Condensed Matter Physics Commons^™

Engineering Room-Temperature Superconductors Via Ab-Initio Calculations, Mamikon Gulian, Gurgen Melkonyan, Armen Gulian

Mathematics, Physics, and Computer Science Faculty Articles and Research

The BCS, or bosonic model of superconductivity, as Little and Ginzburg have first argued, can bring in superconductivity at room temperatures in the case of high-enough frequency of bosonic mode. It was further elucidated by Kirzhnits et al., that the condition for existence of high-temperature superconductivity is closely related to negative values of the real part of the dielectric function at finite values of the reciprocal lattice vectors. In view of these findings, the task is to calculate the dielectric function for real materials. Then the poles of this function will indicate the existence of bosonic excitations which can …

Current-Biased Transition-Edge Sensors Based On Re-Entrant Superconductors, Armen Gulian, Vahan Nikoghosyan, Jeff Tollaksen, V. Vardanyan, A. Kuzanyan

Mathematics, Physics, and Computer Science Faculty Articles and Research

Transition-edge sensors are widely recognized as one of the most sensitive tools for the photon and particles detection in many areas, from astrophysics to quantum computing. Their application became practical after understanding that rather than being biased in a constant current mode, they should be biased in a constant voltage mode. Despite the methods of voltage biasing of these sensors are well developed since then, generally the current biasing is more convenient for superconducting circuits. Thus transition-edge sensors designed inherently to operate in the current-biased mode are desirable. We developed a design for such detectors based on re-entrant superconductivity. In …

Prospective Solid-State Photonic Cryocooler Based On The “Phonon-Deficit Effect”, Gurgen Melkonyan, Armen Gulian

Mathematics, Physics, and Computer Science Faculty Articles and Research

In this design microwave photons are propagating in a sapphire rod, and are being absorbed by a superconductor deposited on the surface of the rod. The frequency of the radiation is tuned to be less than the energy gap in the superconductor, so that the pair breaking is not taking place. This photon pumping redistributes the electron-hole quasiparticles: their distribution function is non-equilibrium, and the “phonon-deficit effect” takes place. There is a dielectric material deposited on top of superconductor, which serves asthe “cold finger” of the cooler. Its “acoustical density” is supposed to be smaller than that of the superconducting …

Nanomechanics Of Flexoelectric Switching, J. Očenášek, Haidong Lu, C. W. Bark, Chang-Beom Eom, J. Alcalá, G. Catalan, Alexei Gruverman

Materials Research Science and Engineering Center: Faculty Publications

We examine the phenomenon of flexoelectric switching of polarization in ultrathin films of barium titanate induced by a tip of an atomic force microscope (AFM). The spatial distribution of the tip-induced flexoelectricity is computationally modeled both for perpendicular mechanical load (point measurements) and for sliding load (scanning measurements), and compared with experiments. We find that (i) perpendicular load does not lead to stable ferroelectric switching in contrast to the load applied in the sliding contact load regime, due to nontrivial differences between the strain distributions in both regimes: ferroelectric switching for the perpendicular load mode is impaired by a strain …

Retrieving Spin Textures On Curved Magnetic Thin Films With Full-Field Soft X-Ray Microscopies, Robert Streubel, Florian Kronast, Peter Fischer, Dula Parkinson, Oliver G. Schmidt, Denys Makarov

Robert Streubel Papers

X-ray tomography is a well-established technique to characterize 3D structures in material sciences and biology; its magnetic analogue - magnetic X-ray tomography - is yet to be developed. Here we demonstrate the visualization and reconstruction of magnetic domain structures in a 3D curved magnetic thin films with tubular shape by means of full-field soft X-ray microscopies. The 3D arrangement of the magnetization is retrieved from a set of 2D projections by analysing the evolution of the magnetic contrast with varying projection angle. Using reconstruction algorithms to analyse the angular evolution of 2D projections provides quantitative information about domain patterns and …

Plotting The Van Der Waals Fluid In Pseudo-3d And The Maxwell Construction, Carl W. David

Chemistry Education Materials

The van der Waals (from his thesis of 1873) equation is a cubic in the molar volume. Plotting the equation in pseudo 3 dimensions is quite simple to do, but including tie lines is quite difficult. Employing the solutions to the cubic van der Waals equation, the tie lines are readily available and can be easily incorporated into the aforementioned 3D plots.

The Effects Of Strain And Vacancies On The Electric And Vibrational Properties Of Ferroelectric Batio3 From First-Principles, Aldo Serge Michael Raeliarijaona

Graduate Theses and Dissertations

The studies of ferroelectricity (FE) are of technological significance because of the multitude of applicable properties that ferroelectric materials exhibit. The mastery, and control of these properties necessitate the knowledge of the fundamental physics governing these insulating materials.

In this dissertation I present the results of first-principles investigations of the behavior of the fundamental ferroelectric properties under strain, and in the presence of vacancies. In the first part I introduce the important FE properties, their common behavior, and their numerous valuable applications. Following this background on FEs, a review of theoretical methods is presented with topics such as: Density Functional …

Static And Dynamical Properties Of Ferroelectrics And Related Material In Bulk And Nanostructure Forms, Zhigang Gui

Graduate Theses and Dissertations

Ferroelectrics (FE) and multiferroics (MFE) have attracted a lot of attentions due to their rich and novel properties. Studies towards FE and MFE are of both fundamental and technological importance. We use a first-principles-based effective Hamiltonian method, conventional ab-initio packages and linear-scale three-dimension fragment method to investigate several important issues about FE and MFE. Tuning the properties of FE and MFE films are essential for miniaturized device applications, which can be realized through epitaxial strain and growth direction. In this dissertation, we use the effective Hamiltonian method to study (i) BaTiO 3 films grown along the (110) pseudocubic direction on …

Engineering The Ground State Of Complex Oxides, Derek Joseph Meyers

Graduate Theses and Dissertations

Transition metal oxides featuring strong electron-electron interactions have been at the forefront of condensed matter physics research in the past few decades due to the myriad of novel and exciting phases derived from their competing interactions. Beyond their numerous intriguing properties displayed in the bulk they have also shown to be quite susceptible to externally applied perturbation in various forms. The dominant theme of this work is the exploration of three emerging methods for engineering the ground states of these materials to access both their applicability and their deficiencies.

The first of the three methods involves a relatively new set …

Universal Far-From-Equilibrium Dynamics Of A Holographic Superconductor, Julian Sonner, Adolfo Del Campo, Wojciech H. Zurek

Physics Faculty Publications

Symmetry-breaking phase transitions are an example of non-equilibrium processes that require real-time treatment, a major challenge in strongly coupled systems without long-lived quasiparticles. Holographic duality provides such an approach by mapping strongly coupled field theories in D dimensions into weakly coupled quantum gravity in Dþ1 anti-de Sitter spacetime. Here we use holographic duality to study the formation of topological defects—winding numbers—in the course of a superconducting transition in a strongly coupled theory in a 1D ring. When the system undergoes the transition on a given quench time, the condensate builds up with a delay that can be deduced using the …

Influence Of Thermal Treatment On Electrical And Physical Properties Of Coated Ceramics, K. Guerch, T. Paulmier, Justin Dekany, Jr Dennison, S. Guillemet-Fritsch, P. Lenormand

Presentations

Technical dielectric materials and ceramics are used in many different high technology industrial areas and especially for spacecraft applications. On satellites, these materials are subjected to extreme conditions due to the space plasma environment. To survive, these ceramic insulators must have exceptional electrical and thermal properties. Boron Nitride (BN) and Aluminum Oxide (Al 2O3) are used in particular because they combine good electrical insulation and high thermal conductivity. However, BN and Al2O3 used in spacecraft interiors are exposed to critical radiation demands, where these insulators are irradiated by electrons with high energies and flux. Charged particles are trapped in the …

Electrical Properties Study Under Electron Beam Of Annealed And Coated Boron Nitride, Kevin Guerch, Thierry Paulmier, Jr Dennison, Justin Dekany, Sophie Guillemet-Fritsch, Pascal Lenormand

Conference Proceedings

The charging and relaxation kinetics of pyrolytic boron nitride (BN) substrates, BN with an aluminium oxide (BN/Al₂O₃) coating, and thermally-annealed alumina-coated boron nitride (an-BN/Al₂O₃) were investigated under low power electron irradiation (5 < E₀ < 20 keV, J_i = 10 nA.cm^-2 at room temperature) in the CEDRE facility at ONERA (Toulouse, France). Surface potentials of each ceramics configuration were measured over time using the Kelvin probe method. The influence of coating and annealing treatments to limit charging is discussed in this paper. A thorough study of a an–BN/Al₂O₃ sample was carried out …

Transient Reflectance Of Photoexcited Cd3As2, Christopher P. Weber, Ernest Arushanov, Bryan S. Berggren, Tahereh Hosseini, Nikolai Kouklin, Alex Nateprov

Physics

We report ultrafast transient-grating measurements of crystals of the three-dimensional Dirac semimetal cadmium arsenide, Cd₃As₂, at both room temperature and 80 K. After photoexcitation with 1.5-eV photons, charge-carriers relax by two processes, one of duration 500 fs and the other of duration 3.1 ps. By measuring the complex phase of the change in reflectance, we determine that the faster signal corresponds to a decrease in absorption, and the slower signal to a decrease in the light's phase velocity, at the probe energy. We attribute these signals to electrons' filling of phase space, first near the photon …

Temperature Dependent Surface Reconstruction Of Freely Suspended Films Of 4-N-Heptyloxybenzylidene-4-N-Heptylaniline, Daniel E. Martinez Zambrano

Lawrence University Honors Projects

Surfaces of freely suspended thick films of 4-n-heptyloxybenzylidene-4-n-heptylaniline (7O.7) in the crystalline-B phase have been imaged using non-contact mode atomic force microscopy. Steps are observed on the surface of the film with a height of 3.0 +/- 0.1 nm corresponding to the upright molecular length of 7O.7. In addition, we find that the step width varies with temperature between 56 and 59 degrees C. The steps are many times wider than the molecular length, suggesting that the steps are not on the surface but instead originate from edge dislocations in the interior. Using a strain model for liquid crystalline layers …

Electrical Properties Of Annealed And Coated Boron Nitride Under Electron Beam Irradiation, Kevin Guerch, Thierry Paulmier, Jr Dennison, Justin Dekany, Sophia Guillemet-Fritsch, Pascal Lenormand

Presentations

Technical dielectric materials and ceramics are used in many different high technology industrial areas and especially for spacecraft applications. On satellites, these materials are subjected to extreme conditions due to the space plasma environment. To survive, these ceramic insulators must have exceptional electrical and thermal properties. Boron Nitride (BN) and Aluminum Oxide (Al2O3) are used in particular because they combine good electrical insulation and high thermal conductivity. However, BN and Al2O3 used in spacecraft interiors are exposed to critical radiation demands, where these insulators are irradiated by electrons with high energies and flux. Charged particles are trapped in the ceramics, …

Critical Point Pairs For Smectic-A* - Smectic-C* Phase Transitions., Ted Cassirer

Physics

Liquid crystals is a class of materials possessing properties from both solids and fluids. Similar to solids the molecules arrange themselves in some sort of order. In the liquid crystal state there are multiple phases, smectic being one of them. In a smectic liquid crystal the molecules are aranged (along $z$) in layers. Of the smectic liquid crystals there exists different phases. In the smectic-A (Sm-A) phase the avarage tilt is $0$ relative to $z$ and in the Smectic-C (Sm-A) phase the avarage tilt is non-zero relative to $z$. Normally the liquid crystal will transition between the two phases by …

Titanium Trisulfide Monolayer: Theoretical Prediction Of A New Direct-Gap Semiconductor With High And Anisotropic Carrier Mobility, Jun Dai, Xiao Cheng Zeng

Xiao Cheng Zeng Publications

A new two-dimensional (2D) layered material, namely, titanium trisulfide (TiS₃) monolayer, is predicted to possess novel electronic properties. Ab initio calculations show that the perfect TiS₃ monolayer is a direct-gap semiconductor with a bandgap of 1.02 eV, close to that of bulk silicon, and with high carrier mobility. More remarkably, the in-plane electron mobility of the 2D TiS₃ is highly anisotropic, amounting to about 10,000 cm² V⁻¹ s⁻¹ in the b direction, which is higher than that of the MoS₂ monolayer, whereas the hole mobility is about two orders of magnitude lower. …

Capacitance Measurements Of Defects In Solar Cells: Checking The Model Assumptions, Justin R. Davis

Senior Theses

Capacitance measurements of solar cells are sensitive to minute changes in charge in the material. For that reason, capacitance is used in several methods to electrically characterize defects in the solar cell. Standard interpretations of capacitance rely on many assumptions, which, if wrong can skew the results. We explore possible alternative explanations for capacitance transitions, such as a non-ideal back contact and series resistance. Using Drive Level Capacitance Profiling measurements, a capacitance step is linked to a defect between the energy bands of a solar cell.

Effects Of Temperature On The Crystal Structure Of Lithium-Lanthanum Zirconate, Mir Iqbal

DePaul Discoveries

ABSTRACT Lithium-lanthanum zirconate (LLZ) can potentially be used as a solid electrolyte in lithium-metal batteries. Li-metal batteries offer superior charge capacities and higher energy densi-ties compared to currently used Li-ion batteries. Lithium is highly reactive, which can be dangerous in consumer electronics, but a layer of LLZ electrolyte inserted alongside the Li-metal electrode greatly stabilizes its reactivity. The cubic phase structure of LLZ (Li₇La₃Zr₂O₁₂) has the highest conductivity of its crystalline phases, making it the most promising crystal form of LLZ for this application. Samples of LLZ were doped with different amounts …

A Static And Dynamic Investigation Of Quantum Nonlinear Transport In Highly Dense And Mobile 2d Electron Systems, Scott A. Dietrich

Dissertations, Theses, and Capstone Projects

Heterostructures made of semiconductor materials may be one of most versatile environments for the study of the physics of electron transport in two dimensions. These systems are highly customizable and demonstrate a wide range of interesting physical phenomena. In response to both microwave radiation and DC excitations, strongly nonlinear transport that gives rise to non-equilibrium electron states has been reported and investigated. We have studied GaAs quantum wells with a high density of high mobility two-dimensional electrons placed in a quantizing magnetic field. This study presents the observation of several nonlinear transport mechanisms produced by the quantum nature of these …