Prototype Catalytic Membrane Reactor For Dimethyl Ether Synthesis Via Co2hydrogenation,
2022
Missouri University of Science and Technology
Prototype Catalytic Membrane Reactor For Dimethyl Ether Synthesis Via Co2hydrogenation, Qiaobei Dong, Weiwei L. Xu, Xiao Fan, Huazheng Li, Naomi Klinghoffer, Travis Pyrzynski, Howard S. Meyer, Xinhua Liang, Miao Yu, Shiguang Li
Chemical and Biochemical Engineering Faculty Research & Creative Works
Dimethyl ether (DME) has become attractive as a potential environmentally friendly substitute for diesel and liquefied petroleum gas (LPG) due to its similar properties to those of LPG, high cetane number, but less carbon emissions. In this work, we developed a novel prototype-scale catalytic membrane reactor to synthesize DME directly from CO2and renewable H2, which could address the environmental and fuel security issues in a cost-effective way. This membrane reactor was equipped with superior hydrophilic NaA zeolite membranes and bifunctional Cu-ZnO-ZrO2-Al2O3/HZSM-5 catalysts. The effects of the reaction temperature and gas …
Reduced Building Energy Consumption By Combined Indoor Co2 And H2o Composition Control,
2022
Missouri University of Science and Technology
Reduced Building Energy Consumption By Combined Indoor Co2 And H2o Composition Control, Anshuman Sinha, Harshul Thakkar, Fateme Rezaei, Yoshiaki Kawajiri, Matthew J. Realff
Chemical and Biochemical Engineering Faculty Research & Creative Works
Rapid growth in global energy consumption has raised concern on the environmental impacts such as ozone layer depletion and climate change. Enclosed space, such as commercial buildings, accounts for about 40% of global energy consumption and the demand is constantly increasing due to increasing population, urbanization, and economic development. The energy demands in the building sector calls for strategic measures to develop energy efficient technologies. This paper presents a strategy to decrease energy demands inside buildings by proposing a ventilation system which regulates the enclosed air quality resulting in reduced air conditioning. The system consists of multiple adsorption beds with …
Atomic Layer Deposited Pt/Tio2-Sio2 And Pt/Zro2-Sio2 For Sequential Adsorption And Oxidation Of Vocs,
2022
Missouri University of Science and Technology
Atomic Layer Deposited Pt/Tio2-Sio2 And Pt/Zro2-Sio2 For Sequential Adsorption And Oxidation Of Vocs, Busuyi O. Adebayo, Han Yu, Ali A. Rownaghi, Xinhua Liang, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
In this work, Pt nanoparticles were loaded on SiO2, TiO2-thin-film-modified SiO2 (TiO2-SiO2), or ZrO2-thin-film-modified SiO2 (ZrO2-SiO2) particles and the composites were investigated for sequential adsorption and desorption/catalytic oxidation of benzene. The SiO2 was prepared via sol–gel method, while TiO2-SiO2 and ZrO2-SiO2 were synthesized via atomic layer deposition (ALD) thin film coating of TiO2 or ZrO2 on SiO2 particles substrate. In the sequential capture-reaction tests, the materials were first exposed to ca. 500 ppmv benzene …
Ionic Liquid Pilocarpine Analog As An Antiglaucoma Drug Candidate,
2022
Missouri University of Science and Technology
Ionic Liquid Pilocarpine Analog As An Antiglaucoma Drug Candidate, Juan Wang, Boxuan Li, Jing Tang, Li Qiu, Xin Qiao, Na Xu, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Ionic liquid pilocarpine analog [Pilo-OEG]Cl, the first-of-its-kind ionic liquid antiglaucoma drug candidate, is synthesized and reported. To synthesize [Pilo-OEG]Cl, pilocarpine was reacted with the oligo-polyethylene glycol chloride, 2-[2-(2-chloroethoxy)ethoxy] ethanol, to form an ionic liquid molecule with an imidazole cation and a chloride anion. The chemical structure of [Pilo-OEG]Cl was confirmed with 1H NMR spectroscopy. Compared with pilocarpine (Pilo) and pilocarpine hydrochloride (PiloHCl), [Pilo-OEG]Cl has improved structural stability according to pH measurements and LC-MS analysis. The corneal permeability coefficient of [Pilo-OEG]Cl is 2-fold higher than that of Pilo and 8-fold higher than that of PiloHCl. [Pilo-OEG]Cl does not show apparent toxicity …
Estimating Flashpoints Of Fuels And Chemical Compounds Using Hybrid Machine-Learning Techniques,
2022
Missouri University of Science and Technology
Estimating Flashpoints Of Fuels And Chemical Compounds Using Hybrid Machine-Learning Techniques, Farid Amirkhani, Amir Dashti, Hossein Abedsoltan, Amir H. Mohammadi, Abdoulmohammad Gholamzadeh Chofreh, Feybi Ariani Goni, Jiří Jaromír Klemeš
Chemical and Biochemical Engineering Faculty Research & Creative Works
Flashpoint of organic materials is a crucial physical property in industrial applications and laboratory experiments, which provides information on safety standards and needed precautions in handling various organic materials. Proposed methods to determine the flashpoint of an organic material suffer from dependency on other physical properties of the chemical or demand complicated calculations which are time-consuming. In this work, a direct system model is proposed to anticipate the flashpoints of organic materials for a wide range of chemical compounds. The following models of genetic algorithm-adaptive neuro-fuzzy inference system, the least-squares version of the support vector machine, particle swarm optimization-adaptive neuro-fuzzy …
Nonordered Dendritic Mesoporous Silica Nanoparticles As Promising Platforms For Advanced Methods Of Diagnosis And Therapies,
2022
University of Manchester
Nonordered Dendritic Mesoporous Silica Nanoparticles As Promising Platforms For Advanced Methods Of Diagnosis And Therapies, S. Malekmohammadi, Riaz Ur Rehman Mohammed, H. Samadian, A. Zarebkohan, A. García-Fernández, G. R. Kokil, F. Sharifi, J. Esmaeili, M. Bhia, M. Razavi, M. Bodaghi, T. Kumeria, R. Martínez-Máñez
Department of Chemical and Biomolecular Engineering: Faculty Publications
Dendritic mesoporous silica nanoparticles (DMSNs) are a new generation of porous materials that have gained great attention compared to other mesoporous silicas due to attractive properties, including straightforward synthesis methods, modular surface chemistry, high surface area, tunable pore size, chemical inertness, particle size distribution, excellent biocompatibility, biodegradability, and high pore volume compared with conventional mesoporous materials. The last years have witnessed a blooming growth of the extensive utilization of DMSNs as an efficient platform in a broad spectrum of biomedical and industrial applications, such as catalysis, energy harvesting, biosensing, drug/gene delivery, imaging, theranostics, and tissue engineering. DMSNs are considered great …
Advances In Energy Hybridization For Resilient Supply: A Sustainable Approach To The Growing World Demand,
2022
Missouri University of Science and Technology
Advances In Energy Hybridization For Resilient Supply: A Sustainable Approach To The Growing World Demand, Haider Al-Rubaye, Joseph D. Smith, Mohammed H.S. Zangana, Prashant Nagapurkar, Yishu Zhou, Gregory M. Gelles
Chemical and Biochemical Engineering Faculty Research & Creative Works
Energy poverty, defined as a lack of access to reliable electricity and reliance on traditional biomass resources for cooking, affects over a billion people daily. The World Health Organization estimates that household air pollution from inefficient stoves causes more premature deaths than malaria, tuberculosis, and HIV/AIDS. Increasing demand for energy has led to dramatic increases in emissions. The need for reliable electricity and limiting emissions drives research on Resilient Hybrid Energy Systems (RHESs), which provide cleaner energy through combining wind, solar, and biomass energy with traditional fossil energy, increasing production efficiency and reliability and reducing generating costs and emissions. Microgrids …
Quantifying The Workability Of Calcium Sulfoaluminate Cement Paste Using Time-Dependent Rheology,
2022
Missouri University of Science and Technology
Quantifying The Workability Of Calcium Sulfoaluminate Cement Paste Using Time-Dependent Rheology, Sukanta K. Mondal, Adam Welz, Carrie Clinton, Kamal Khayat, Aditya Kumar, Monday Uchenna Okoronkwo
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Poor workability is a common feature of calcium sulfoaluminate (CSA) cement paste. Multiple chemical admixtures, such as set retarders and dispersants, are frequently employed to improve the workability and delay the setting of CSA cement paste. A quantitative assessment of the compatibility, efficiency, and the effects of the admixtures on cement paste workability is critical for the design of an appropriate paste formulation and admixture proportioning. Very limited studies are available on the quantitative rheology-based method for evaluating the workability of calcium sulfoaluminate cement pastes. This study presents a novel and robust time-dependent rheological method for quantifying the workability of …
High-Performance Catalytic Four-Channel Hollow Fibers With Highly Dispersed Nickel Nanoparticles Prepared By Atomic Layer Deposition For Dry Reforming Of Methane,
2022
Missouri University of Science and Technology
High-Performance Catalytic Four-Channel Hollow Fibers With Highly Dispersed Nickel Nanoparticles Prepared By Atomic Layer Deposition For Dry Reforming Of Methane, Baitang Jin, Shiguang Li, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Highly dispersed nickel (Ni) nanoparticles (NPs) with an average particle size of 4.3 nm were uniformly deposited on the outer surface, the inner channel surface, and inside the pores of 20 cm long four-channel α-Al2O3hollow fibers (HFs) by atomic layer deposition (ALD) for dry reforming of methane (DRM). Cerium oxide (CeO2) was added to promote the catalytic performance of Ni/Al2O3-HF catalysts. Rationally designed filling methods, by tuning the reactor size and inert fillings, can reduce the catalyst bed voidage in a fixed bed reactor for better reactant gas distribution, effectively …
Impact Of Ultrathin Coating Layer On Lithium-Ion Intercalation Into Particles For Lithium-Ion Batteries,
2022
Missouri University of Science and Technology
Impact Of Ultrathin Coating Layer On Lithium-Ion Intercalation Into Particles For Lithium-Ion Batteries, Yufang He, Hiep Pham, Xinhua Liang, Jonghyun Park
Chemical and Biochemical Engineering Faculty Research & Creative Works
Ultrathin film coatings on battery materials via atomic layer deposition (ALD) have been demonstrated as an efficient technology for battery performance enhancement. However, the fundamental understanding on lithium intercalation into active materials through the interface between the coating and active materials is unclear, which makes it difficult to optimize ALD coating strategies. Further, like most active materials, a coating layer can undergo volume change during the intercalation process, which can produce detrimental structural changes and mechanical failure of the layer. In this work, first-principles calculations are conducted to reveal the behavior of a coating layer on an active material particle …
Aryl Sulfonic Acid Catalysts: Effect Of Pendant Group Structure On Activity In Hydrolysis Of Polyethylene Terephthalate,
2022
Missouri University of Science and Technology
Aryl Sulfonic Acid Catalysts: Effect Of Pendant Group Structure On Activity In Hydrolysis Of Polyethylene Terephthalate, Hossein Abedsoltan, Maria R. Coleman
Chemical and Biochemical Engineering Faculty Research & Creative Works
A series of aryl sulfonic acids were tested as catalysts for acid hydrolysis occurring at the surface of poly(ethylene) terephthalate (PET) particles. Specifically, p-toluene sulfonic acid monohydrate (PTSA), 2-naphthalenesulfonic acid (2-NSA), and 1,5-naphthalenedisulfonic acid tetrahydrate (1,5-NDSA) were chosen to provide sulfonic acid active groups and varying hydrophobic functionality. The effect of catalyst concentration and reaction temperature on PET hydrolysis rate was studied. The aryl sulfonic acid catalysts exhibited much higher rates of PET hydrolysis than the mineral acid, H2SO4. At 150°C and 4 M catalyst, the time required to achieve more than 90% TPA yield was …
Analysis Of Sequential Adsorption-Oxidation Of Vocs On Atomic Layer-Deposited Ptni/Zro2-Sio2dual-Function Materials,
2022
Missouri University of Science and Technology
Analysis Of Sequential Adsorption-Oxidation Of Vocs On Atomic Layer-Deposited Ptni/Zro2-Sio2dual-Function Materials, Busuyi O. Adebayo, Han Yu, Ali A. Rownaghi, Xinhua Liang, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
To develop efficient dual-function materials (DFMs) for capture and destruction of volatile organic compounds (VOCs), we prepared a series of composite materials comprising PtNi nanoparticles supported on ZrO2-promoted SiO2(PtNi/ZrO2-SiO2) via atomic layer deposition (ALD) method and investigated them for sequential adsorption and desorption/catalytic oxidation of benzene, as a model VOC compound. ZrO2was first deposited on a unimodal SiO2support, followed by deposition of Pt and Ni nanoparticles with varried amount. Dynamic adsorption experiments were conducted using a 500 ppmv-laden feed at 25 °C and 1 atm, followed by in …
Scale Up Of A Novel Method To Maximize Malonyl-Coa In Escherichia Coli,
2022
Louisiana State University and Agricultural and Mechanical College
Scale Up Of A Novel Method To Maximize Malonyl-Coa In Escherichia Coli, Clifford Harris Leblanc Iv
LSU Master's Theses
The instability of oil’s price along with its limited availability and impact on the environment motivate the search for an alternative feedstock that can sustain the profitability of chemical companies. Industrial biotechnology can promote renewable sources of energy and products by using microorganisms to produce a wide range of chemical compounds. The three-carbon metabolite, malonyl-CoA, can serve as a precursor to a variety of industrial chemicals. The major hurdle with using malonyl-CoA in industry is that its intracellular concentration in Escherichia Coli is very low. Previous attempts to increase the intracellular level of malonyl-CoA have ranged from genetic engineering of …
Experimentation And Correlation Development Of Mass Transfer In A Mimicked Fischer–Tropsch Slurry Bubble Column Reactor,
2022
Missouri University of Science and Technology
Experimentation And Correlation Development Of Mass Transfer In A Mimicked Fischer–Tropsch Slurry Bubble Column Reactor, Lu Han, Mahmoud M. Taha, Premkumar Kamalanathan, Nora Y. Selem, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Gas–liquid volumetric mass transfer coefficient "kLa " for CH4, CO2, and Ar were experimentally measured at different conditions in a mimicked Fischer–Tropsch (FT) slurry bubble column reactor by using a non-invasive gaseous tracer technique and the axial dispersion model. Results validate the square root relation, between kLa and diffusivity "Dg", that can be used to predict kLa for different species with k La values available in the literature. Additionally, Higbie's penetration theory was adopted along with bubble dynamics parameters estimation to develop a correlation for predicting kL …
Effect Of Arginine And Nano-Hydroxyapatite Application On The Hypersensitivity And Color Change Of Bleached Enamel: A Randomized Controlled Clinical Trial,
2022
Missouri University of Science and Technology
Effect Of Arginine And Nano-Hydroxyapatite Application On The Hypersensitivity And Color Change Of Bleached Enamel: A Randomized Controlled Clinical Trial, Lamiaa M. Moharam, Sherif Khadr, Ahmed Abdou, Shaymaa M. Nagi
Chemical and Biochemical Engineering Faculty Research & Creative Works
Background: To evaluate the effect of 2.5% Arginine and nano-hydroxyapatite (nHA) application on the post-bleaching hypersensitivity (HS) and color change in a randomized controlled trial. Material and Methods: Sixty-four participants were randomly allocated to four groups (n=16) according to the investigated desensitizing agents (UltraEZ gel, experimental 2.5% Arginine, 2.5% nHA pastes and control (no treatment) groups). An in-office chemical bleaching agent (40% hydrogen peroxide) was used for vital bleaching of the anterior teeth. The desensitizing agents were applied to the assigned groups and left for 30 min then rinsed off the teeth. HS was evaluated using Visual Analogue Scale (VAS) …
Porcine Liver Injury Model To Assess Tantalum-Containing Bioactive Glass Powders For Hemostasis,
2022
Missouri University of Science and Technology
Porcine Liver Injury Model To Assess Tantalum-Containing Bioactive Glass Powders For Hemostasis, Malvika Nagrath, Danielle Bince, Corwyn Rowsell, Deanna Polintan, Joao Rezende-Neto, Mark R. Towler
Chemical and Biochemical Engineering Faculty Research & Creative Works
This study evaluates compositions of tantalum-containing mesoporous bioactive glass (Ta-MBG) powders using a porcine fatal liver injury model. The powders based on (80-x)SiO2-15CaO-5P2O5-xTa2O5 compositions with x = 0 (0Ta/Ta-free), 1 (1Ta), and 5 (5Ta) mol% were made using a sol–gel process. A class IV hemorrhage condition was simulated on the animals; hemodynamic data and biochemical analysis confirmed the life-threatening condition. Ta-MBGs were able to stop the bleeding within 10 min of their application while the bleeds in the absence of any intervention or in the presence of a commercial agent, AristaTM …
Engineering Metal-Oxide Interface By Depositing Zro2 Overcoating On Ni/Al2o3 For Dry Reforming Of Methane,
2022
Missouri University of Science and Technology
Engineering Metal-Oxide Interface By Depositing Zro2 Overcoating On Ni/Al2o3 For Dry Reforming Of Methane, Baitang Jin, Shiguang Li, Yuzi Liu, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Zirconium oxide (ZrO2) was deposited onto Ni/Al2O3 catalyst as overcoating by atomic layer deposition (ALD) for dry reforming of methane (DRM). High-temperature heating during H2-reduction could transform the ALD-prepared ZrO2 thin film to tetragonal phase and crack the encapsulating layer on Ni sites, which constructed a beneficial Ni-ZrOx interface. Interfacial surface oxygen vacancies on ZrO2 overcoating were induced by the partial reduction of ZrO2 surface during high-temperature H2 reduction, with the assistance of Ni. During DRM, the interfacial oxygen vacancies enhanced CO2 activation by dissociating CO2 …
Study Of Gas Holdup Distribution In Cylindrical Split Airlift Reactor By Using Gamma-Ray Densitometry (Grd),
2022
Missouri University of Science and Technology
Study Of Gas Holdup Distribution In Cylindrical Split Airlift Reactor By Using Gamma-Ray Densitometry (Grd), Abbas J. Sultan, Laith S. Sabri, Hasan Shakir Majdi, Shadha K. Jebur, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
The local gas holdup details and behaviors in the cylindrical split airlift column by using an unconventional gamma-ray densitometry (GRD) measurement in non-invasive manner technique was investigated for the first time in this work for such kind of airlift column. With different gas velocities, 1, 2, and 3 cm/s, at three various axial planes (different levels) in z = 3, 60, and 110 cm were studied for local distribution in radial gas holdup profiles. The distribution in gas–liquid phases (air-water system) in the entire split reactor column, in the rising and descending sides, including their behavior in the upper and …
Process Evaluation And Kinetic Analysis Of 3d-Printed Monoliths Comprised Of Cao And Cr/H-Zsm-5 In Combined Co2 Capture-C2h6 Oxidative Dehydrogenation To C2h4,
2022
Missouri University of Science and Technology
Process Evaluation And Kinetic Analysis Of 3d-Printed Monoliths Comprised Of Cao And Cr/H-Zsm-5 In Combined Co2 Capture-C2h6 Oxidative Dehydrogenation To C2h4, Khaled Baamran, Shane Lawson, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
In this study, dual-function materials (DFMs) comprised of CaO and Cr/H-ZSM-5 were formulated in 3D-printed monolithic structures and investigated in a combined process for capture and utilization of CO2 in oxidative dehydrogenation of C2H6 to C2H4 (CO2-ODHE). Various formulation strategies were employed to fabricate these DFM structures. Two bed designs were considered: i) a layered-bed in which adsorbent (CaO) and catalyst were printed separately and stacked on top of each other, and ii) a single-layer bed where the adsorbent-catalyst materials were 3D-printed into a singular monolith and loaded into the bed …
Integration Of Dynamic Growth Modeling And Hydrodynamics In An Internal-Loop Split Photobioreactor,
2022
Missouri University of Science and Technology
Integration Of Dynamic Growth Modeling And Hydrodynamics In An Internal-Loop Split Photobioreactor, Laith S. Sabri, Aastha Ojha, Abbas J. Sultan, Muthanna H. Aldahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
In this study, new high-quality experimental data for culturing green microalgae Scenedesmus in tubular and cylindrical split airlift photobioreactors were obtained under different operating conditions. The obtained experimental data of culturing microalgae Scenedesmus in a tubular photobioreactor were used for determining the kinetic parameters of the photosynthetic reaction. On the other hand, the culturing of green microalgae in a split airlift photobioreactor was used to measure the microalgae cell trajectory using an advanced radioactive particle tracking (RPT) technique. The obtained results in terms of kinetic parameters of the photosynthetic reaction and microalgae cell trajectory were integrated for the first time …
