Rejection Of Fe (Iron) And Kmno4 (Organic Substance) Parameters In Peat Water Using Organic Membranes, Muhamad Rafli Sakti Mulia Gonera, Siti Umi Kalsum, Sarah Fiebrina Heraningsih

Journal of Materials Exploration and Findings

Peat water is a surface water source widely used by people in swampy and lowland areas, but it has poor quality characteristics such as high organic matter content, low pH, and dissolved metal levels such as iron that exceed the threshold. These conditions can cause health problems and reduce the quality of clean water so that effective treatment technology is needed. This study aims to analyze the effectiveness of ultrafiltration membranes made from chitosan from shrimp shell waste in rejecting iron (Fe) and organic substances in peat water, and to determine the effect of pressure on separation performance. This study …

Quantification Of Uncertainty Propagation For Transient Heat Transfer In A Hollow Sphere, Rama Subba Reddy Gorla, Lochlan Joyce, Elie John Barbari

Faculty Publications

Uncertainty propagation and transient heat transfer for a hollow sphere are analyzed. The stochastic Biot number, stochastic linear non-dimensional initial conditions, and various boundary conditions are introduced to define uncertainty propagation influencing the temperature distribution throughout the hollow sphere. The resulting uncertainty amplitude was observed to have transient evolution in time. The uncertainty can either increase or decrease depending on the stochastic parameters. Results are presented for the variation in temperature due to uncertainties in the initial conditions and particular boundary conditions.

Percolation-Induced Thermo-Rheological Transitions In Biobased Graphene Nanoplatelet Nanofluids, Abiodun A. Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Biobased lubricants with thermally responsive rheology are increasingly needed for high-efficiency mechanical systems. Graphene nanoplatelet (GnP) nanofluids in vegetable oils are promising candidates, yet their percolation-driven thermo-rheological transitions remain insufficiently understood. In particular, the coupled concentration–temperature landscape controlling network-mediated flow transitions has not previously been established. Here, surfactant-free GnP nanofluids were prepared in high-oleic soybean oil (HOSO) at concentrations of 0.025–2.15% v/v (ϕ), and their rheological response was mapped between 25°C and 80 °C under steady-shear and oscillatory conditions. Below the percolation threshold (ɸ ≤ 0.1% v/v), the nanofluids exhibit near-Newtonian behavior, moderate reversible viscosity enhancement, and classical Arrhenius-type temperature …

Magnesium-Enhanced Methane: A Novel Metalized Fuel For Mars Return Missions And Next-Generation Propulsion Systems, Kinga Wysocka

Discovery Day - Daytona Beach

This research investigates magnesium-enhanced methane as a novel metalized fuel concept for high-performance, in-situ resource utilization (ISRU)-compatible rocket propulsion. While methane is a leading candidate for Mars missions due to its producibility via the Sabatier process, its combustion performance is limited by the high activation energy of the initial C–H bond (~4 eV). To address this limitation, density functional theory (DFT) calculations were performed to analyze methane and hydrogen interactions with a Mg(0001) surface. A converged slab model (3×3×4 and 3×3×5) was validated with energy differences below 1 meV per atom for k-point sampling and ~13.99 meV per atom for …

Cadmium Biosorption By Fusarium Venenatum And Its Application In Functional Permeable Materials For Metal Removal, Bradley Lawson

All Graduate Theses and Dissertations, Fall 2023 to Present

Heavy metals are pollutants of increasing concern as continued industrialization and urbanization have escalated the discharge of these toxins into aquatic environments. Cadmium (Cd) is a metal of particular concern due to its acute toxicity and high mobility in aquatic ecosystems. Given these characteristics Cd poses significant health risks to both humans and aquatic ecosystems. The continued development of sustainable, low-cost remediation technology is imperative to manage metal pollution.

This research explores the use of fungal-based remediation systems to remove Cd from contaminated water. Living biomass of the filamentous fungus Fusarium venenatum was evaluated as a biosorbent material for Cd …

Asm And A Culture Of Sharing, Caring, And Fun In Education, David J. Westenberg

Biological Sciences Faculty Research & Creative Works

One doesn't always equate a professional scientific society with sharing, caring, and fun, but in this age of public distrust, public engagement with science and active student learning are ways to regain trust. ASM holds a leadership position in promoting and recognizing the value of education in the future of our profession and is there to support your educational journey. From K12 outreach and public engagement, to professional development, to presenting and publishing scholarship of teaching and learning, ASM has been at the forefront of biology education. Under the leadership of visionary directors such as Amy Chang and now Irene …

Thermal Conversion Of Cotton Gin Byproducts Into Liquid Fuels And High-Value Chemicals, Emmanuel Asare

Mechanical Engineering Theses

In this study, we performed fast pyrolysis, catalytic fast pyrolysis (CFP), and catalytic hydropyrolysis (CHP) of cotton gin byproducts (CGB) to investigate their conversion into hydrocarbon-rich liquid fuels and high-value aromatic chemicals. Five CGB fractions (CC1, CC2, SM, TM, and FCGB) were collected from different stages of cotton ginning operation and characterized by proximate, ultimate, and higher heating value (HHV) analysis. The feedstocks contained 41.5 44.8 wt.% carbon, 54.2–58.5 wt.% volatile matter, 6.0–15 wt.% ash, and higher heating values of 15.2–16.8 MJ kg⁻¹. All pyrolysis experiments were performed using a Pyroprobe 5200 coupled with GC-MS/FID, while catalyst loading, hydrogen pressure, …

Machine Learning For Predictive Energy And Emissions Modeling Of Vehicles And Power Grids In The United States, S M Tanvir Faysal Alam Chowdhoury

Dissertations

The environmental benefits of electric vehicle (EV) adoption depend on more than replacing internal combustion engine vehicles with electric powertrains. EV adoption reshapes electricity demand, interacts with regional generation mixes, and influences travel behavior and congestion, creating a coupled transportation-energy system in which vehicle and power-plant emissions must be evaluated together. This dissertation develops machine-learning frameworks for predicting energy consumption and emissions from vehicles and power grids under rising EV adoption. The first component forecasts grid emissions from EV charging. Using simulation data from NREL's Cambium database, a Prophet-based time-series framework predicts carbon dioxide, nitrous oxide, and methane emission rates …

Electrokinetic Flow Instabilities In Non-Newtonian Fluids With Conductivity Gradients, Md Mainul Islam

All Theses

Electrokinetic instabilities (EKI) arise in electrically driven flows because the applied electric field interacts with spatial variations in electrical conductivity, generating electric body forces that can destabilize fluid interfaces. EKI can be beneficial by enhancing mixing in microchannels where diffusion is slow, but it can also be detrimental by disrupting stable sample transport, focusing, and separation. EKI has been widely studied in Newtonian fluids, and the electric Rayleigh number is known to govern the onset of this instability. However, very few studies have examined its behavior in non-Newtonian fluids, despite their prevalence in biological, chemical, and industrial applications. 

This thesis …

Functionalized Loblolly Pine Derived Ultraporous Activated Hydrochars For Efficient Carbon Capture, Swarna Saha

Theses and Dissertations

The increasing concentration of anthropogenic carbon dioxide (CO₂) emissions has intensified the demand for efficient and sustainable carbon capture technologies. This dissertation investigates the development of functionalized ultraporous activated hydrochars derived from loblolly pine through hydrothermal carbonization (HTC) followed by chemical activation for enhanced CO₂ capture applications. Different functionalization strategies, including deep eutectic solvent (DES) modification, zeolite-assisted HTC, palladium-assisted HTC, and CO₂-assisted HTC, were systematically explored to evaluate the influence of pore structure, surface chemistry, and adsorption energetics on CO₂ capture performance. The synthesized materials were characterized using BET, FTIR, XRD, TGA, SEM, and adsorption isotherm modeling to establish the …

Experimental Thermal-Hydraulic Performance Enhancement Of A Parabolic-Trough Solar Collector Using 3d-Printed Propeller-Shaped Turbulators, Shayan Pourhemmati, Barun Kumar Das, Majid Tolouei-Rad, Abdellah Shafieian

Research outputs 2022 to 2026

This experimental study investigates the thermal-hydraulic performance of a parabolic trough collector (PTC) equipped with propeller-shaped turbulators, which were 3D printed and installed along the absorber tube to enhance convective heat-transfer by increasing flow mixing. Nine turbulator configurations were tested by varying the blade angle (β = 22.5° and 45°, and β = 67.5°) and the number of turbulators (Nt = 6, 12, and Nt = 18) over a Reynolds number range of 1000 to 6000. To ensure a rigorous and unbiased comparison, all experiments were conducted under identical operating conditions, including a constant inlet temperature and a constant Reynolds …

Decarbonizing The C3 Splitter: Performance Optimization And Environmental Impact Of Mvr Integration, Dalia A. Ali Associate Prof.

Chemical Engineering

Due to the relatively low volatility (α) of propane and propene components, their separation is one of the most energy-intensive processes in the petrochemical industry. This study evaluates the technical, environmental and thermodynamic performance of a mechanical vapor recompression (MVR) heat pump integrated into a C3 splitter, compared to a conventional steam-heated distillation column. A sensitivity study was conducted using Aspen Plus software at different pressures, reflux ratios (RR) and at turndown operations. According to the results, the MVR system uses a compressor to raise the overhead vapor pressure to 38.7 bar to operate the heater without the need for …

Enhanced Transdermal Immunization Via Solid-In-Oil Nanodispersions Incorporating Dendritic Cell-Targeting Peptide, Md Samiul Islam, Md. Shahin Ekka Sarker, Yoshirou Kawaguchi, Rie Wakabayashi, Noriho Kamiya, Muhammad Moniruzzaman, Masahiro Goto

Publications and Research

Transdermal immunization represents a promising needle-free alternative to conventional vaccination. However, efficient antigen delivery and robust immune activation remain major challenges. In this study, a solid-in-oil (S/O) nanodispersion system comprising a dendritic cell-targeting peptide (HR8), ovalbumin (OVA), and an adjuvant was developed for transdermal immunization. The HR8 peptide along with OVA was successfully incorporated into an S/O nanodispersion with an optimal hydrodynamic diameter of particles (< 200 nm) and exhibited stable physical properties for up to 90 days. In vitro and in vivo studies demonstrated enhanced antigen delivery with insignificant skin irritation in C57BL/6N mice. Moreover, in vivo transdermal immunization studies demonstrated that the addition of the HR8 peptide enhanced OVA-specific IgG responses (~1.5-fold). Notably, the HR8 peptide also promoted an approximately 2.5-fold increase in IgG2c levels, suggesting a shift toward a more T helper type 1-biased immune response, as reflected by an increased IgG2c/IgG1 ratio. Overall, these findings demonstrate that the incorporation of HR8 peptide into an S/O nanodispersion enables efficient transdermal antigen delivery and improved immunogenicity, highlighting its potential as a simple, non-invasive, and patient-friendly immunization strategy.

Investigating Nanoparticle Capture By Condensed Phase Coacervates And Their Mixtures, Sanjna A. Bhakta

Chemical and Biological Engineering ETDs

The thermoresponsive polymers elastin-like polypeptides (ELPs) and poly(N-isopropylacrylamide) (PNIPAM) have served as a programmable bioseparation tool for applications in nanoparticle capture due to biocompatibility and tunable properties. This work investigates how the polymer composition of ELP and PNIPAM coacervates influences their phase behavior, structural morphology, and nanoparticle recruitment. In addition, the influence of interfacial interactions in nanoparticle recruitment using Tween 80 as a mechanistic probe was also investigated. Different mixtures of ELPs E1.40, E1.80, and E3 with PNIPAM14 and PNIPAM20 were used to characterize their phase behavior and analyze structural morphology using turbidity measurements and microscopy, respectively. Nanobead recruitment using …

Preparation And Performance Study Of In-Situ Self-Assembled Biphasic Smmn2O5-Nimn2O4 Composite Cathode, Neng-Chu Xia, Yu Zhou, Qin Wang, Jia-You Zhang, Chun Yu, Yang Zhang, Wan-Bing Guan, Jian-Xin Wang

Journal of Electrochemistry

Mullite-structured oxides exhibit excellent oxygen reduction reaction activity, possess a low thermal expansion coefficient due to their unique crystal structure, and can eliminate the need for a barrier layer and simplify the preparation process as they contain no alkaline earth elements. Thus, they hold great promise as novel cathode materials for solid oxide fuel cells. In this work, a mullite-spinel-structured SmMn₂O₅-NiMn₂O₄ (SMO-NMO) composite cathode was one-step synthesized via a solid-liquid composite route, and its in-situ self-assembly enabled good compatibility with the electrolyte without any barrier layer. Characterization results showed that the SMO:NMO = …

Dynamic Reconstruction Engineering Of Anti-Corrosion Ni-Based Anodes For Alkaline Seawater Electrolysis, Yi-Gang Zhang, Wen-Wen Xu, Tian-Yu Zhang, Zhi-Yi Lu

Journal of Electrochemistry

Green hydrogen production via alkaline seawater electrolysis offers an environmentally sustainable and potentially cost-effective route to address both energy and climate challenges. Achieving long-term anode stability under complex ionic environments and industrial current densities remains a central bottleneck. Specifically, Ni-based anodes exhibit intense surface reconstruction during the oxygen evolution reaction, necessitating dynamic anti-corrosion strategies. This mini review systematically summarizes reconstruction engineering approaches to develop anti-corrosion Ni-based anodes of alkaline seawater electrolysis across increasingly complex ionic environments from simulated seawater to real seawater: (i) Cl^– dominated; (ii) Cl^– with co-existing oxyanions, and (iii) Cl^–  with co-existing Br^{– …}

In Situ Stm Visualization Of Molecular Structural Evolution During Electrochemical Oxidation Coupling Of Para-Aminothiophenol On Au(111), Zi-Wei Ma, Tai-Rui Wu, An-Ni Zheng, Lai-Ke Chen, Yuan-Hui Xiao, Zhao-Bin Chen, Qing-Na Zheng, Jian-Zhang Zhou, Jia-Wei Yan, De-Yin Wu

Journal of Electrochemistry

Para-aminothiophenol (PATP) is not only a widely-used probe molecule in the field of surface-enhanced Raman spectroscopy (SERS), but also an important model molecule for interfacial reactions, exhibiting distinct photo- and electro-oxidation pathways, so that PATP is selectively activated under different external fields. The evolution of products and intermediates during electrochemical oxidative coupling remains unknown. In this study, we have investigated the dynamic electrochemical oxidation process of PATP on the Au(111) surface using cyclic voltammetry, electrochemical (EC)-SERS, and in situ electrochemical scanning tunneling microscopy (EC-STM). The results showed that PATP forms an unsaturated adsorption coverage on Au(111) in an acidic solution. …

Impact Of Gas Interactions With Nano Porous Geological Material In The Presence Of Water Vapor, Matthew D. Powell

Chemical and Biological Engineering ETDs

Predicting gas transport in nanoporous geological material requires understanding competitive adsorption and transport under humid conditions. However, most adsorption studies rely on single-component equilibrium measurements that do not capture these effects. This dissertation develops an experimental methodology to directly quantify multicomponent gas adsorption and breakthrough behavior under controlled relative humidity. The method was first applied to the Kr/Xe–N2–H2O system, where it resolved competitive adsorption behavior in humid porous media and produced a bivariate model relating noble gas adsorption to noble gas partial pressure and water saturation. The methodology was then extended to the CO2–N2 H2O system. Results showed that water …

Multiscale Network Modeling Of Native And Modified Photosynthetic Light-Harvesting Complexes, Zane E. Armijo

Chemical and Biological Engineering ETDs

Photosynthetic light-harvesting complexes harvest solar energy and direct electronic excitations toward reaction centers with exceptional efficiency. This dissertation models the Fenna--Matthews--Olson complex of green sulfur bacteria, coupled to the PscA1 reaction center, as a chromophoric network. Forster resonance energy transfer theory, validated against numerically exact hierarchical equations of motion, was implemented in kinetic Monte Carlo simulations to resolve fine-grained excitation-transport pathways. The predicted charge-transfer efficiency of 77\% agrees with experiment, with the FMO2 monomer and its gateway pigment governing interfacial transfer. Systematic single, multi, and symmetry-preserving site removals, interpreted through Mobius inversion, identify critical pigments and show that cooperative effects …

Prepration And Characterization Of Alginate Biocomposite Films From Natural Seaweed Containing Glycerol And Silica, Bahareh Ebrahimi Mojaveri

Master's Theses

This study focuses on the development of sodium alginate, a seaweed-derived biopolymer, as a sustainable alternative to conventional food packaging films. The alginate is extracted from natural brown seaweed with a yield of 31% and is formed into alginate films by the solution casting method. This study discusses the alginate extraction and film formation techniques as well as the conditions that affect film properties. Additionally, it explores using composite formulations to enhance alginate properties through additives such as glycerol and silica. Glycerol, tested at different concentrations (15, 25, and 50 wt.%), works as a plasticizer to enhance the flexibility of …