Polymer Chemistry Commons^™

Polymers For Dna Binding, Sue Yuan Li

Seton Hall University Dissertations and Theses (ETDs)

.

Experimenting With Polymer Blend Solar Cells And Active Layer Thickness, Ryan Blumenthal

Physics

Bulk heterojunction organic photovoltaics utilize the electrical characteristics of semi-conductive polymers. These solution processable materials are beneficial because of their low material cost, light weight, and simple fabrication requirements. Our devices employ multiple photoactive polymers, P3HT and PCPDTBT, to absorb photons over a wide spectral range. We optimized various device characteristics including thickness and thermal anneal usage to reach a power conversion efficiency of 3.0% in AM1.5 sunlight. Device performance degrades over time due to atmospheric water and oxygen, prompting us to investigate device packaging to extend cell lifetime for additional testing.

Molecularly Woven Materials From Metal-Organic Precursors, Gellert Mezei, Jaafar Hachem, Isurika R. Fernando, Natasha R. Wadhwa, Neil C. Hughes

Faculty Research and Creative Activities Award (FRACAA)

No abstract provided.

Hideki Shirakawa: Synthesized Counductive Polymers, Erika Rosenberger

Natural Sciences Student Research Presentations

Hideki Shirakawa discovered how to create polyacteylene thin films by accidentally adding extra Zieglar-Natta catalyst. this led him to discovering conductive polymers by using a technique called chemical doping, which oxydizes polyacetylene. This is a project for the Natural Sciences Poster Session at Parkland College.

Studies Of Functionalized Nanoparticles For Smart Self-Assembly And As Controlled Drug Delivery, Xiaochu Ding

Dissertations, Master's Theses and Master's Reports - Open

This dissertation is related to the studies of functionalized nanoparticles for self-assembly and as controlled drug delivery system. The whole topic is composed of two parts. In the first part, the research was conducted to design and synthesize a new type of ionic peptide-functionalized copolymer conjugates for self-assembly into nanoparticle fibers and 3D scaffolds with the ability of multi-drug loading and governing the release rate of each drug for tissue engineering. The self-assembly study confirmed that such peptide-functionalized amphiphilic copolymers underwent different self-assembly behavior. The bigger nanoparticles were more easily assembled into nanoparticle fibers and 3D scaffolds with larger pore …

Analysis And Simulation Of Kinetic Model For Active Suspensions, Panon Phuworawong

Mathematics & Statistics Theses & Dissertations

In this research, we study the recently proposed kinetic model for active suspensions, where the active particles are assumed to be rigid rod and are driven in the suspension either by their own biological/chemical forces or external electric/magnetic fields. We first study the stability of the isotropic suspension in quiescent flow. Then we investigate the weak shear perturbation of the isotropic state and study some rheological properties of the suspension by explicit analytic formulas derived directly from the model. For imposed shear, we give some bifurcation diagrams of the stable states in some parametric spaces through numerical simulations. Some rheological …

Fluorinated Arene, Imide And Unsaturated Pyrrolidinone Based Donor Acceptor Conjugated Polymers: Synthesis, Structure-Property And Device Studies, Arawwawala Don T. Liyanage

Theses and Dissertations--Chemistry

FLUORINATED ARENE, IMIDE AND LACTAM-FUNCTIONALIZED DONOR ACCEPTOR CONJUGATED POLYMERS: SYNTHESIS, STRUCTURE-PROPERTY AND DEVICE STUDIES

After the discovery of doped polyacetylene, organic semiconductor materials are widely studied as high impending active components in consumer electronics. They have received substantial consideration due to their potential for structural tailoring, low cost, large area and mechanically flexible alternatives to common inorganic semiconductors. To acquire maximum use of these materials, it is essential to get a strong idea about their chemical and physical nature. Material chemist has an enormous role to play in this novel area, including development of efficient synthetic methodologies and control the …

Characterizing Interactions Between Chromophores In Synthetic And Natural Macromolecular Films Via Maldi-Tof, Ibf And Dielectric Analyzer, Parul Jain

USF Tampa Graduate Theses and Dissertations

With the emergence of Matrix Assisted Laser Desorption/Ionization-Time-of-flight as a tool for diagnosis of diseases via proteomics, there is an increasing need for greater sensitivity. Analysis of peptides by MALDI-TOF-MS is affected by sample formulation and spotting onto a MALDI target. This dissertation investigates a novel MALDI sample preparation technique, Induction Based Fluidics (IBF), for depositing precise volumes (pL to nL) of samples onto the target. We have seen that while using IBF, the induced electric field accompanying deposition enhances matrix crystallization yielding smaller crystals with more homogeneity, as compared to conventional manual micropipette (MP) depositions. An investigation of the …

Ultra-Stable Protein-Polymer Bioconjugates, Kyle S. Cole

Master's Theses

No abstract provided.

The Effects Of Color Concentrates On The Rheology Of Tint Bases, Doug James Herrick

Master's Theses

ABSTRACT

THE EFFECTS OF COLOR CONCENTRATES ON THE RHEOLOGY OF TINT BASES

Douglas James Herrick

Waterborne coatings are formulated with a number of different ingredients; water, latex polymers, pigments, surfactants, dispersants, defoamers, biocides, coalescing aids, and rheology modifiers or thickeners. Rheology modifiers are necessary in order to improve the physical properties of the coating before, during, and after application to a substrate. There are two kinds of rheology modifiers used in waterborne coatings; associative thickeners and non-associative thickeners. Coatings formulated with associative thickeners are quite sensitive to coating variations; the slightest change in the formulation has profound effects on the …

In Situ Measurements Of Electron-Beam-Induced Surface Voltage Of Highly Resistive Materials, Joshua Hodges

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Surface charging and subsequent electrostatic discharge due to interactions with the space environment is one of the primary concerns of spacecraft charging studies. Laboratory measurements of the evolution of surface voltages and dissipation currents under simulated space conditions are the primary method used to determine the response of key spacecraft materials to diverse incident fluxes. Increasing the database of information for the electronic properties of insulating materials can assist spacecraft designers in mitigating the harsh effects of the space environment.

The Utah State Materials Physics Group, with the funding of the NASA James Webb Space Telescope project and personnel support …

Controlling Nanoparticle Dispersion For Nanoscopic Self-Assembly, Nathan S. Starkweather

Master's Theses

Nanotechnology is the manipulation of matter and devices on the nanometer scale. Below the critical dimension length of 100nm, materials begin to display vastly different properties than their macro- or micro- scale counterparts. The exotic properties of nanomaterials may trigger the start of a new technological revolution, similar to the electronics revolution of the late 20^th century. Current applications of nanotechnology primarily make use of nanoparticles in bulk, often being made into composites or mixtures. While these materials have fantastic properties, organization of nano and microstructures of nanoparticles may allow the development of novel devices with many unique properties. …

Understanding Corrosion Protection And Failure Through Model Polymers In Thin Films, Joshua Smith Hanna

Dissertations

When developing a model polymeric system to facilitate in the detection of molecular and microscopic events that preface macroscopic corrosive failure; a better understanding of how polymers can indicate corrosion was accomplished. Initially, the thought that molecular chain scission as a necessity for corrosion to occur had to be tested. Through the utilization of high molecular weight thermoplastic (HMWTP) model polymers, it was found that corrosion protection did not correlate to the quantity of weak bonds within an epoxy-amine polymer matrix. Therefore more sensitive methods of detecting corrosion had to be developed since changes within the polymer matrix did not …

Polymer Surface Engineering Via Thiol-Mediated Reactions, Ryan Matthew Hensarling

Dissertations

Synthesis of polymer brushes to decorate a surface with desired functionality typically involves surface-initiated polymerization (SIP) of functional, but non-reactive monomers. This approach suffers major drawbacks associated with synthesizing sufficiently thick polymer brushes containing surface-attached polymer chains of high molecular weight at high grafting density (i.e. cost, synthetic effort and functional group intolerance during polymerization). The research herein seeks to circumvent these limitations by the decoration of surfaces with polymer chains bearing specific pendent functional groups amenable to post-polymerization modification (PPM). In particular, this dissertation leverages PPM via a specific class of click reactions – thiol-click – that 1) enables …

Synthesis And Characterizations Of Pyridinium Salts Including Poly(Pyridinium Salt)S And Their Applications, Tae Soo Jo

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pyridinium salts, both molecular and polymeric, are an interesting class of multifunctional materials that exhibit liquid-crystalline and light-emitting properties. Moreover, their properties can be easily tuned by introducing new types of anions or by modifying their chemical structures. This dissertation describes synthesis and characterization of poly(pyridinium salt)s containing macrocounterions and fluorene moieties in their backbones, synthesis and characterization of nanocomposites of poly(pyridinium salt)s with single-walled carbon nanotubes via non-covalent interactions, and synthesis and characterizations of pyridinium salts having different aliphatic linkages and their application in organic acid sensing.

First, all of these ionic polymers were prepared by either ring-transmutation or …

Synthesis, Structure And Attempted Polymerization Of A Diepoxide Macrocycle, Paul Yarincik, Jeffrey H. Glans

Chemistry & Physics Faculty Publications

A novel diepoxide containing paracyclophane was synthesized by peracid oxidation of a known paracyclophane diene. The resulting diepoxide was characterized. It was investigated as a potential monomer for a cyclophane containing polyether by cationic ring opening polymerization. None of the standard catalyst systems for such a polymerization were successful in producing polymer.

Magnesium-Based Sacrificial Anode Cathodic Protection Coatings (Mg-Rich Primers) For Aluminum Alloys, Shashi S. Pathak, Sharathmukar K. Mendon, Michael D. Blanton, James W. Rawlins

Faculty Publications

Magnesium is electrochemically the most active metal employed in common structural alloys of iron and aluminum. Mg is widely used as a sacrificial anode to provide cathodic protection of underground and undersea metallic structures, ships, submarines, bridges, decks, aircraft and ground transportation systems. Following the same principle of utilizing Mg characteristics in engineering advantages in a decade-long successful R&D effort, Mg powder is now employed in organic coatings (termed as Mg-rich primers) as a sacrificial anode pigment to protect aerospace grade aluminum alloys against corrosion. Mg-rich primers have performed very well on aluminum alloys when compared against the current chromate …

Anti-Corrosion Performance Of Primer And Top Coat Formulations For Metal Substrates, Laural Elizabeth Hargrove

Master's Theses

This project involved the improvement of several properties of the current “universal” primer coating sold by Kelly-Moore Paint Company. This formulation is an all purpose primer used both for interior and exterior applications. However, its corrosion resistance has room for improvement. The addition of sodium nitrite, an aminocarboxylate salt, and a zinc phosphate-based additive were all tested as corrosion inhibitors. In addition, during the project the coating binder was changed to improve adhesion. After a systematic experimental program, a new “universal” primer with increased corrosion resistance and adhesion was formulated.

A direct to metal top coat formulation sold by Kelly-Moore …

A Review On The Visible Light Active Titanium Dioxide Photocatalysts For Environmental Applications, Miguel Pelaez, Nicholas Nolan, Suresh Pillai, Michael Seery, Polycarpos Falaras, Athanassios G. Kontos, Patrick S.M. Dunlop, Jeremy W.J. Hamiltone, J. Anthony Byrne, Kevin O’Shea, Mohammad H. Entezari, Dionysios D. Dionysiou

Articles

Development of visible light active (VLA) titania photocatalysts

Fujishima and Honda (1972) demonstrated the potential of titanium dioxide (TiO 2) semiconductor mate-rials to split water into hydrogen and oxygen in a photo-electrochemical cell. Their work triggered the development of semiconductor photocatalysis for a wide range of environmental and energy applica-tions. One of the most significant scientific and commercial advances to date has been the development of visible light active (VLA) TiO2 photocatalytic materials. In this review, a background on TiO2 struc-ture, properties and electronic properties in photocatalysis is presented. The development of different strategies to modify TiO2 for the utilization …

Immobilized Bis-Indenyl Ligands For Stable And Cost-Effective Metallocene Catalysts Of Hydrogenation And Polymerization Reactions, Thomas Max Simerly

Electronic Theses and Dissertations

Reactions of catalytic hydrogenations and polymerizations are widely used in industry for manufacture of fine chemicals, pharmaceuticals, and plastics. Homogeneous catalysts for the processes that have low stability and their separation is difficult. Therefore, the development of new highly active and stable catalysts for hydrogenations and polymerizations is a necessity. The objective of this research was the development of a strategy for immobilization of heterogeneous metallocene catalysts. First, a methodology of immobilization of bis-indenyl ligands on the surface of mesoporous silica gel was designed. Four bis-indenyl ligands containing functionalized tethers of various lengths with terminal alkene groups were synthesized. All …