Geochemistry Commons^™

Augmenting Field Nuclear Forensics Capabilities With Handheld Atomic Spectroscopy Devices For Nuclear Debris Analysis, Ashwin P. Rao, Christopher M. Sutphin, Christina L. Dugan

Faculty Publications

The realm of technical nuclear forensics remains a critical part of joint counterproliferation capabilities. Since the passage of the Nuclear Forensics and Attribution Act (H.R.730) in 2010, the nuclear science community has undertaken steps to bolster national nuclear forensics capabilities under the National Technical Nuclear Forensics Center. Within the technical nuclear forensics umbrella, one particular area of interest involves developing capabilities for in-field analysis of nuclear material. This includes engaging in field training exercises across relevant branches of the military and investigating new technologies to conduct field nuclear forensic analyses. The integration of novel analytical technologies into real-world nuclear detection …

Contrasting Styles Of Inter-Caldera Volcanism In A Peralkaline System: Case Studies From Pantelleria (Sicily Channel, Italy), Pierangelo Romano, John C. White, Silvio G. Rotolo, Nina J. Jordan, Rosolino Cirrincione, Giovanni De Giorgio, Patrizia Fiannacca, Epifanio Vaccaro

EKU Faculty and Staff Scholarship

The recent (<190 ka) volcanic history of Pantelleria is characterized by the eruption of nine peralkaline ignimbrites, ranging in composition from comenditic trachyte to comendite to pantellerite. The ~46 ka Green Tuff (GT) was the last of these ignimbrites, which was followed by many effusive and explosive low-volume eruptions of pantellerite from vents within the caldera moat and along the caldera rim. Although recent studies have shed additional light on the age, petrochemistry, and volcanology of the older ignimbrites, there is very little knowledge of magmatism that occurred between these older ignimbrites, primarily due to the very scarce exposures. In this paper, we present new field descriptions and geochemical data for three local peralkaline centers never studied before, two pre-GT and one post-GT, which share a similar setting with respect to the caldera scarps but differ in terms of their age, composition, and eruptive style. These centers include: (i) the older (~125 ka) Giache center (comenditic trachyte), (ii) the ~67 ka Attalora center (comendite, pantellerite), and (iii) the younger (~14 ka) Patite center (pantellerite).

Stratigraphic And Geochemical Evaluation Of Distal Flows Of The Columbia River Flood Basalts In The Greater Vale Area, Southeastern Oregon, Lena Marie Fox

Dissertations and Theses

Exposures of Columbia River Basalt Group (CRBG) in southeastern Oregon are dominated by the four main phase CRBG units: Steens Basalt, Imnaha Basalt, Grande Ronde Basalt (GRB), and Picture Gorge Basalt (PGB). These units are best seen in stratigraphic sequence along the Malheur Gorge corridor of southeastern Oregon, between the towns of Vale and Juntura, with flows of Steens Basalt from the south overlain by flows of Imnaha and GRB from the north. Recently, PGB flows were found to be part of the eastern Malheur Gorge stratigraphy as well.

In Malheur Gorge, local units of Birch and Hunter Creek Basalt …

Geologic Homogenization, Conditioning, & Reuse, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about the Energy & Environmental Research Center project to evaluate the geologic homogenization, conditioning, and reuse (GHCR) concept of water management. Describes the GHCR concept and summarizes results of the multiyear project.

Exceptional Agate Formation Found In Spokane Basalt, Matthew J. Markus

2022 Symposium

People don’t normally associate semi-precious gems with basalt or the “boring black rock” that dominates the Eastern Washington landscape. However, a site just northeast of Cheney in the West Planes of Spokane, shows where a system of gem-filled veins can be found nestled into the 16-million-year-old (Kasbohm and Schoene, 2018) Priest Rapids Member of the Wanapum Basalt that is a part of the greater Columbia River Basalt. The volcanic rocks are the host to millimeter - 10 cm wide fractures with variable colored agate and opal.

Mining-Contaminated Sediment And Metal Storage In Channel Deposits In Turkey Creek, Tri-State Mining District, Missouri And Kansas, Max Quinn Hillermann

Graduate Theses/Dissertations

The Joplin subdistrict, within the Tri-State Mining District (TSMD), was a major producer of lead (Pb) and zinc (Zn) ore between the 1880s to 1920s. Metalliferous mining wastes are still stored in the channel deposits of local streams raising environmental and health concerns. This study quantifies the volume, sediment size, and metal concentrations in channel bed, bar, bench, and chute deposits to quantify the spatial variability of contaminated sediment storage in Turkey Creek (119 km²). Sample reaches (n=14) contained metal concentrations elevated above the Tri-State Mining District specific probable effects concentration at every site with mean concentrations in …

Aucanquilcha Volcanic Cluster Magma Evolution And Magma Plumbing System Architecture During The Gordo Stage (6-4 Ma), Kasey Lynn Buckley

Graduate Theses/Dissertations

Aucanquilcha Volcanic Cluster (AVC) is an 11 m.y. volcanic system in the central Andes that is evolving over four distinct stages of activity. Stages include the Aloncha (11-8 Ma), Gordo (6-4 Ma), Polán (4-2 Ma), and Aucanquilcha (Ma) stages. The AVC evolved from a series of magmatic underpinnings during the Aloncha Stage to a larger zone of melting, assimilation, storage, and homogenization (MASH) by the Polán Stage. The transition from smaller underpinnings to MASH zones began during the Gordo Stage. At ~5-2 Ma the AVC reached thermal maturity before beginning its volcanic death during the Aucanquilcha Stage. This study focuses …

Disequilibrium Melting Of The Continental Crust During Emplacement Of The Mt. Princeton Batholith, Central Colorado Volcanic Field, Loren A. Bohannon

Graduate Theses/Dissertations

Assimilation and crystallization are difficult to constrain at magmatic boundaries, including the interactions of magma with the surrounding country rock. The assumption of the relationship between a magma and what it is intruding upon is relegated to homogenous bodies or epizonal plutons. Realistically, wall rock influences chemical heterogeneity and isotopic variance at the outcrop scale and changes depending on distance from the magma-wall rock interface. Here, we present a case study of the 35 Ma Mt. Princeton Batholith and the host Precambrian rocks of the Central Colorado Volcanic Field. We assess chemical heterogeneity by whole rock and mineral trace element …

Evaluating Holocene Precipitation Variability In The Baltic Region Using Oxygen Isotopes Of Lacustrine Carbonate From Estonia, Maxwell Gordon Boes

Graduate Research Theses & Dissertations

A high-resolution Holocene record of groundwater isotopic composition from eastern Europe enhances the current understanding of ocean atmosphere interactions and moisture transport dynamics. In the modern system, it has been established that the amount of regional winter precipitation is driven by the strength and direction of the sea level atmospheric pressure gradient over the Atlantic Ocean. This is defined by the North Atlantic Oscillation (NAO) index, that shows a positive correlation with precipitation amount during the cold season. This study aims to discover the link between atmospheric dynamics and the ratio of warm season to cold season precipitation through the …

Spatial Geochemical Changes In Central And East Texas Soils Over Time Resulting From Human Decomposition, Isabela Marisol Overturf

CMC Senior Theses

Human decomposition is studied to aid forensic investigations and better understand the impact of cemeteries on urban resources like soil and groundwater. The purpose of this study was to identify changes in soil geochemistry at and around a human grave to search for lateral nutrient movement and possibly identify new patterns in elemental concentrations that could be used in estimating post-mortem intervals (PMIs). At the Forensic Anthropology Research Facility (FARF) at Texas State San Marcos, soil samples were collected from a shallow grave over the course of 54 days to conduct analysis for organic matter content, texture, pH, and bulk …

Using Triple Oxygen Isotopes To Reveal The Origin And Evolution Of Mantle Eclogite, Catherine Mary Peshek

Earth and Planetary Sciences ETDs

Triple oxygen isotope (TOI) measurements of mantle eclogite from the Orapa kimberlite pipe have reconstructed bulk rock '18O values from 4.587 to 9.542‰ (vs. VSMOW) and '17O from -0.075 to -0.044‰ (vs. VSMOW,  ~0.528). TOI values show increasing '18O with decreasing '17O, overlapping with modern measured altered oceanic crust. Orapa eclogite xenoliths with alkali enrichments show variable mantle-like and heavy 18O, consistent with subduction of seafloor altered basalt. Na# (Na/Na+Ca) in clinopyroxene for some xenoliths pairs with mantle-like oxygen, variable and extreme LREE enrichment, elevated Mg# and lower jadeite contents. These samples preserve records of eclogite melting, mantle interaction …

Stable Isotope Analysis Of A Platecarpus Tympaniticus (Squamata, Mosasauridae) With Actinocamax Sternbergi (Mollsuca, Belemnoidea) Reveals Possible Endothermic Thermoregulation, Mitchell Lukens

Master's Theses or Doctor of Nursing Practice

Mosasaurs, ancient marine reptiles, dominated the late Cretaceous oceans. However, their ecological success is a contentious topic. Were they ectothermic, like their modern relatives the varanid lizards? Or endothermic like extant marine mammals? Stable isotopes can reveal temperature and physiological variances within skeletons, but do not differentiate between body temperature and ambient environmental temperature. A rare mosasaur specimen from the Smoky Hill Chalk of a partial, articulated Platecarpus tympaniticus with stomach contents of belemnites provides a possible direct temperature contrast between predator and prey. The belemnites, related to modern coleoids, are identified as Actinocamax sternbergi. These animals possessed body …

Using Geochemical Composition To Determine Paleo Environmental Conditions And Source Inputs In Paleozoic Rocks Within The Central Kansas Uplift Usa, Christiana Fumnanya Eziashi

Master's Theses or Doctor of Nursing Practice

Paleoenvironmental conditions, sediment characteristics and lateral continuity using chemostratigraphy are not well established for stratigraphic units associated with some small fields within the Central Kansas Uplift (CKU). Samples of drill cuttings recovered from six wells (Hottman #1, and Hottman-Furthmeyer#1, Yocemento #1, Mong Benno #2, Rhian #3 and Worcester #1) at 10 ft intervals between 3150 ft and 3900 ft below ground level, were processed and analyzed using X-ray fluorescence (XRF) and X-Ray diffraction (XRD). The XRF technique was used to determine elemental compositions, and XRD was used to determine mineral content. The composition of the rock cuttings was used to …

Validation Of The Use Of Clathromorphum Compactum Growth And Skeletal Δ18o As A Proxy For Seawater Conditions, Teagan Mcmahon

Pitzer Senior Theses

Crustose coralline algae (CCA) are important organisms that create benthic habitat in the photic zone of oceans worldwide. CCAs mechanisms of photosynthesis and calcification may, in some cases, make them vulnerable to climate change and ocean acidification. Therefore, CCA are important not only for their ecological role within ecosystems but also for their ability to indicate the effects that ocean acidification and climate change may have on other marine calcifying organisms. Some species of CCA are known to be useful recorders of paleo oceanic conditions. These climate archives and reconstructions of past environmental conditions are important for understanding past changes …

Distribution Of Particulate Organic Carbon – Fluxes And Inventories – In Growth-Faulted Coastal Wetlands, Samuel Joel Whitehead

Theses and Dissertations--Earth and Environmental Sciences

Coastal wetlands along the Northern Gulf of Mexico (NGOMx) are critically important but threatened environments which provide significant and diverse economic, social, and environmental value. These environments are essential components to the global carbon cycle, serving as one of the most efficient terrestrial carbon sinks. Since onset of the Industrial Revolution increasing rates of coastal wetland loss have been documented due to a variety of anthropogenic activities, neotectonic processes, subsidence, and rising sea-levels. This research utilized an array of methods and sedimentological analyses to test the hypothesis that growth-fault induced changes at Earth’s surface affects the delivery to, and storage …

U-Pb Apatite Chronometry Of Intrusions In An Accretionary Metamorphic Belt In Western Idaho, Usa, Colleen Grace Rankin

Graduate Theses/Dissertations

The Salmon River suture zone in west-central Idaho, USA records the tectonic processes where island arcs, similar to modern-day Japan, were accreted to the North American continent in the Jurassic and Cretaceous periods (160-90 million years ago). This suture zone contains metamorphic rocks that were buried deep within the crust at depths of 20 kilometers or more and have subsequently been brought to the surface. The exhuming processes responsible for the metamorphic rocks in the Salmon River suture zone remains unclear. Two competing hypotheses have been proposed to explain the transport of the rocks from the Salmon River suture zone …

Downstream Dispersal Of Fine Tailings, Chat And Metals In Channel Sediment Of Big River, Old Lead Belt, Southeast Missouri, Jennifer Pace Witt

Graduate Theses/Dissertations

In St. François County, Missouri, compromised above-ground tailings piles and containment ponds from historical mining activities in the Old Lead Belt released considerable amounts of dolomitic, Pb- and Zn-contaminated waste sediments to the Big River, contributing to significant downstream floodplain and channel sediment contamination. Previous studies have documented the effects of heavy metals on Big River biota and water quality, as well as benthic habitat disruption resulting from the influx of small sediments. Few have considered the effects and future contamination risk of the coarse waste sediments (2-16 mm in diameter), locally called “chat”, which retain high Pb and Zn …

Chemical And Thermal Influence On Intermediate Magma Storage Conditions: Volcán Ollagüe, Chile-Bolivia, Central Andes, Drew Allen Laviada-Garmon

Graduate Theses/Dissertations

Continental arc volcanoes are the single best portrayal of the evolution of recycled earth material stemming from subduction, one of the most important and foundational phenomena in global tectonics. Understanding the genesis of intermediate-composition magmas produced at arc volcanoes is a difficult process making them a focal point for investigation. Geochemical investigation of zircon and plagioclase mineral phases erupted from continental arcs can provide insight into magma process, generation, storage conditions, timescales and differentiation of sub-volcanic plumbing systems prior to eruption events. The Central Volcanic Zone is a prime example of continental arc volcanism through subduction, and is host to …

Defining The Endmember System Of Us Soils And Quantifying Relationships, And A Hyperspectral Approach To The Alteration Strength Index, Rachel Rulison

Dissertations, Master's Theses and Master's Reports

Soils form a complex part of the environment, providing important functions in systems such as food production, groundwater movement, and ecosystem health. There have been numerous studies on soil geochemistry and the origin of elements within soils, but few studies into quantifying the relationships between elements and geographical data on a national scale. Using geochemical data obtained by the USGS, the surficial soils of the US were defined by a 13-endmember system using Polytopic Vector Analysis and mapped in GIS. Correlation matrices provided Pearson’s correlation coefficients for elements in the Top 5 cm soil profile, the A horizon, and the …

Determining Spatial Controls On Snow Isotopic Signature And Tracing The Snowmelt Pulse As It Moves Through Two Montane Catchments, Jenna K. Rolle

Graduate Student Theses, Dissertations, & Professional Papers

In this study, we investigate the spatial and temporal distribution of stable isotopes of oxygen and hydrogen in water across two mountainous catchments in west-central Montana to trace the input of snow to local soil, bedrock aquifers, and streams. Snowpack and snowmelt samples were collected throughout the winter season at ten sites selected to encompass a range of elevation, aspect, slope angle and hillslope position. Soil and bedrock wells at five of the ten sites were sampled after the initial snowmelt pulse and stream samples were collected weekly at the outlets of both catchments to trace the timing and partitioning …