Distinct Co2 Electroreduction Behaviors Over Planar And Non-Planar Cobalt Molecular Catalysts, Ru Jia, Cheng-Biao Zhu, Zi-Mo Zhang, Tuo Wang, Kai-Cong Yang, Guang-Zhe Wang, Yang Hu, Ting-Ting Zhang, Zhen-Wei Wei, Li Xiao, Gong-Wei Wang, Lin Zhuang

Journal of Electrochemistry

Molecular catalysts serve as ideal platforms for studying electrocatalytic reaction mechanisms. While current research mainly focuses on modulating central metals or surrounding ligands, the influence of molecular spatial configuration remains largely unexplored. Herein, we synthesized two cobalt complexes with similar ligand environments but distinct spatial geometries, a planar cobalt hexaazamacrocyclic complex (CoHAM) and a non-planar acyclic Co(phen)₂Cl₂, and evaluated their performance in CO₂ reduction reaction (CO₂RR). The planar CoHAM exhibited dramatically superior CO₂RR performance compared to the non-planar Co(phen)₂Cl₂. Through a series of combined analyses using in-situ …

On The Use Of Lorawan For Smart Fishing Applications In The Blue Economy Sector, Eva Shayo

Tanzania Journal of Engineering and Technology (TJET)

The growth of digital technology is expected to transform small-scale fishery sectors, where a need for robust, low-cost, long-range communication networks becomes critical. There exist several technologies that are used in the fishery sector but they are never affordable to small scale fisheries. This study evaluates the feasibility of using low cost Long Range Wide Area Network (LoRaWAN) technology specifically tailored for smart fishing environments to small scale fishery sector. Using simulation, we assess the performance of the key performance metrics including probability of success and energy efficiency under varying device densities and time. During evaluation, we considered end devices …

Physicochemical Properties And Chemical Compositions Of Cashew Nut Shell Liquid Extracted With Carbon Dioxide–Expanded Hexane, Neema Msuya, Joseph Yn Philip, Frank Jacob, Kando K. Janga

Tanzania Journal of Engineering and Technology (TJET)

Cashew nut shell liquid (CNSL) is a mixture of phenolic compounds that can effectively replace commercially available phenols in various applications. This study investigated the physicochemical properties and chemical composition of CNSL extracted using CO₂–expanded hexane (CXH) and compared to the traditional Soxhlet extraction method. Steamed cashew nut shells (sCNS) were used in both cases.  The CXH was carried under varying CO₂-mole fractions (0.468-0.892) and temperatures (20-36 °C) whereas Soxhlet extraction was performed at atmospheric pressure and hexane boiling point. Response Surface Methodology (RSM) with Central Composite Face-Centred Design (CCFD) was employed to evaluate the effect …

Review And Development Of An Explicit Machine Learning Model For Pollutant Gas Solubility In Ionic Liquids As Green Solvents, Amir Dashti, Farid Amirkhani, Mojtaba Raji, John L. Zhou, Ali Altaee, Ali Braytee, Brett Turner, Hossein Ali Khonakdar, Amir Razmjou

Research outputs 2022 to 2026

The increasing release of greenhouse gases (GHGs) like CO₂, CH₄, N₂O, and industrial contaminants (indirect GHGs) such as SO₂ and H₂S has prompted significant global worries due to their role in climate change, air pollution, and harm to the environment. Ionic liquids (ILs) as green solvents have emerged as promising alternatives to traditional solvents because of their minimal volatility, high thermal stability, and adjustable physicochemical characteristics. Yet, limited gas solubility data in ILs is hindering their applications in carbon capture and air pollution control. Machine learning (ML) is a powerful tool for modeling and simulating the solubility of polluting gases …

Lafe0.925ti0.075o3 Perovskite Coated With Ethyl Cellulose: A High-Stability, Low-Hysteresis Platform For Advanced Humidity Sensing, Akhmad Futukhillah Fataba Alaih, Djoko Triyono, Rifqi Almusawi Rafsanjani

Makara Journal of Science

Humidity sensors are pivotal in numerous sectors, such as environmental monitoring, industrial automation, and health-care. This study presents the fabrication and detailed evaluation of an advanced humidity sensor using ethyl cellulose (EC)-coated LaFe_0.925Ti_0.075O₃ (LFTO) perovskite nanoparticles synthesized via the sol-gel method. The LFTO nanopar-ticles exhibited a mesoporous structure with an enhanced surface area, which significantly improved their moisture adsorption capabilities. The innovative application of EC coating addresses critical substrate adhesion issues, enhancing mechanical stability without compromising sensor sensitivity. Comprehensive performance evaluations revealed minimal hysteresis (

Laminarin-Loaded Solid-In-Oil Nanodispersion For Enhanced Non-Invasive Transdermal Immunization, Md. Shahin Ekka Sarker, Yoshirou Kawaguchi, Rie C. Wakabayashi, Noriho J. Kamiya, Muhammad Moniruzzaman, Masahiro Goto

Publications and Research

Simple and non-invasive transdermal vaccination is an attractive alternative to conventional injection-based immunization. However, the effectiveness of transdermal vaccines is often constrained by the stratum corneum barrier. Although the use of solid-in-oil (S/O) nanodispersion technology has successfully facilitated skin permeation to induce an immunological response, the antibody titers remain suboptimal. Herein, a dectin-1 selective ligand, laminarin, was used as an immunostimulatory adjuvant to enhance the immune response. S/O nanodispersions loaded with laminarin and ovalbumin (OVA) were systematically developed and characterized in terms of particle size, in vitro OVA release behavior, and skin permeation performance using excised mouse skin. In vivo …

Modeling And Optimization Of Li-Ion Battery Recycling Process, Wang Lingling, Zhou Panpan, Ma Yulong

Dianchi(Changsha)

No abstract provided.

Review On Capacity Degradation Mechanisms And Lifetime Prediction Of Energy Storage Li-Ion Battery, Ma Yue, Chen Yanqiao, Wang Chu, Wang Xianwen, Liu Hui, Chen Yifei, Chen Lai, Yan Kang, Su Yuefeng

Dianchi(Changsha)

No abstract provided.

Opportunities And Challenges Of Cross-Border E-Commerce In Li-Ion Batteries, Ma Jingjing, Chen Xianyi

Dianchi(Changsha)

No abstract provided.

Innovative Hybrid Eor Formulations: Low Salinity Water Coupled With Nanoparticles And Nanopolymers For Carbonate Reservoirs, Aquib Azhar Hakeem

Thesis/ Dissertation Defenses

The recovery of oil from oil-wet carbonated reservoirs remains a challenge due to the unfavorable wettability characteristics and the poor sweep efficiency during the displacement process. In this work, the nano-assisted polymer flooding with Sav10 polymer and silica (SiO2), single-walled carbon nanotube (SWCNT), and titanium dioxide (TiO2) nanoparticles were investigated to enhance the oil recovery from the carbonate core samples at low-salinity conditions. The rheology analysis showed that a Sav10 concentration of 1000 ppm resulted in the most appropriate viscosity, around 3 cP, to effectively control mobility during flooding. The contact angle measurements of the individual nanoparticle dispersions and hybrid …

Photocatalysts Based On Titanium Dioxide And Zinc Phthalocyanine Composites For Photodegradation Of Methylene Blue, Albert R. Koldarov, Mastura Kh. Aripova, Odilzhon E. Abdurakhmonov, Zuhra Ch. Kadirova, Abror O. Tashpulatov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to analyze the photocatalytic degradation of a model methylene blue solution using titanium dioxide composites with zinc phthalocyanine as the sensitizing photocatalyst under sunlight. The objects of the study are TiO₂-based photocatalysts derived from the spent catalyst of the Shurtan GCC after heat treatment at 650°C (T-650), as well as a composite containing zinc phthalocyanine (T-650/PcZn). It has been established that the photodegradation reaction follows a pseudo-first-order model, while the rate constant for the TiO₂/PcZn composite is significantly higher than that of pure TiO₂, indicating greater efficiency. The …

Magnetic Cellulose Nanocrystal Composites: Synthesis, Properties, Applications, And Opportunities, Mohammad Jahid Hasan, Kishore Chand, Esteban E. Ureña-Benavides, Erick S. Vasquez-Guardado

Chemical and Materials Engineering Faculty Publications

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Magnetic Cellulose Nanocrystal Composites: Synthesis, Properties, Applications, and Opportunities

Transport And Interfacial Dynamics Of Electrochemical Formation Processes In Li-Based Batteries, Penghao Zhang

McKelvey School of Engineering Graduate Student Theses & Dissertations

Next-generation high-capacity batteries often rely on electrochemical formation processes rather than conventional intercalation alone. Such processes include lithium metal deposition and Li–O2 discharge-product formation, in which new phases form at the electrochemical interface during operation. As a result, the measured response reflects both electrochemical driving forces and the evolving product morphology. This coupling makes it difficult to interpret electrochemical data, microscopic observations, or model results in isolation. This dissertation examines this problem through three main studies and one preliminary extension on Li–O2 batteries and lithium metal deposition, each addressing a different factor that affects how electrochemical product formation is measured, …

Integrasi Metodologi Hazop Dalam Pengendalian Risiko Dan Keberlanjutan Operasional Pada Unit Pemulihan Urea: Studi Kasus Pada Industri Pupuk, Riny Yolandha Parapat, Arin Nur'aini Putri, Aryasatya Ramadhan Sukresno

National Journal of Occupational Health and Safety

The fertilizer industry is one of the chemical sectors with high-risk potential due to its operational processes involving hazardous materials as well as extreme pressure and temperature conditions. This study aims to identify and analyze hazards in the urea recovery unit using the Hazard and Operability Study (HAZOP) method, while also formulating effective risk control strategies to support the operational sustainability of the plant. The study was conducted directly at a commercial fertilizer plant in West Java using a semi-quantitative approach, which included field observations, review of technical documents such as Process Flow Diagrams (PFD), Piping and Instrumentation Diagrams (P&ID), …

Rheological Protocol To Assess And Optimize Latex Coagulation Dynamics For The Thin Glove Coagulant Dipping Process, Monday U. Okoronkwo, Kok Kong Ng, Wolfram Franke, Gaurav Sant

Chemical and Biochemical Engineering Faculty Research & Creative Works

Many products that directly impact the quality of human life today — gloves, catheters, condoms, and baby bottle teats — are made through the latex-dipping technology. While a variety of methods have been developed – e.g., particle counting, turbidimetry, microscopy, and light scattering – which are suitable for studying the coagulation of latex at very low concentrations, much less work has focused on methods suitable for in-situ characterization of latex coagulation in concentrated solutions (e.g., as relevant to the dipping process). This paper presents a process-relevant rheological protocol for assessing and optimizing latex coagulation dynamics for the thin glove coagulant …

Optimizing Graphene Oxide In Self-Compacting Concrete: A Sustainable Nano-Material Strategy For Enhanced Durability And Structural Performance, Mohammed Shakeebulla Khan, Vijaya G. S

Journal of Sustainable Construction Materials and Technologies

In order to reduce the environmental impact of the constructed world, advanced and sustainable construction materials are needed. This work is a summary of the comprehensive study on a novel self-compacting concrete with nano-engineered material (graphene oxide) modified self-compacting concrete (GO-SCC). The optimum dosage of GO was determined using Taguchi method, Analysis of Variance (ANOVA) and Response Surface Methodology (RSM) multi-objective statistical optimization method, and was found to be 0.10% by weight of cement (bwoc). This dosage of 0.10% GO led to the overall desirability score of 0.87, which confirmed that this was the optimum dosage for six response variables …

Beneficial Investigation Of Sustainable Recycled Waste Plastic In Treating The Consolidation Behavior Of Fine Soil, Aram Mohammed Raheem, Cumaraswamy Vipulanandan, Mohammed Hiwa Abdullrahman, Ali Tariq Omer

Journal of Sustainable Construction Materials and Technologies

Recycled waste plastic is one of the regular garbage utilized as a sustainable material in soil remediation. This study examines the efficacy of utilizing local recycled waste plastic as an ecological quantifiable along with soil containing fine particles to analyze the consolidation behavior. Various recycled waste plastic contents ranging from 2% to 10% were employed experimentally in two patterns where in the first pattern the recycled waste plastic were mixed as dry material with the fine soil particles while in the second pattern a sandwich layer of 10% of the recycled waste plastic was placed in the middle of the …

Enhanced Thermal Energy Storage In Buildings: Impregnation, Leakage, And Environmental Performance Of Organic And Inorganic Pcm Composites, Gökhan Genç, Esra Yılmaz, M. Yusuf Yazıcı

Journal of Sustainable Construction Materials and Technologies

This study experimentally investigates the impregnation and leakage performance of various organic (tobacco, sawdust, bay leaf, black cumin) and inorganic (vermiculite, perlite, bentonite, sepiolite) carrier materials used for phase change material (PCM) integration in building applications. The commercial paraffin-based PCM RT-31 was used as the thermal storage medium. Impregnation and leakage tests were conducted to evaluate the PCM absorption capacity, form stability, and energy storage potential of each carrier. The results revealed that perlite (C = 80%) and bay leaf (C = 78%) exhibited the highest impregnation capacities due to their porous and fibrous structures; however, they also demonstrated significant …

Modeling Of Tensile Stress-Strain Response For Steel Fiber Reinforced Self-Compacting Concretes, Anıl Niş, Nilufer Özyurt, Turan Özturan

Journal of Sustainable Construction Materials and Technologies

Main aim of the research was to further understand self-compacting concrete reinforced with steel fibers (SFR-SCC) behavior and to contribute modeling of the tensile stress-strain diagrams for the standardization of the fiber reinforced materials for structural utilization. Fiber reinforced materials has not been used without structural rebar because of the absence of stress-strain curve in tension required for the structural design codes. Hence, an inverse analysis (multi-layer model) was further modified for various steel fibers to predict tensile stress-strain behaviour. For this purpose, 5 different mixes; control, reinforced with long fibers with 0.5% and 1%, short fiber with 0.5% and …

Extraction Of High-Quality Cashew Nutshell Liquid Using Carbon Dioxide-Expanded Hexane, Frank N. Jacob, Neema Msuya, Joseph Y.N Philip, Kando Khalifa Janga

Tanzania Journal of Science

Cashew nutshell liquid (CNSL) is a by–product from cashew processing industries containing four naturally occurring phenolic compounds. This study investigated an extraction approach using CO2–expanded hexane. The central composite design (CCD) was employed in experimental design to investigate the effects and interaction of CO 2 mole fractions and extraction temperature on the CNSL yield and quality (Colour) from Steamed CNSL. The dissolution power of the CO2–expanded hexane was assessed by determining the solubility of CNSL during the initial stages of extraction at different extraction conditions. Findings indicated that higher CO2 mole fractions reduced CNSL solubility, while higher temperatures enhanced it. …