysis of foliage and its role during wildland fires. While the majority of the volatiles released during the pyrolysis of foliage later combust and promote fire propagation, studies on the energy released from combustion of these compounds are scarce. Samples of chamise (Adenostoma fasciculatum), Eastwood’s manzanita (Arctostaphylos glandulosa), scrub oak (Quercus berberidifolia), hoaryleaf ceanothus (Ceanothus crassifolius), all native to southern California, and sparkleberry …
Dynamic Metabolic Flux Analysis Amidst Data Variability: Sphingolipid Biosynthesis Case Study In Arabidopsis Thaliana Cell Cultures,
2024
University of Nebraska-Lincoln
Dynamic Metabolic Flux Analysis Amidst Data Variability: Sphingolipid Biosynthesis Case Study In Arabidopsis Thaliana Cell Cultures, Abraham Boluwatife Osinuga
Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research
Sphingolipids are pivotal for plant development and stress responses. Growing interest has been directed towards fully comprehending the regulatory mechanisms of the sphingolipid pathway. In this study, we explore its de novo biosynthesis and homeostasis in Arabidopsis thaliana cell cultures, shedding light on fundamental metabolic mechanisms. Employing 15N isotope labeling and quantitative dynamic modeling approach, we obtained data with notable variations and developed a regularized and constraint-based Dynamic Metabolic Flux Analysis (r-DMFA) framework to predict metabolic shifts due to enzymatic changes. Our analysis revealed key enzymes such as sphingoid-base hydroxylase (SBH) and long-chain-base kinase …
Carbon-Based Nanocomposite Membranes For Membrane Distillation: Progress, Problems And Future Prospects,
2024
University of Arkansas, Fayetteville
Carbon-Based Nanocomposite Membranes For Membrane Distillation: Progress, Problems And Future Prospects, Chhabilal Regmi, Yuwaraj K. Kshetri, S. Ranil Wickramasinghe
Chemical Engineering Faculty Publications and Presentations
The development of an ideal membrane for membrane distillation (MD) is of the utmost importance. Enhancing the efficiency of MD by adding nanoparticles to or onto a membrane’s surface has drawn considerable attention from the scientific community. It is crucial to thoroughly examine state-of-the-art nanomaterials-enabled MD membranes with desirable properties, as they greatly enhance the efficiency and reliability of the MD process. This, in turn, opens up opportunities for achieving a sustainable water–energy–environment nexus. By introducing carbon-based nanomaterials into the membrane’s structure, the membrane gains excellent separation abilities, resistance to various feed waters, and a longer lifespan. Additionally, the use …
Impact Of Non-Thermal Plasma Generated Using Air And Nitrogen On Functional Properties Of Milk Protein Dispersions,
2024
University of Arkansas, Fayetteville
Impact Of Non-Thermal Plasma Generated Using Air And Nitrogen On Functional Properties Of Milk Protein Dispersions, Nikitha Modupalli, Md Mahfuzur Rahman
Food Science Faculty Publications and Presentations
This study focuses on improving the functionalities of milk protein concentrate (MPC) using a nonthermal plasma jet and plasma-activated water (PAW) with atmospheric air and nitrogen as source gases. The 5% and 10% MPC dispersions were directly treated with a plasma jet, and PAW was used to make the MPC dispersions. The dispersions were analyzed for changes in protein structure and functional properties. The treatment altered the secondary structure of MPC protein structure by increasing β-components and changing the order of random coils. The solubility of the PAW-treated 5% protein dispersions doubled due to plasma-induced modification of hydrophilic and covalent …
Preparation Of Β-Ni (Oh)2 Nanosheet–Modified Glassy Carbon For Pseudocapacitors,
2024
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok 16424, Indonesia
Preparation Of Β-Ni (Oh)2 Nanosheet–Modified Glassy Carbon For Pseudocapacitors, Muhammad Buchari Setia Putra, Aliyah Aliyah, Afiten Rahmin Sanjaya, Respati Kevin Pramadewandaru, Hoeil Chung, Tribidasari Anggraningrum Ivandini
Makara Journal of Science
β-Nickel hydroxide (Ni(OH)2) nanosheet–modified glassy carbon for pseudocapacitors was successfully prepared. The nanosheets were synthesized via a conventional growth seeding method combined with hydrothermal treatment. Transmission electron microscopy (TEM) characterization indicated the hexagonal structure of the nanosheets of around 15 nm in size, and X-ray diffraction (XRD) pattern confirmed the β-phase lattice crystal. These nanosheets used to modify the glassy carbon surface, increased the electroactive surface area by around 15 times. Furthermore, electrochemical investigation of the modified glassy carbon revealed an excellent performance and a specific capacitance of 628.01 F g−1 at a 1 A g−1 …
Optimizing The Expression Of Polyethylene Terephtalate Hydrolase-Encoding Synthetic Gene In Escherichia Coli Arctic Express (De3),
2024
Department of Biology, University of Indonesia, Depok 16424, West Java
Optimizing The Expression Of Polyethylene Terephtalate Hydrolase-Encoding Synthetic Gene In Escherichia Coli Arctic Express (De3), Jocelyn Nataniel, Maria Ulfah, Dini Achnafani, Niknik Nurhayati, Gabriela Christy Sabbathini, Sri Rezeki Wulandari, Abinawanto Abinawanto, Is Helianti
Makara Journal of Science
The waste of polyethylene terephthalate (PET) plastic waste in Indonesia is a pressing concern due to its slow degradation and potential environmental damage. One promising solution is to utilize polyethylene terephthalate hydrolase from Ideonella sakaiensis (IsPETase), an enzyme that specifically degrades PET. However, inducing the expression of IsPETase synthetic gene in Escherichia coli BL21 (DE3) has been challenging because much of it remains insoluble. This study aimed to express IsPETase in E. coli Arctic Express (DE3) and optimize the conditions to enhance its production. First, pET22b(+)pelB-IsPETase was inserted into E. coli Arctic Express (DE3). The …
Algorithms And Models For Synthesis Of Elements Of Digital Information Systems,
2024
Navoi state university of mining and technologies. Address: Street Galaba, 76V, Navoi city, Republic of Uzbekistan. E-mail: [email protected];
Algorithms And Models For Synthesis Of Elements Of Digital Information Systems, Odil Abdujalilovich Jumaev, M.T. Ismoilov, V.B. Pulatov, G.X. Rashidov
Chemical Technology, Control and Management
The development of algorithms for noise-tolerant and high-speed measurement systems involves an integrated approach that encompasses methods of data processing and transmission, as well as mechanisms for rapid response to changes. This paper presents the key principles and techniques used in such technologies. The information systems are thoroughly analyzed, including the use of signal processing techniques and their identification, filtering using various statistical techniques to determine signal parameters and the development of algorithms to analyze and classify signals. Critical aspects of the system such as performance, reliability, security and scalability are also evaluated. The paper discusses information system structures and …
Ultrasonic Flow Meter Calibration Via The Internet Using An Analog-To-Digital Converter,
2024
Tashkent State Transport University, Address: Adilxujaev 1 str. Tashkent, Uzbekistan. E-mail: [email protected];
Ultrasonic Flow Meter Calibration Via The Internet Using An Analog-To-Digital Converter, Aliev Ravshan, A.U. Djalilov
Chemical Technology, Control and Management
The purpose of scientific research work is remote control of improving the metrological properties of the water flow measuring device. Therefore, the Arduino platform with an additional ESP8266 NodeMcu v3 and analog-to-digital converter, module was installed in the scientific article for automatic calibration/checking of ultrasonic flow meters used in irrigation networks. The module is integrated into a 32-bit microcontroller with low power consumption. The ESP8266 NodeMcu v3 module operates at 80 and 160 MHz clock frequencies, supports real-time operating system (RTOS), built-in Wi-Fi, and has a microstrip antenna on board. Through this, the data exchange between the computing equipment and …
Research Of The Fuzzy Control System For Adjusting Thread Tension During The Warping Process,
2024
Tashkent institute of textile and light industry. Address: 5, Shokhjakhon st., 100100, Tashkent city, Republic of Uzbekistan. E-mail: [email protected], Phone: +998974502206.
Research Of The Fuzzy Control System For Adjusting Thread Tension During The Warping Process, To'xtamurod Hayitmurodovich Avezov, Zokhid Ergashboyevich Iskandarov
Chemical Technology, Control and Management
The paper considered issues of research into a fuzzy control system for the warping process. During the warping process, the reasons that cause defects in the final finished product have been studied, firstly (remove this word) which are thread breakage, thread tangling, the formation of loops on or under the belt, hanging loose threads and similar factors. To study the warping process, its mathematical model is constructed. Kinematic parameters of stationary movement corresponding to the equilibrium mode were determined by solving the nonlinear functional matrix - equation of movement. The process of breakage the warp of the threads under oscillation …
Research Of A New Technological Flowsheet Parameters For Uranium Mining From Technogenic Uranium Ores,
2024
Navoi state university of mining and technologies. Address: Street Galaba, 76V, Navoi city, Republic of Uzbekistan. E-mail: [email protected];
Research Of A New Technological Flowsheet Parameters For Uranium Mining From Technogenic Uranium Ores, Nazarov Jamol, G.M. Allaberganova, H.L. Pulatov, A.M. Muzafarov
Chemical Technology, Control and Management
This paper presents the results of a study of the parameters of a new technological scheme for the extraction of uranium from technogenic uranium ores. The results of the analytical determination of the concentration of parent - 238U and daughter radionuclides - 234U , 230Th , 226Ra , 222Rn , 218Pa , 214Pb , etc. are presented . in the studied technogenic uranium ores. The principal scheme of the new uranium extraction technology from technogenic uranium ores is presented. The use of the classifier in a new scheme for separating granules of technogenic …
Assessment Of Metrological Errors Of Recognition Metrics In The Intelligent Control And Regulation System Of The Cotton Harvesting Machine,
2024
Tashkent State Technical University. Address: 2 Universitetskaya st., 100095, Tashkent city, Republic of Uzbekistan; E-mail: [email protected];
Assessment Of Metrological Errors Of Recognition Metrics In The Intelligent Control And Regulation System Of The Cotton Harvesting Machine, Erkin Uljaev, Utkirjon Murodillaevich Ubaydullaev, Azizjon Abdulla Ugli Abdulhamidov
Chemical Technology, Control and Management
This article presents a method for assessing the error of metrics of an intelligent system for monitoring and regulating the width of the working gap of the harvesting apparatus of a cotton picker. To assess the error, the calculation of the average value of the standard deviation of metrics, absolute systematic and random errors, as well as absolute and relative total errors are used. The results of these calculations will allow us to determine the accuracy of the recognition system and opportunities for its improvement.
Environmental Monitoring And Control System Of Greenhouse Based On Internet Of Things Technology,
2024
Institute of Automation, Qilu University of Technology (Shandong Academy of Sciences). Address: 19 Keyuan st., 250000, Jinan city, China. E-mail: [email protected], Phone: +998-77-309-09-17.
Environmental Monitoring And Control System Of Greenhouse Based On Internet Of Things Technology, Ru Jiang, Nadirbek Yusupbekov
Chemical Technology, Control and Management
Greenhouse is an important application scene of modern agriculture. In this paper, a set of greenhouse environmental monitoring, facility remote control and production management system is designed and implemented based on Internet of Things technology for the development needs of modern agriculture in greenhouse. The system selects STM32F407 control board as the main controller to realize real-time monitoring of greenhouse environmental parameters including temperature and humidity, soil nutrients, soil pH and other greenhouse environmental information, and can adjust greenhouse environmental parameters by controlling the irrigation system, roller shutters, fans, shading curtains and other facilities in the greenhouse. The main controller …
Structural And Parametric Identification Of Recycling Systems,
2024
Doctor of Technical Sciences, Professor, Academician of the Academy of Sciences of the Republic of Uzbekistan, Tashkent State Technical University named after Islam Karimov. Address: 2 Universitetskaya st., 100095, Tashkent city, Republic of Uzbekistan;
Structural And Parametric Identification Of Recycling Systems, Khusan Igamberdiev, Madina Mirxalilovma Fozilova
Chemical Technology, Control and Management
The issue of identifying recirculation systems with a specific control loop, in which information and control information about various technological processes circulate, is being considered. A methodology for identifying recirculation systems has been developed, based on algorithms for structural identification of the model based on the results of assessing the sensitivity of the optimum of control parameters and a fuzzy inference algorithm based on production rules that contribute to solving the problem of parametric identification.
