Chemical Engineering Commons^™

Printing Functional Electronic Circuits And Components, Ahmed Tausif Aijazi

Dissertations

The purpose of this study was to investigate the challenges in printing reliable multilayer flexible circuits, devices and components. Gravure was used as the primary printing process for this work, but due to some limitations of gravure, other printing methods were also investigated. At first a systematic study was done to determine the optimum parameters for the gravure printing of sub 50 micron lines. Commercially available silver nanoparticle inks were printed on a lab scale gravure printer, Accupress®. The highest resolution line that was electrically conductive was 36μm wide. The 9μm, 18μm and 27μm lines were printed but were not …

Lntegration Of Conventional Lithography And Printing Processes As A Key Enabling Technology For Printed And Flexible Sensing Systems, Binu Baby Narakathu

Dissertations

Sensors, which are used ubiquitously in a wide variety of applications, are revolutionizing the already ever-changing world we live in by providing real-time information about our surroundings. This dissertation focuses on the integration of conventional photolithography and printing processes as a key enabling technology for printed and flexible sensing systems.

Initially, an efficient opto-electrochemical sensing system, for the dual detection of heavy metal compounds was successfully developed. A novel microfluidic flow cell, with a reservoir volume of 25 μl, was designed and fabricated using acrylic. An electrochemical sensor with gold (Au) interdigitated electrodes (IDE) on a glass substrate was photolithographically …

Using Greet To Analyze Natural Gas Usage In Municipal Fleets, Bradley E. Gibson

Honors Theses

GREET was used to calculate energy consumption and pollutants emitted from specific fuel/vehicle types when given a specific set of parameters. In this case, the parameters were the type of fuel mix from TVA, the selected vehicle year of 2015, the vehicle weight specified in the heavy-duty vehicle range, and type of simulation technique, which was the Hammersely Sequence Sampling. These inputs, along with seventeen fuel/vehicles mixes, specific pollutants, and cost considerations, were used to investigate the environmental impact of the transition from petrol diesel to natural gas in the municipal fleets of Chattanooga, Tennessee. The energy consumption included coal, …

Kinetic Experimental And Modeling Studies On Iron-Based Catalysts Promoted With Lanthana For The High-Temperature Water-Gas Shift Reaction Characterized With Operando Uv-Visible Spectroscopy And For The Fischer-Tropsch Synthesis, Basseem Bishara Hallac

Theses and Dissertations

The structural and functional roles of lanthana in unsupported iron-based catalysts for the high-temperature water-gas shift reaction and Fischer-Tropsch synthesis were investigated. The performance of the catalysts with varying lanthana contents was based on their activity, selectivity, and stability. With regard to the former reaction, extent of reduction of the iron in Fe2O3/Cr2O3/CuO/La2O3 water-gas shift catalysts is a key parameter that was characterized using UV-visible spectroscopy. Minor addition of lanthana (<0.5 wt%) produces more active and stable catalysts apparently because it stabilizes the iron-chromium spinel, increases the surface area of the reduced catalysts, enhances the reduction of hematite to the magnetite active phase, and facilitates the adsorption of CO on the surface of the catalyst modeled by an adsorptive Langmuir-Hinshelwood mechanism. Statistical 95% confidence contour plots of the adsorption equilibrium constants show that water adsorbs more strongly than CO, which inhibits the reaction rate. A calibration curve that correlates the oxidation state of surface iron domains to normalized absorbance of visible light was successfully generated and applied to the water-gas shift catalysts. UV-visible studies indicated higher extent of reduction for surface Fe domains for the catalysts promoted with 1 wt% of lanthana and showed potential to be a more convenient technique for surface chemistry studies than X-ray absorption near edge spectroscopy (XANES). Lanthana addition to iron-based Fischer-Tropsch catalysts enhances the olefin-to-paraffin ratio, but decreases their activity, stability, and selectivity to liquid hydrocarbons. Adding lanthana at the expense of potassium reduces the water-gas shift selectivity and enhances the activity and stability of the catalysts. Finally, a model that simulates heat and mass transfer limitations on the particle scale for the Fischer-Tropsch reaction applicable at lab-scale suggests optimal operating and design conditions of 256°C, 30 bar, and 80 mirons are recommended for higher selectivity to liquid hydrocarbons. The model considers pressure drop, deactivation, pore diffusion, film heat transfer, and internal heat transfer when solving for the optimal conditions, and maps them as functions of design variables. This model can be up-scaled to provide guidance for optimal design of commercial-size reactors.

Fabrication Of A Thin Silver Nanowire Composite Film And Investigation Of A Patterning Technique., Richard S. Korte 1991-

Electronic Theses and Dissertations

Electrically conductive polymers encompass an exciting field of research for applications in dye-sensitized solar cells (DSSC’s). DSSC’s possess several advantages over other types of solar cells. They offer the potential for high quantum efficiency, solar conversion efficiency approaching that of traditional silicon panels, rapid charge transfer kinetics for photo-excited electrons, mechanical flexibility, and cost efficient manufacturing processes. However, key drawbacks to their large scale production and performance lifetime lie in their reliance on costly indium tin oxide (ITO), fluorinated tin oxide (FTO), and platinum for electrode materials, and the mechanical fragility inherent to a liquid electrolyte layer component. Much of …

Optimized Photogrammetric Network Design With Flight Path Planner For Uav-Based Terrain Surveillance, Ivan Yair Rojas

Theses and Dissertations

This work demonstrates the use of genetic algorithms as a stochastic optimization technique for developing a camera network design and the flight path for photogrammetricapplications using Small Unmanned Aerial Vehicles. This study develops a Virtual Optimizer for Aerial Routes (VOAR) as a new photogrammetric mapping tool for acquisition of images to be used in 3D reconstruction. 3D point cloud models provide detailed information on infrastructure from places where human access may be difficult. This algorithm allows optimized flight paths to monitor infrastructure using GPS coordinates and optimized camera poses ensuring that the set of images captured is improved for 3D …

The Development Of A Laminated Copolyester Electric Guitar, Addison S. Karnes

Electronic Theses and Dissertations

This thesis is an investigation of the fabrication and assembly methodologies employed in the development of a proof-of-principle prototype electric guitar composed of laminated copolyester. The objective of the project was to develop the processes and procedures to create an optimized physical and visual bond between layers to minimize vibratory dissipation, thus maximizing sustain. A high speed CNC router, abrasive waterjet, laser engraver-cutter, as well as various manual fabrication and assembly methods were investigated in the construction of the guitar prototypes. The lamination processes explored include low-temperature, heat-assisted pressure bonding, solvent and chemical welding, and contact adhesives. The project concluded …

Water System For Developing Countries / Disaster Relief Made With Local Materials, Shumon Hasan

Chemistry & Biochemistry Undergraduate Honors Theses

The objective of this project was to design a water purification system that can be constructed from easily available materials, common to the particular country, and is capable of the complete water purification process.

Solar Brine Concentrator, Aric Gregory Fisher

Chemical Engineering Undergraduate Honors Theses

In arid regions of the United States potable water is a valuable resource and is sometimes produced using energy intensive processes by removing salts from brackish water. Task 4 provides a solar option for producing potable water from brackish water; in competing in Task 4, H2OGS has developed a simple, cost effective solar desalination process to provide these regions with necessary, potable water. H2OGS’ design takes into account WERC requirements, including cost, energy usage, worker safety, and easily obtained materials. U.S. government regulatory requirements are also taken into account as the proposed location for this process is Alamogordo, New Mexico. …

Werc: Solar Brine Concentrator, Sarah K. Haley

Chemical Engineering Undergraduate Honors Theses

In arid regions of the United States potable water is a valuable resource and is sometimes produced using energy intensive processes by removing salts from brackish water. Task 4 provides a solar option for producing potable water from brackish water; in competing in Task 4, H2OGS has developed a simple, cost effective solar desalination process to provide these regions with necessary, potable water. H2OGS’ design takes into account WERC requirements, including cost, energy usage, worker safety, and easily obtained materials. U.S. government regulatory requirements are also taken into account as the proposed location for this process is Alamogordo, New Mexico. …

Simultaneous Conversion Of All Cell Wall Components By Oleaginous Fungus Without Chemi-Physical Pretreatment, Shangxian Xie, Xin Qin, Yanbing Cheng, Dhrubojyoti Laskar, Weichuan Qiao, Su Sun, Luis Reyes, Xin Wang, Susan Dai, Scott Sattler, Katy Kao, Bin Yang, Xiaoyu Zhang, Joshua Yuan

Faculty Publications

Lignin utilization during biomass conversion has been a major challenge for lignocellulosic biofuel. In particular, the conversion of lignin along with carbohydrate for fungible fuels and chemicals will both improve the overall carbon efficiency and reduce the need for chemical pretreatments. However, few biomass-converting microorganisms have the capacity to degrade all cell wall components including lignin, cellulose, and hemicellulose. We hereby evaluated a unique oleaginous fungus strain, Cunninghamella echinulata FR3, for its capacity to degrade lignin during biomass conversion to lipid, and the potential to carry out consolidated fermentation without chemical pretreatment, especially when combined with sorghum (Sorghum bicolor) bmr …

Low Molecular Weight Glucosamine/L-Lactide Copolymers As Potential Carriers For The Development Of A Sustained Rifampicin Release System: Mycobacterium Smegmatis As A Tuberculosis Model, Jorge Ragusa

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Tuberculosis, a highly contagious disease, ranks as the second leading cause of death from an infectious disease, and remains a major global health problem. In 2013, 9 million new cases were diagnosed and 1.5 million people died worldwide from tuberculosis. This dissertation aims at developing a new, ultrafine particle-based efficient antibiotic delivery system for the treatment of tuberculosis. The carrier material to make the rifampicin (RIF)-loaded particles is a low molecular weight star-shaped polymer produced from glucosamine (molecular core building unit) and L-lactide (GluN-LLA). Stable particles with a very high 50% drug loading capacity were made via electrohydrodynamic atomization. Prolonged …

Synthesis And Characterization Of Chemically Functionalized Shape Memory Nanofoams For Unattended Sensing Applications, Anna Paola Soliani

All Dissertations

The work in this dissertation is devoted to the synthesis and characterization of novel materials for off-line unattended sensing: shape-memory grafted nanofoams. The fabrication process and characterization of highly efficient, polymeric nanosensor element with the ability to selectively detect analytes and retain memory of specific exposure events is reported. These shape memory nanofoams could potentially act as efficient and highly sensitive coatings for evanescent waveguide-based optical monitoring systems. On exposure to specific analytes, the polymeric coatings locally change their internal structure irreversibly at the nanolevel, affecting the local optical properties such as refractive index. Currently, enrichment polymer layers (EPLs) are …

Thermally Responsive Polymer Electrolytes For Inherently Safe Electrochemical Energy Storage, Jesse Kelly

All Dissertations

Electrochemical double layer capacitors (EDLCs), supercapacitors and Li-ion batteries have emerged as premier candidates to meet the rising demands in energy storage; however, such systems are limited by thermal hazards, thermal runaway, fires and explosions, all of which become increasingly more dangerous in large-format devices. To prevent such scenarios, thermally-responsive polymer electrolytes (RPEs) that alter properties in electrochemical energy storage devices were designed and tested. These RPEs will be used to limit or halt device operation when temperatures increase beyond a predetermined threshold, therefore limiting further heating. The development of these responsive systems will offer an inherent safety mechanism in …

Backfolding Of Wormlike Chains Confined In Nanochannels, Abhiram Muralidhar, Douglas R. Tree, Kevin D. Dorfman

Faculty Publications

Using pruned-enriched Rosenbluth method (PERM) simulations of a discrete wormlike chain model, we provide compelling evidence in support of Odijk’s prediction of two distinct Odijk regimes for a long wormlike chain confined in a nanochannel. In both cases, the chain of persistence length lp is renormalized into a series of deflection segments of characteristic length D2/3lp1/3, where D is the channel size. In the first (classic) Odijk regime, these deflection segments are linearly ordered. In the second Odijk regime, thin, long wormlike chains can backfold at a length scale quantified by the global persistence length. We …

Microwave-Assisted Synthesis Of Pd Nanoparticles Supported On Fe3o4, Co3o4, And Ni(Oh)2 Nanoplates And Catalysis Application For Co Oxidation, Hany A. Elazab

Chemical Engineering

In this paper, we report a simple, versatile, and rapid method for the synthesis of Pd nanoparticle catalysts supported on Fe3O4, Co3 O4, and Ni(OH)2 nanoplates via microwave irradiation. The important advantage of microwave dielectric heating over convective heating is that the reactants can be added at room temperature (or slightly higher temperatures) without the need for high-temperature injection. Furthermore, the method can be used to synthesize metal nanoparticle catalysts supported on metal oxide nanoparticles in one step. We also demonstrate that the catalyst-support interaction plays an important role in the low temperature oxidation of CO. The current results reveal …

Field-Limited Migration Of Li-Ions In Li-Ion Battery, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

The migration of Li-ions in lithium-ion battery cannot be simply described by Fick's second law; the interactions among ionic migration, field, and stress need to be taken into account when analyzing the migration of Li-ions. Using the theory of thermal activation process, the flux for ionic migration under concurrent action of electric field and mechanical stress is found to be a nonlinear function of the gradient of electric potential and the gradient of stress. Electric field can either accelerate or retard the growth of the lithiation layer, depending on polarity of the field.

Nonlinear Modeling, Estimation And Predictive Control In Apmonitor, John Hedengren, Reza Asgharzadeh Shishavan, Kody M. Powell, Thomas F. Edgar

Faculty Publications

This paper describes nonlinear methods in model building, dynamic data reconciliation, and dynamic optimization that are inspired by researchers and motivated by industrial applications. A new formulation of the ℓ₁-norm objective with a dead-band for estimation and control is presented. The dead-band in the objective is desirable for noise rejection, minimizing unnecessary parameter adjustments and movement of manipulated variables. As a motivating example, a small and well-known nonlinear multivariable level control problem is detailed that has a number of common characteristics to larger controllers seen in practice. The methods are also demonstrated on larger problems to reveal algorithmic …

Investigating The Release Mechanism Of Calcein From Eliposomes At Higher Temperatures, Ghaleb A. Husseini, William G. Pitt, Jacob B. Williams, Marjan Javadi

Faculty Publications

Numerous nanocarriers are currently being investigated as drug delivery vehicles for transporting chemotherapeutics to cancer cells. Our research group has recently synthesized a new generation of echogenic liposomes based on the concept of encapsulating one or more nanoemulsion droplets inside a liposome (called an “eLiposome”). The concept is to use a nanoemulsion droplet with a low boiling point near body temperature, thus requiring only a small acoustic nudge to vaporize the droplet from liquid to gas and break open the eLiposome, thus releasing its contents. The purpose of this note is twofold. First, we wanted to show experimentally that eLiposomes …

Going From Microbial Ecology To Genome Data And Back: Studies On A Haloalkaliphilic Bacterium Isolated From Soap Lake, Washington State, Melanie R. Mormile

Biological Sciences Faculty Research & Creative Works

Soap Lake is a meromictic, alkaline (∼pH 9.8) and saline (∼14-140 g liter^-1) lake located in the semiarid area of eastern Washington State. Of note is the length of time it has been meromictic (at least 2000 years) and the extremely high sulfide level (∼140 mM) in its monimolimnion. As expected, the microbial ecology of this lake is greatly influenced by these conditions. A bacterium, Halanaerobium hydrogeniformans, was isolated from the mixolimnion region of this lake. Halanaerobium hydrogeniformans is a haloalkaliphilic bacterium capable of forming hydrogen from 5- and 6-carbon sugars derived from hemicellulose and cellulose. Due …