Investigation Of Fouling Mechanisms On Ion Exchange Membranes During Electrolytic Separations,
2019
University of Mississippi
Investigation Of Fouling Mechanisms On Ion Exchange Membranes During Electrolytic Separations, Matthew James Edwards
Honors Theses
The global water crisis is a major problem in our developing world due to the increasing growth of our global population, the depletion of natural water resources, and the continuing contamination of existing water resources as a result of industrialization. Membrane separation is a potential solution for these issues. Electrodialysis (ED) is a separation process which employs membranes to separate inorganic and organic substances. This study investigated how different fouling agents influenced membrane surface characteristic and separation efficiency within an electrodialysis system. While applicable for waste water, this study focuses on model salt water solutions with various fouling agents added …
Replacement Of A Liquid Filling System For Corrosive Materials,
2019
Western Michigan University
Replacement Of A Liquid Filling System For Corrosive Materials, William Breining
Honors Theses
An aging liquid filling system in contact with highly corrosive materials required replacement to protect personnel and surrounding equipment. The current system was investigated to identify areas where efficiency, safety, and productivity could be improved. Several competing solutions, including fillers and bulk chemical storage, were determined along with the corresponding economic and safety studies. The completed study provides information for filler and storage options and provides the necessary legwork for purchase of a replacement system.
Metabolon-Inspired Design Of Multi-Modal Catalytic Cascade,
2019
University of New Mexico - Main Campus
Metabolon-Inspired Design Of Multi-Modal Catalytic Cascade, Madelaine Seow Chavez
Chemical and Biological Engineering ETDs
Developing hybrid catalytic systems has been researched for the past decade in an effort to efficiently incorporate catalysts of different modalities in catalytic cascades. It has become imperative to design a cascade system where the catalysts are spatially organized to control the delivery of precursors, intermediates, and products. In this work, we have shown that a molecular catalyst, biocatalyst, and metallic catalyst can be co-localized using a carbonaceous support to create a hybrid catalytic system and complete the oxidation of oxalic acid to create a microchemical reactor. The molecular, pyrene-TEMPO catalyst oxidizes glyoxalic acid to oxalic acid. The enzyme oxalate …
Mass-Transfer Driven Spinodal Decomposition In A Ternary Polymer Solution,
2019
Brigham Young University
Mass-Transfer Driven Spinodal Decomposition In A Ternary Polymer Solution, Douglas R. Tree, Lucas F. Dos Santos, Caden B. Wilson, Timothy R. Scott, Jan Ulric Garcia, Glenn H. Fredrickson
Faculty Publications
Nonsolvent induced phase separation (NIPS) is a widely occuring process used in industrial membrane production, nanotechnology and Nature to produce microstructured polymer materials. A variety of process-dependent morphologies are produced when a polymer solution is exposed to a nonsolvent that, following a period where mass is exchanged, precipitates and solidifies the polymer. Despite years of investigation, both experimental and theoretical, many questions surround the pathways to the microstructures that NIPS can produce. Here, we provide simulation results from a model that simultaneously captures both the processess of solvent/nonsolvent exchange and phase separation. We show that the time it takes the …
Stabilized Interleukin-4-Loaded Poly(Lactic- Co-Glycolic) Acid Films Shift Proinflammatory Macrophages Toward A Regenerative Phenotype In Vitro,
2019
Missouri University of Science and Technology
Stabilized Interleukin-4-Loaded Poly(Lactic- Co-Glycolic) Acid Films Shift Proinflammatory Macrophages Toward A Regenerative Phenotype In Vitro, Alexis M. Ziemba, Anthony R. D'Amato, Taylor M. Macewen, Devan L. Puhl, Abigail N. Koppes, Ryan A. Koppes, Michelle R. Lennartz, Ryan J. Gilbert
Chemical and Biochemical Engineering Faculty Research & Creative Works
Macrophages are immune cells involved in wound healing and tissue regeneration; however, the sustained presence of proinflammatory macrophages in wound sites impairs healing. In this study, we shifted peritoneal macrophage polarization away from a proinflammatory (M1) phenotype through exposure to stabilized interleukin-4 (IL-4) in poly (lactic-co-glycolic acid) films in combination with topographical guidance from electro spun poly-l-lactic acid fibers. To our knowledge, this was the first study to stabilize IL-4 with bovine serum albumin (BSA) within a biomaterial. When IL-4 was coloaded with BSA for stabilization, we saw increased IL-4 bioactivity compared to no added stabilization, trehalose stabilization, or murine …
Iron-Containing Nanoparticles For The Treatment Of Chrionic Biofilm Infections In Cystic Fibrosis,
2019
University of New Mexico - Main Campus
Iron-Containing Nanoparticles For The Treatment Of Chrionic Biofilm Infections In Cystic Fibrosis, Leisha M. A. Martin
Nanoscience and Microsystems ETDs
Cystic fibrosis (CF) is the most common genetic disease resulting in the morbidity and mortality of Caucasian children and adults worldwide. Due to a genetic mutation resulting in malfunction of the Cystic Fibrosis Transmembrane Conductance Regulator (CFTR) protein, CF patients produce highly viscous mucus in their respiratory tract. This leads to impairment of the mucociliary clearance of inhaled microbes. In addition to reduced microbial clearance, anoxic environmental conditions in the lungs promote biofilm-mode growth of the pathogenic bacterial species Pseudomonas aeruginosa. Chronic infections of P. aeruginosa begin in early childhood and typically persist until respiratory failure and death result. The …
Hydrothermal Synthesis Of Graphene Supported Pd/Fe3o4 Nanoparticles As Efficient Magnetic Catalysts For Suzuki Cross – Coupling,
2019
The British University in Egypt
Hydrothermal Synthesis Of Graphene Supported Pd/Fe3o4 Nanoparticles As Efficient Magnetic Catalysts For Suzuki Cross – Coupling, Hany A. Elazab Dr
Chemical Engineering
This research reports a reproducible, reliable, and efficient method for preparing palladium nanoparticles dispersed on a composite of Fe3O4 and graphene as an active catalyst with high efficiency for being used in Suzuki cross – coupling reactions. Graphene supported Pd/Fe3O4 nanoparticles (Pd/Fe3O4/G) exhibit a remarkable catalytic performance towards Suzuki coupling reactions. Moreover, the prepared catalyst recyclability was up to nine times without losing its high catalytic activity. The catalyst was prepared using hydrothermal synthesis; the prepared catalyst is magnetic in order to facilitate catalyst separation out of the reaction medium after reaction completion simply through using a strong magnet. This …
Surface-Controlled Dissolution Rates: A Case Study Of Nanoceria In Carboxylic Acid Solutions,
2019
University of Kentucky
Surface-Controlled Dissolution Rates: A Case Study Of Nanoceria In Carboxylic Acid Solutions, Eric A. Grulke, Matthew J. Beck, Robert A. Yokel, Jason M. Unrine, Uschi M. Graham, Matthew L. Hancock
Chemical and Materials Engineering Faculty Publications
Nanoparticle dissolution in local milieu can affect their ecotoxicity and therapeutic applications. For example, carboxylic acid release from plant roots can solubilize nanoceria in the rhizosphere, affecting cerium uptake in plants. Nanoparticle dispersions were dialyzed against ten carboxylic acid solutions for up to 30 weeks; the membrane passed cerium-ligand complexes but not nanoceria. Dispersion and solution samples were analyzed for cerium by inductively coupled plasma mass spectrometry (ICP-MS). Particle size and shape distributions were measured by transmission electron microscopy (TEM). Nanoceria dissolved in all carboxylic acid solutions, leading to cascades of progressively smaller nanoparticles and producing soluble products. The dissolution …
Reactions At Noble Metal Contacts With Methylammonium Lead Triiodide Perovskites: Role Of Underpotential Deposition And Electrochemistry,
2019
Princeton University
Reactions At Noble Metal Contacts With Methylammonium Lead Triiodide Perovskites: Role Of Underpotential Deposition And Electrochemistry, Ross A. Kerner, Philip Schulz, Jeffrey A. Christians, Sean P. Dunfield, Benjia Dou, Lianfeng Zhao, Glenn Teeter, Joseph J. Berry, Barry P. Rand
Faculty Publications
Chemical reactivity of halide perovskites coupled with a low energy of formation makes it a challenge to characterize material properties and achieve long-term device stability. In this study, we elucidate electrochemical reactions occurring at the methylammonium lead triiodide (MAPbI3)/Au interface. X-ray photoemission spectroscopy is used to identify a type of reduction/oxidation reaction termed underpotential deposition (UPD) involving lead, iodine, and hydrogen occurring at interfaces with noble metals. Changes in surface compositions and oxidation states suggest that UPD derived adsorbates at MAPbI3/Au interfaces lower the energy barrier for release of volatile HI and/or I2catalyzing degradation …
Biodegradable Polymeric Film For Food Packaging,
2019
Delhi Technological University
Biodegradable Polymeric Film For Food Packaging, Neelam Yadav, Raminder Kaur
Journal of Applied Packaging Research
Food packaging films that show post-consumer biodegradability are rarely explored by researchers. The present study was carried out to investigate the physicomechanical characteristics of ethyl cellulose (EC) based films to be used in food packaging. Ethyl cellulose was plasticized with different percentage of polyethylene glycol (PEG). The samples of standard dimensions were subjected to different testing such as soluble matter content, moisture content, oil permeability, surface morphology, mechanical testing etc. The data obtained was analysed to decide the moderate percentage of plasticizer that can be used to provide a rational explanation of a perfect quality specimen. It has been revealed …
Green Synthesis Nanocomposite Membranes,
2019
University of Kentucky
Green Synthesis Nanocomposite Membranes, Dibakar Bhattacharyya, Vasile Smuleac, Rajender S. Varma, Subhas K. Sikdar
Chemical and Materials Engineering Faculty Patents
A nanocomposite membrane includes a macroporous polymer membrane having a plurality of pores. A plurality of metal nanoparticles are synthesized and immobilized within those plurality of pores. The nanoparticles are reduced and capped with a green reducing and capping agent such as green tea extract.
Molecularly Conductive Behavior Of Blended Polymer Electrolyte-Based Cmc/Pva,
2019
Department of Chemistry, Center for Foundation Studies, International Islamic University Malaysia, 26300 Gambang, Pahang
Molecularly Conductive Behavior Of Blended Polymer Electrolyte-Based Cmc/Pva, Noor Saadiah Mohd Ali, Dishen Zhang, Yuki Nagao, Ahmad Salihin Samsudin
Makara Journal of Technology
This study investigated the electrical conduction and structural behavior of blended polymer electrolyte (BPE)-based carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) in the development of solid-state electrochemical devices. Based on impedance spectroscopy and correlating Fourier transform infrared (FTIR) with thermogravimetric analysis, a framework was proposed to explain the structural enhancement of the BPE system. As revealed by FTIR, the optimum conductivity of CMC/PVA BPEs was 9.21 × 10−6 Scm−1 for 80:20 composition attributed to the intermolecular attraction between the polymers. Thermal stability of the CMC/PVA was influenced by the formation of a hydrogen bond between the hydroxyl (-OH), carboxylate (-COO-), …
Multistage Sonication Effect On The Composition And Properties Of Degraded Chitosan Product,
2019
Department of Mechanical Engineering, Politeknik Negeri Batam, Batam 29461, Indonesia
Multistage Sonication Effect On The Composition And Properties Of Degraded Chitosan Product, Nurul Laili Arifin, Emma Savitri, Anjar Indah, Fesa Putra, Sumarno Sumarno
Makara Journal of Technology
The sonication method randomly breaks polymer chains to produce a varied distribution of products. A scheme with multi-stage sonication steps is proposed to identify oligomers and low molecular weight chitosan based on changes to the degrad-ed product. For each sonication level, 1% (w/v) chitosan in 1% (v/v) aqueous acetic acid was sonicated for 120 min at 60 °C. The products of the sonication treatment were deprotonized by adding an alkali solution, freeze dried and insoluble product re-sonicated until a low molecular weight was produced. Low molecular weight chitosan/insoluble products were character-ized with Fourier-transform infrared spectra (FT-IR) and X-ray diffraction (XRD) …
Study Of Zno Nanospheres Fabricated Via Thermal Evaporation For Solar Cell Application,
2019
Material Technology Programme, Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, Lebuhraya Tun Razak, Gambang 26300, Kuantan, Pahang, Malaysia
Study Of Zno Nanospheres Fabricated Via Thermal Evaporation For Solar Cell Application, Fatin Farisha Alia Azmi, Bouchta Sahraoui, Saifful Kamaluddin Muzakir
Makara Journal of Technology
A solar cell is a device that absorbs light energy to generate electrical energy. A typical example of a solar cell is the quantum dot solar cell (QDSC), which consists of three main components: (i) fluorophore: the component that absorbs light and generates excited state electrons and holes, (ii) photoelectrode: the component that transports the excited state electron and prevents recombination of excited state electrons and holes, and (iii) electrolyte: the component that re-plenishes the vacancy left by the excited electron in the hole. Despite the increasing number of research in the QDSC field, to date, a device with significant …
Electrical Properties Of A Novel Solid Biopolymer Electrolyte Based On Algi-Nate Incorporated With Citric Acid,
2019
Ionic Materials Team, Faculty of Industrial Science & Technology, Universiti Malaysia, Pahang 26300, Kuantan, Pahang, Malaysia
Electrical Properties Of A Novel Solid Biopolymer Electrolyte Based On Algi-Nate Incorporated With Citric Acid, Ahmad Faizrin Ahmad Fuzlin, Noor Syahida Ismail, Yuki Nagao, Ahmad Salihin Samsudin
Makara Journal of Technology
In the present study, a novel solid biopolymer electrolyte (SBE) system is introduced by doping citric acid into alginate polymer. A sample of the alginate-citric acid SBE system was prepared via a solution casting technique. Using electrical impedance spectroscopy (EIS), the electrolytes of alginate-citric acid analyzed from 5 Hz to 1 MHz achieved the highest conductivity at 20 wt.% of 5.49 × 10-7 S cm-1. The temperature dependence of various citric acid amounts obeyed the Arrhenius rule with R2~1, where all SBE systems were thermally activated with increasing temperature. The dielectric studies of the alginate-citric acid SBE system showed non-Debye …
Design And Optimization Of A Microfluidic Device To Study The Effects Of Fluid Shear Stress On Extravasation,
2019
Louisiana State University
Design And Optimization Of A Microfluidic Device To Study The Effects Of Fluid Shear Stress On Extravasation, Joseph B. Balhoff
Honors Capstones
No abstract provided.
Nanoparticle Burst Timing Optimization,
2019
Louisiana State University
Nanoparticle Burst Timing Optimization, Simon Grigoryan
Honors Capstones
No abstract provided.
Microfluidic Generation Of Orthogonal Chemical Gradients To Study Cellular Decision Making During 3d Migration,
2019
Louisiana State University
Microfluidic Generation Of Orthogonal Chemical Gradients To Study Cellular Decision Making During 3d Migration, Joshua M. Campbell
Honors Capstones
No abstract provided.
Hierarchal Control Of Magnetic Metal Oxide Nanoparticles,
2019
Louisiana State University
Hierarchal Control Of Magnetic Metal Oxide Nanoparticles, Hunter Simonson
Honors Capstones
No abstract provided.
Generation Of Silver Nanoparticle Pharmacokinetic Profiles In A Lung Model,
2019
University of Dayton
Generation Of Silver Nanoparticle Pharmacokinetic Profiles In A Lung Model, Rachel Galaska
Honors Theses
Nanomaterial technologies are becoming increasingly prevalent in consumer and industrial applications, including drug delivery, energy harvesting, environmental applications, and medicine due to their unique physiochemical properties. As nanomaterial use increases, so too does human exposure. This has made it progressively more important to understand the toxicological effects of nanomaterials and their interactions with the human body. Silver nanoparticles (AgNPs) are one of the most commonly used nanomaterials due to their antibacterial properties. As inhalation is one of the most common exposure routes, understanding the toxicity of these AgNPs on lung tissue was studied. Using A549 cells for a lung tissue …
