Using Paleolimnology To Establish Baseline Conditions For Metal Contaminants In Advance Of Proposed Mining To Inform A Northern Community-Led Aquatic Monitoring Program, Tłı̨Chǫ Lands, Northwest Territories, Canada., James Telford

Theses and Dissertations (Comprehensive)

The Marian Watershed Stewardship Program (MWSP), a community-driven aquatic ecosystem monitoring program, was developed by the Tłı̨chǫ Government to address concerns regarding the cumulative impacts of multiple potential stressors. In particular, the MWSP aims to develop methods that will be effective for detecting potential pollution from the proposed cobalt-gold-copper-bismuth NICO mine within Tłı̨chǫ Lands. In collaboration with the MWSP, paleolimnological methods and geochemical normalization are used to establish pre-mine baselines of lake sediment metals concentrations in the Marian River watershed prior to mine development. This baseline framework can be used to assess for pollution from surficial sediment once the mine …

Petrophysical And Geomechanical Characterization Of The Marcellus Shale In The Appalachian Basin, Yixuan Zhu

Graduate Theses, Dissertations, and Problem Reports (ETD)

In recent years, more and more attention is paid to shale gas and hydrocarbon liquids exploration and exploitation in unconventional reservoirs. With the development of horizontal drilling and hydraulic fracturing, production from unconventional reservoirs has been greatly increased. However, not all wells, regions and basins harbor highly successful shale gas and liquids producers. In order to improve the production efficiency and reduce the cost of projects, detailed analysis needs to be undertaken to characterize the reservoir. As opposed to conventional reservoirs, extraction of gas in the unconventional reservoir is dependent not only on the reservoir quality, but also on completion …

Submarine Groundwater Discharge Data At Meter Scale (223ra, 224ra, 226ra, 228ra And 222rn) In Indian River Bay (Delaware, Us), Carlos Duque, Karen L. Knee, Christopher J. Russoniello, Mahmound Sherif, Usama A. Abu Risha, Neil C. Sturchio, Holly A. Michael

Faculty & Staff Scholarship

Abstract

Submarine groundwater discharge (SGD) was sampled at high-spatial resolution in Indian River Bay, DE, USA, in July 2016 to characterize the spatial variability of the activity of the radium and radon isotopes commonly used to estimate SGD. These data were part of an investigation into the methods and challenges of characterizing SGD rates and variability, especially in the coastal aquifer transition from freshwater to saltwater (Hydrogeological processes and near shore spatial variability of radium and radon isotopes for the characterization of submarine groundwater discharge (Duque et al., 2019)). Samples were collected with seepage meters and minipiezometers to obtain sufficient …

Geochronology And Depositional History Of The Sandy Springs Aeolian Landscape In The Unglaciated Upper Ohio River Valley, United States, Mathew P. Purtill, J. Steven Kite, Steven L. Forman

Faculty & Staff Scholarship

The study of active and stabilized late Quaternary aeolian landforms provides important proxies for past climate events and environmental transitions. Despite an overall increase in the study of aeolian landforms in previously glaciated and coastal settings in eastern North America, the history of aeolian sedimentation in many unglaciated inland alluvial settings remain poorly understood. This study reports on the geochronology and depositional history of aeolian landforms and sediments in the unglaciated upper Ohio Valley at the Sandy Springs site. Aeolian landforms and sediments include complex, linear, barchan-like, and climbing dunes; an interdune sand sheet; and sandy loess that blankets high …

X-Ray Fluorescence Applications In Mudrock Characterization: Investigations Into Middle Devonian Stratigraphy, Appalachian Basin, Usa, Keithan Garrett Martin

Graduate Theses, Dissertations, and Problem Reports (ETD)

Mudrocks are characterized by nanometer-scale pore sizes and nano-darcy permeability, which plays a significant role in hydrocarbon flow during production. Resulting from these characteristics, mudrocks were exclusively considered a source rock, which charged overlying, more porous mediums. Hydraulic fracturing, a technology used to create artificial fractures to liberate hydrocarbons from the reservoir, enabled natural gas to be produced from mudrock reservoirs economically. Over the last fifteen years, this technology motivated research efforts to understand reservoir characteristics of mudrock. These investigations significantly improved our knowledge of mudrock systems, but have also highlighted key areas that are undeveloped and/or where conflicting hypotheses …

Post-Wildfire Recovery Of An Upland Oak-Pine Forest On The Cumberland Plateau, Kentucky, Usa, Devin E. Black, Zachary W. Poynter, Claudia A. Cotton, Suraj Upadhaya, David D. Taylor, Wendy Leuenberger, Beth A. Blankenship, Mary A. Arthur

Forestry and Natural Resources Faculty Publications

Background: Many forests within the southern Appalachian region, USA, have experienced decades of fire exclusion, contributing to regeneration challenges for species such as oaks (Quercus spp. L.) and pines (Pinus spp. L.), and threatening the maintenance of oak-dominated forests in the future. While the use of prescribed fire as a forest management tool is increasing within this region, there remains a lack of information on the potential role of wildfire. A wildfire within the Daniel Boone National Forest, Kentucky, USA, provided an opportunity to investigate how wildfire affected forest vegetation response.

Results: We examined the effects of fire …

Groundwater Level Response To The Wenchuan Earthquake Of May 2008, Anhua He, Ramesh Singh

Mathematics, Physics, and Computer Science Faculty Articles and Research

We have comprehensively analysed the co-seismic response of the groundwater levels of 280 wells in mainland China that were associated with the Wenchuan earthquake (Mw 7.9) that occurred on 12 May 2008. The observed co-seismic responses can be classified as step-like changes in 138 wells, variations in 69 wells and non-responses in 73 wells. After a quantitative analysis of spatial distribution, there was no spatially coherent signal found in the step-like changes (positive values indicate a step-like rise, and negative values indicate a step-like fall), even within 300 km of the epicenter. The amplitude and the phase shift of the …

Climate Evolution Across The Mid-Brunhes Transition, Aaron M. Barth, Peter U. Clark, Nicholas S. Bill, Feng He, Nicklas G. Pisias

School of Earth & Environment Departmental Research

The Mid-Brunhes Transition (MBT) began ∼ 430 ka with an increase in the amplitude of the 100 kyr climate cycles of the past 800 000 years. The MBT has been identified in ice-core records, which indicate interglaciations became warmer with higher atmospheric CO2 levels after the MBT, and benthic oxygen isotope (δ18O) records, which suggest that post-MBT interglaciations had higher sea levels and warmer temperatures than pre-MBT interglaciations. It remains unclear, however, whether the MBT was a globally synchronous phenomenon that included other components of the climate system. Here, we further characterize changes in the climate system across the MBT …

Geomorphology Of Shell Ridges And Their Effect On The Stabilization Of The Biloxi Marsh, East Louisiana, Frances R. Crawford

LSU New Orleans Theses and Dissertations

Extensive shell ridges frame the edges of marsh platforms in parts of the Biloxi Marsh of southeast Louisiana. The exact sources of the shells in these accumulations have not been clearly identified but the most likely source is a combination of shells from modern offshore and shells excavated from buried St. Bernard delta deposits. Larger or fetch-protected ridges remain stable through time, whereas ridges facing open water are more mobile, moving as much as 38 m inland from July 2017 to January 2018. Behind stable ridges, marsh platform biomass is relatively unaffected. When ridges are mobile, vegetation is smothered, leaving …

The Relationship Between The Phosphate And Structural Carbonate Fractionation Of Fallow Deer Bioapatite In Tooth Enamel, Holly Miller, Carolyn Chenery, Angela L. Lamb, Hilary Sloane, Ruth F. Carden, Levent Atici, Naomi Sykes

Anthropology Faculty Research

Rationale The species‐specific relationship between phosphate (δ18OP values) and structural carbonate (δ18OC values) oxygen isotope ratios has been established for several modern and fossil animal species but until now it has not been investigated in European fallow deer (Dama dama dama). This study describes the relationship between phosphate and structural carbonate bioapatite in tooth enamel of extant fallow deer, which will help us further understand the species' unique environmental and cultural history. Methods The oxygen isotope composition of phosphate (δ18OP value) and structural carbonate (δ18OC value) of hydroxylapatite was determined in 51 modern fallow deer tooth enamel samples from across …

Magmatic Response To Subduction Initiation: Part 1. Fore-Arc Basalts Of The Izu-Bonin Arc From Iodp Expedition 352, John W. Shervais, Mark Reagan, Emily A. Haugen, Renat R. Almeev, Julian A. Pearce, Julie Prytulak, Jeffrey G. Ryan, Scott A. Whattam, Marguerite Godard, Timothy Chapman, Hongyan Li, Walter Kurz, Wendy R. Nelson, Daniel Heaton, Maria Kirchenbaur, Kenji Shimizu, Tetsuya Sakuyama, Yibing Li, Scott K. Vetter

Geosciences Faculty Publications

The Izu-Bonin-Mariana (IBM) fore arc preserves igneous rock assemblages that formed during subduction initiation circa 52 Ma. International Ocean Discovery Program (IODP) Expedition 352 cored four sites in the fore arc near the Ogasawara Plateau in order to document the magmatic response to subduction initiation and the physical, petrologic, and chemical stratigraphy of a nascent subduction zone. Two of these sites (U1440 and U1441) are underlain by fore-arc basalt (FAB). FABs have mid-ocean ridge basalt (MORB)-like compositions, however, FAB are consistently lower in the high-field strength elements (TiO2, P2O5, Zr) and Ni compared to MORB, with Na2O at the low …

Mercury In Big Cypress Bayou And Caddo Lake Watersheds In Marion And Harrison Counties Texas, Joseph Watkins

Electronic Theses and Dissertations

Caddo Lake has been included on the Texas Commission on Environmental Quality 303(d) list for impairment due to mercury (Hg) content since 1996. One of the primary tributaries, Big Cypress Bayou, flows across Eocene-aged rocks and sediments associated with the Wilcox Group; the Wilcox is of interest because it contains lignite coal, which has a direct link to mercury. Previous research has focused on dry deposition from fossil fuel combustion as the primary source of mercury but has not addressed the potential watershed contribution to mercury concentrations in Caddo Lake.

Big Cypress Bayou flows through Harrison and Marion counties in …

Delineation Of Karst Potential Using Lidar And Gis Analyses, Fort Hood Military Installation, Texas, Colby Reece

Electronic Theses and Dissertations

ABSTRACT

Traditional karst surveys require extensive field investigations to completely characterize large areas. They are often time-consuming, requiring up to several years to collect and categorize data. Bias is given to areas that are most easily accessible and false negatives are common. The implementation of geographic information systems (GIS) has aided in the aggregation and standardization of karst data; however, these systems have also been used to develop terrain models that allow the user to remotely delineate sinkholes and other surficial features. The Fort Hood Military Installation is a karst landscape that has been altered significantly for use in military …

Petrogenesis Of Enriched And Intermediate Poikilitic Shergottites: From Magmatic Source To Emplacement, Rachel Rahib

UNLV Theses, Dissertations, Professional Papers, and Capstones

Poikilitic shergottites, making up >20% of martian meteorites, likely represent a significant composition of the martian crust, as intrusive gabbroic rocks. To further constrain petrogenetic relationships amongst enriched and intermediate poikilitic shergottites, we utilize bulk rock trace element compositions, mineral major element compositions, phosphorus maps of olivine grains, oxygen fugacity (ƒO2) values, subsolidus equilibration temperatures, and quantitative textural analyses, of the most comprehensive suite of poikilitic shergottites yet (11 samples), including three newly recovered samples (Northwest Africa [NWA] 11065, NWA 11043, NWA 10961). Although petrographically light rare earth element (LREE) enriched and intermediate poikilitic shergottites are similar, distinct LREE abundances …

Prokaryotic Diversity And Aqueous Geochemistry Of Subsurface Environments Of The Death Valley Regional Flow System, Joshua David Sackett

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation summarizes over four years of effort towards the completion of a Ph.D. in Biological Sciences. The work presented in this document covers a broad range of topics, but a central unifying theme is prokaryotic life in the continental subsurface. The work presented in each chapter relied heavily on cultivation-independent methods for assessing prokaryotic communities, including prokaryotic community structure reconstruction from high-throughput sequencing of 16S rRNA gene libraries and single-cell genome analysis of novel uncultivated bacteria.

Chapter 2 examines the aqueous geochemistry and prokaryotic diversity of Devils Hole, a cavernous limnocrene and sole natural habitat for the critically endangered …

Monitoring The Impact Of Groundwater Pumping On Infrastructure Using Geographic Information System (Gis) And Persistent Scatterer Interferometry (Psi), Kirsten Deprekel, El Hachemi Bouali, Thomas Oommen

Department of Geological and Mining Engineering and Sciences Publications

Transportation infrastructure is critical for the advancement of society. Bridges are vital for an efficient transportation network. Bridges across the world undergo variable deformation/displacement due to the Earth’s dynamic processes. This displacement is caused by ground motion, which occurs from many natural and anthropogenic events. Events causing deformation include temperature fluctuation, subsidence, landslides, earthquakes, water/sea level variation, subsurface resource extraction, etc. Continual deformation may cause bridge failure, putting civilians at risk, if not managed properly. Monitoring bridge displacement, large and small, provides evidence of the state and health of the bridge. Traditionally, bridge monitoring has been executed through on-site surveys. …

Mineralogy, Petrology, And Geochemistry Of The Unique Silica-Rich Ungrouped Achondrite Northwest Africa 11575, Mya Ann Habermann

Earth and Planetary Sciences ETDs

We report here on a unique, newly discovered, silica-rich ungrouped achondrite Northwest Africa 11575 (NWA 11575). NWA 11575 is one of four known silica-rich ungrouped achondrites, presenting evidence for igneous processes resulting in evolved compositions early in the history of the solar system. It is unique from the other silica-rich ungrouped achondrites in that it has pyroxene compositional trends matching those of lunar samples and martian meteorites; contains quartz and potassium feldspar; and contains oxygen, hydrogen, and chromium isotopes that are similar to those of LL chondrites. Together, these four silica-rich ungrouped achondrites provide evidence for evolved compositions resulting from …

Insights Into Fluid-Rock Interactions On The Cv3 Carbonaceous Chondrite Asteroid: The Complex Record In The Allende-Like Cv3 Chondrite, Nwa 2364., Jessica Marie Johnson

Earth and Planetary Sciences ETDs

The two subgroups of the CV3 chondrites, oxidized and reduced, contain primitive solar system materials that provide many insights into early solar system processes. Both subgroups record significant evidence of secondary alteration that has modified their primary characteristics. In this work, we have studied the petrography, mineralogy, and oxygen isotopic composition of the NWA 2364 CV3_OxA chondrite and a large lithic inclusion using SEM, electron microprobe, FIB/TEM, and laser fluorination oxygen isotope analyses in order to characterize their alteration histories in detail. The NWA 2364 host and lithic inclusion consist of chondrules, Calcium-Aluminum-rich Inclusions (CAIs), and fine-grained matrix. In …

The Ages2 (Awards For Geochronology Student Research 2) Program: Supporting Community Geochronology Needs And Interdisciplinary Science, Rebecca M. Flowers, J. Ramón Arrowsmith, Vicki Mcconnell, James R. Metcalf, Tammy M. Rittenour, Blair Schoene

Geosciences Faculty Publications

Geochronology is essential in the geosciences. It is used to resolve the durations and rates of earth processes, as well as test causative relationships among events. Such data are increasingly required to conduct cutting-edge, transformative, earth-science research. The growing need for geochronology is accompanied by strong demand to enhance the ability of labs to meet this pressure and to increase community awareness of how these data are produced and interpreted. For example, a 2015 National Science Foundation (NSF) report on opportunities and challenges for U.S. geochronology research noted: "While there has never been a time when users have had greater …

Widespread, Prolonged Microbial Limestone Deposition And Large, Rapid Sulfur Isotope Excursions: A New Perspective On The Early Triassic From The Western U.S., Brad M. Jeffrey

Earth and Planetary Sciences ETDs

The Early Triassic records a ~5 My period of marine biological recovery following the end-Permian mass extinction (EPME, ~252 My). Global oceans were characterized by warm sea-surface temperatures (SSTs), widespread anoxia, and major perturbations to the carbon cycle, the collective result of repeated massive Siberian Traps eruptions and associated global climate feedbacks. Globally widespread microbial deposits (stromatolites, thrombolites) developed in shallow marine environments. Several marine isotope records (C, O, S, U) indicate repeated, large-magnitude shifts related to paleoceanographic events during the recovery of marine ecosystems following the EPME.

Chapter 1 describes and interprets a widespread (~400 km along strike) Smithian …