Chemical Engineering Commons^™

Natural Gas Conversion Into Value Added Chemicals Using Solid Acid Catalysts, Swarom Ravindra Kanitkar

LSU Doctoral Dissertations

Direct, non-oxidative conversion of natural gas to value-added chemicals has been identified as one of the grand challenges of the 21^st century. Circumventing indirect and costly reforming steps is highly sought after and solid acids can play an important role in that.

The direct conversion of methane to higher hydrocarbons and hydrogen can be catalyzed using “superacids” at < 450 °C. Reported superacid catalysts in solid, liquid, and gas phase included sulfated zirconia (SZ), HF-SbF₅, FSO₃H-SbF₅, and HBr-AlBr₃. Liquid and gas phase superacids presented difficulties in separation while the solid ones provided low yields. Here, we report a new class of Br-based solid superacids, AlBr_x/H-ZSM-5 (“ABZ-5”, …

Tin Assisted Fully Exposed Platinum Clusters Stabilized On Defect-Rich Graphene For Dehydrogenation Reaction, Jiayun Zhang, Yuchen Deng, Xiangbin Cai, Yunlei Chen, Mi Peng, Zhimin Jia, Zheng Jiang, Pengju Ren, Siyu Yao, Jinglin Xie, Dequan Xiao, Xiao-Dong Wen, Ning Wang, Hongyang Liu, Ding Ma

Chemistry and Chemical Engineering Faculty Publications

Tin assisted fully exposed Pt clusters are fabricated on the core-shell nanodiamond@graphene (ND@G) hybrid support (a-PtSn/ND@G). The obtained atomically dispersed Pt clusters, with an average Pt atom number of 3, were anchored over the ND@Gsupport by the assistance of Sn atoms as a partition agent and through the Pt-C bond between Pt clusters and defect-rich graphene nanoshell. The atomically dispersed Pt clusters guaranteed a full metal availability to the reactants, a high thermal stability, and an optimized adsorption/desorption behavior. It inhibits the side reactions and enhances catalytic performance in direct dehydrogenation of n-butane at a low temperature of 450 °C, …

Design Of A Portable Biogas Purification And Storage System, Anikumar Kosna, Bade Shrestha

Faculty Research and Creative Activities Award (FRACAA)

The objective of this study is to propose and design a commercial portable purification and storage system to commercialize biogas (which mainly consists of 45 - 75 % of methane and 15 - 16% of carbon dioxide), produced from household/non-commercial biogas plants. The selection of purification process is based on the portability of the purification system.

Photocatalytic Degradation Of Profenofos And Triazophos Residues In The Chinese Cabbage, Brassica Chinensis, Using Ce-Doped Tio2, Xiangying Liu, You Zhan, Zhongqin Zhang, Lang Pan, Lifeng Hui, Kailin Liu, Xuguo Zhou, Lianyang Bai

Entomology Faculty Publications

Pesticides have revolutionized the modern day of agriculture and substantially reduced crop losses. Synthetic pesticides pose a potential risk to the ecosystem and to the non-target organisms due to their persistency and bioaccumulation in the environment. In recent years, a light-mediated advanced oxidation processes (AOPs) has been adopted to resolve pesticide residue issues in the field. Among the current available semiconductors, titanium dioxide (TiO₂) is one of the most promising photocatalysts. In this study, we investigated the photocatalytic degradation of profenofos and triazophos residues in Chinese cabbage, Brassica chinensis, using a Cerium-doped nano semiconductor TiO₂ (TiO …

Bio-Based Thiol-Ene Polymer Electrolytes, Elyse Antonia Baroncini

Theses and Dissertations

Industrial and consumer demand for smaller and safer technologies motivates a global research effort to improve electrolytic polymer separators in lithium-ion batteries (LIBs). To incorporate the aromatic structural advantages of lignin, an abundant and renewable resource, into polymer electrolytes, molecules that can be derived from lignin are functionalized and UV-polymerized with multifunctional thiol monomers. Monomer aromaticity, thiol molecular weight, and total functionality are varied, allowing for analysis of the relationships between polymer structure and electrochemical properties.

The synthesized polymers display conductivities on the order of 10^-5 S/cm for gel polymer electrolytes and 10^-4 S/cm for solid polymer electrolytes, comparable to …

Scaling Film Cooling Adiabatic Effectiveness With Mass Transfer And Thermal Experimental Techniques, Luke J. Mcnamara

Theses and Dissertations

With increasing engine temperatures, it is becoming more important to design effective film cooling schemes. Low temperature, large scale tests are often implemented in the design process to reduce cost and complexity. A nondimensional adiabatic effectiveness can be used as an indication of the performance of a film cooling scheme. However, the coolant flow rate must be properly scaled between the low temperature tests and engine temperatures to accurately predict film cooling effectiveness. This process is complicated by gas property variation with temperature. Tests are commonly conducted using thermal measurement techniques with infrared thermography (IR), but the use of pressure …

Tactical Missile Performance For Single And Multi-Wire Embedded Propellant Configurations With Discontinuities, Paul B. Wilson

Theses and Dissertations

This research analyzes the performance of a nominal air-to-air tactical missile with varying configurations of wire-embedded end-burning solid propellant grains. Single and multi-wire models are developed to determine if total impulse and range is improved. Discontinuities in the wires are simulated to determine if gaps in the wire will affect overall performance. Five wire materials, seven wire diameters, and nine different break locations are tested. This research demonstrates wire discontinuities have negligible impact on performance and carbon nanotube fibers can theoretically improve total impulse by up to 25% compared to radially burning boost-phase grains while providing similar thrust outputs.

Examination Of Flow Dynamics And Passive Cooling In An Ultra Compact Combustor, Tylor C. Rathsack

Theses and Dissertations

The Ultra Compact Combustor (UCC) promises to greatly reduce the size of a gas turbine engine’s combustor by altering the manner in which fuel is burnt. Differing from the common axial flow combustor, the UCC utilizes a rotating flow, coaxial to the engine’s primary axis, in an outboard circumferential cavity as the primary combustion zone. The present study investigates two key UCC facets required to further this combustor design. The first area of investigation is cooling of the Hybrid Guide Vane (HGV). This UCC specific hardware acts as a combustor center body that alters the exit flow angle and acts …

3d Printed Zeolite Monoliths For Co₂ Removal, Fateme Rezaei, Harshul V. Thakkar

Chemical and Biochemical Engineering Faculty Research & Creative Works

Carbon dioxide (CO₂) capture materials comprising one or more 3D-printed zeolite monoliths for the capture and or removal of CO₂ from air or gases in enclosed compartments, including gases or mixtures of gases having less than about 5% CO₂. Methods for preparing 3D-printed zeolite monoliths useful as CO₂ capture materials and filters, as well as methods of removing CO₂ from a gas or mixture of gases in an enclosed compartment using 3D-printed zeolite monoliths are provided.

Introducing Concept Maps In Undergraduate Thermodynamics, Jessie Lofton

ASEE IL-IN Section Conference

Concept maps, also called mind maps, are a widely utilized educational tool. While numerous studies cite the benefits of concept mapping as a tool for student learning, the use of concept maps is more common in non-engineering disciplines. This study examines student perceptions and academic performance in an undergraduate, introductory Thermodynamics course for students majoring in Mechanical Engineering. The pedagogical approach includes incorporating student-developed concept maps, as well as an interactive study tool for First Law analysis. Qualitative and quantitative results are presented. Results are limited to a single institution and a small sample size of students. Future work will …

Theoretical Investigation Of The Ring Opening Of Cyclohexane On Ir(111) And Pt(111), Kushal Ghale

LSU Master's Theses

Diesel engines have higher fuel efficiency and can burn cleaner than gasoline engines. To enhance quality of diesel fuels as measured by the cetane number (CN), the removal of aromatic compounds is necessary. A potentially highly efficient approach would be to convert aromatics to saturated cycloparaffin, followed by selective ring opening to linear or branched alkanes, to increase the CN. Here the focus of the project is to study the mechanism of metal-catalyzed ring opening (RO) of cyclohexane (denoted CHA, or c-C₆H₁₂) through theoretical and computational modeling. CHA, a simplest cycloparaffin, is used as probe molecule …

String Out And Compressibility Effect On Pressure Rise In A Shut-In Well, Nicholas Henry

LSU Master's Theses

Gas kick migration experiments were performed in a small-scale well prototype model of annular geometry to analyze the behavior of gas kicks in highly non-Newtonian fluids. The objective was to isolate and estimate the effects system compressibility and bubble string out have on the pressure build up in a situation in which a gas kick rises through a noncirculating drilling mud in a vertical well.

The experiments consisted of 2 tests. The first test measured the apparent compressibility of the liquid phase of the experiment – that phase which simulated the drilling mud in a gas kick situation. The second …

A Comprehensive Techno-Economic Framework For Shale Gas Exploitation And Distribution In The United States, Jorge Asis Charbel Chebeir

LSU Doctoral Dissertations

Over the past years, shale gas has turned into one of the most significant sources of energy in the United States. Technological advancements have provided the energy industry with the necessary tools to allow the economic exploitation of an enormous volume of natural gas trapped in shale formations. This has boosted the domestic gas production and generated a boom in other sectors of the economy in the country. However, major challenges are involved in the development of shale gas resources. A drastic decline of wells’ productivity, the costs involved in the gas production and distribution facets, and the volatile behavior …

Fischer–Tropsch: Product Selectivity–The Fingerprint Of Synthetic Fuels, Wilson D. Shafer, Muthu Kumaran Gnanamani, Uschi M. Graham, Jia Yang, Cornelius M. Masuku, Gary Jacobs, Burtron H. Davis

Center for Applied Energy Research Faculty and Staff Publications

The bulk of the products that were synthesized from Fischer–Tropsch synthesis (FTS) is a wide range (C₁–C₇₀₊) of hydrocarbons, primarily straight-chained paraffins. Additional hydrocarbon products, which can also be a majority, are linear olefins, specifically: 1-olefin, trans-2-olefin, and cis-2-olefin. Minor hydrocarbon products can include isomerized hydrocarbons, predominantly methyl-branched paraffin, cyclic hydrocarbons mainly derived from high-temperature FTS and internal olefins. Combined, these products provide 80–95% of the total products (excluding CO₂) generated from syngas. A vast number of different oxygenated species, such as aldehydes, ketones, acids, and alcohols, are also embedded in this product range. …

Material And Regenerative Properties Of An Osteon-Mimetic Cortical Bone-Like Scaffold, Danial Barati, Ozan Karaman, Seyedsina Moeinzadeh, Safaa Kader, Esmaiel Jabbari

Faculty Publications

The objective of this work was to fabricate a rigid, resorbable and osteoconductive scaffold by mimicking the hierarchical structure of the cortical bone. Aligned peptide-functionalize nanofiber microsheets were generated with calcium phosphate (CaP) content similar to that of the natural cortical bone. Next, the CaP-rich fibrous microsheets were wrapped around a microneedle to form a laminated microtube mimicking the structure of an osteon. Then, a set of the osteon-mimetic microtubes were assembled around a solid rod and the assembly was annealed to fuse the microtubes and form a shell. Next, an array of circular microholes were drilled on the outer …

Exergetic Relationship Between The Thermal Properties Of Direct Contact Membrane Distillation, D. Perdue, L. Chen, L. Schaefer

Publications

Direct contact membrane distillation (DCMD) is a process that has shown promise within the field of desalination due to its less energy intensive methods and widespread applications. DCMD is a thermally driven microfiltration separation process that operates on the principle of vapor–liquid equilibrium conditions where heat and mass transfer occur simultaneously. Fundamentally, DCMD is based on a porous hydrophobic membrane separating the hot solution (feed) from the cold solution (permeate) where desalinated water condenses. The membrane interfacial temperatures determine the vapor pressure difference across the membrane. In this work, a direct simulation Monte Carlo analysis is employed to investigate how …

Use Of Penetrating Asphalt Emulsions To Address High-Void Pavement Areas, Andrew Eicher, Curt Higginbotham

Purdue Road School

Longitudinal joints are high in air voids due to compaction limitations. Lowering the void content of these areas improves the durability of the pavement. Project data indicate that rapid penetrating emulsion (RPE) fills the voids beneath the surface of the pavement, reducing air and water intrusion while maintaining surface texture, whereas traditional emulsions seal the surface only. Lab tests have been developed to quantify the penetrating ability of an emulsion and resistance to water exposure. Join us for a discussion.

Controlled Anchoring Of Iron Oxide Nanoparticles On Polymeric Nanofibers: Easy Access To Core@Shell Organic-Inorganic Nanocomposites For Magneto-Scaffolds, Hussein Awada, Assala Al Samad, Danielle Laurencin, Ryan Gilbert, Xavier Dumail, Ayman El Jundi, Audrey Bethry, Rebecca Pomrenke, Christopher Johnson, Laurent Lemaire, Florence Franconi, Gautier Félix, Joulia Larionova, Yannick Guari, Benjamin Nottelet

Chemical and Biochemical Engineering Faculty Research & Creative Works

Composites combining superparamagnetic iron oxide nanoparticles (SPIONs) and polymers are largely present in modern (bio)materials. However, although SPIONs embedded in polymer matrices are classically reported, the mechanical and degradation properties of the polymer scaffold are impacted by the SPIONs. Therefore, the controlled anchoring of SPIONs onto polymer surfaces is still a major challenge. Herein, we propose an efficient strategy for the direct and uniform anchoring of SPIONs on the surface of functionalized-polylactide (PLA) nanofibers via a simple free ligand exchange procedure to design PLA@SPIONs core@shell nanocomposites. The resulting PLA@SPIONs hybrid biomaterials are characterized by electron microscopy (scanning electron microscopy and …

Improving The Distribution And Use Of Biogas By Conversion To Methanol, Zachary Christman

Department of Agronomy and Horticulture: Dissertations, Theses, and Student Research

In this technology review, the process of turning an average biogas into methanol will be presented. The purpose is to find a better method of transporting the energy contained within biogas so that it may be used in industry as a value added product. The first step is removal of hydrogen sulfide, a corrosive chemical that can breakdown mechanical parts. The second step is carbon capture and conversion of the biogas into hydrogen. The final step is the hydrogenation of carbon dioxide into methanol using a copper catalyst and an alcohol co-catalyst.

Urea Functionalization Of Ultrasound-Treated Biochar: A Feasible Strategy For Enhancing Heavy Metal Adsorption Capacity, Baharak Sajjadi, James William Broome, Wei Yin Chen, Daniell L. Mattern, Nosa O. Egiebor, Nathan Hammer, Cameron L. Smith

Faculty and Student Publications

© 2018 Elsevier B.V. The main objective of a series of our researches is to develop a novel acoustic-based method for activation of biochar. This study investigates the capability of biochar in adsorbing Ni(II) as a hazardous contaminant and aims at enhancing its adsorption capacity by the addition of extra nitrogen and most probably phosphorous and oxygen containing sites using an ultrasono-chemical modification mechanism. To reach this objective, biochar physically modified by low-frequency ultrasound waves (USB) was chemically treated by phosphoric acid (H3PO4) and then functionalized by urea (CO(NH2)2). Cavitation induced by ultrasound waves exfoliates and breaks apart the regular …