Condensed Matter Physics Commons^™

Silicon Nitride Thin Film Deposited By Plasma-Enhanced Chemical Vapour Deposition Technique For Various Device Applications, Anayesu Bariki Malisa

Tanzania Journal of Science

This work reports on silicon nitride (SiNx) thin film deposited by the Plasma-Enhanced Chemical Vapour Deposition (PECVD) technique. The film was characterized by Variable Angle Spectroscopic Ellipsometry (VASE) to obtain optical constants 𝑛, 𝑘 and thickness using the Cauchy layer built on the Lorentz oscillator model and the B-spline model. The determined optical band gap 𝐸𝑜𝑝𝑡𝑖𝑐𝑎𝑙 for direct transition was 3.2 𝑒𝑉 and that for indirect transition was 2.13 𝑒𝑉. Film characterization was performed by Fourier Transform Infra-Red spectroscopy (FTIR) at two different angles of incidence of 15 degrees to probe deep layers and 65 degrees (Brewster’s angle) to excite …

Characterization Of Combined Adsorption Using Fermi Levels, Molecular Dynamics, And Monte Carlo Simulations To Prevent Cu–Zn (111) Alloy Corrosion, Mushtaq Jerri Meften, Ammar Abdul Jabbar Kadhim, Mohammed Shafeeq Abed

Makara Journal of Science

Experimentally developing corrosion inhibitors requires a significant amount of money and time. In silico advancement empowers selecting inhibitor molecules based on their properties derived from theoretical studies, thereby reducing costs. Our main approaches include theoretical studies such as Fermi levels, electrostatic potential surface (EPS), Fukui indices, molecular dynamics stimulations, and Monte Carlo as indispensable tools to investigate the adsorption mechanisms of molecules 6-((5-(((3S,5R)-2-oxo-5-((2-(pyrazin-2-yloxy) thiazol-5-yl) thio) tetrahydro-2H-thiopyran-3-yl) oxy)isothia-zol-3-yl)thio) nicotinic acid (PTT), and (S)-2-((5-((6-((3-(2-thioxoethoxy)-1,2,4-thiadiazol-5-yl)thio)-1,6-dihydropyra-zin-2-yl)oxy)-1,3,4-thiadiazol-2-yl) thio) acetaldehyde (TTD) on the Cu/Zn (111) alloy. We electronically characterized PTT and TTD, which were proven effective inhibitors. Notably, all results suggested that the two exhibited high …

A Unified Sensitivity Kernel For Coherent Wave Tomography In Radar, Seismic, Ultrasound And Optical Imaging, Alexey Yamilov

Research Data

Overview:

This deposit contains the three figures of Ref. [1] that report numerical simulations, main-text Fig. 4 and Supplementary Figs. S1 and S2, together with the plotted data, one CSV file per figure. The simulations are described in Supplementary Note S3 of Ref. [1]. They were computed with MESTI [2] in two dimensions and with the modified Born series [3] in three, on the Mill [4] and Hellbender [5] clusters. The remaining figures of the paper are schematics (Figs. 1 and 5), a diagram drawn from the numbers listed in Table I (Fig. 3), or evaluations of closed-form expressions given …

On-Shell Compression And Reconstruction (Oscar) Of Monochromatic Wave Fields In Weakly Scattering Media, Pablo Jara, Alexey Yamilov

Research Data

Overview

This deposit contains one realization of each of the two simulation platforms of Ref. [1], a two-dimensional (2D) scalar field and a three-dimensional (3D) vector-field component, together with two self-contained Python scripts that perform On-Shell Compression and Reconstruction (OSCAR) on them. Each script Fourier-transforms the stored field, measures the shell radius from the spectrum, retains only the Fourier components inside the shell of full width α/ℓs around it for α = 1, 3, 5, 8, 12, reconstructs the field by the inverse transform, and plots the reconstructed intensities, panels (a)–(e), next to the original field, panel (f), on a …

Mesoscopic Scaling Of Microwave Transmittance And Disorder-Induced Alignment, Israel Kurtz

Dissertations, Theses, and Capstone Projects

This thesis presents microwave measurements and numerical simulations of wave propagation and transmission through random mesoscopic waveguides. We analyze the scaling of mesoscopic microwave conductance, including departures from Ohm’s law near channel openings, which are frequencies at which new propagating modes enter the system, and the evolution of modal phase alignment within the medium, which leads to the observed diversity of transmission eigenvalues. We extend the transmission matrix formalism to all sample depths using the flux matrix, which relates the flux amplitude within the sample to the incident flux, and decompose the flux at each sample depth into forward- and …

Field-Like- And Self-Spin-Orbit Torques In Magnetic Multilayer Films, Kyle Jeffrey Peterson

Electronic Theses and Dissertations

Spin-orbit torques (SOTs) have been realized as an energy efficient mechanism to manipulate and drive magnetization dynamics in magnetic multilayer films. Their damping-like and field-like components provide distinct pathways for controlling the magnetization, enabling switching, sustaining magneto-oscillations, and driving domain-wall motion with potential applications in nonvolatile memory, spin-based logic, and microwave signal generation. However, the accurate quantification and interpretation of these torques remains complicated by experimental sensitivity, the co-symmetry of the Oersted field and the effective field due to the field-like torque, and assumptions regarding the material layers from which the torques originate. The body of work set forth in …

Exploring Red Palm Oil As A Sustainable Plasticizer For Carbon Black-Filled Ssbr/Br Tire Tread Compounds: A Comparative Evaluation Of Commercial Alternatives, Norma Arisanti Kinasih, Mohamad Irfan Fathurrohman, Santi Puspitasari, Dewi Kusuma Arti, Abdulhakim Masa

Journal of Materials Exploration and Findings

This study investigates the application of red palm oil (RPO) as an alternative vegetable oil resource to substitute petroleum-based plasticizers, which have environmental and health concerns, in carbon black (CB)-filled SSBR/BR tire tread compounds. The plasticizing effects of RPO were thoroughly evaluated by comparing them with a commercial bio-based plasticizer, Epoxidized Soybean Oil (ESBO), and two safer petroleum-based oils, Naphthenic Oil (NYNAS) and Treated Distillate Aromatic Extract (TDAE). The initial investigation shows that fatty acid composition is imposing regarding the plasticizing effect. The higher unsaturated fatty acid content in RPO than in ESBO improved tensile strength and degraded rolling resistance …

Metallurgical Investigation Of A Modified Eye Bolt Failure Caused By Improper Weld Extension, Specification Deviation, And Crevice Corrosion, Dimas Muhammad Fawwaz, Reza Miftahul Ulum, Johny Wahyuadi Soedarsono, Yudha Pratesa

Journal of Materials Exploration and Findings

A modified eye bolt from the David Arm Manhole Storage Tank underwent thorough metallurgical study due to the consequences of the bolt's malfunction during operation. Safety issues arose when the manhole door detached during operation. The mechanical testing and chemical composition analysis of the bolts indicated they were manufactured from an ASTM A193 Grade B7 material used for high-temperature bolting. This material did not conform to the engineering drawing, which mentioned SA 563A, which is about nuts, not bolts. This contradiction clearly shows that the eye bolt which was installed does not conform to the intended design. Welded connections of …

Rejection Of Fe (Iron) And Kmno4 (Organic Substance) Parameters In Peat Water Using Organic Membranes, Muhamad Rafli Sakti Mulia Gonera, Siti Umi Kalsum, Sarah Fiebrina Heraningsih

Journal of Materials Exploration and Findings

Peat water is a surface water source widely used by people in swampy and lowland areas, but it has poor quality characteristics such as high organic matter content, low pH, and dissolved metal levels such as iron that exceed the threshold. These conditions can cause health problems and reduce the quality of clean water so that effective treatment technology is needed. This study aims to analyze the effectiveness of ultrafiltration membranes made from chitosan from shrimp shell waste in rejecting iron (Fe) and organic substances in peat water, and to determine the effect of pressure on separation performance. This study …

Synthesis And Characterization Of Carbon Quantum Dots And Gold Nanoparticles For Norovirus Biosensing Applications In Water Systems, Breanne Evans

Master's Theses

Rapid, reliable detection of viral pathogens remains a significant challenge across water-treatment and environmental monitoring systems, including drinking-water, wastewater, water reuse, and environmental surveillance applications. Waterborne viral contamination can pose substantial public-health risks, making early detection essential for protecting water quality and responding quickly to treatment failures or contamination events. Direct potable reuse (DPR) is one particularly demanding example because it requires continuous verification of treatment performance and the broader need for rapid virus monitoring extends across many water-treatment and environmental surveillance applications. Norovirus is a priority target because of its widespread occurrence in wastewater, environmental persistence, and exceptionally low …

A Study On The Complex Doping Of Na2x2teo6 (X = Ni, Cu, Fe, Co, Zn), Omar Salas

Open Access Theses & Dissertations

Na2Ni2TeO6 is a layered honeycomb antiferromagnet in which Ni2+ ions form magnetic honeycomb planesseparated by sodium layers. In this work, four compositionally complex oxides derived from Na2Ni2TeO6 were synthesized to test whether the NNTO-type structure remains stable when 50% of the Ni sublattice is replaced by mixtures of Cu, Zn, Fe, and Co. Powder X-ray diffraction and neutron powder diffraction show that all four samples retain the hexagonal P 63/mcm average structure of the parent NNTO phase, demonstrating that the layered honeycomb framework is stable against substantial multiple-cation substitution. A small CoFe2O4 secondary phase is present in all four samples …

Atomic-Scale Investigation Of Functional Molecular Systems And Graphene Nanoribbons Using Scanning Probe Microscopy, A.M. Shashika D. Wijerathna

Physics Theses & Dissertations

Emerging molecular electronics, molecular devices, and carbon-based nanotechnologies increasingly rely on the precise control of molecular structures and interfaces at the atomic scale. Advancing these systems requires experimental techniques capable of resolving atomic structures, quantifying molecular behavior, and revealing the mechanisms governing nanoscale assembly. Scanning probe microscopy uniquely provides these capabilities by combining atomic-resolution imaging with local spectroscopy and manipulation. This dissertation employs ultra-high-vacuum low-temperature scanning tunneling microscopy (UHV-LT-STM) and qPlus atomic force microscopy (qPlus AFM) to address three complementary challenges: (i) atomic-scale characterization of complex supramolecular architectures, (ii) quantitative investigation of mechanically induced conformational switching of individual molecules, and …

Glassy Magnetic Freezing Of Interacting Clusters In Materials Related To The Lk-99 Family, Serafim Teknowijoyo, Domenico Napoletani, Vahan Nikoghosyan, Armen Gulian

Mathematics, Physics, and Computer Science Faculty Articles and Research

We report reproducible magnetization anomalies appearing below room temperature in copper-doped apatite materials belonging to the LK-99 family synthesized via hydrothermal methods. These anomalies are observed consistently across samples prepared under comparable conditions. Although the extracted Mydosh parameter lies within the range often associated with vortex-glass behavior in superconductors, a detailed analysis of DC magnetization, AC susceptibility, field dependence, and magnetic memory effects demonstrates that the observed phenomena are not related to superconductivity. Instead, the data are consistent with glassy magnetic freezing of interacting clusters. Compositional and structural analysis identifies covellite (CuS), one of the constituent phases in these multiphase …

Establishing Ferromagnetism In Van Der Waals Antiferromagnets Mps3, Dinesh Upreti

Graduate Theses and Dissertations

Recent discoveries of magnetism in low dimensions not only have gained fundamental scientific interest but also holds significant potential in numerous technological applications, such as spintronics. This has led to a wide range of efforts in the synthesis of new layered materials or tuning their existing magnetic properties, which has been instrumental in understanding the novel physical concept and development of new technological frontiers. Transition metal thiophosphate, MPS3, is a class of layered antiferromagnet family. The rich magnetic/crystal structure with delicate choice of transition metal (M) together with intriguing optical, electronic, and ferroelectric properties have placed them as a model …

The Role Of Zinc Precursor Concentration In Modulating The Structural, Optical, And Electrical Properties Of Sol-Gel Derived Czts Thin Films, Justine John Tibaijuka

Tanzania Journal of Science

This study reports on CZTS thin films fabricated by sol–gel spin coating using zinc acetate dihydrate, copper acetate dihydrate, tin chloride, and thiourea dissolved in methanol with monoethylamine as a stabilizer. The films were annealed rapidly at 540 °C by using an RTP furnace. Results show the significant influence of zinc concentration on films’ properties with band gap evolution between 1.46 and 1.7 eV, along with high absorption coefficients exceeding 10⁴ cm⁻¹ in the visible range. Structurally, the films evolved from poorly crystalline at low Zn content to well- crystallized, (112)-oriented kesterite near stoichiometry. However, excessive Zn caused slight degradation …

Phenomenological Dynamical Mean-Field Theory Of Temperature-Dependent Optical Conductivity And Metal-Insulator Transition In La0.7ca0.3mno3, Listiana Satiawati, Adam Badra Cahaya, Eddwi Hesky Hasdeo, Muhammad Aziz Majidi, Anto Sulaksono, Andrivo Rusydi

Makara Journal of Science

As an extension of our previous theoretical study, we perform temperature-dependent optical conductivity calculations on La_0.7Ca_0.3MnO₃ over a wide photon-energy range up to ∼22 eV, aiming to capture the metal–insulator transition while preserving the general temperature-dependent profile at higher photon energies. The system is modeled with simple Mn–O coordination via the tight-binding method, where some hopping integrals are considered functions of magnetization. Upon incorporating the static Jahn–Teller effect with Coulomb–Hubbard and magnetic exchange interactions, with the exception of a quantitative difference in the calculated of  K versus the experimental value (260 K) and discrepancies in …

Lafe0.925ti0.075o3 Perovskite Coated With Ethyl Cellulose: A High-Stability, Low-Hysteresis Platform For Advanced Humidity Sensing, Akhmad Futukhillah Fataba Alaih, Djoko Triyono, Rifqi Almusawi Rafsanjani

Makara Journal of Science

Humidity sensors are pivotal in numerous sectors, such as environmental monitoring, industrial automation, and health-care. This study presents the fabrication and detailed evaluation of an advanced humidity sensor using ethyl cellulose (EC)-coated LaFe_0.925Ti_0.075O₃ (LFTO) perovskite nanoparticles synthesized via the sol-gel method. The LFTO nanopar-ticles exhibited a mesoporous structure with an enhanced surface area, which significantly improved their moisture adsorption capabilities. The innovative application of EC coating addresses critical substrate adhesion issues, enhancing mechanical stability without compromising sensor sensitivity. Comprehensive performance evaluations revealed minimal hysteresis (

Fabrication Of Two-Dimensional Optoelectrical Devices, Holly Walworth

Honors Projects

Optoelectrical devices enable the exploration of interesting quantum states observed in two-dimensional (2D) condensed material systems. 2D materials, such as graphene and transition metal dichalcogenides, exhibit unique electronic properties, including the Fractional Quantum Anomalous Hall effect (FQAHE). The realization of the FQAHE offers a pathway toward topological quantum computing via non-Abelian anyons. Still, fabricating high-quality 2D optoelectrical devices remains a significant experimental challenge. Using mechanical exfoliation and stacking techniques within an inert argon environment, we attempted to fabricate optoelectrical devices using twisted molybdenum ditelluride (tMoTe2) and gallium telluride (GaTe). Three devices were successfully assembled; however, structural defects including hexagonal boron …

Momentum Space Algorithm For Electronic Structure Of Double-Incommensurate Trilayer Graphene, Kenneth Silver Beard

LSU Doctoral Dissertations

Numerical algorithms for computing the electronic structure of incommensurate 2D-materials using ab initio models are critical for predicting material properties and guiding experiments. For bilayers, momentum space and continuum models have been introduced to approximate observables of ab initio tight-binding models using a momentum description, despite the lack of periodicity in the tight-binding model required for Bloch theory. A similar structure has been introduced for double-incommensurate trilayers using a continuum model, where the three lattices are mutually incommensurate. However, this description leads to a four-dimensional lattice space, and numerical convergence of the density of states has been observed to be …

Designing Enhanced Nonlinearity In Plasmonic Devices With Epsilon-Near-Zero Films, Kevin Tran Le

Electrical Engineering and Computer Science (MS) Theses

The growing demand for energy-efficient optical information processing motivates compact nonlinear photonic devices that can operate at low power. Silicon photonics is a mature platform for linear optical functions, but nonlinear operation remains challenging because of its weak Kerr response, two-photon absorption at telecommunication wavelengths, and limited compatibility with deeply subwavelength plasmonic confinement. This thesis computationally investigates epsilon-near-zero thin films integrated into plasmonic waveguide architectures as a route toward stronger light–matter interaction in compact nonlinear devices.

Two waveguide geometries are examined: a hybrid metal-insulator-metal plasmonic slab waveguide incorporating an ultrathin indium tin oxide epsilon-near-zero layer (5–50 nm), and a dielectric-loaded …

Structural Relaxation In Glass-Forming Liquids At Extreme Pressure: Photon-Correlation Spectroscopy And Constrained Thermodynamic Surface Modeling, Kevin Wayne Lyon

Graduate Theses and Dissertations

Structural relaxation in glass-forming liquids is strongly dependent on both temperature and pressure, yet direct measurement of structural α-relaxation under multi-gigapascal compression has remained experimentally challenging. This work extends depolarized photon correlation spectroscopy (DPCS) to pressures approaching 5 GPa in a diamond anvil cell, representing the highest-pressure implementation of this technique and enabling direct measurement of the structural α-relaxation in a pure liquid at extreme compression. This capability provides access to dynamical regimes previously unexplored by photon correlation spectroscopy and establishes a platform for probing glassy dynamics at high pressure. To describe these measurements, a constrained relaxation-time surface framework is …

Strain Engineering Of Excitonic And Vibrational Properties In Two-Dimensional Transition Metal Dichalcogenides, Sneha Minesh Patel

Graduate Theses and Dissertations

Mechanical strain represents a robust and non-invasive method for tuning the electronic and vibrational properties of two-dimensional transition-metal dichalcogenides (TMDs). This work examines homogeneous biaxial strain as a symmetry-preserving control parameter that governs excitonic and interlayer dynamics in atomically thin TMDs. In monolayer MoSe2, biaxial tensile strain is intrinsically generated during high-temperature physical vapor deposition due to thermal expansion mismatch with amorphous substrates. Optical spectroscopy demonstrates substantial and tunable excitonic energy shifts exceeding 100 meV per percent strain. Polarization-resolved second harmonic generation confirms the retention of lattice symmetry under biaxial deformation. The investigation is further extended to bilayer MoS2, where …

First-Principles Study Of Uranium Mononitride, Roy Noe Herrera Navarro

Open Access Theses & Dissertations

This thesis presents a first-principles investigation of uranium mononitride (UN), withemphasis on the connection between uranium 5f electron correlation and defect stability. Electronic-structure calculations were performed within density functional theory using the Vienna Ab initio Simulation Package. Exchange-correlation effects were treated within the generalized gradient approximation, and a Hubbard correction was applied to the uranium 5f manifold. The adopted Hubbard parameter was motivated by first-principles linear-response analysis and considered in the broader context of DFT+DMFT descriptions of correlated uranium systems, including recent interpretations of UN as a Hund-metal system. Bulk UN was studied in unit-cell and 2 x 2 x …

Exactly Solving One-Dimensional Models For The Fractional Quantum Hall Effect, Joseph R. Cruise

Arts & Sciences Graduate Student Theses and Dissertations

Nearly fifty years after its experimental debut, the quantum hall effect has produced perhaps more unique descriptions than any other subject of condensed matter physics. From topological band theory to non-commutative geometry, topological and conformal field theories, random matrix models and more, each approach captures a subset of the essential features, and compliments the others to produce a beautiful mosaic description. In this thesis, we revisit the fractional quantum hall (FQH) effect from its oldest vantage point, that of the trial wavefunctions and the parent Hamiltonians which stabilize them. Laughlin's observation of the importance of the theory of holomorphic functions …

The Role Of Interactions In Moiré Quantum Materials, Liangtao Peng

Arts & Sciences Graduate Student Theses and Dissertations

Moiré quantum materials have emerged as a highly tunable platform for studying strongly interacting electrons in low dimensions. By twisting or lattice-mismatching atomically thin crystals, one can generate long-wavelength moiré superlattices that reconstruct the electronic bands, produce narrow bandwidths, and greatly enhance the importance of Coulomb interactions. As a result, these systems host a wide range of correlated phenomena, including symmetry breaking, magnetism, and superconductivity. This dissertation develops and applies Green's-function-based many-body methods to understand the role of interactions in moiré quantum materials. This dissertation consists of four chapters. The first chapter introduces moiré quantum materials and reviews the basic …

3Ω Thermal Transport In Atomically Thin Materials, Yiwei Le

Arts & Sciences Graduate Student Theses and Dissertations

Since the discovery of graphene, research on two-dimensional (2D) materials has become a central focus of condensed matter physics. While an enormous number and variety of investigations of their electrical, optical, and mechanical properties have been undertaken, their thermal properties remain comparatively underexplored, despite the importance for understanding low-energy excitations and phase transitions. Here, we introduce an extension of the 3ω method thermal measurement technique to the 2D limit of materials. We develop analytical models of thermal transport in the 3ω geometry with boundary conditions tailored for suspended 2D flakes. We then experimentally confirm the feasibility of this approach in …

Electron Emission From Unactivated Gaas: Towards The Development Of Novel Sources Of Spin-Polarized Electrons, William Truslow Newman

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Spin-polarized electrons are commonly emitted from GaAs photocathodes with treated surfaces in a process called negative electron affinity activation. These sources require stringent vacuum conditions that are often hard to achieve and lead to significant downtimes in experiments. In this dissertation, I present new investigations of electron emission from unactivated GaAs towards the development of novel sources of spin-polarized electrons. The work entails two primary directions. The first is the investigation of electron emission using multiphoton ionization processes enhanced by nanoscale surface structures. We explore GaAs electron sources including, shards, nanotip arrays of pyramid structures, wedges, and ion-milled tips. The …

Feasibility Analysis Of Thermal Oxidizer To Determine Remaining Life Using Fitness- For-Service Level 3 Method, Yudhi Yudistirawan, Donanta Dhaneswara, Wahyuaji Narottama Putra, Gama Widyaputra, Dewi Kurnia Suci, Agung Putra Mahardhika

Journal of Materials Exploration and Findings

An aged thermal oxidizer (TOX) in the oil and gas industry necessitates a comprehensive evaluation to ensure its continued safe operation. This study presents a Remaining Life Assessment (RLA) and a Fitness for Service (FFS) evaluation for the four main components of the TOX, in accordance with API 510, API 579/ASME FFS-1, and ASME BPVC Section VIII Div-1 standards. The investigation includes the determination of maximum stress and maximum temperature required to assess the operational viability of the reactor. The four components are radiant, convection, transition, and stack sections—were modeled using the finite element method (FEM). Following the geometric modeling, …

Assessing Passenger Electric Vehicle Growth Strategies And Their Impacts On Electricity Demand Load And Co2 Emissions In Aceh Province To Achieve Net Zero Emission Target By 2060, Taufik Hidayat, Widodo Wahyu Purwanto

Journal of Materials Exploration and Findings

The electrification of the transport sector is a crucial pathway for achieving Indonesia’s Net Zero Emissions (NZE) target by 2060. This study assesses the potential impact of passenger electric vehicle (EV) penetration on electricity demand and CO2 emissions in Aceh Province through a scenario-based modelling approach. Two policy-aligned scenarios are assessed: a low-penetration (LP) scenario and a high-penetration (HP) scenario. Using the Gompertz model and the ASIF framework, total CO2 emissions were projected from 2020 to 2060. Results show that although higher EV penetration reduces direct emissions from internal combustion engine (ICE) vehicles, total CO2 emissions increase more significantly under …

Developing A Workforce To Build A Star On Earth, Vola Andrianarijaona, Angelina Castillo, Sean Walters

Campus Research Month

This study is meant to help understand why fusion has remained "30 years away" for decades and why that may finally be changing.We see nuclear fusion not merely as a physics phenomenon, but as a complex engineering challenge requiring coordination across different disciplines, including physics, materials science, electrical and mechanical engineering, systems engineering, robotics, and computer science, etc. Indeed, nuclear fusion is not just about "making atoms fuse"—it's about controlling, powering, measuring, and stabilizing one of the most extreme environments humans have ever built. Advances in superconducting magnets, new materials are bringing fusion closer to reality than ever before, and …