Chemical Engineering Commons^™

Fundamental Study Of Nonlinear Electrophoresis, Joseph Armakan Bentor

All Dissertations

Classical electrophoretic theory describes the linear response of particles suspended in Newtonian fluids under weak electric fields. When the electric field exceeds this weak limit, a nonlinear response arises due to non-uniform surface conduction over the curved particles. This nonlinear behavior introduces dependencies on fluid and particle properties not considered in the classical theory, offering potential advantages for microfluidic particle manipulation. While this phenomenon has been extensively studied theoretically and numerically in Newtonian fluids, experimental investigations have been relatively limited.

Fluid rheology can significantly alter particle dynamics under applied electric fields. Rheological properties like shear-thinning and elasticity which are not …

Analysis Of The Relationship Between Flow Patterns In The Post-Stenotic Region Of Model Arteries And Stenosis Severity., Michael Laroche

Electronic Theses and Dissertations

In this study, contour fields of mean age and turbulence kinetic energy (TKE) in the post-stenotic region of model arteries were analyzed to explore their correlation with FFR. While both high and low FFR cases exhibited similarities with an inner low-age region and an outer high-age region, low FFR cases displayed asymmetry in their low-age regions due to eccentric stenosis. Moreover, gradients of age across the artery diameter were more pronounced for low FFR cases. Additionally, low FFR cases demonstrated significantly higher TKE in the post-stenotic blood jet stream compared to high FFR cases that are reflected in low-age boundary …

Investigating The Detection And Transport Of Low Molecular Weight Species To Better Understand Their Impact On Disease Pathology And Treatment, Haley Michelle Duncan

Graduate Theses and Dissertations

Due to the drastic differences in the projects involved, this dissertation will be split into two sections: Alzheimer’s disease and chronic kidney disease. Each chapter will contain an introduction, materials and methods section, results and discussion, conclusions, and works cited section. The Alzheimer’s disease chapter will also have a supplemental figures section containing the polyacrylamide gels that were silver stained and quantified via ImageJ. The presence of elevated levels of amyloid beta oligomeric species in the brain has been related to the pathology of Alzheimer’s disease. As these oligomeric species are transient in nature, their kinetics pose a challenge to …

Comparing Gas Composition From Fast Pyrolysis Of Live Foliage Measured In Bench-Scale And Fire-Scale Experiments, David R. Weise, Thomas H. Fletcher, Timothy J. Johnson, Wei Min Hao, Mark Dietenberger, Marko Princevac, Bret W. Butler, Sara S. Mcallister, Joseph J. O'Brien, E Louise Loudermilk, Roger D. Ottmar, Andrew T. Hudak, Akira Kato, Babak Shotorban, Shankar Mahalingham, Tanya L. Myers, Javier Palarea-Albaladejo, Stephen P. Baker

Faculty Publications

Background. Fire models have used pyrolysis data from oxidising and non-oxidising environments for flaming combustion. In wildland fires pyrolysis, flaming and smouldering combustion typically occur in an oxidising environment (the atmosphere). Aims. Using compositional data analysis methods, determine if the composition of pyrolysis gases measured in non-oxidising and ambient (oxidising) atmospheric conditions were similar. Methods. Permanent gases and tars were measured in a fuel-rich (non-oxidising) environment in a flat flame burner (FFB). Permanent and light hydrocarbon gases were measured for the same fuels heated by a fire flame in ambient atmospheric conditions (oxidising environment). Log-ratio balances of the measured gases …

Fatigue Performance Of 3d-Printed Poly-Lactic-Acid Bone Scaffolds With Triply Periodic Minimal Surface And Voronoi Pore Structures, Hamed Bakhtiari, Alireza Nouri, Majid Tolouei-Rad

Research outputs 2022 to 2026

Bone scaffolds serve a crucial role in tissue engineering, particularly in facilitating bone regeneration where natural repair is insufficient. Despite advancements in the fabrication of polymeric bone scaffolds, the challenge remains to optimize their mechanical resilience. Specifically, research on the fatigue behaviour of polymeric bone scaffolds is scarce. This study investigates the influence of pore architecture on the mechanical performance of poly-lactic-acid (PLA) scaffolds under quasi-static and cyclic compression. PLA scaffolds with a 60% porosity were fabricated using extrusion-based 3D printing in various designs: Gyroid, Lidinoid, Fischer–Koch, IWP, and Voronoi. Results demonstrated that Gyroid scaffolds had the highest compressive strength …

Design And Development Of Uio-67-Coated Pim-1-Based Composites And Demonstration Of Their Detoxification Performance, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

Polymer-supported MOF composites have emerged as versatile candidates for various separation and catalytic applications. In this study, we demonstrate design and development of UiO-67-coated Ce(OH)₄@PIM-1 composites via dip-coating, drop-casting, solid-phase coating, and supramolecular assembly, and assess their preparation-structure-performance relations. The catalytic performance of the composites was investigated through hydrolysis of dimethyl 4-nitrophenyl phosphate (DMNP), as a nerve agent simulant. The findings revealed that while dip-coating method was unable to achieve a thick and uniform coverage of the MOF layer on the Ce(OH)₄@PIM-1, the supramolecular assembly gave rise to 16 wt.% MOF loading and the composite prepared …

Constant-Ph Molecular Dynamics At Inorganic Interfaces: Adding A New Dimension To Simulations Of Interfacial Phenomena., Ted Kalbfleisch

Electronic Theses and Dissertations

This dissertation explores the application of novel molecular dynamics simulation methods to better understand complex systems, with a particular focus on silica materials and protein interactions. Silica materials, known for their versatile surface and solution chemistries, play critical roles in catalysis, chromatography, and wastewater treatment. Despite their widespread use, the molecular-level interactions between silica surfaces and their environments remain poorly understood. To address this knowledge gap, we employed λ-dynamics enabled constant pH molecular dynamics to dynamically model protonation and deprotonation events on silica surfaces. Traditional experimental techniques such as x-ray crystallography, NMR, and cryo-EM are inadequate for probing structures in …

Carboxen Micropreconcentrator Performance For Analyzing Btex In Air., Raymond Daniel Spargo

Electronic Theses and Dissertations

Volatile Organic Compounds (VOCs) are a class of toxic chemicals in environmental air associated with several serious health risks. Some of the most common and concerning VOCs are Benzene, Toluene, Ethyl Benzene, and Xylene (BTEX). To maintain healthy air quality in these environments, researchers pursue instruments and processes to quickly and accurately predict sub-ppb concentrations of BTEX in indoor and outdoor air. By employing a micropreconcentrator (μPC) to combine Solid-Phase Micro-Extraction (SPME) with Gas Chromatography Mass Spectrometry (GC-MS) analysis, trace BTEX content in air samples can be captured, extracted and analyzed. In this thesis, a dual-compartment μPC with Carboxen 1000 …

Genetically-Encoded Optical Barcodes For Single-Cell Analysis, Daniel Pritko

All Theses

Cell barcodes are capable of being used to answer many different biological questions. They have been used to track the lineage of cells to identifying the function of a gene. While there are multiple different methods to creating cell barcodes, they are limited in their scalability and application. In a previous publication we propose and computationally prove an optical single-cell barcoding method that bridges fast and scalable readouts with the benefits of genetic encoding. In this approach fluorescent proteins (fps) are combined to form fluorescent barcodes that can then be analyzed using a spectral flow cytometer. Here, we test the …

Extraction Of Neutron-Gamma Irradiated Diffusion Pump Oils, Cooper L. Tillman

All Theses

This work successfully demonstrates solvent extraction methods for separation of oil from the by-products when two commercially available vacuum pump oils were exposed to an intense neutron and gamma-ray radiation environment. Nuclear fusion power at a commercial scale has accelerated the need for radiation resistant vacuum technology, such as oil-based diffusion pumps. Polyphenyl ether and aromatic silicone oils were irradiated at the Rhode Island Nuclear Science Center (RINSC) up to MGy absorbed doses with neutron and gamma-ray radiation. Solvent extractions were performed using hexane and isopropanol to characterize the oil extraction as a function of total absorbed dose. The by-products …

Modeling Rate Dependent Volume Change In Porous Electrodes In Lithium-Ion Batteries, Taylor R. Garrick, Miguel A. Fernandez, Brian J. Koch, Erin Efimoff, Matthew Jones, Rafid Mollah, Hunter Teel, Xiaoniu Du, Sirivatch Shimpalee, Song-Yul Choe, Venkat R. Subramanian, Jason B. Siegel

Faculty Publications

Automotive manufacturers are working to improve individual cell, module, and overall pack design by increasing the performance, range, and durability, while reducing cost. One key piece to consider during the design process is the active material volume change, its linkage to the particle, electrode, and cell level volume changes, and the interplay with structural components in the rechargeable energy storage system. As the time from initial design to manufacture of electric vehicles decreases, design work needs to move to the virtual domain; therefore, a need for coupled electrochemical-mechanical models that take into account the active material volume change and the …

Mixed Potential Sensor For Natural Gas Leak Detection Design, Manufacturing, And Simulation, Sleight Halley

Chemical and Biological Engineering ETDs

There is a need for a low-cost robust sensor accurately detecting leaks from oil and gas infrastructure. This work presents the development of an electrochemical sensor based on an yttria stabilized zirconia (YSZ) electrolyte with La_0.87Sr_0.13CrO₃, Indium Tin Oxide (In₂O₃ 90 wt%, SnO₂ 10 wt%), Au, Pt electrodes. Selectivity to target gasses of the three sensing electrodes in conjunction with machine learning allows for the accurate discrimination between possible methane sources as well as the quantification of methane concentration. Sensor sensitivity is improved through a low-ionic conductivity substrate of magnesia …

Advances In Electrocatalytic Dehydrogenation Of Ethylamine To Acetonitrile, Yanlin Zhu, Dezhen Wu, Jinyao Tang, Dakota Braaten, Bin Liu, Zhenmeng Peng

Faculty Publications

The electrocatalytic dehydrogenation of ethylamine (EDH), owing to its high hydrogen content, holds broad prospects in electrochemical hydrogen (H2) production, H2 storage, and addressing energy issues, thus deserving wide attention. In this feature article, we first summarized the fundamentals of thermocatalytic and electrocatalytic EDH and reviewed the recent state-of-the-art advances in catalyst research, specifically platinum group metal (PGM) catalysts and non-PGM catalysts. We systematically discussed the potential applications of electrocatalytic EDH in energy storage and conversion. Finally, we provide our perspective on the key challenges and future developments in this field. We believe this feature article will offer helpful guidance …

Opening And Constructing Stable Lithium-Ion Channels Within Polymer Electrolytes, Yangmingyue Zhao, Libo Li, Da Zhou, Yue Ma, Yonghong Zhang, Hang Yang, Shubo Fan, Hao Tong, Suo Li, Wenhua Qu

School of Integrative Biological & Chemical Sciences Faculty Publications

Lithium-ion batteries play an integral role in various aspects of daily life, yet there is a pressing need to enhance their safety and cycling stability. In this study, we have successfully developed a highly secure and flexible solid-state polymer electrolyte (SPE) through the in-situ polymerization of allyl acetoacetate (AAA) monomers. This SPE constructed an efficient Li+ transport channel inside and effectively improved the solid-solid interface contact of solid-state batteries to reduce interfacial impedance. Furthermore, it exhibited excellent thermal stability, an ionic conductivity of 3.82×10-4 S cm-1 at room temperature (RT), and a Li+ transport number (tLi+) of 0.66. The numerous …

Experimental Study On The Effect Of Micro Concentrations Of Hybrid Nanofluids Through Microchannel Heat Sinks, Mohamed Salaheldin Elsherbiny, Moustafa Ali, Moatsem Shahin, Mahmoud El-Kady

Renewable Mechanical Energy

The current study examines the convective heat transfer coefficient experimentally. It assesses the performance of Al2O3, CuO, ZnO, and Ag/ distilled water nanofluids up to a tetra level of hybridization utilized in microprocessor cooling systems equipped with MCHS. An equal ratio of 50%, 33.3%, and 25% for di-, tri-, and tetra-nanofluids, respectively, with a focus on micro-volume fraction 0.025% and comparing it with 0.05%. Operating conditions were as follows: heat loading from 136.4 up to 196.4 watts; and flow rate from 0.35 up to 0.5 LPM. The findings showed that all types of mono nanofluids showed an increase in Nu …

Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (1/4): Report 1: High-Performance Oxygen Reduction Catalysts For Fuel Cells, Fa-Dong Chen, Zhuo-Yang Xie, Meng-Ting Li, Si-Guo Chen, Wei Ding, Li Li, Jing Li, Zi-Dong Wei

Journal of Electrochemistry

Two major challenges, high cost and short lifespan, have been hindering the commercialization process of low-temperature fuel cells. Professor Wei’s group has been focusing on decreasing cathode Pt loadings without losses of activity and durability, and their research advances in this area over the past three decades are briefly reviewed herein. Regarding the Pt-based catalysts and the low Pt usage, they have firstly tried to clarify the degradation mechanism of Pt/C catalysts, and then demonstrated that the activity and stability could be improved by three strategies: regulating the nanostructures of the active sites, enhancing the effects of support materials, and …

Kai Wu, The Editorial Board Member Of Journal Of Electrochemistry And Chief Scientist Of Catl, Receives The National Science And Technology Progress Award, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Sorbitol-Electrolyte-Additive Based Reversible Zinc Electrochemistry, Qiong Sun, Hai-Hui Du, Tian-Jiang Sun, Dian-Tao Li, Min Cheng, Jing Liang, Hai-Xia Li, Zhan-Liang Tao

Journal of Electrochemistry

The unstable zinc (Zn)/electrolyte interfaces formed by undesired dendrites and parasitic side reactions greatly hinder the development of aqueous zinc ion batteries. Herein, the hydroxy-rich sorbitol was used as an additive to reshape the solvation structure and modulate the interface chemistry. The strong interactions among sorbitol and both water molecules and Zn electrode can reduce the free water activity, optimize the solvation shell of water and Zn²⁺ ions, and regulate the formation of local water (H₂O)-poor environment on the surface of Zn electrode, which effectively inhibit the decomposition of water molecules, and thus, achieve the thermodynamically stable …

First Announcement Of 76th Annual Meeting Of The International Society Of Electrochemistry, International Society Of Electrochemistry (Ise)

Journal of Electrochemistry

No abstract provided.

Professor Yong Yang, The Editorial Board Member Of Journal Of Electrochemistry, Is Elected As A Fellow Of The Electrochemical Society, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.