Condensed Matter Physics Commons^™

Structural Relaxation In Glass-Forming Liquids At Extreme Pressure: Photon-Correlation Spectroscopy And Constrained Thermodynamic Surface Modeling, Kevin Wayne Lyon

Graduate Theses and Dissertations

Structural relaxation in glass-forming liquids is strongly dependent on both temperature and pressure, yet direct measurement of structural α-relaxation under multi-gigapascal compression has remained experimentally challenging. This work extends depolarized photon correlation spectroscopy (DPCS) to pressures approaching 5 GPa in a diamond anvil cell, representing the highest-pressure implementation of this technique and enabling direct measurement of the structural α-relaxation in a pure liquid at extreme compression. This capability provides access to dynamical regimes previously unexplored by photon correlation spectroscopy and establishes a platform for probing glassy dynamics at high pressure. To describe these measurements, a constrained relaxation-time surface framework is …

Strain Engineering Of Excitonic And Vibrational Properties In Two-Dimensional Transition Metal Dichalcogenides, Sneha Minesh Patel

Graduate Theses and Dissertations

Mechanical strain represents a robust and non-invasive method for tuning the electronic and vibrational properties of two-dimensional transition-metal dichalcogenides (TMDs). This work examines homogeneous biaxial strain as a symmetry-preserving control parameter that governs excitonic and interlayer dynamics in atomically thin TMDs. In monolayer MoSe2, biaxial tensile strain is intrinsically generated during high-temperature physical vapor deposition due to thermal expansion mismatch with amorphous substrates. Optical spectroscopy demonstrates substantial and tunable excitonic energy shifts exceeding 100 meV per percent strain. Polarization-resolved second harmonic generation confirms the retention of lattice symmetry under biaxial deformation. The investigation is further extended to bilayer MoS2, where …

First-Principles Study Of Uranium Mononitride, Roy Noe Herrera Navarro

Open Access Theses & Dissertations

This thesis presents a first-principles investigation of uranium mononitride (UN), withemphasis on the connection between uranium 5f electron correlation and defect stability. Electronic-structure calculations were performed within density functional theory using the Vienna Ab initio Simulation Package. Exchange-correlation effects were treated within the generalized gradient approximation, and a Hubbard correction was applied to the uranium 5f manifold. The adopted Hubbard parameter was motivated by first-principles linear-response analysis and considered in the broader context of DFT+DMFT descriptions of correlated uranium systems, including recent interpretations of UN as a Hund-metal system. Bulk UN was studied in unit-cell and 2 x 2 x …

Exactly Solving One-Dimensional Models For The Fractional Quantum Hall Effect, Joseph R. Cruise

Arts & Sciences Graduate Student Theses and Dissertations

Nearly fifty years after its experimental debut, the quantum hall effect has produced perhaps more unique descriptions than any other subject of condensed matter physics. From topological band theory to non-commutative geometry, topological and conformal field theories, random matrix models and more, each approach captures a subset of the essential features, and compliments the others to produce a beautiful mosaic description. In this thesis, we revisit the fractional quantum hall (FQH) effect from its oldest vantage point, that of the trial wavefunctions and the parent Hamiltonians which stabilize them. Laughlin's observation of the importance of the theory of holomorphic functions …

The Role Of Interactions In Moiré Quantum Materials, Liangtao Peng

Arts & Sciences Graduate Student Theses and Dissertations

Moiré quantum materials have emerged as a highly tunable platform for studying strongly interacting electrons in low dimensions. By twisting or lattice-mismatching atomically thin crystals, one can generate long-wavelength moiré superlattices that reconstruct the electronic bands, produce narrow bandwidths, and greatly enhance the importance of Coulomb interactions. As a result, these systems host a wide range of correlated phenomena, including symmetry breaking, magnetism, and superconductivity. This dissertation develops and applies Green's-function-based many-body methods to understand the role of interactions in moiré quantum materials. This dissertation consists of four chapters. The first chapter introduces moiré quantum materials and reviews the basic …

3Ω Thermal Transport In Atomically Thin Materials, Yiwei Le

Arts & Sciences Graduate Student Theses and Dissertations

Since the discovery of graphene, research on two-dimensional (2D) materials has become a central focus of condensed matter physics. While an enormous number and variety of investigations of their electrical, optical, and mechanical properties have been undertaken, their thermal properties remain comparatively underexplored, despite the importance for understanding low-energy excitations and phase transitions. Here, we introduce an extension of the 3ω method thermal measurement technique to the 2D limit of materials. We develop analytical models of thermal transport in the 3ω geometry with boundary conditions tailored for suspended 2D flakes. We then experimentally confirm the feasibility of this approach in …

Electron Emission From Unactivated Gaas: Towards The Development Of Novel Sources Of Spin-Polarized Electrons, William Truslow Newman

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Spin-polarized electrons are commonly emitted from GaAs photocathodes with treated surfaces in a process called negative electron affinity activation. These sources require stringent vacuum conditions that are often hard to achieve and lead to significant downtimes in experiments. In this dissertation, I present new investigations of electron emission from unactivated GaAs towards the development of novel sources of spin-polarized electrons. The work entails two primary directions. The first is the investigation of electron emission using multiphoton ionization processes enhanced by nanoscale surface structures. We explore GaAs electron sources including, shards, nanotip arrays of pyramid structures, wedges, and ion-milled tips. The …

Feasibility Analysis Of Thermal Oxidizer To Determine Remaining Life Using Fitness- For-Service Level 3 Method, Yudhi Yudistirawan, Donanta Dhaneswara, Wahyuaji Narottama Putra, Gama Widyaputra, Dewi Kurnia Suci, Agung Putra Mahardhika

Journal of Materials Exploration and Findings

An aged thermal oxidizer (TOX) in the oil and gas industry necessitates a comprehensive evaluation to ensure its continued safe operation. This study presents a Remaining Life Assessment (RLA) and a Fitness for Service (FFS) evaluation for the four main components of the TOX, in accordance with API 510, API 579/ASME FFS-1, and ASME BPVC Section VIII Div-1 standards. The investigation includes the determination of maximum stress and maximum temperature required to assess the operational viability of the reactor. The four components are radiant, convection, transition, and stack sections—were modeled using the finite element method (FEM). Following the geometric modeling, …

Assessing Passenger Electric Vehicle Growth Strategies And Their Impacts On Electricity Demand Load And Co2 Emissions In Aceh Province To Achieve Net Zero Emission Target By 2060, Taufik Hidayat, Widodo Wahyu Purwanto

Journal of Materials Exploration and Findings

The electrification of the transport sector is a crucial pathway for achieving Indonesia’s Net Zero Emissions (NZE) target by 2060. This study assesses the potential impact of passenger electric vehicle (EV) penetration on electricity demand and CO2 emissions in Aceh Province through a scenario-based modelling approach. Two policy-aligned scenarios are assessed: a low-penetration (LP) scenario and a high-penetration (HP) scenario. Using the Gompertz model and the ASIF framework, total CO2 emissions were projected from 2020 to 2060. Results show that although higher EV penetration reduces direct emissions from internal combustion engine (ICE) vehicles, total CO2 emissions increase more significantly under …

Developing A Workforce To Build A Star On Earth, Vola Andrianarijaona, Angelina Castillo, Sean Walters

Campus Research Month

This study is meant to help understand why fusion has remained "30 years away" for decades and why that may finally be changing.We see nuclear fusion not merely as a physics phenomenon, but as a complex engineering challenge requiring coordination across different disciplines, including physics, materials science, electrical and mechanical engineering, systems engineering, robotics, and computer science, etc. Indeed, nuclear fusion is not just about "making atoms fuse"—it's about controlling, powering, measuring, and stabilizing one of the most extreme environments humans have ever built. Advances in superconducting magnets, new materials are bringing fusion closer to reality than ever before, and …

Harnessing Wavefront Shaping Control For Sensing Applications, Pablo Jara

Miners Solving for Tomorrow Research Conference

Diffuse optical tomography (DOT) and functional near-infrared spectroscopy (fNIRS) enable deep, non-invasive sensing in biological tissue but are fundamentally limited by the photon budget - most injected light is lost to scattering before reaching the detector. Wavefront shaping (WFS) can enhance signal strength inside scattering media via interference, but the conventional diffusion-based sensitivity model breaks down under coherent illumination. We develop a microscopic theory of optical sensitivity that captures interference effects neglected by diffusion theory. We prove analytically that the microscopic and diffusive descriptions coincide under random illumination and identify WFS strategies that enhance sensitivity beyond this limit. The maximum …

Optimization Of Niobium Film For Particle Accelerators And Quantum Applications, Bektur Abdisatarov

Electrical & Computer Engineering Theses & Dissertations

Niobium (Nb) films play a central role in superconducting technologies used in particle accelerators and superconducting quantum circuits. Optimizing the physical properties of Nb films is therefore critical for improving both radiofrequency (RF) performance in superconducting radiofrequency (SRF) cavities and coherence in superconducting qubits. This thesis investigates the relationship between Nb film microstructure, impurity content, and electromagnetic response across these two application domains.

For particle accelerator applications, we studied Nb films deposited using high-power impulse magnetron sputtering (HiPIMS) with DC bias onto a 1.3 GHz elliptical SRF cavity. Nb film cavities exhibit a pronounced medium-field Q-slope, limiting their achievable accelerating …

Fabrication And Analysis Of Bi₂O₃/Si Heterojunction For Solar Cell Applications, Maher Khaleel Ibrahim, Assel Mustafa Abdul Majeed, Randa Kamel Husain, Jamal M. Rzaij

Al-Bahir

Bismuth oxide (Bi₂O₃) nanoparticles were synthesized via a green route and integrated into Bi₂O₃/Si heterojunction solar cells. Structural analysis confirmed the monoclinic α-Bi₂O₃ phase with a nanoscale crystallite size, while SEM revealed a uniform morphology. Optical studies showed a direct band gap suitable for absorbing visible light. Photoluminescence spectra exhibited dual emissions at 498 nm and 250 nm, attributed to defect states and quantum confinement, highlighting the dual role of Bi₂O₃ as both absorber and transparent window layer. Electrical characterization under dark conditions demonstrated rectifying diode behavior, confirming the formation of a junction. Capacitance–voltage analysis yielded a built-in potential of …

Extension Of The Local Vibrational Mode Theory To Periodic Systems, Filippo Bodo

Chemistry Theses and Dissertations

Over the years, vibrational spectroscopy was used to gain a deeper understanding of the electronic structure and the chemical bond in both molecular and periodic systems. In this framework, the Local Vibrational Mode Theory (LVMT), as first introduced by Konkoli and Cremer in 1998, provides a unique tool to quantify the strength of a chemical bond, and better interpret the molecular vibrational spectra, thanks to the adiabatic force constants ($k^a$) and the composition of normal modes (CNM). While LVMT was originally developed for molecular systems, its application to periodic solids has remained limited. This thesis presents a complete and systematic …

Characterization Of Physical And Structural Properties In A Quaternary Li2o-B2o3-Bi2o3-V2o5 Glass System, Alan Ikram Ahmed, Mowfaq Jalil Ahmed

Polytechnic Journal

Borate-based glasses modified with alkali oxides are of considerable interest due to their tunable structural and optical properties, which are important for optical and energy storage applications. In this work, glasses with a novel nominal composition of xLi2O-(75-x) B2O3—20Bi2O3—5V2O5, in which (x ¼ 5, 10, 15, 20, 25 mol %) were produced using the traditional melt-quenching technique to investigate the effect of substituting the glass former B2O3 with the modifier Li2O. The structural and optical properties were examined by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and UV—visible spectroscopy. The XRD analysis confirms the amorphous nature of the samples produced. …

Electronic Transport In Twisted Bilayer Tungsten Diselenides, Walid Zaher

Theses and Dissertations

This thesis investigates density waves (DWs) in twisted bilayer tungsten diselenide (tWSe₂) using a mean field approximation, with a focus on electron-electron interactions, and the system’s free energy at zero temperature. For the mean field approximation, the study initially employed same-spin nesting vectors, which were found insufficient to induce DWs formation. In contrast, when opposite-spin nesting vectors were used, DWs emerged, indicating that these vectors can support DWs formation. The plots were produced under perfect nesting conditions, where van Hove singularities (VHS) occur. At zero temperature, perfect nesting provides a complete picture of the upper limit of DWs formation, as …

Ultrafast Terahertz Spectroscopy And The Suppression Of Superconductivity In Strained Iron Selenide Below 1 Kelvin, Tracy Glen Hastings

ETDs from 2020-2029

We report on terahertz time-domain spectroscopy measurements of iron selenide thin films of various thicknesses grown on a magnesium oxide substrate, focusing on the frequency-dependent complex conductivity in the range of 0.25 - 7 THz. By an- alyzing films with and without an approximately 100 nm thick Se capping layer, we examined the role of oxidation in the suppression of superconductivity. X-ray photo- electron spectroscopy data confirmed that oxidation was effectively mitigated, yet the films exhibited insulating behavior down to 200 mK, a temperature range that has not been extensively studied in this system. Our results indicate that the suppression …

Enhanced Superconductivity And Vortex Dynamics In Quasi-1d Tas2 Nanowires, Mathew Pollard, Visakha Ho, Clarissa Wisner, Eric W. Bohannan, Yew San Hor

Chemistry Faculty Research & Creative Works

We report the synthesis of high-quality 2H-TaS₂ nanowires via a controlled two-step conversion process from TaS₃ precursors, achieving robust superconductivity with a transition temperature T c ≈ 3.6K, which is significantly higher than bulk 2H-TaS₂ (T c ≈ 0.8K). Structural and compositional analyses confirm phase purity and preserved one-dimensional morphology, while magneto transport measurements reveal an enhanced upper critical field μ 0 H c2 (2K)≈5 T, far exceeding the bulk value (_μ0H_c2 (0)≈1.17T), attributed to dimensional confinement and suppression of charge-density wave order. Magnetic characterization demonstrates complex vortex dynamics, including flux jumps and a …

Magnetic Anisotropy Engineering In Rare-Earth-Free Iron-Based Magnetic Materials, Pramanand Joshi

Physics Dissertations - Archive

The development of high-performance, rare-earth-free hard magnetic materials is critical for next-generation energy, information, and spin-based technologies. This dissertation investigates structure-property relationships in iron-based magnetic systems, including iron carbides, Fe-Co-B boride alloys, hexaferrites, and FeCo nanostructures, synthesized via chemical and metallurgical routes. Through controlled synthesis and comprehensive structural and magnetic characterization, this work demonstrates that magnetic anisotropy, coercivity, and thermal stability can be systematically controlled through morphology design, compositional tuning, microstructural refinement, and interparticle interaction modulation.

Morphology-driven enhancement of magnetic properties, particularly coercivity and blocking temperature, is established in phase-pure Fe₅C₂ nanostructures. By precisely controlling particle geometry, …

Applications Of Doppler Broadening Spectroscopy For The Characterization Of The Surface And Near Surface Of Two-Dimensional Heterostructures, Hany M. Mahdy

Physics Dissertations

This dissertation describes experiments and the analysis of Doppler broadening spectroscopy applied to metal surfaces (Cu, Ag, Au), graphene/Cu heterostructures, and SiGe heterostructures, with particular emphasis on the development of new approaches for extracting quantitative information from annihilation spectra.

The first part establishes the capability of Doppler broadening spectroscopy, particularly coincidence Doppler broadening (CDB), as a surface-sensitive technique. Measurements on clean and adsorbate-covered Cu, Ag, and Au surfaces demonstrate that Doppler-broadened annihilation spectra retain element-specific signatures from the topmost atomic layer. New analysis methods based on ratio-curve modeling enable identification and quantification of sub-monolayer adsorbates, including sulfur, oxygen, selenium, and …