Geochemistry Commons^™

Characterization Of Rare Earth Elements In The Illinois Basin Coals, Alireza Valian

Theses and Dissertations--Mining Engineering

The purpose of this study is to characterize the distribution and occurrence of rare earth elements (REEs) in the coal and coal-related material from the Illinois Basin. For characterizing the distribution of REEs, 17 core samples were investigated from various parts in the basin. Also, several individual samples from coal preparation plants and isolated geological occurrences were included in the study. In result, the average REE concentrations were calculated on a bed-to-bed basis, although the distribution of REEs in the coal beds was found laterally and vertically heterogeneous. A number of trends were found that describe the variations. Most importantly, …

Abiotic Formation Of Dissolved Organic Sulfur In Anoxic Sediments Of Santa Barbara Basin, Hussain A. Abdulla, David J. Burdige, Tomoko Komada

OES Faculty Publications

Sulfurization has been found to enhance organic matter preservation and petroleum formation in marine sediments. However, we do not yet have a comprehensive understanding of sulfurization mechanisms. In this study, we investigated several possible mechanisms of dissolved organic sulfur (DOS) formation in the top 4.5 m of anoxic sediments of Santa Barbara Basin (SBB), California Borderland. Using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS), we identified chemical formulas of potential dissolved organic matter (DOM) precursors to these DOS compounds. We also examined how the formulas of abiotically formed DOS changed as a function of depth across a major redox …

Geochemical Flux Analysis Of Glacial River Runoff For Sólheimajökull, Iceland, Jessica Garrison

Mahurin Honors College Capstone Experience/Thesis Projects

Geochemical fluxes in aqueous studies are an essential component of research to understand weathering and changes in a hydrologic system. These data can indicate any discrepancies, outliers, or gradual changes in a water environment to gain information on pollutants, carbon cycles, biological input, etc. Glacial melt is the majority of the surface water present throughout the country. The melting amount is increasing with the temperatures, which can be monitored by the changes in geochemical flux during increased discharge in glacial rivers. A high-resolution data set of Sόlheimajökull Glacier in Iceland was used to determine how changing climatic conditions for the …

Applying Garnet And Zircon Ree Linkages To Determine Timing Of P-T Conditions And Tectonic Implications For Uhp Eclogites And Hp Granulites, Dulan Uhp Terrane, China, Wesley Weisberg

All Master's Theses

The Dulan ultrahigh-pressure (UHP) terrane in western China hosts rocks that record continental collision, however; the timing of peak P-T conditions in UHP eclogites and HP granulites, and the tectonic significance of their spatial relationship within the Dulan UHP terrane are not well understood. This study, (1) evaluates rare earth element (REE) equilibrium between garnet and zircon, to assess coeval growth; (2) links timing (from zircon) to the P-T history (from garnet) to constrain the P-T-t path of the Dulan UHP terrane and interpret implications for zircon growth; (3) refines P-T conditions for HP granulite; and (4) evaluates the tectonic …

Recovering Lost Information From Avocational Projectile Point Collections, Mackenzie Hughes

All Master's Theses

Human prehistory in North America has sparked the interest of private citizens for decades, sometimes leading to an accumulation of avocational artifact collections that lack site-level provenience. The Wild/Clymer artifacts (n = 1,371) are one such collection where precise site provenience was lost. The analysis aims to recover regional provenience by using morphology, raw material sourcing, and typology to create a data set. The avocational collection data set was analyzed by comparing it to the professionally recorded archaeological data sets from within 100 miles of Frenchglen, Oregon. A paradigmatic classification approach identified 606 typeable points in the avocational collection, in …

The Role Of Cumulate Plagioclase Entrainment In The Steens Basalt, Se Oregon: Insights From The Magma Chamber Simulator, Valerie Strasser

All Master's Theses

The Steens Basalt, located in SE Oregon, is the oldest and most mafic member of the Columbia River Basalt Group (CRBG). Because the Steens Basalt contains large (up to 6 cm) and abundant (up to 40%) plagioclase crystals, it is classified as a Giant Plagioclase basalt (GPB). Understanding the origin of these giant plagioclase yields insight into magmatic processes like recharge, crustal assimilation, cumulate entrainment, and fractional crystallization. Because large and abundant plagioclase are found in other flood basalt provinces worldwide, these results could also enhance understanding of magma evolution and storage conditions for GPB worldwide. The Steens basalt is …

Crystalline Architecture And Stratigraphy Of Coral Skeletal Density Banding: A Geobiological Record Of Changing Coral Reef Ecology, Kyle Fouke

Honors Theses

Coral skeletal density banding (CSDB), composed of alternating high density band (HDB) and low density band (LDB) layers that comprise the CaCO₃ (aragonite) skeleton of scleractinian corals, are used as chronometers for global paleoclimatic reconstructions of sea surface temperature (SST). Scleractinian coral skeletons have been intensively studied for centuries with detail analysis of the macro- and microscale skeletal structure to establish taxonomic and evolutionary relationships of coral species, mechanisms of biomineralization, and seafloor physical, chemical and biological alteration (diagenesis) of the skeleton. This study is the first to determine the crystalline architecture of HDBs and CSDB stratigraphic …

The Limits Of Lead (Pb) Phytoextraction And Possibilities Of Phytostabilization In Contaminated Soil: A Critical Review, Sara Perl Egendorf, Peter M. Groffman, Gerry Moore, Zhongqi Cheng

Advanced Science Research Center

This review article focuses on lead (Pb), one of the most ubiquitous and harmful toxicants found in soil. Our objective is to address misconceptions regarding the ability of plants to uptake Pb through their roots and translocate it to above-ground tissues, and their ability to act as hyperaccumulators and thereby phytoextract Pb. In accordance with a number of cited definitions, we suggest that species capable of Pb phytoextraction can be rated with the following three criteria: (1) root uptake above a nominal threshold of 1,000 mg Pb/kg, (2) bioconcentration factor (BCF or shoot/soil concentration) >1, and (3) translocation factor (TF …

Development Of A Synthesis Method For O2-Releasing Compound For Microbiological Experiments, Danae Greco

Williams Honors College, Honors Research Projects

Many celestial bodies within our solar system may have habitable environments due to the presence of liquid water. Europa, one of Jupiter’s moons, may be habitable because of its liquid ocean and other potentially biologically favorable conditions. The ocean on Europa is hypothesized to contain large amounts of oxidants and low pH due to the radiolytically processed icy ocean shell. This suspected environment on Europa is similar to the composition of acid mine drainage on Earth, which can house microbial communities in environments of extreme acidity. Similar chemical reactions in Europa’s ocean may occur to produce the appropriate reduction-oxidation gradients …

Relating Recharge Mechanisms To Chemical Changes In An Updip Appalachian Coal Mine Discharge: A Case Study From Lambert Run, West Virginia, Matthew Lewis Bell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Impaired drainage from active and abandoned mines degrades the water quality of receiving streams and aquifers. Coal mine drainage (CMD) has been studied for decades in Appalachia, but unknowns and uncertainties are still present, including the influence of mine hydrogeology on the outflow chemistry of above-drainage mines. To evaluate the influence of recharge type on above-drainage mine chemistry, samples were collected every two weeks at a CMD outflow treatment system in Harrison County, West Virginia.

Samples were collected to measure geochemical changes taking place in the mine workings and along the flowpath of the passive treatment system. Samples were divided …

Geochemical Constraints On Mantle Sources And Basalt Petrogenesis In The Strait Of Sicily Rift Zone (Italy): Insights Into The Importance Of Short Lengthscale Mantle Heterogeneity., John C. White, David A. Neave, Silvio G. Rotolo, Don F. Parker

EKU Faculty and Staff Scholarship

Igneous activity from the late Miocene to historic time (most recently 1891 ce) in the Strait of Sicily has created two islands (Pantelleria and Linosa) and several seamounts. These volcanoes are dominated by transitional (ol+hy-normative) to alkaline (ne-normative) basaltic lavas and scoriae; peralkaline felsic rocks (trachyte-rhyolite) crop out only on Pantelleria. Although most likely erupted through continental crust, basalts demonstrate no evidence of crustal contamination and are geochemically similar to oceanic island basalts (OIB). Despite their isotopic similarities, there are considerable compositional differences with respect to major and trace element geochemistry both between and within the two islands that are …

Model-Based Estimates Of The Timing Of Brine Flux Into The Victoria Land Basin From The Mcmurdo Dry Valleys, Antarctica, Valerie Nicole Voisin

Graduate Research Theses & Dissertations

Submarine groundwater discharge (SGD) at a continental scale is one of the least constrained components of the hydrologic cycle and may represent a significant flux of iron and silica waters to the global ocean. Quantifying SGD along the Antarctic margin is complicated by complex subglacial and subsurface hydrogeology and limited observational data. Airborne transient electromagnetic (AEM) surveys have identified extensive high-salinity subsurface brines in the McMurdo Dry Valleys (MDV) that are hydrologically connected to surface features in the MDV (e.g. Taylor Glacier, saline lakes) and are potentially a significant source of SGD to McMurdo Sound. A 2D numerical model was …

Copper And Gold In Vapors And Liquids As A Function Of Hcl At 700°C And 100 Mpa, Corrie A. Lucchesi

Graduate Research Theses & Dissertations

Porphyry ore deposits are major sources of copper (Cu) and gold (Au) and form when a magmatic volatile phase (MVP) exsolves from a porphyritic intermediate to felsic melt and transports metals to surrounding country rock where they precipitate in an ore zone. There is a consensus that the chloride concentration of the MVP has a direct relationship to the concentration of Cu and Au in the MVP, but the role of dissolved HCl on Cu and Au concentrations has not been addressed. It is hypothesized that increasing HCl concentrations in the MVP will result in higher concentrations of Cu and …

Water Sourcing Strategies Of Highly Resilient Vegetation In Desert Soils: Stable Isotope Analysis Of A Northern Chihuahuan Desert Ecosystem, Hayden Eleanor Thompson

Open Access Theses & Dissertations

Plant water use strategies and water transport dynamics are important for understanding ecosystem productivity and soil-vegetation-atmosphere interactions within an environment (Li et al., 2007). Recent research using stable isotope analysis in wet and humid climates has found that vegetation uses tightly particle-bound water stored in the soil that does not participate in translatory flow (Brooks et al., 2010; Goldsmith et al., 2011; McDonnell 2014). In arid and semi-arid deserts of the United States, highly resilient vegetation, such as the Honey Mesquite (Prosopis glandulosa) and the Creosote shrub (Larrea tridentata), exhibit some degree of activity year-round despite limited water availability during …

Uranium Series Dating And Geochemistry Of Fault Zone Precipitated Secondary Carbonates: Insights Into Paleo Fluid Sources, Tectonics And Climate In The Rio Grande Rift, Victor Higareda Garcia

Open Access Theses & Dissertations

Fault zones in the shallow crust impact a variety of geological processes including mineral deposition, fluid flow patterns in shallow and deep groundwater aquifers, and most importantly seismic activity. The specific interplays of fault zones, seismicity, and groundwater flows are complex and not well understood despite the importance they have to society. The Rio Grande rift is a region impacted by seismic and volcanic activity that place the first order control on mineral formation and fluid flow patterns. It is also a region that is often disregarded as a seismic hazard due to its inferred low tectonic rates and long …

Anatomy Of The Magmatic Plumbing System Of Los Humeros Caldera (Mexico): Implications For Geothermal Systems., Federico Lucci, Gerardo Carrasco-Nuñez, Federico Rossetti, Thomas Theye, John C. White, Stefano Urbani, Hossein Azzizi, Yosihiro Asahara, Guido Giordano

EKU Faculty and Staff Scholarship

Understanding the anatomy of magma plumbing systems of active volcanoes is essential not only for unraveling magma dynamics and eruptive behaviors but also to define the geometry, depth, and temperature of the heat sources for geothermal exploration. The Pleistocene–Holocene Los Humeros volcanic complex is part of the eastern Trans- Mexican Volcanic Belt (central Mexico), and it constitutes one of the most important exploited geothermal fields in Mexico with ca. 90MWof produced electricity. With the aim to decipher the anatomy (geometry and structure) of the magmatic plumbing system feeding the geothermal field at Los Humeros, we carried out a field-based petrological …

Investigating Diel, Seasonal, And Interannual Variability Of Dissolved And Particulate Stable Carbon Isotope Values In A Eutrophic Boreal Lake, Rachel Henderson

Theses and Dissertations (Comprehensive)

Lakes are globally significant sources, sinks, and conduits of carbon. Cultural eutrophication of freshwater promotes the growth of phytoplankton blooms, which can transform, respire, and sequester large amounts of carbon. Analysis of stable carbon isotopes is a common tool to study the movement of carbon through the aquatic carbon cycle. The causes of temporal variability in δ¹³C values at different timescales are not well understood, and differ between lakes. In this study, I investigated diel, seasonal, and interannual variability in δ¹³C values of dissolved inorganic carbon (DIC) and particulate organic carbon (POC) in Lake 227, an …

Reconstructing Hydrologic Conditions And Metals Supplied By The Peace River To The Peace-Athabasca Delta, Jelle André Faber

Theses and Dissertations (Comprehensive)

The Peace-Athabasca Delta (PAD) in northern Alberta, Canada, is recognized internationally for its ecological, historical, and cultural significance. The delta is mostly within Wood Buffalo National Park, a UNESCO World Heritage Site, and is a Ramsar Wetland of International Importance. The construction of the WAC Bennett Dam (1967) and the Site C Dam (ongoing, 2024) on the Peace River, and expansion of the Alberta Oil Sands industry along the Athabasca River have raised concerns over water quantity and quality in the delta. When industry operations began, effective monitoring had not been implemented. Consequently, pre-industrial reference conditions are unknown and can …

Groundwater Investigations To Support Irrigated Agriculture At La Grange, Western Australia: 2013–18 Results, Robert J. Paul, Gregory Paul Raper, Richard J. George Dr, Nicholas J. Wright, Adam M. Lillicrap, Peter S. Gardiner

Resource management technical reports

The Broome Sandstone aquifer is the main aquifer and groundwater resource in the La Grange area, near Broome in the West Kimberley, Western Australia. Land use is dominated by cattle grazing on pastoral stations, dispersed mining and tourism. Irrigated agriculture has developed at a small scale, with about 470 hectares under cultivation in 2014. Groundwater abstraction is licensed under the La Grange groundwater allocation plan (Department of Water 2010) and managed by the Department of Water and Environmental Regulation. The La Grange groundwater allocation area is split into the La Grange North subarea and La Grange South subarea, with groundwater …

Temporal And Spatial Scales Of Correlation In Marine Phytoplankton Communities, A. M. Kuhn, S. Dutkiewicz, O. Jahn, Sophie Clayton, T. A. Rynearson, M. R. Mazloff, A. D. Barton

OES Faculty Publications

Ocean circulation shapes marine phytoplankton communities by setting environmental conditions and dispersing organisms. In addition, processes acting on the water column (e.g., heat fluxes and mixing) affect the community structure by modulating environmental variables that determine in situ growth and loss rates. Understanding the scales over which phytoplankton communities vary in time and space is key to elucidate the relative contributions of local processes and ocean circulation on phytoplankton distributions. Using a global ocean ecosystem model, we quantify temporal and spatial correlation scales for phytoplankton phenotypes with diverse functional traits and cell sizes. Through this analysis, we address these questions: …