Chemical Engineering Commons^™

The Role Of Surface Active Compounds In Crude Oil On Reservoir Wettability., Paulina Metili Mwangi

LSU Doctoral Dissertations

This study examines the role of crude oil’s surface active compounds (SAC) in determining the reservoir wettability. Wettability describes the relative preference of a reservoir rock for oil or water. Wettability influences the distribution of fluids in a reservoir and the efficiency of oil recovery methods. Unfortunately, the chemical mechanisms controlling wettability in individual reservoirs remain hazy. Wettability is conditional and is influenced by rock mineralogy, fluid chemistry, and temperature. An extensive experimental study was executed to understand the impact of naturally-occurring SACs typically found in crude oil, on the wettability of sandstone and carbonate rocks over a range of …

The Formation Of Polycyclic Aromatic Hydrocarbons From The Pyrolysis Of Model 1-Alkene Fuels, Eva Christine Caspary

LSU Doctoral Dissertations

To understand the role of 1-alkenes and allylic radicals in the reaction pathways leading to the formation and growth of polycyclic aromatic hydrocarbons (PAH), pyrolysis experiments have been performed with three 1-alkene fuels—propylene (CH₂=CH–CH₃), 1-butene (CH₂=CH–CH₂–CH₃), and 1-pentene (CH₂=CH–CH₂–CH₂–CH₃)—at temperatures of 600 – 1000 °C and a fixed residence time of 0.31 s. The experiments are carried out in an isothermal laminar-flow quartz-tube reactor. Analyses of the pyrolysis products by gas-chromatographic and high-pressure liquid-chromatographic techniques reveal that the three fuels differ in: 1) their conversion behavior, 2) the relative amounts of the major C₂ – C₄ species produced, and 3) …

Theoretical Investigation Of The Catalytic Hydrodeoxygenation Of Levulinic Acid Over Ru (0001) Catalyst Surface, Osman Mamun

Theses and Dissertations

Due to the rapidly declining fossil fuel reserves and the onset of global climate change, the development of active, selective, and stable catalytic materials for the efficient production of biomass derived platform chemicals, i.e., levulinic acid (LA), succinic acid (SA), γ-valerolactone (GVL) etc., is receiving considerable attention in order to produce second generation biofuels and commodity chemicals. Though solid lignocellulosic biomass is significantly cheaper than petroleum; however, the available technology is the significant barrier for large scale utilization of biomass for the production of biofuels. The development of biomass conversion technology requires, 1) identification of potential biomass chemicals that can …

Catalytic Activity Of Cu-Ceo2zro2 For Biodiesel Production, Wasupon Wongvitvichot

Chulalongkorn University Theses and Dissertations (Chula ETD)

CeO2-ZrO2 was synthesized by co-precipitation (CZ copre) and nanocasting (MSP CZ) methods for supporting 9%wt Cu catalyst loaded by deposition-precipitation (DP) method (CuCZ copre and Cu-MSP CZ, respectively). Both CuCZ copre and Cu-MSP CZ were used in esterification reaction for biodiesel production. Structure and specific surface area of the synthesized supports and catalysts were characterized by XRD and BET tecnhiques. It was found that the specific surface area of CZ copre was less than MSP CZ support. The XRD result of CuCZ copre exhibited the diffraction peak of CuO, indicating the agglomeration of Cu species on support while that of …

Designing Efficient Petroleum Fiscal System For Mozambique, Nelson Victor

Chulalongkorn University Theses and Dissertations (Chula ETD)

Nowadays, tax regime is designed to attract investment and provide the contractor with fair return on investment, at the same time, provide the host government with adequate resources for rent, thereby resulting in win-win situation. This study analyses the existing petroleum fiscal regime in the Republic of Mozambique and proposes a more efficient and flexible regime. The analysis shows that the government take currently remains at around 39% while the contactors' net present value (NPV) increases as field sizes and oil prices increase. The current system is considered a regressive system which is inefficient in distributing wealth from oil profit. …

A Comprehensive Analysis Of Lost Circulation Materials And Treatments With Applications In Basra's Oil Fields, Iraq: Guidelines And Recommendations, Husam Hasan Alkinani

Masters Theses

"Lost circulation materials (LCM's) have been widely used to avoid or stop losses. Due to a large number of current available LCM's and their different applications, classification of LCM's is very important. The most recent LCM classification was published around 50 years ago, and this paper intends to fill this gap with an updated classification including conventional and new technologies. Lost circulation materials and treatments are re-classified into various categories based on their appearance, applications, chemical and physical properties.

Wells in Basra's oil fields are highly susceptible to lost circulation problems when drilling through the Dammam, Hartha, and Shuaiba formations. …

Evaluation Of Preformed Particle Gels Penetration And Propagation Behavior For A Conformance Control Treatment In Partially Open Conduits, Ahmed Mohamed Aldalfag

Masters Theses

"Preformed particle gels (PPGs) serve as a conformance control agent and have been used widely to control excess water production through conduits, fractures or fracture-like features. This research ranks the parameters that impact PPG resistance to water flow in partially opened conduits. Experiments were conducted to examine the effect of brine concentration, PPG injection pressure, back pressure, reducing water salinity and matrix permeability on PPG resistance to water flow through conduits, PPG penetration to the matrix. PPGs were swelled in different concentration brines and were injected into the conduits at a few designed injection pressures. PPG swollen in high brine …

Determination Of Significant Parameters That Drive Fracture Optimization In The Glauconite Formation, Southern Chile, Ghassan Saleh Mahdi Alqatrani

Masters Theses

"The Glauconite Formation in the Magallanes Basin of Southern Chile is a clay- and silica-rich formation with low permeability. As with many of the unconventional resources, the Glauconite Formation requires a hydraulic fracturing operation to enhance the productivity of the wells in this area.

Data and pertinent information of fracturing, completion, and reservoir quality parameters along with post-fracture production data were collected to initiate a database of nearly 70 wells, to be used to develop a better understanding of the fracturing behavior, optimize the well stimulation, and overcome the major barriers in the hydraulic fracturing of the Glauconite Formation. The …

Deformation Processes At The Leading Edge Of The Sevier Fold And Thrust Belt, Southwest Utah, William Joseph Michael Chandonia

Masters Theses

"Deformation processes leading to formation and abandonment of 'triangle zones' along the leading edge of the Sevier fold and thrust belt are investigated near Kanarraville, Utah through construction of a detailed geologic map and cross-section along Spring Creek. Here the eastern limb of the Kanarra fold, a Sevier structure, is well exposed along the Hurricane Cliffs due to uplift and erosion of the footwall of the Hurricane Fault. The east-verging Kanarra fold changes from upright to overturned within Spring Creek. Within the fold limb, parasitic folds, minor thrust faults, and duplex structures result in local tectonic overthickening of units and …

Advanced Buffer Materials For Indoor Air Co₂ Control In Commercial Buildings, Pavithra Ethi Rajan

Masters Theses

"The following describes a novel passive approach to control the indoor CO₂ levels in enclosed spaces, primarily focusing on commercial buildings. Amine impregnated silica sorbents were identified as suitable candidates and synthesized; the amine loading ratio was varied to create a range of materials. These samples along with other commercial zeolite candidates have been tested over a range of CO₂ concentrations to determine the CO₂ adsorption capacity in laboratory systems and under simulated room conditions. The research work also focuses on the CO₂ desorption capacity of the candidate adsorbents. The desorption is allowed to occur gradually …

Cathodic Protection Measurement Through Inline Inspection Technology Uses And Observations, Briana Ley Ferguson

Masters Theses

"This research supports the evaluation of an impressed current cathodic protection (CP) system of a buried coated steel pipeline through alternative technology and methods, via an inline inspection device (ILI, CP ILI tool, or tool), in order to prevent and mitigate external corrosion. This thesis investigates the ability to measure the current density of a pipeline's CP system from inside of a pipeline rather than manually from outside, and then convert that CP ILI tool reading into a pipe-to-soil potential as required by regulations and standards. This was demonstrated through a mathematical model that utilizes applications of Ohm's Law, circuit …

Effect Of Fracture Heterogeneity On Proppant Transport And Settling Mechanism, Dhurgham Abdulameer Kadhim

Masters Theses

"Proppant transport modeling through fractures with slickwater fluid systems assumes uniform and homogeneous fracture widths by implying constant fluid behavior at wall boundaries. Hydraulic fracturing mineback operations have demonstrated that induced fractures are heterogeneous and varying in width. This work investigates the impact of fracture width heterogeneity, roughness, and leak-off on ceramic proppant transport and settling, using proppant distribution concepts of Equilibrium Dune Level (EDL) and equilibrium Dune Length (EDX). Experimental work was conducted to investigate the impact of fracture width heterogeneity by varying fracture width along two plexiglass sheets. To mimic actual hydraulic fractures, the injection side was designed …

Geomechanical Analysis Of The Wellbore Instability Problems In Nahr Umr Formation Southern Iraq, Haider Qasim Mohammed

Masters Theses

"Wellbore instability problems play a major rule of increasing nonproductive time (NPT) during drilling processes. In most cases, the cost of drilling a well can be reduced by designing a suitable operational window using geomechanical models. Several wellbore instability problems have been encountered during drilling Nahr Umr Formation in an oil field in southern Iraq. These problems include but are not limited to, mechanical stuck, caving, and tight holes. Data from twenty vertical wells are investigated to reveal the major factors that control the instability problems and to design an optimum mud window. A geomechanical model is developed to determine …

Quantifying Ceramic Proppant Transport In Complex Fracture Networks, Vivekvardhan Reddy Kesireddy

Masters Theses

"Water fracs have become an essential part of unconventional reservoirs to create deeper fracture networks. Proppant transport in water fracs is challenging in terms of fluids ability to carry the proppant deeper into these fracture networks. This experimental study investigates the impact of the flow rates, fracture widths and complexity controlling the ability of proppant to flow into complex fracture networks. This research attempts to nullify the knowledge gap in understanding width heterogeneity in primary and secondary fractures. This study speaks for settling pattern and proppant transport through a slot flow model with a unique approach to understand stage wise …

Evaluation Of Preformed Particle Gel As A Diverting Agent For Acidizing, Bo Wei

Masters Theses

"Preformed particle gels (PPGs) have been developed and successfully used to improve conformance in heterogeneous reservoirs. However, no research has been reported to show their potential diverting applications in acidizing because of their unknown performance in this process. This work targets on evaluating the potential of PPGs to be used as diverting agents and factors influencing the diverting performance.

The swelling properties of three types of PPGs (PPG #1, #2, and #3) were first studied in brine and acid, including the swelling kinetics and equilibrium, PPG strength, and deswelling performance. Effects of different brine concentration, acid concentration, and temperature were …

Design And Modeling Of An Aluminum Smelting Process To Analyze Aluminum Smelter And Identify The Alternative Uses Of Nuclear Power Small Modular Reactor, Rajesh Ramkrushna Patharabe

Masters Theses

"This thesis focuses on design and analysis of an Aluminum Smelting process using computer simulation which performs a dynamic state computation. The objective is to develop a Dynamic Simulation Model of an Aluminum Smelter using Mimic Simulator to analyze the dynamic behavior of an Aluminum Smelter to evaluate strategies for alternative design or uses of Nuclear Power Small Modular Reactor to improve the efficiency of the process and to reduce the heat losses.

Increasing energy needs, decrease of the availability of cheap electricity and the need to reduce the greenhouse gases emissions are the biggest hurdles for running Aluminum smelters …

Development Of Standard Operating Procedure: Admicellar Polymerization Of Polystyrene Thin Film (Aibn) On Polysciences 30-50Μm Glass Beads Using Cetyltrimethyl-Ammonium Bromide Surfactant, David Langford

Honors Theses

Poly(1-phenylethene), commonly referred to as Polystyrene, is one of the world's most common polymers. Made from the monomer styrene (ethenylbenzene), this polymer is used in a wide range of products from packing peanuts to disposable cutlery. The method of polymerization used in this research project is called admicellar polymerization. This process consists of four main steps: admicelle formation, adsolubilization, polymerization, and removal of admicelle and polymer. Admicellar polymerization has a number of advantages over related methods of thin film polymerization including simplicity and low cost of components and process.

Thermal Denox Optimization: A Case Study In Fluid Catalytic Cracking, David E. Rozier

Honors Theses

This thesis will first provide background information on fluid catalytic cracking (FCC), a highly important unit operation to the process of petroleum refining, and a description of Thermal DeNOx, an environmental treatment system common to FCC units and other process units where high temperature furnaces are used. Next, this thesis will detail a project which I had the chance to lead as a process engineering intern at ExxonMobil's Baton Rouge Refinery in the fall of 2016. The objective of the project was to optimize Thermal DeNOx systems installed on two FCC units at the refinery. Experiments were conducted on these …

The Pharmacodynamic Functions Of Low-Dose Rapamycin As A Model For Universal Influenza Protection, William Gust

Honors Theses

One of the most sought after breakthroughs in modern influenza research is the creation of a universal influenza vaccine that would protect against all strains of avian influenza. An unlikely model for this kind of protection might be found in the mTOR inhibitor rapamycin. Traditionally used to prevent organ transplant rejection, low doses of rapamycin have been found to protect mice against infection with distinct subtypes of influenza. However, it is not understood how a partial block in this pathway provides optimal heterosubtypic immunity. Interestingly, previous experiments have shown that low dose rapamycin inhibits germinal center formation to reduce antibody …

Evaluation Of Sigma Ligand Az66 Analgesic Potentiation Of Cannabinoids, Jacqueline Morris

Honors Theses

Sigma receptors have become a popular subject for research the past few decades, but there is still much mystery behind these receptors and how they work. Sigma receptors, like cannabinoid-1 (CB1) receptors, have effects on the human body including appetite regulation, depression, and analgesia. AZ66 is a highly selective sigma receptor ligand that has antagonistic properties. Sigma receptor antagonists have been shown to potentiate the analgesic effects of opiates; however, there are no known literature reports about the interaction between the sigma receptor system and the endocannabinoid system, including CB1 receptors. The purpose of this study is to evaluate AZ66 …