Chemical Engineering Commons^™

Investigation Of Cased Wellbore Integrity In The Wabamun Area Sequestration Project, Benjamin Lee Weideman

Masters Theses

"Loss of cased wellbore integrity can cause many significant problems, including lost production, aquifer contamination, blowouts, and other environmental damage. The objective of this study is to conduct an analysis of the Wabamun Area Sequestration Project (WASP) to determine if wells in that area are suitable for CO₂ sequestration. This was done by conducting laboratory experiments on the common cement compositions found in the area, simulating the various conditions possible in a wellbore, and by analyzing three case studies from the WASP. The cases include two existing production wells and a proposed injection well specifically designed for CO₂ sequestration. This …

Data Mining And Statistical Analysis Of Completions In The Canadian Montney Formation, Mustafa Adil Al-Alwani

Masters Theses

"This thesis documents a data-mining study and statistical analysis of well completion methods and their impact on production for more than 3300 horizontal wells in the Canadian Montney resource play.

The statistical software JMP is used to analyze well and production data for both horizontal Montney gas and oil wells, examining production trends with changes in completion parameters, such as the type of completion, fluid volume pumped, proppant load, number of fracture stages and completion costs. The analysis also provides a general understanding of average treatment characteristics, and how completions have changed with time for the Montney play.

Among the …

Influence Of Erosional Unloading On The State Of Stress For Low Amplitude Single-Layer Buckle Folds - Implications For Tensile Fracture Occurrence, Mengke Li

Masters Theses

"The existence of fractures associated to buckle folds is related to the strain distribution of the fold. The erosional unloading process can amplify the remnant strain in the folded layer. Two-dimensional plane strain Finite Element Analysis (FEA) is used to investigate the influence of the erosional unloading step on both the evolution of the state of stress and the associated failure patterns in low amplitude buckle folds. Sensitivity analyses on different input parameters, including viscosity, shortening ratio, and overburden pressure, are performed. Based on the simulation results, tensile stress can be initiated both in the crest and in the limb …

Performance Comparison Of Transverse And Longitudinal Fractured Horizontal Wells Over Varied Reservoir Permeability, Fen Yang

Masters Theses

"Since the first application in the mid-1980's, multiple fractured horizontal wells have proven to be an effective means of extracting hydrocarbons. These wells require careful consideration of wellbore orientation relative to the horizontal principle stress. Wellbore orientation can lead to transverse fractures which are perpendicular to the wellbore, or longitudinal fractures parallel the wellbore. Questions arise regarding whether one fracture orientation is consistently preferred over the other, or if certain conditions affect the choice.

Historical work has examined the impact of horizontal wellbore azimuth in the Barnett and Marcellus Shale where public data was reviewed and statistical well analysis was …

Effects Of Sodium Hydroxide Pretreatment On Structural Components Of Biomass, Alicia A. Modenbach, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

Pretreatment is a unit operation in the conversion of biomass to valuable products that utilizes various combinations of conditions, including chemicals, heat, pressure, and time, to reduce the recalcitrance of lignocellulose. Many such pretreatments have been developed over the years, as the operating conditions can be adapted so that lignocellulose is modified in ways unique to each pretreatment. By tailoring pretreatment conditions to achieve these modifications, the types of final products produced can be controlled. The purpose of this review is to provide a consolidated source of information for sodium hydroxide effects on lignocellulose. The structural characteristics of lignocellulose and …

Rheological Signatures In Limit Cycle Behaviour Of Dilute, Active, Polar Liquid Crystalline Polymers In Steady Shear, M. Gregory Forest, Panon Phuworawong, Qi Wang, Ruhai Zhou

Mathematics & Statistics Faculty Publications

We consider the dilute regime of active suspensions of liquid crystalline polymers (LCPs), addressing issues motivated by our kinetic model and simulations in Forest et al. (Forest et al. 2013 Soft Matter 9, 5207-5222 (doi:10.1039/c3sm27736d)). In particular, we report unsteady two-dimensional heterogeneous flow-orientation attractors for pusher nanorod swimmers at dilute concentrations where passive LCP equilibria are isotropic. These numerical limit cycles are analogous to longwave (homogeneous) tumbling and kayaking limit cycles and two-dimensional heterogeneous unsteady attractors of passive LCPs in weak imposed shear, yet these states arise exclusively at semi-dilute concentrations where stable equilibria are nematic. The results in Forest …

Development Of Cementitious Materials For Adhesion Type Applications Comprising Calcium Sulfoaluminate (Csa) Cement And Latex Polymer, Joshua V. Brien

Theses and Dissertations--Civil Engineering

The objective of this research was to develop high performing polymer modified calcium sulfoaluminate (CSA) cement materials for use in applications requiring superior adhesion characteristics. Little information is available describing interactions of CSA cement containing minor phase tri-calcium aluminate (C₃A) with commonly used admixtures. Given the scarcity of information, a basic approach for developing cementitious materials was followed. The basic approach consisted of four tasks: cement design, admixture design, polymer design and testing developed materials. The iterative, time consuming process is necessary for understanding the influence of specific constituent components on overall system behavior. Results from the cement …

Quantification Of Factors Governing Drug Release Kinetics From Nanoparticles: A Combined Experimental And Mechanistic Modeling Approach, Kyle Daniel Fugit

Theses and Dissertations--Pharmacy

Advancements in nanoparticle drug delivery of anticancer agents require mathematical models capable of predicting in vivo formulation performance from in vitro characterization studies. Such models must identify and incorporate the physicochemical properties of the therapeutic agent and nanoparticle driving in vivo drug release. This work identifies these factors for two nanoparticle formulations of anticancer agents using an approach which develops mechanistic mathematical models in conjunction with experimental studies.

A non-sink ultrafiltration method was developed to monitor liposomal release kinetics of the anticancer agent topotecan. Mathematical modeling allowed simultaneous determination of drug permeability and interfacial binding to the bilayer from release …

Ultrasound Assisted Hydration Of Navy Beans (Phaseolus Vulgaris), N. Misra

Articles

The use of ultrasound to enhance the transport phenomena in food processes has been well recognised in recent times. The objective of this study was to evaluate the effect of sonication on hydration rate and pasting profile of navy beans. The hydration kinetics for control and ultrasound assisted soaking was mathematically described using mechanistic (Fickian diffusion) and empirical (Peleg’s equation, Weibull model and First Order equation) models. Ultrasound enhanced the rate of hydration which was evident from the plot of kinetic data and model parameters. The effective diffusivities for water transport without and with ultrasound application were estimated to be …

Design Of A Multi-Agent System For Process Monitoring And Supervision, Onur Dogu

LSU Master's Theses

New process monitoring and control strategies are developing every day together with process automation strategies to satisfy the needs of diverse industries. New automation systems are being developed with more capabilities for safety and reliability issues. Fault detection and diagnosis, and process monitoring and supervision are some of the new and promising growth areas in process control. With the help of the development of powerful computer systems, the extensive amount of process data from all over the plant can be put to use in an efficient manner by storing and manipulation. With this development, data-driven process monitoring approaches had the …

G-Box Model For The Fate Of Emerging Contaminants In Soil, Eileen Cranfield

LSU Master's Theses

Pesticides applied to agriculture fields move and react into the soil system. The objective of this research was to develop a model that uses the natural soil processes (diffusion, advection, or reaction type processes in multiple phases) to track pesticides and other emerging contaminants (EMCONs) in the soil over space and time. The model separates the soil into a series of boxes with soil processes passing through and into the boxes. With a system of equations developed from these processes, the model produces a gradient concentration profile, hence the Gradient Box, or G-box Model. The model is first tested against …

Effects Of Drill-Pipe Whirling Motion On Cuttings Transport Performance For Horizontal Drilling, Yasin Demiralp

LSU Master's Theses

Dispersion, deposition, and suspension of particulate materials in the carrier fluid play a significant role in the oil industry. Increasing the cuttings transport performance in deviated wells is difficult due to the rolling/sliding transport, and cuttings settling on the low side of the annulus. Insufficient cuttings transport may lead to some crucial problems such as pipe sticking, increasing in torque and drag, material damage and bed cementing quality. Increasing flow rates and improving mud properties may not be applicable for a proper hole cleaning because of the hydraulic and mechanical limitations. In such cases, additional pressure may be generated, and …

Effect Of Forced Flow Oscillation On Churn And Annular Flow In Vertical Wellbores, Catalina Posada

LSU Master's Theses

Producing oil and gas from marginal hydrocarbon reservoirs and mature fields present particular challenges. One of the challenges for these types of fields is flow instability. Pipeline risers and artificial gas-lift systems experience instabilities, which cause significant reductions in production among others operational drawbacks. Different types of instabilities (static and dynamic) have been identified affecting those systems. However, there is still a lack of systematic investigations associated with the understanding of dynamic instabilities (periodic oscillations) and their impact in production systems. A systematic investigation of the effects of periodic forced oscillations on gas-liquid flows in a 42 m (140-ft) long, …

Plasma Processes And Polymers Special Issue On: Plasma And Cancer, Mounir Laroussi, Michael Keidar

Electrical & Computer Engineering Faculty Publications

During the last two decades, research efforts on the application of low temperature plasmas in biology and medicine have positioned nonequilibrium lowtemperature plasmas as a technology that has the potential of revolutionizing healthcare.[1,2] Low temperature plasmas can be applied in direct contact with living tissues to inactivate bacteria,[3] to disinfect wounds and accelerate wound healing,[4] and to induce damage in some cancer cells.[5–11]

Total Safety Management: What Are The Main Concerns In The Integration Of Best Available Methods And Tools, Maria Chiara Leva, Nora Balfe, Tom Kontogiannis, Emmanuel Plot, Micaela De Michela

Articles

“BP released findings from its own internal investigation of the oil spill in the Gulf of Mexico, revealed inefficient Organization interfaces among BP management, the rig crew and well site leader. Also according to the investigation, one important contributor to the accident was inadequate guidelines for critical tests and operations”. (Pires and Mosleh 2011) Over the recent past, the accumulation of major mishaps, crises and accidents have made it clear that organisations must still improve their capabilities to address safety “not as a stand-alone activity that is separate from the main activities and processes of the organization” but as an …

Microwave-Assisted Synthesis Of Pd Nanoparticles Supported On Fe 3o4, Co3o4, And Ni(Oh)2 Nanoplates And Catalysis Application For Co Oxidation, Hany A. Elazab, Sherif Moussa, B. Frank Gupton, M. Samy El-Shall

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this paper, we report a simple, versatile, and rapid method for the synthesis of Pd nanoparticle catalysts supported on Fe₃O₄, Co₃O₄, and Ni (OH)2 nanoplates via microwave irradiation. The important advantage of microwave dielectric heating over convective heating is that the reactants can be added at room temperature (or slightly higher temperatures) without the need for high-temperature injection. Furthermore, the method can be used to synthesize metal nanoparticle catalysts supported on metal oxide nanoparticles in one step. We also demonstrate that the catalyst-support interaction plays an important role in the low …

Stereoselective Transformations Of Α-Trifluoromethylated Ketoximes To Optically Active Amines By Enzyme-Nanometal Cocatalysis: Synthesis Of (S)-Inhibitor Of Phenylethanolamine N-Methyltransferase, Guilin Cheng, Qi Wu, Zeyu Shang, Xinhua Liang, Xianfu Lin

Chemical and Biochemical Engineering Faculty Research & Creative Works

One-pot cascade synthesis of optically active α-trifluoro methylated amines directly from ketoximes was accomplished with the use of Candida antarctica lipase B and catalysts prepared by atomic layer deposition (ALD). Compared to the commercial palladium catalyst, the ALD-prepared catalysts showed much higher activity and afforded various α-trifluoro methylated amides in good yields and with high enantioselectivity. One of the enantiopure amides was further hydrolyzed into the corresponding amine, which was treated as a crucial starting material for total synthesis of (S)-inhibitor of phenyl ethanolamine N-methyltransferase without loss of chiral information. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Utilizing Reversible Addition Fragmentation Chain Transer For The Synthesis Of Polymeric Gene Delivery Vehicles, Jared Spoons

Honors Theses

There are many techniques used today to make a variety of polymers but this thesis investigates the reversible addition-fragmentation chain transfer (RAFT) polymerization technique and illustrates the advantages and importance of using RAFT polymerization technique to make the desired polymer. The research focused on two monomer units that were to form the diblock copolymer; the hydrophilic part, oligo(ethylene glycol) methacrylate, and the cationic hydrophobic part 2-diethylaminoethyl methacrylate. The goal was to produce a target diblock copolymer with a Mn value of 44K and a PDI under 1.5 with the block sizes being a 35K Mn OEGMA chain and a 9K …

Virus Purification, Detection And Removal, Khrupa Saagar Vijayaragavan

Dissertations, Master's Theses and Master's Reports - Open

The biopharmaceutical industry has a growing demand and an increasing need to improve the current virus purification technologies, especially as more and more vaccines are produced from cell-culture derived virus particles. Downstream purification strategies can be expensive and account for 70% of the overall manufacturing costs. The economic pressure and purification processes can be particularly challenging when the virus to be purified is small, as in our model virus, porcine parvovirus (PPV). Our efforts are focused on designing an easy, economical, scalable and efficient system for virus purification, and we focused on aqueous two-phase systems. Industry acceptable standards for virus …

Utilizing Dielectrophoresis To Determine The Physiological Differences Of Eukaryotic Cells, Tayloria Nicole Gail Adams

Dissertations, Master's Theses and Master's Reports - Open

Type 1 diabetes affects over 108,000 children, and this number is steadily increasing. Current insulin therapies help manage the disease but are not a cure. Over a child’s lifetime they can develop kidney disease, blindness, cardiovascular disease and many other issues due to the complications of type 1 diabetes. This autoimmune disease destroys beta cells located in the pancreas, which are used to regulate glucose levels in the body. Because there is no cure and many children are affected by the disease there is a need for alternative therapeutic options that can lead to a cure.

Human mesenchymal stem cells …