Chemical Engineering Commons^™

Atomic/Molecular Layer Deposition Prepared Size-Selective Catalysts And Supported Nickel Catalysts, Zeyu Shang

Doctoral Dissertations

"Heterogeneous catalysts are widely used because of their many advantages. In this dissertation, the application of atomic/molecular layer deposition (ALD/MLD) in heterogeneous catalyst synthesis and modification was examined.

A novel nanostructured size-selective catalyst was synthesized by depositing ultra-thin porous shells on the surface of catalysts. The ultra-thin porous shells were formed by oxidation of aluminum alkoxide films deposited by MLD. The catalytic activity of the size-selective catalyst was improved by introducing gaps between the porous shell and catalytic metal nanoparticles. The introduction of gaps greatly reduced the catalyst activity loss, which resulted from the contact areas between the active sites …

Experimental Investigations Of Natural Circulation In A Separate-And-Mixed Effects Test Facility Mimicking Prismatic Modular Reactor (Pmr) Core, Mahmoud M. Taha

Doctoral Dissertations

"After the Fukushima Daiichi nuclear power plant accident in 2011, significant attention was directed to investigate natural circulation thermal-hydraulics in Prismatic Modular Reactors (PMRs). Natural circulation is employed as a passive safety feature that passively removes the decay heat released after the loss of flow accidents (LOFA). Several computational studies have addressed such phenomena, however, validation of Computational Fluid Dynamics (CFD) is needed by providing high-quality data obtained from separate test facilities designed with reference to the corresponding reference PMRs. To address this need, a separate effects Plenum-to-Plenum Facility (P2PF) was designed and developed with dual channels and plena for …

Performance Evaluation Of Integrated Co2 Huff-N-Puff And Wag In Low-Pressure Heterogeneous Reservoir, Hutthapong Yoosook

Chulalongkorn University Theses and Dissertations (Chula ETD)

The integrated CO2 Huff-n-Puff and WAG is a novel technique to combine CO2 Huff-n-Puff technique that conducted at early state and followed by WAG technique until the end of operating time. This technique is effectiveness in term of increased oil recovery and reduced CO2 utilization. However, the integrated CO2 Huff-n-Puff and WAG process contains numerous adjustable operating parameters. Hence, numerical simulation study and sensitivity analysis become essential to investigate the effects of main operational parameters and evaluate the performance of the integrated CO2 Huff-n-Puff and WAG process in low-pressure heterogeneous reservoir to achieve the maximum benefits. According to simulation results, …

Designing And Development Of A Photobioreactor For Optimizing The Growth Of Micro Algae And Studying Its Growth Parameters, Sarmila Katuwal

Electronic Theses and Dissertations

This thesis presents the estimated value of materials required to grow 1g of biomass and the analysis of the light intensity with respect to flow path and flow rate. This thesis aims to design the sparger for a flat plate Photobioreactor, study the flow patterns at different flow rate of air flow and check the performance of flat plate PBR by growing the cyanobacteria. The estimated value to produce 1g of biomass (C_44.6H₇O₂₅N_7.68P_0.9S_0.3) was 0.099g of N, 0.493g of C, 0.160 g of Na, 0.026 g of P, …

Engineering Of Organic Nanocrystals By Electrocrystallization, Mohamed Kilani

Wayne State University Theses

This work discusses the experimental and theoretical methods used to control the morphology of nanocrystals. The hypothesis of the thermodynamic/kinetic control of the morphology was verified. We applied the electrocrystallization to make K(def)TCP nanocrystals and we tuned the electrochemical parameters to determine their influence on the nanocrystals morphologies. The characterization was mainly performed with AFM and FE-SEM. We presented in this work the possibility to control the morphology of K(def)TCP using the electrochemical parameters. The obtained shapes ranged from nanorods to rhombohedral shape, which is reported for the first time. The observed growth behavior was modeled and simulated with a …

Green Thermosetting Factory: Novel Star-Shaped Bio-Based Systems And Their Thermosetting Resins; Synthesis And Characterization, Arash Jahandideh

Electronic Theses and Dissertations

Increasing attentions toward sustainable development, economic and environmental issues have led to many attempts at replacing the petroleum-based materials with renewables. Substitution of petroleum-based platforms with green alternative technologies is beneficiary in different ways. Using bio-renewables reduces the dependency of the national plastic industry to the petroleum resources and substantially promotes the environmental profile and sustainability of the product. It is expected that the emergence of the corn-based thermosetting industry generates substantial profits for the corn production sector. Developments in the emerging biobased thermosets are spectacular from a technological point of view. However, there are still several disadvantages associated with …

Accuracy And Precision In Force-Distance Curves, Stephen Morgan

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Using Better Solvents To Functionalize Glass With Chlorotrimethylsilane, Jonathan Cookston

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Fundamental Investigation Of The Electrocatalytic Activity Of Layered Mixed Metal Oxides For Low Temperature Oxygen Electrocatalysis, Ayad M. Nacy

Wayne State University Dissertations

Li–O2 (Li–air) batteries are among the most promising energy storage technologies due to their high theoretical specific capacity and energy density. Key challenges with this technology include high overpotential losses associated with catalyzing the electrochemical reactions (i.e., oxygen reduction and evolution reactions) at the cathode of the battery. One way to address this challenge is to incorporate an active electrocatalyst, such as first-order Ruddlesden-Popper series of layered oxides. We show that the composition of the A-site in first-order Ruddlesden-Popper series of layered oxides (A2BO4) has a significant effect in the electrochemical activity of Li-O2 cathodes. Among the oxides composed of …

Impedance Biosensors And Deep Crater Salivary Gland Scaffolds For Tissue Engineering, Robert Arthur Schramm

Legacy Theses & Dissertations (2009 - 2024)

The salivary gland is a complex, branching organ whose primary biological function is the production of the fluid critical to alimentary function and the lubrication and maintenance of the oral cavity, saliva. The most frequent disruption of the salivary organ system is one in which the rate of supply of saliva into the oral cavity is diminished, and this may vary from a minor reduction, to near cessation. Regenerative medicine is a field which seeks to find ways to overcome the symptoms of organ malfunction or damage by inducing regrowth, repair and replacement of partial or whole organ function. Historically, …

Optimal Combined Long-Term Facility Design And Short-Term Operational Strategy For Chp Capacity Investments, Jose Mojica, Damon Petersen, Brigham Hansen, Kody Powell, John Hedengren

Faculty Publications

This work presents a detailed case study for the optimization of the expansion of a district energy system evaluating the investment decision timing, type of capacity expansion, and fine-scale operational modes. The study develops an optimization framework to find the investment schedule over 30 years with options of investing in traditional heating sources (boilers) or a next-generation combined heat and power (CHP) plant that provides heat and electricity. In district energy systems, the selected capacity and type of system is dependent on demand-side requirements, energy prices, and environmental costs. This work formulates capacity planning over a time horizon as a …

Estimation And Utilization Of Landfill Gas From Egyptian Municipal Wastes, A Case Study, Ali Habib, Ahmed A. Abdel-Rehim

Mechanical Engineering

Purpose

As the first Author had the chance to invest in landfill gas plant (EL Hammam plant) that flare approximately 1000 m3/hr. to generate electricity. Two critical question must be answered in order to proceed with the feasibility study. The three questions are:

1. 1- How many years this landfill gas emission will last?

2. 2- How much energy can be generated from one million ton if landfilled?

3. 3- How much CO2 in tons will be saved during the project life time?

Methods: Experimental method is used to determine BMP (Biochemical methane potential) ton CH4/ton waste. With

results we can know the …

Uses For Graphene, Marcus R. Schmidt

Natural Sciences Student Research Presentations

This slide presentation for the Natural Sciences Poster Session at Parkland College discusses graphene, which is a chemically or mechanically produced single layer of pure carbon atoms. The thinnest compound known to man is also one of the strongest, with uses in technology and the health industry from faster charging batteries to motorcycle helmets. The remaining slides summarize a process by which free radicals are reduced in graphene by being treated with butyl acrylate polymerization.

Evaluation Of Captured Co2 And Waste H2 As Potential Feedstock For Methanol Production, Kankanit Kitsahawong

Chulalongkorn University Theses and Dissertations (Chula ETD)

Global warming is the critical issue that is the result of Greenhouse Gases (GHGs) emission. Carbon dioxide (CO2) is concerned to be major GHGs. Thus, Carbon dioxide utilization is the promising pathway to reduce the emission of CO2. To utilize CO2, waste hydrogen from sodium methoxide production is used to produce methanol which can be recycled as reactant of sodium methoxide synthesis. Carbon dioxide hydrogenation process is used for produce methanol from CO2 and waste H2 from various size of sodium methoxide production process. In every size of methanol production process, methanol which produce from the process is 16.3% of …

Biphasic Cellulose Acetate/Rtil Membranes And Functionalized Graphene Adsorbents For Natural Gas Processing: Experimental And Molecular Simulation Studies, Amir Khakpay

Electronic Theses and Dissertations

In this dissertation, gas separation using membranes is investigated for natural gas upgrading. The main objectives of this study are separation of high value hydrocarbons such as propane (c3h8) from natural gas and carbon dioxide (co2) separation from light gases such as nitrogen (n2) and methane (ch4). To achieve these goals, supported ionic liquid membranes (silms), biphasic membranes, and nanoporous graphene (npg) and graphene oxide (npgo) membranes are studied. Biphasic membranes are proposed to overcome silms issues for gas separation. The major issues with silms are low room temperature ionic liquid (rtil) content and instability at high cross-membrane pressure. For …

Monte-Carlo-Simulation-Based, Product-Quality-Focused Analysis Of Nanocoating Curing And Post Curing Process, Jianming Zhao

Wayne State University Theses

ABSTRACT

MONTE CARLO SIMULATION BASED

PRODUCT QUALITY ANALYSIS OF

POLYMER COATING CURING AND POST CURING

By

Jianming Zhao

May 2017

Advisor：Dr. Yinlun Huang

Major: Chemical Engineering

Degree: Master of Science

To achieve better property of polymer coatings, different categories of nanoparticles are applied before coating’s curing process. However, one of the adverse effects is the change of final property, which leads the difficulty of product quality control. Using mathematical modeling method can actually improve the cost and time to get a prediction of product quality. Still now, different series of models are developed for various purposes. For example, Monte-Carlo simulation …

Preformed Particle Gel Conformance Control Performance In Partially Opened Fracture And Fully Opened Fracture Systems, Ghith Ali Ahmed Biheri

Masters Theses

"Conformance problems, such as reservoir heterogeneity can result in a significant decrease in oil recovery, and an excessive water production. Millimeter particle gels (PPG) have been used as conformance control agents to plug open fractures, however, very little research has been conducted to study their ability to plug partially open fractures. This research studies the ability of the PPG to plug partially open fracture to improve conformance and increase recovery in oil reservoirs. Rectangular Sandstone cores were used to conduct the experiments. Fracture widths used include 2, 3.5, 5 mm. For each fracture width, four gel strengths were used; gel …

Design And Modeling Of An Aluminum Smelting Process To Analyze Aluminum Smelter And Identify The Alternative Uses Of Nuclear Power Small Modular Reactor, Rajesh Ramkrushna Patharabe

Masters Theses

"This thesis focuses on design and analysis of an Aluminum Smelting process using computer simulation which performs a dynamic state computation. The objective is to develop a Dynamic Simulation Model of an Aluminum Smelter using Mimic Simulator to analyze the dynamic behavior of an Aluminum Smelter to evaluate strategies for alternative design or uses of Nuclear Power Small Modular Reactor to improve the efficiency of the process and to reduce the heat losses.

Increasing energy needs, decrease of the availability of cheap electricity and the need to reduce the greenhouse gases emissions are the biggest hurdles for running Aluminum smelters …

A Comprehensive Analysis Of Lost Circulation Materials And Treatments With Applications In Basra's Oil Fields, Iraq: Guidelines And Recommendations, Husam Hasan Alkinani

Masters Theses

"Lost circulation materials (LCM's) have been widely used to avoid or stop losses. Due to a large number of current available LCM's and their different applications, classification of LCM's is very important. The most recent LCM classification was published around 50 years ago, and this paper intends to fill this gap with an updated classification including conventional and new technologies. Lost circulation materials and treatments are re-classified into various categories based on their appearance, applications, chemical and physical properties.

Wells in Basra's oil fields are highly susceptible to lost circulation problems when drilling through the Dammam, Hartha, and Shuaiba formations. …

Advanced Buffer Materials For Indoor Air Co₂ Control In Commercial Buildings, Pavithra Ethi Rajan

Masters Theses

"The following describes a novel passive approach to control the indoor CO₂ levels in enclosed spaces, primarily focusing on commercial buildings. Amine impregnated silica sorbents were identified as suitable candidates and synthesized; the amine loading ratio was varied to create a range of materials. These samples along with other commercial zeolite candidates have been tested over a range of CO₂ concentrations to determine the CO₂ adsorption capacity in laboratory systems and under simulated room conditions. The research work also focuses on the CO₂ desorption capacity of the candidate adsorbents. The desorption is allowed to occur gradually …