Induction Vacuum Swing Adsorption Over Magnetic Sorbent Monoliths And Extrudates For Ethylene/Ethane Separation,
2024
Missouri University of Science and Technology
Induction Vacuum Swing Adsorption Over Magnetic Sorbent Monoliths And Extrudates For Ethylene/Ethane Separation, Khaled Baamran, Usman Shareef, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Electrification of adsorption processes is emerging as an adaptable solution for future gas separations. This study develops magnetic sorbent structures for use in induction vacuum swing adsorption (IVSA) process specifically designed for olefin/paraffin separation. Two sorbents, namely Fe3O4/ZIF-7 (ethane-selective) and Fe3O4/13X (ethylene-selective) were developed and formulated into extrudates (Fe20/ZIF-7-P) and monoliths (Fe20/13X-M), and tested under different regeneration scenarios, including simultaneous and subsequent induction-evacuation, induction only, and evacuation only. The dynamic adsorption results demonstrated that regeneration under subsequent induction-evacuation improves desorption rate and capability. Under this regeneration scenario, Fe …
High–Strength Porous Tinbzrtafe Alloys Fabricated By Sintering Of Nanocomposite Powder Precursor With Space Holder Technique,
2024
Edith Cowan University
High–Strength Porous Tinbzrtafe Alloys Fabricated By Sintering Of Nanocomposite Powder Precursor With Space Holder Technique, Yuhua Li, Yuxin He, Rong Zhao, Libin Niu, Juxin Qu, Lai Chang Zhang
Research outputs 2022 to 2026
Although introducing high porosity in biomedical Ti alloys can reduce their elastic modulus and promote new bone ingrowth, relieving the stress–shielding effect and implant failure, this also causes a decline in the alloys’ mechanical strength. In this work, a new preparation method for the high–strength and high–porosity Ti65Nb23.33Zr5Ta1.67Fe5 (TNZTF, at.%) alloy was suggested by sintering nanocomposite powder precursor in combination with the use of a space holder technique, in which NH4HCO3 is adopted to achieve a porous structure. The highly porous TNZTF alloy possesses a homogeneous fine–grained microstructure consisting of equiaxed α–Ti and a small amount of FeTi2, the latter …
Dual Light Emission Of Cssni3-Based Powders Synthesized Via A Mechanochemical Process,
2024
University of Kentucky
Dual Light Emission Of Cssni3-Based Powders Synthesized Via A Mechanochemical Process, Xuan Huang, Xiaobing Tang, Xiyu Wen, Yuebin Charles Lu, Fuqian Yang
Chemical and Materials Engineering Faculty Publications
Lead toxicity has hindered the wide applications of lead halide perovskites in optoelec- tronics and bioimaging. A significant amount of effort has been made to synthesize lead-free halide perovskites as alternatives to lead halide perovskites. In this work, we demonstrate the feasibility of synthesizing CsSnI3-based powders mechanochemically with dual light emissions under ambi- ent conditions from CsI and SnI2 powders. The formed CsSnI3-based powders are divided into CsSnI3-dominated powders and CsSnI3-contained powders. Under the excitation of ultraviolet light of 365 nm in wavelength, the CsSnI3-dominated powders emit green light with a wavelength centered at 540 nm, and the CsSnI3-contained powders …
Impact Of Non-Thermal Plasma Generated Using Air And Nitrogen On Functional Properties Of Milk Protein Dispersions,
2024
University of Arkansas, Fayetteville
Impact Of Non-Thermal Plasma Generated Using Air And Nitrogen On Functional Properties Of Milk Protein Dispersions, Nikitha Modupalli, Md Mahfuzur Rahman
Food Science Faculty Publications and Presentations
This study focuses on improving the functionalities of milk protein concentrate (MPC) using a nonthermal plasma jet and plasma-activated water (PAW) with atmospheric air and nitrogen as source gases. The 5% and 10% MPC dispersions were directly treated with a plasma jet, and PAW was used to make the MPC dispersions. The dispersions were analyzed for changes in protein structure and functional properties. The treatment altered the secondary structure of MPC protein structure by increasing β-components and changing the order of random coils. The solubility of the PAW-treated 5% protein dispersions doubled due to plasma-induced modification of hydrophilic and covalent …
Response To Replication Stress And Maintenance Of Genome Stability By Wrn, The Werner Syndrome Protein,
2024
University of Kentucky
Response To Replication Stress And Maintenance Of Genome Stability By Wrn, The Werner Syndrome Protein, David K. Orren, Amrita Machwe
Markey Cancer Center Faculty Publications
Werner syndrome (WS) is an autosomal recessive disease caused by loss of function of WRN. WS is a segmental progeroid disease and shows early onset or increased frequency of many characteristics of normal aging. WRN possesses helicase, annealing, strand exchange, and exonuclease activities and acts on a variety of DNA substrates, even complex replication and re- combination intermediates. Here, we review the genetics, biochemistry, and probably physiological functions of the WRN protein. Although its precise role is unclear, evidence suggests WRN plays a role in pathways that respond to replication stress and maintain genome stability particularly in telomeric regions.
Preparation, Reaction Mechanism And Microwave-Absorbing Application Of Functional Transition Metal Carbide/Nitride Ceramic Materials,
2024
Edith Cowan University
Preparation, Reaction Mechanism And Microwave-Absorbing Application Of Functional Transition Metal Carbide/Nitride Ceramic Materials, Zhengbo Xu, Shu Qing Kou, Bai Xin Dong, Xinmiao Zhong, Hongyu Yang, Lin Liu, Ruifen Guo, Shi Li Shu, Feng Qiu, Lai Chang Zhang
Research outputs 2022 to 2026
The explosive growth of wireless communications and electronic devices has brought electromagnetic radiation's harmfulness and hidden trouble to light, which has a major impact on electrical equipment's ability to function normally. MXene, a material with favorable features like conductivity, a unique two-dimensional multiple-layer structure and abundant surface functional groups, has made it a viable contender for high-performance microwave-absorbers. This article introduces the synthesis strategy of MXene/MXene-based materials and their parent phase MAX, comprehensively summarizes and analyzes the current progress in the study on the microwave-absorbing properties of MXene/MXene-based materials, analyzes the main problems and bottlenecks. Future research directions for MXene …
Resilient Forward Osmosis Membranes Against Microplastics Fouling Enhanced By Mwcnts/Uio-66-Nh2 Hybrid Nanoparticles,
2024
Edith Cowan University
Resilient Forward Osmosis Membranes Against Microplastics Fouling Enhanced By Mwcnts/Uio-66-Nh2 Hybrid Nanoparticles, Mitra Golgoli, Javad Farahbakhsh, Mohadeseh Najafi, Mehdi Khiadani, Michael L. Johns, Masoumeh Zargar
Research outputs 2022 to 2026
The escalating presence of microplastics (MPs) in wastewater necessitates the investigation of effective tertiary treatment process. Forward osmosis (FO) emerges as an effective non-pressurized membrane process, however, for the effective implementation of FO systems, the development of fouling-resistance FO membranes with high-performance is essential. This study focuses on the integration of MWCNT/UiO-66-NH2 as metal-organic frameworks (MOFs) and multi-wall carbon nanotubes (MWCNT) nanocomposites in thin film composite (TFC) FO membranes, harnessing the synergistic power of hybrid nanoparticles in FO membranes. The results showed that the addition of MWCNT/UiO-66-NH2 in the aqueous phase during polyamide formation changed the polyamide surface structure, and …
Rock Structural Changes Monitored By Fibre Bragg Grating Sensors And Nuclear Magnetic Resonance During Static And Dynamic Carbonated Brine Core Flooding Experiments,
2024
Edith Cowan University
Rock Structural Changes Monitored By Fibre Bragg Grating Sensors And Nuclear Magnetic Resonance During Static And Dynamic Carbonated Brine Core Flooding Experiments, Bruno Da Silva Falcão, Lionel Esteban, Ausama Giwelli, Ahmed Al-Yaseri, Alireza Keshavarz, Jeremie Dautriat, Stephanie Vialle, Stefan Iglauer
Research outputs 2022 to 2026
One proposed solution to reduce greenhouse gas emissions is the capture and storage of carbon dioxide (CCS) in geological formations such as depleted oil and gas reservoirs. Injected carbon dioxide (CO2) forms carbonic acid once dissolved in the formation water, which can lead to dissolution of certain types of rock minerals. This may weaken rock geomechanical properties that can jeopardize the safety of long-term storage. In this work, the use of Fibre Bragg Grating (FBG) sensors associated with Nuclear Magnetic Resonance (NMR) was investigated to measure the change in rock strain during core flooding experiments. Optical fibres were glued onto …
Simulation Of A Passive Osmosis-Integrated Electrolyzer For Seawater Electrolysis,
2024
University of South Carolina
Simulation Of A Passive Osmosis-Integrated Electrolyzer For Seawater Electrolysis, Masoomeh Ghasemi
Theses and Dissertations
Efforts to develop direct seawater electrolysis technology have been ongoing due to the need for pure water in electrolysis and the abundance of seawater. However, progress has been hampered by several issues, including competition with the chlorine evolution reaction, higher membrane resistance, corrosion of electrodes, and scaling from multivalent cations [1]. To avoid these issues, our project has proposed a new reactor that integrates passive osmosis (extracting fresh water from seawater) with electrolysis. In this thesis, we will discuss the operation of the osmosis-integrated electrolyzer and show theoretical predictions of the osmotic pressure differential and water flux/velocity profiles under different …
Dynamic Metabolic Flux Analysis Amidst Data Variability: Sphingolipid Biosynthesis Case Study In Arabidopsis Thaliana Cell Cultures,
2024
University of Nebraska-Lincoln
Dynamic Metabolic Flux Analysis Amidst Data Variability: Sphingolipid Biosynthesis Case Study In Arabidopsis Thaliana Cell Cultures, Abraham Boluwatife Osinuga
Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research
Sphingolipids are pivotal for plant development and stress responses. Growing interest has been directed towards fully comprehending the regulatory mechanisms of the sphingolipid pathway. In this study, we explore its de novo biosynthesis and homeostasis in Arabidopsis thaliana cell cultures, shedding light on fundamental metabolic mechanisms. Employing 15N isotope labeling and quantitative dynamic modeling approach, we obtained data with notable variations and developed a regularized and constraint-based Dynamic Metabolic Flux Analysis (r-DMFA) framework to predict metabolic shifts due to enzymatic changes. Our analysis revealed key enzymes such as sphingoid-base hydroxylase (SBH) and long-chain-base kinase …
Applications Of Catalytic Ammonia Chemistry: From Low-Pressure Ammonia Synthesis To The Decomposition Of Tritiated Ammonia As A By-Product Of Magnetically Confined Nuclear Fusion,
2024
University of South Carolina
Applications Of Catalytic Ammonia Chemistry: From Low-Pressure Ammonia Synthesis To The Decomposition Of Tritiated Ammonia As A By-Product Of Magnetically Confined Nuclear Fusion, Jennifer Kules Naglic
Theses and Dissertations
Ammonia is the 2nd most produced chemical in the world with vital importance for its use in fertilizer as the global population has grown in accordance with the industrialization of NH3. While 80% of NH3 produced goes to fertilizer, it has gained attention recently as a hydrogen storage and transportation vessel. Industrially, NH3 is produced at high temperatures and pressures which in turn require high electrical input. Turning to a green NH3 cycle with low temperature and pressure membrane reactors for both NH3 synthesis and decomposition would allow for much lower energy input as well as a renewable energy to …
Investigation Of Ethane Dehydrogenation And Hydrogenolysis On Pt(111), Pt(211) And Pt(100): Bayesian Quantification And Correction Of Dft-Based Enthalpic And Entropic Uncertainties,
2024
University of South Carolina
Investigation Of Ethane Dehydrogenation And Hydrogenolysis On Pt(111), Pt(211) And Pt(100): Bayesian Quantification And Correction Of Dft-Based Enthalpic And Entropic Uncertainties, Mubarak Bello
Theses and Dissertations
Computational investigations of heterogeneously catalyzed reactions using density functional theory (DFT) are often inaccurate, largely due to uncertainties in the choice of DFT functional (enthalpic uncertainty) and approximations for modeling adsorbate movement along the catalyst surface (entropic uncertainty). This work illustrates that both uncertainties are significant in the investigation of the ethane dehydrogenation (EDH) and hydrogenolysis on Pt catalysts by considering the complete deconstruction of ethane on Pt(111), Pt(211), and Pt(100) using microkinetic modeling (MKM). Hence, this work uses both non-calibrated and Bayesian calibrated MKMs to quantify and correct inaccuracies in macroscopic properties due to both uncertainties. A Bayesian approach …
Exploring Shape Dependency Of Catalysts For Chemical Reactions,
2024
University of South Carolina
Exploring Shape Dependency Of Catalysts For Chemical Reactions, Kaveh Shariati
Theses and Dissertations
Recent advancements in the synthesis of nanoparticles, particularly one-dimensional (1D) nanoparticles, have significantly enhanced the catalytic activity of various processes by enabling precise control over their morphologies and exposing unique crystallographic facets. The shape of nanoparticles is closely linked to their chemical, physical, electrical, optical, magnetic, and catalytic properties. This dissertation investigates the impact of 1D nanoparticle catalysts on two distinct and well-known chemical reactions. In the first part of the study, we explore the catalytic activity and selectivity of silver catalysts in the ethylene epoxidation reaction, which are intrinsically linked to their faceting. Silver nanowire catalysts representing Ag(100) and …
Characteristics Of Pyrolysis Products Of California Chaparral And Their Potential Effect On Wildland Fires,
2024
Brigham Young University - Provo
Characteristics Of Pyrolysis Products Of California Chaparral And Their Potential Effect On Wildland Fires, Mahsa Alizadeh, David R. Weise, Thomas H. Fletcher
Faculty Publications
The aim of this study was to investigate the pyrolysis of selected California foliage and estimate the energy content of the released volatiles to show the significance of the pyrolysis of foliage and its role during wildland fires. While the majority of the volatiles released during the pyrolysis of foliage later combust and promote fire propagation, studies on the energy released from combustion of these compounds are scarce. Samples of chamise (Adenostoma fasciculatum), Eastwood’s manzanita (Arctostaphylos glandulosa), scrub oak (Quercus berberidifolia), hoaryleaf ceanothus (Ceanothus crassifolius), all native to southern California, and sparkleberry …
Optimizing The Expression Of Polyethylene Terephtalate Hydrolase-Encoding Synthetic Gene In Escherichia Coli Arctic Express (De3),
2024
Department of Biology, University of Indonesia, Depok 16424, West Java
Optimizing The Expression Of Polyethylene Terephtalate Hydrolase-Encoding Synthetic Gene In Escherichia Coli Arctic Express (De3), Jocelyn Nataniel, Maria Ulfah, Dini Achnafani, Niknik Nurhayati, Gabriela Christy Sabbathini, Sri Rezeki Wulandari, Abinawanto Abinawanto, Is Helianti
Makara Journal of Science
The waste of polyethylene terephthalate (PET) plastic waste in Indonesia is a pressing concern due to its slow degradation and potential environmental damage. One promising solution is to utilize polyethylene terephthalate hydrolase from Ideonella sakaiensis (IsPETase), an enzyme that specifically degrades PET. However, inducing the expression of IsPETase synthetic gene in Escherichia coli BL21 (DE3) has been challenging because much of it remains insoluble. This study aimed to express IsPETase in E. coli Arctic Express (DE3) and optimize the conditions to enhance its production. First, pET22b(+)pelB-IsPETase was inserted into E. coli Arctic Express (DE3). The …
Preparation Of Β-Ni (Oh)2 Nanosheet–Modified Glassy Carbon For Pseudocapacitors,
2024
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok 16424, Indonesia
Preparation Of Β-Ni (Oh)2 Nanosheet–Modified Glassy Carbon For Pseudocapacitors, Muhammad Buchari Setia Putra, Aliyah Aliyah, Afiten Rahmin Sanjaya, Respati Kevin Pramadewandaru, Hoeil Chung, Tribidasari Anggraningrum Ivandini
Makara Journal of Science
β-Nickel hydroxide (Ni(OH)2) nanosheet–modified glassy carbon for pseudocapacitors was successfully prepared. The nanosheets were synthesized via a conventional growth seeding method combined with hydrothermal treatment. Transmission electron microscopy (TEM) characterization indicated the hexagonal structure of the nanosheets of around 15 nm in size, and X-ray diffraction (XRD) pattern confirmed the β-phase lattice crystal. These nanosheets used to modify the glassy carbon surface, increased the electroactive surface area by around 15 times. Furthermore, electrochemical investigation of the modified glassy carbon revealed an excellent performance and a specific capacitance of 628.01 F g−1 at a 1 A g−1 …
Decision-Making Algorithms For Drilling Instrument Control Systems,
2024
Tashkent State Technical University. Address: 2 Universitetskaya st., 100095, Tashkent city, Republic of Uzbekistan. E-mail: [email protected].
Decision-Making Algorithms For Drilling Instrument Control Systems, Fuzayl Fozil Ugli Odilov
Chemical Technology, Control and Management
The control of the movement of the drilling tool and the structure of the well are considered. An effective control algorithm for drilling systems that provides control of well trajectory parameters is analyzed. In technological processes, it is necessary to control several parameters or several systems at the same time. It is considered necessary to create decision-making algorithms for the formation of managerial effects for the control system of such technological processes. The controlled oriented type of the bottom of the drill string was analyzed. Work was carried out on the decision-making algorithm for the processing of control effects. The …
Environmental Monitoring And Control System Of Greenhouse Based On Internet Of Things Technology,
2024
Institute of Automation, Qilu University of Technology (Shandong Academy of Sciences). Address: 19 Keyuan st., 250000, Jinan city, China. E-mail: [email protected], Phone: +998-77-309-09-17.
Environmental Monitoring And Control System Of Greenhouse Based On Internet Of Things Technology, Ru Jiang, Nadirbek Yusupbekov
Chemical Technology, Control and Management
Greenhouse is an important application scene of modern agriculture. In this paper, a set of greenhouse environmental monitoring, facility remote control and production management system is designed and implemented based on Internet of Things technology for the development needs of modern agriculture in greenhouse. The system selects STM32F407 control board as the main controller to realize real-time monitoring of greenhouse environmental parameters including temperature and humidity, soil nutrients, soil pH and other greenhouse environmental information, and can adjust greenhouse environmental parameters by controlling the irrigation system, roller shutters, fans, shading curtains and other facilities in the greenhouse. The main controller …
Structural And Parametric Identification Of Recycling Systems,
2024
Doctor of Technical Sciences, Professor, Academician of the Academy of Sciences of the Republic of Uzbekistan, Tashkent State Technical University named after Islam Karimov. Address: 2 Universitetskaya st., 100095, Tashkent city, Republic of Uzbekistan;
Structural And Parametric Identification Of Recycling Systems, Khusan Igamberdiev, Madina Mirxalilovma Fozilova
Chemical Technology, Control and Management
The issue of identifying recirculation systems with a specific control loop, in which information and control information about various technological processes circulate, is being considered. A methodology for identifying recirculation systems has been developed, based on algorithms for structural identification of the model based on the results of assessing the sensitivity of the optimum of control parameters and a fuzzy inference algorithm based on production rules that contribute to solving the problem of parametric identification.
Research Of A New Technological Flowsheet Parameters For Uranium Mining From Technogenic Uranium Ores,
2024
Navoi state university of mining and technologies. Address: Street Galaba, 76V, Navoi city, Republic of Uzbekistan. E-mail: [email protected];
Research Of A New Technological Flowsheet Parameters For Uranium Mining From Technogenic Uranium Ores, Nazarov Jamol, G.M. Allaberganova, H.L. Pulatov, A.M. Muzafarov
Chemical Technology, Control and Management
This paper presents the results of a study of the parameters of a new technological scheme for the extraction of uranium from technogenic uranium ores. The results of the analytical determination of the concentration of parent - 238U and daughter radionuclides - 234U , 230Th , 226Ra , 222Rn , 218Pa , 214Pb , etc. are presented . in the studied technogenic uranium ores. The principal scheme of the new uranium extraction technology from technogenic uranium ores is presented. The use of the classifier in a new scheme for separating granules of technogenic …
