Ambit Of Multiphase Cfd In Modelling Transport Processes Related To Oil Spill Scenario And Microfluidics,
2015
Louisiana State University and Agricultural and Mechanical College
Ambit Of Multiphase Cfd In Modelling Transport Processes Related To Oil Spill Scenario And Microfluidics, Abhijit Rao
LSU Doctoral Dissertations
During the ‘Deepwater Horizon’ accident in the deep sea in 2010, about 4.9 million barrels of oil was released into the Gulf of Mexico, making the spill one of the worst ocean spills in recent times. To mitigate the ill effects of the event on the environment, subsea injection of dispersants was carried out. Dispersant addition lowers the interfacial tension at oil/water interface and presence of local turbulence enhances the droplet disintegration process. The oil droplets contain a plethora of hydrocarbons which are soluble in water. In deep spill scenarios, droplets spend large amounts of time in water column; hence, …
Analyses Of The Mec1 Dna Damage Pathway In Saccharomyces Cerevisiae,
2015
Louisiana State University and Agricultural and Mechanical College
Analyses Of The Mec1 Dna Damage Pathway In Saccharomyces Cerevisiae, William Barrett Ainsworth
LSU Doctoral Dissertations
Eukaryotic organisms implement conserved surveillance machinery to sense and respond to DNA damage. Fundamental to the repair process is coordinated regulation of repair genes and initiation of cell cycle arrest protocols. Failure to preserve these checkpoints results in accumulation of mutated DNA and aberrant cell phenotypes that are characteristic of human disease. The yeast, Saccharomyces cerevisiae, utilizes the MEC1 checkpoint pathway to regulate the DNA damage response. This study addressed two overarching themes of transcriptional and post-translational regulation within the MEC1 pathway. We first applied our understanding of the MEC1 DNA damage transcriptional response to develop advanced luciferase whole cell …
Modelling Of Channelization In Unconsolidated Formations Due To Liquid Injection,
2015
Louisiana State University and Agricultural and Mechanical College
Modelling Of Channelization In Unconsolidated Formations Due To Liquid Injection, Juan Felipe Bautista Barake
LSU Master's Theses
Fluid injection has been increasingly implemented in oil and gas producing fields to optimize hydrocarbon production in both young and mature oil fields across the globe. This situation arises from the realization that early planning of second and tertiary recovery methods may improve project economics significantly. Injectors are then intended to perform at high injection rates with low bottomhole flowing pressures for as long as possible. In the case of injectors drilled in unconsolidated formations, deficient performance often times seems to be the norm. With a majority of these fields being offshore developments in which capital expenditures are high, a …
Deepwater Gulf Of Mexico Oil Spill Scenarios Development And Their Associated Risk Assessment,
2015
Louisiana State University and Agricultural and Mechanical College
Deepwater Gulf Of Mexico Oil Spill Scenarios Development And Their Associated Risk Assessment, Muhammad Zulqarnain
LSU Doctoral Dissertations
World’s growing energy demand has pushed oil companies to explore and produce hydrocarbons in complex and technologically challenging deepwater environments. These difficult and complex operations involve the risk of major accidents as well, demonstrated by disasters such as the explosion and fire on the UK production platform Piper Alpha and capsizing of the Deepwater Horizon rig in the Gulf of Mexico (GoM). Accidents cause death, suffering, pollution of the environment, disruption of business and bad reputation to oil industry. A quantitative risk analysis technique has been used in this study to identify and categorize risk associated with different life phases …
Electrochemical Study Of Ammonium Interaction With Au,Sn And Cu Electrodes In Nonaqueous Electrolytes,
2015
Louisiana State University and Agricultural and Mechanical College
Electrochemical Study Of Ammonium Interaction With Au,Sn And Cu Electrodes In Nonaqueous Electrolytes, Guoying Qu
LSU Doctoral Dissertations
Nonaqueous electrolytes play an important role in electrochemical devices such as flip chip and lithium-air batteries. In this work, we examine ammonium-Cu, Sn and Li interactions in nonaqueous electrolytes to optimize the future flip chip flux and electrolyte additive of lithium-air battery. The activity of halogen-free carboxylic acid flux is considered one of the most important aspects in controlling flip chip joint quality recently. CuOx removal effectiveness of carboxylic acid solutions at Cu substrates using electrochemical methods at elevated temperatures from 100ºC to 180ºC is studied thoroughly by chronopotentiometry and gravimetric analysis. Carboxylic acid-based solutions with ethanolamine show oxide removal …
Application Of Discrete Element Method And Computational Fluid Dynamics To Selected Dispersed Phase Flow Problems,
2015
Louisiana State University and Agricultural and Mechanical College
Application Of Discrete Element Method And Computational Fluid Dynamics To Selected Dispersed Phase Flow Problems, Oladapo Olanrewaju Ayeni
LSU Doctoral Dissertations
A parallel discrete particle modelling framework (PAR_DPM3D) is applied to study three fundamental multiphase flow problems: The sedimentation of a cluster of particles in a viscous ambient fluid, multiphase flow in a bench-scale fluidized bed and granular segregation and mixing dynamics in a rotating drum. Various phenomena including torus formation and particle cluster breakup are reproduced. We provide new insights into the volume fraction dependence of the dynamic characteristics of a settling particle cluster and find a similar dependence in the simulations as in the theoretical predictions of Nitsche and Batchelor 1. Similarities in the interaction between a system of …
Modeling The Crude Oil Scheduling Problem With Integration With Lower Level Production Optimization And Uncertainty,
2015
Louisiana State University and Agricultural and Mechanical College
Modeling The Crude Oil Scheduling Problem With Integration With Lower Level Production Optimization And Uncertainty, Jorge Asis Charbel Chebeir
LSU Master's Theses
This research is focused on the modeling and optimization of the crude oil scheduling problem in order to generate the most appropriate schedule for the unloading, charging, blending, and movement of crude oil in a refinery, which means obtaining the schedule that generates the lowest costs. Uncertainty, which is often present in these types of optimization problems, is also analyzed and taken into account for the resolution of crude oil scheduling problem. A comprehensive novel model is proposed to describe the upper level crude oil scheduling problem, generate an optimal solution for the mentioned problem, and allow integration with the …
Applications Of Cfd Simulations On Fractal Fluid Distributor,
2015
Louisiana State University and Agricultural and Mechanical College
Applications Of Cfd Simulations On Fractal Fluid Distributor, Gongqiang He
LSU Master's Theses
Since its emergence in 1970s, process intensification has been attracting extensive research interests from both academic and industrial societies over the years. One good example of process intensification in chemical industry is the optimization of flow distributors. In many chemical processes, the uniformity of flow distributions plays the key role in determining the overall efficiency. Conventional distributors rely on high pressure drop to achieve acceptable flow distribution. With scaling symmetry from fractal, fractal distributors can handle fluid distribution much better than conventional distributors. With the rapid development of computation power and numerical simulation algorithms, Computer Fluid Dynamics (CFD) provides us …
Application Of Computational Fluid Dynamics To Near-Wellbore Modeling Of A Gas Well,
2015
Louisiana State University and Agricultural and Mechanical College
Application Of Computational Fluid Dynamics To Near-Wellbore Modeling Of A Gas Well, Oscar Mauricio Molina
LSU Master's Theses
Well completion plays a key role in the economically viable production of hydrocarbons from a reservoir. Therefore, it is of high importance for the production engineer to have as many tools available that aid in the successful design of a proper completion scheme, depending on the type of formation rock, reservoir fluid properties and forecasting of production rates. Because well completion jobs are expensive, most of the completed wells are usually expected to produce as much hydrocarbon and as fast as possible, in order to shorten the time of return of the investment. This research study focused on the evaluation …
A Model-Based Framework To Control The Crystal Size Distribution,
2015
Louisiana State University and Agricultural and Mechanical College
A Model-Based Framework To Control The Crystal Size Distribution, Navid Ghadipasha
LSU Master's Theses
Crystallization is an old unit operation in the industry which is widely used as a separation process due to its ability to produce highly valued chemical with high purity. Despite the long history of batch crystallization, industry still relies on rule of- thumb techniques for their crystallization processes. Thus, any method to improve the products characteristics such as size and morphology will be highly valued. Advances in robustness and accuracy of automated in situ sensors give the possibility to move towards an engineering based approach by implementing the real-time monitoring and control of the process. The research undertaken here investigates …
Saccharomyces Cerevisiae Tel1 & Tel2 Role In Dna Double-Strand Break Repairs,
2015
Louisiana State University and Agricultural and Mechanical College
Saccharomyces Cerevisiae Tel1 & Tel2 Role In Dna Double-Strand Break Repairs, Tommy Nhan Trieu
LSU Master's Theses
Genomic DNA is constantly in danger of being damaged by endogenous cellular processes and exogenous agents. Eukaryotes have mechanisms, collectively termed the DNA damage response, that detect and repair DNA damage. After a double-stranded break occurs, protein complexes are recruited to the break site to promote resection. Two main protein kinases involved in DNA repair are the Tel1 and Mec1 proteins. Recent studies have found that the Tel2 protein binds to both the Tel1 and Mec1 proteins and a point mutation of TEL2 on the 129th amino acid disrupts this interaction. Since both of the Tel1 and Mec1 proteins are …
Sinking Of Crude Oil Amended-Model Oil Mixtures Due To Evaporative Or Dissolution Weathering On The Surface And Submerged In Water,
2015
Louisiana State University and Agricultural and Mechanical College
Sinking Of Crude Oil Amended-Model Oil Mixtures Due To Evaporative Or Dissolution Weathering On The Surface And Submerged In Water, Cameron Joseph Loebig
LSU Master's Theses
Despite the popular belief that crude oil is a mixture of hydrocarbons that floats on the surface of water, tar balls continue to wash up on beaches from the sea floor years after the Deep Water Horizon oil spill. This is because of the rarely studied weathering effects that occur during deep sea spills. While the evaporative weathering process of oil at the water’s surface has been studied, no currently implemented models assess the weathering effects of dissolution within the water column. The evaporative effects at the sea surface and the dissolution of soluble components within droplets located in the …
A Comprehensive Optimization Framework For Designing Sustainable Renewable Energy Production Systems,
2015
Louisiana State University and Agricultural and Mechanical College
A Comprehensive Optimization Framework For Designing Sustainable Renewable Energy Production Systems, Aryan Geraili Nejadfomeshi
LSU Doctoral Dissertations
As the world has recognized the importance of diversifying its energy resource portfolio away from fossil resources and more towards renewable resources such as biomass, there arises a need for developing strategies which can design renewable sustainable value chains that can be scaled up efficiently and provide tangible net environmental benefits from energy utilization. The objective of this research is to develop and implement a novel decision-making framework for the optimal design of renewable energy systems. The proposed optimization framework is based on a distributed, systematic approach which is composed of different layers including systems-based strategic optimization, detailed mechanistic modeling …
Post-Treatment Assessment Of Hydraulic Fracturing With Integrated Modeling Of Natural Fracture Distribution,
2015
Louisiana State University and Agricultural and Mechanical College
Post-Treatment Assessment Of Hydraulic Fracturing With Integrated Modeling Of Natural Fracture Distribution, Ping Puyang
LSU Master's Theses
Hydraulic fracturing has been serving as the principal reservoir stimulation technique for decades to improve production capacities of low permeability formations. On the other hand, through core and outcrop studies, advanced logging tools, microseismic fracture mapping and well testing analysis, it has been further revealed that many of the shale gas formations are naturally fractured. The presence of natural fractures and their interactions with hydraulic fractures must be taken into consideration while designing fracturing treatment. Although most natural fractures are cemented by precipitations during diagenesis, they may be reactivated during hydraulic fracturing and serve as weak paths for fluid flow …
Multiscale Modeling Of Particle Transport In Petroleum Reservoirs,
2015
Louisiana State University and Agricultural and Mechanical College
Multiscale Modeling Of Particle Transport In Petroleum Reservoirs, Layne Bryan French
LSU Master's Theses
Modeling subsurface particle transport and retention is important for many processes, including sand production, fines migration, and nanoparticle injection. In this study, a pore-scale particle plugging simulator is concurrently coupled with a streamline reservoir simulator to predict the behavior of particles in the subsurface. The coupled simulators march forward in time together. The automated communication between the two models enables the prediction of spatially and time dependent parameters that control the particle transport process. At each time step, the reservoir simulator provides the inlet velocity and particle concentration of the fluid suspension to the pore-scale model which outputs the permeability, …
Insights From A Global Engineering Outreach Course,
2014
Brigham Young University - Provo
Insights From A Global Engineering Outreach Course, Randy S. Lewis
Faculty Publications
A two-semester multi-disciplinary Global Engineering Outreach (GEO) course was initiated in 2007 to provide an opportunity for junior and senior-level engineering and technology students to design and implement humanitarian-based engineering projects in developing communities. Recently, the course was integrated with a sociology course to enhance the educational opportunities between social scientists and engineers. During the GEO course, students work on small-scale projects that are selected in conjunction with members of the developing communities. Students regularly interact with community members during project development. Following the GEO course, students participate in a two-week implementation trip. Learning outcomes associated with the course are …
Platinum Hollow Nanospheres With Different Sizes: Controllable Synthesis And Electrocatalytic Oxidation Toward Methanol,
2014
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China;
Platinum Hollow Nanospheres With Different Sizes: Controllable Synthesis And Electrocatalytic Oxidation Toward Methanol, Xuan Lin, Mei-Qin Cheng, Zhong-Jin Shang, Ting Xiong, Xian-Tu Zhang, Wei Tian, Jian-Yun Lin, Qi-Ling Zhong, Bin Ren
Journal of Electrochemistry
The selenium (Se) templates and hollow platinum (Pthollow) nanospheres with different sizes were controllably synthesized by adjusting the concentration of sodium dodecyl sulphonate (SDSN) (CSDSN, μmol·L-1) which was used as a surfactant. Accordingly, the Pthollow nanospheres modified glassy carbon (GC) electrode (Pthollow/GC) was prepared. The morphology and composition of Pthollow nanospheres were characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM), energy dispersive X-ray spectroscopy (EDX), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and X-ray diffraction (XRD) techniques. The electrocatalytic activities of Pthollow/GC and electrodeposited Pt nanoparticles modified glassy carbon electrode (Ptnano/GC) toward methanol oxidation …
Comparison In Factors Affecting Electrochemical Properties Of Thermal-Reduced Graphene Oxide For Supercapacitors,
2014
School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China;Laboratory of Clean Energy Chemistry and Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;
Comparison In Factors Affecting Electrochemical Properties Of Thermal-Reduced Graphene Oxide For Supercapacitors, Peng Xiao, Da-Hui Wang, Jun-Wei Lang
Journal of Electrochemistry
In this paper, thermal-reduced graphene oxide (T-RGO) materials are synthesized by modified Hummer’s method, followed by thermal reduction under argon atmosphere at different temperatures. Electrochemical investigations show that, for T-RGO electrodes, good electrical conductivity is necessary and the surface functional groups play more significant role than the specific surface area in determining the electrochemical capacitance. The T-RGO obtained at 900 °C (T-RGO900) with a relatively high Brunauer-Emmett-Teller (BET) surface area (314 m2·g-1) and a high electrical conductivity (2421 S·m-1) shows a low specific capacitance of 56 F·g-1. In comparison, the T-RGO obtained …
Synthesis Of Namnpo4 By Spraying Drying-High Temperature Sintering And Its Electrochemical Performance,
2014
Xiamen University
Synthesis Of Namnpo4 By Spraying Drying-High Temperature Sintering And Its Electrochemical Performance, Xiao-Chen Lin, Xiao-Biao Wu, Xu Hou, Yong Yang
Journal of Electrochemistry
As a cathode material for sodium ion batteries, NaMnPO4/C nanocomposite is successfully synthesized by the combination of spraying drying and high temperature sintering methods. The crystal structure of the as-synthesized phosphate material is confirmed as the natrophilite NaMnPO4, which possesses orthorhombic symmetry and Pmnb space group. It is shown that the precursors are hollow spherical particles and the obtained product consists of micro-scaled secondary particles, which are composed of NaMnPO4 nanocrystallites (tens of nanometres) and amorphous carbon networks. The ionic and electronic conductivities of NaMnPO4 are both effectively enhanced with the help of this …
One-Step Synthesis Of Pani/Nihcf Hybrid Film Using Unipolar Pulse Electrodeposition And Its Electrocatalytic Reduction Performance For H2O2 Detection,
2014
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China;
One-Step Synthesis Of Pani/Nihcf Hybrid Film Using Unipolar Pulse Electrodeposition And Its Electrocatalytic Reduction Performance For H2O2 Detection, Sen-Liang Liao, Xiu-Min Li, Xiao-Gang Hao, Yan-Hong Wang, Chun-Feng Xue, Yong-Hong Wang
Journal of Electrochemistry
Organic–inorganic hybrid films composed of polyaniline/nickel hexacyanoferrate (PANI/NiHCF) were fabricated on platinum substrates using unipolar pulse one-step electrodeposition. The deposition mechanism of hybrid film was proposed: Due to high potential of unipolar pulse electrodeposition, which avoided the reduction of Fe(CN)63-, the films with high electrocatalytic property and “insoluble” form of NiHCF were achieved. The morphology and composition of PANI/NiHCF hybrid film were characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and Fourier transform infrared spectroscopy (FT-IR). The effect of pulse potential on the electrochemical performance of hybrid film was investigated in detail. Results showed that …
