Metabolomics Reveal Size-Dependent Impacts Of Cerium Oxide Nanoparticles On Grains Of Barley (Hordeum Vulgare L.),
2022
Missouri State University
Metabolomics Reveal Size-Dependent Impacts Of Cerium Oxide Nanoparticles On Grains Of Barley (Hordeum Vulgare L.), Naum Jepkemei Kirwa
Graduate Theses/Dissertations
Plants are exposed to emerging contaminants including nanoparticles, due to the novel but wide uses of these materials. However, researchers have shown contradicting effects of CeO2-NPs on barley grains with focus mostly on concentration effects and not sizes of these CeO2-NPs. Therefore, this study aimed at comparing the effects of 0nm (control), 8nm, and 40nm (250 mg CeO2-NPs/kg soil) on the metabolite profile of barley grains. GC-FID and GC-QTOF-MS were used to measure fatty acid contents and metabolomic changes respectively. GC-FID analysis revealed that palmitic acid, oleic acid, linoleic acid, and the total fatty …
Efficient Removal Of Lead Ions From Aqueous Media Using Sustainable Sources On Marine Algae,
2022
Old Dominion University
Efficient Removal Of Lead Ions From Aqueous Media Using Sustainable Sources On Marine Algae, Hannah Namkoong, Erik Biehler, Gon Namkoong, Tarek M. Abdel-Fattah
Electrical & Computer Engineering Faculty Publications
The goal of this project is to explore a new method to efficiently remove Pb(II) ions from water by processing Undaria pinnatifida into immobilized beads using sodium alginate and calcium chloride. The resulting biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS). Using immobilized U. pinnatifida, we investigated the effect of various factors on Pb(II) ion removal efficiency such as temperature, pH, ionic strength, time, and underlying biosorption mechanisms. For Pb(II) ion biosorption studies, Pb(II) ion biosorption data were obtained and analyzed using Langmuir and Freundlich adsorption models. It …
Scale-Up Of Flow-Electrode Capacitive Deionization Method For Hard Water Softening,
2022
The University of Akron
Scale-Up Of Flow-Electrode Capacitive Deionization Method For Hard Water Softening, Noah Henry
Williams Honors College, Honors Research Projects
This study’s purpose is to further document a capacitive deionization design that could be capable of purifying H2O at a household scale where clean water is otherwise unobtainable in applicable regions of the world. The hypothesis behind this study was continuously larger scaled electrochemical cell-units would increase their water softening capabilities in sustainable fashion. The trend at which performance will scale is currently unknown. The units studied were constructed using graphite plates, anion exchange membranes, cation exchange membranes, and Teflon channels. Three streams, two being CaCl2 solutions in DI H2O (one being concentrated with CaCl …
The Influence Of Hydrogen Peroxide On The Enrichment Of Fe(Iii) Reducing Bacteria From Acid Mine Drainage,
2022
The University of Akron
The Influence Of Hydrogen Peroxide On The Enrichment Of Fe(Iii) Reducing Bacteria From Acid Mine Drainage, Susami Seth
Williams Honors College, Honors Research Projects
It is hypothesized that the ocean of Europa, a Jupiter moon, hosts bacteria on its oceanic floor. Understanding how Fe(III) reducing bacteria (FeRB) from AMD utilize organic materials within its surrounding environment outlines how FeRB could thrive and tolerate extreme conditions. FeRB are known to tolerate metals and highly reactive oxidants species (ROS), but in this experiment, H2O2 was the experimental factor to further test FeRB tolerance. H2O2 is a common ROS and is damaging to living material such as proteins, DNA, and RNA. A range of H2O2 concentrations were fed …
On-Road Vehicle Emission Measurements And Their Use In Evaluating Emission Control Effectiveness {Presentation},
2022
University of Denver
On-Road Vehicle Emission Measurements And Their Use In Evaluating Emission Control Effectiveness {Presentation}, Gary A. Bishop
Fuel Efficiency Automobile Test Publications
No abstract provided.
Calcification, Dissolution And Test Properties Of Modern Planktonic Foraminifera From The Central Atlantic Ocean,
2022
Old Dominion University
Calcification, Dissolution And Test Properties Of Modern Planktonic Foraminifera From The Central Atlantic Ocean, Stergios D. Zarkogiannis, Shinya Iwasaki, James William Buchanan Rae, Matthew W. Schmidt, P. Graham Mortyn, George Kontakiotis, Jennifer E. Hertzberg, Rosalind E.M. Rickaby
OES Faculty Publications
The mass of well-preserved calcite in planktonic foraminifera shells provides an indication of the calcification potential of the surface ocean. Here we report the shell weight of 8 different abundant planktonic foraminifera species from a set of core-top sediments along the Mid-Atlantic Ridge. The analyses showed that near the equator, foraminifera shells of equivalent size weigh on average 1/3 less than those from the middle latitudes. The carbonate preservation state of the samples was assessed by high resolution X-ray microcomputed tomographic analyses of Globigerinoides ruber and Globorotalia truncatulinoides specimens. The specimen preservation was deemed good and does not overall explain …
Insights Into The Deglacial Variability Of Phytoplankton Community Structure In The Eastern Equatorial Pacific Ocean Using [231Pa/230Th]Xs And Opal-Carbonate Fluxes,
2022
Old Dominion University
Insights Into The Deglacial Variability Of Phytoplankton Community Structure In The Eastern Equatorial Pacific Ocean Using [231Pa/230Th]Xs And Opal-Carbonate Fluxes, Danielle Schimmenti, Franco Marcantonio, Christopher T. Hayes, Jennifer Hertzberg, Matthew Schmidt, John Sarao
OES Faculty Publications
Fully and accurately reconstructing changes in oceanic productivity and carbon export and their controls is critical to determining the efficiency of the biological pump and its role in the global carbon cycle through time, particularly in modern CO2 source regions like the eastern equatorial Pacific (EEP). Here we present new high-resolution records of sedimentary 230Th-normalized opal and nannofossil carbonate fluxes and [231Pa/230Th]xs ratios from site MV1014-02-17JC in the Panama Basin. We find that, across the last deglaciation, phytoplankton community structure is driven by changing patterns of nutrient (nitrate, iron, and silica) availability which, in …
Influence Of Dissolved Organic Matter On Phosphate Interactions With Hydrous Ferric Oxides,
2022
Wilfrid Laurier University
Influence Of Dissolved Organic Matter On Phosphate Interactions With Hydrous Ferric Oxides, Alaa Hasan Alsherbi
Theses and Dissertations (Comprehensive)
Phosphorus, iron oxides, and dissolved organic matter (DOM) are components present in all aquatic systems. Excess amounts of phosphorus in aquatic systems have the potential for toxic effects, in particular, contributing to eutrophication. Most of the previous studies performed looked at the surface complexation of inorganic phosphate anions (P) to mineral surfaces such as hydrous ferric oxide (HFO). However, the role of DOM on the interactions between HFO and P is unknown. This study investigates the influence of DOM on the surface complexation of P onto HFO surfaces. Moreover, this study looks at the possibility of cation bridging formation (Ca …
2021 West Los Angeles Data Summary,
2022
University of Denver
2021 West Los Angeles Data Summary, Gary Bishop
Fuel Efficiency Automobile Test Publications
Simple data summary for 2021 West Los Angeles on-road emission measurements.
2022 Oakland Ca Data Summary,
2022
University of Denver
2022 Oakland Ca Data Summary, Gary Bishop
Fuel Efficiency Automobile Test Publications
Simple data summary for 2022 on-road vehicle emission measurements from Oakland CA.
The Art Of Poetry And Its Place In The History Of The Coordinating Research Councils Real World Emissions Workshop {Poster},
2022
University of Denver
The Art Of Poetry And Its Place In The History Of The Coordinating Research Councils Real World Emissions Workshop {Poster}, Gary A. Bishop
Fuel Efficiency Automobile Test Publications
No abstract provided.
Pascoite Minerals And Potential Application Of Nmr Spectroscopy,
2022
Illinois State University
Pascoite Minerals And Potential Application Of Nmr Spectroscopy, Craig C. Mclauchlan, Beth Trent-Ringer, Debbie C. Crans
Faculty Publications – Chemistry
The 20 minerals encompassing the pascoite family of decavanadate isopolyanion-containing [V10O28]6− minerals include a few minerals, such as rakovanite, that have been described as containing a protonated decavanadate anion. Rakovanite was originally assigned the formula Na3[H3V10O28]•15H2O and now is redefined with an ideal formula (NH4)3Na3[V10O28]•12H2O. Nuclear magnetic resonance (NMR) and particularly 51V NMR spectroscopy is an informative method used to describe the protonation state and speciation in both solid and solution states …
The Inhibition Activity Of Tert-Butylhydroquinone Towards Corrosion Of Aluminum, Copper And Stainless Steel In Biodiesel Blend B20 Alternative Fuel,
2021
Post Graduate Student, Faculty of Science, Beirut Arab University, Lebanon
The Inhibition Activity Of Tert-Butylhydroquinone Towards Corrosion Of Aluminum, Copper And Stainless Steel In Biodiesel Blend B20 Alternative Fuel, Chaza Joumaa, Ibtissam Saad, Ghassan Younes
BAU Journal - Science and Technology
Tert-butylhydroquinone (TBHQ) has been investigated as corrosion inhibitor for aluminum; copper and stainless steel in biodiesel blend B20 by using electrochemical impedance spectroscopy (EIS) method. The results showed that the inhibition efficiency increases with an increase in the concentration of TBHQ but decreases with increasing temperature from 30℃ to 60℃. A maximum inhibition efficiency of about 61.52% for aluminum was recorded for THBQ in biodiesel blend B20 at temperature 30℃ and at a concentration of 4x10-6 M which is the lowest concentration used compared to the concentrations of TBHQ used for the other metals (copper and stainless steel). Theoretical …
Characterization Of Landfill Leachate For Enhanced Metal Recovery,
2021
Purdue University
Characterization Of Landfill Leachate For Enhanced Metal Recovery, Hanna Fulford, Amisha Shah, Inez Hua, Nadezhda Zyaykina, Lori Hoagland, Alejandro Rodriguez Sanchez, Umut Bicim
Discovery Undergraduate Interdisciplinary Research Internship
Landfills contain a trove of valuable materials, such as critical, precious, and rare earth metals, that are integral to the United State’s economy and national security. The leachate that filters through landfills picks up these materials, which allows for the possibility of recovery. For this research, samples will be analyzed from landfills throughout the Midwestern United States to provide a baseline on water quality constituents, elements present, and microbial activity. Preliminary data for this study was acquired by analyzing samples of landfill leachate from a landfill in northern Indiana. pH readings indicate that the leachate is slightly basic. It also …
Modeling Nitrous Oxide Emissions From Large-Scale Intensive Cropping Systems In The Southern Amazon,
2021
CGIAR Research Program on Climate Change, Agriculture and Food Security (CCAFS), Colombia
Modeling Nitrous Oxide Emissions From Large-Scale Intensive Cropping Systems In The Southern Amazon, Ciniro Costa Jr., Gillian L. Galford, Michael T. Coe, Marcia Macedo, Kathijo Jankowski, Christine S. O'Connell, Christopher Neill
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Nitrogen (N) fertilizer use is rapidly intensifying on tropical croplands and has the potential to increase emissions of the greenhouse gas, nitrous oxide (N2O). Since about 2005 Mato Grosso (MT), Brazil has shifted from single-cropped soybeans to double-cropping soybeans with maize, and now produces 1.5% of the world's maize. This production shift required an increase in N fertilization, but the effects on N2O emissions are poorly known. We calibrated the process-oriented biogeochemical DeNitrification-DeComposition (DNDC) model to simulate N2O emissions and crop production from soybean and soybean-maize cropping systems in MT. After model validation with …
Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions,
2021
University of Arkansas, Fayetteville
Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions, Huong Thu Pham
Graduate Theses and Dissertations
NDMA occurrence and formation pathways in drinking water systems are reviewed and NDMA yields are compared on the basis of disinfectant type, water chemistry, and precursor category. In chloramination, despite monochloramine being the predominant species between pH 7-9, evidence suggests that dichloramine is the primary species involved in NDMA formation. This is somewhat confounding as NDMA yields are maximal at pH 9, yet at pH 9 dichloramine decays faster than it forms and hence is present at trace levels; additionally, the proposed mechanism involves a spin-forbidden incorporation of dissolved oxygen as a triplet, which is presumably kinetically slow. This review …
Is Bog Water Chemistry Affected By Increasing N And S Deposition From Oil Sands Development In Northern Alberta, Canada?,
2021
Villanova University
Is Bog Water Chemistry Affected By Increasing N And S Deposition From Oil Sands Development In Northern Alberta, Canada?, R. Kelman Wieder, Melanie A. Vile, Kimberli D. Scott, James C. Quinn, Cara M. Albright, Kelly J. Mcmillen, Caitlyn Herron, Hope Fillingim
Public Health Sciences Faculty Publications
Nitrogen and sulfur emissions from oil sands operations in northern Alberta, Canada have resulted in increasing deposition of N and S to the region's ecosystems. To assess whether a changing N and S deposition regime affects bog porewater chemistry, we sampled bog porewater at sites at different distances from the oil sands industrial center from 2009 to 2012 (10-cm intervals to a depth of 1 m) and from 2009 to 2019 (top of the bog water table only). We hypothesized that: (1) as atmospheric N and S deposition increases with increasing proximity to the oil sands industrial center, surface porewater …
On-Road Nox Emissions Evaluation Of The Repair Effectiveness For Recalled Volkswagen Group Light-Duty Diesel Vehicles In The United States,
2021
University of Denver
On-Road Nox Emissions Evaluation Of The Repair Effectiveness For Recalled Volkswagen Group Light-Duty Diesel Vehicles In The United States, Gary A. Bishop
Fuel Efficiency Automobile Test Publications
The admission by the Volkswagen Group in the fall of 2015 that they had duped the United States new vehicle emissions certification testing resulted in perhaps the most expensive violation of U.S. environmental vehicle emission regulations in its history. As part of the subsequent recall of more than 500,000 vehicles in the U.S., owners could sell their vehicles back to the companies or have them repaired. We have used a number of large on-road emission measurement data sets that were routinely collected before and after the recall to evaluate the fuel specific NOx emissions benefit for the vehicles that …
A Chemical Mineralogy Study Of The Pad Laba Rocks And The Amber Formation In Al-Basit, North- Western Syria,
2021
Tishreen University, Syria
A Chemical Mineralogy Study Of The Pad Laba Rocks And The Amber Formation In Al-Basit, North- Western Syria, Mahmoud Qoujah
Jerash for Research and Studies Journal مجلة جرش للبحوث والدراسات
The aim of this research is to investigate pillow - lava rocks and amper formation, which located in the top of Syrian ophiolite complex. We test about (50) chemical and mineralogical analyses, to find out the concentration, type, and the distribution of these metals and minerals, in the Bassit region in Latakia. This study help to define the petrogenesis of ambers and he's relationship with upper pillow - lava, we thought that amber was formed by the result of some reasons such destruc tion of pillow - lava, or the result of reaction of lava with seawater, or hydrothermal activity …
Corrosion Prevention On Aluminum Alloy,
2021
Kennesaw State University
Corrosion Prevention On Aluminum Alloy, Andrea Brenner
Symposium of Student Scholars
Aluminum alloy (Al-alloy) is a widely used metal in construction, aerospace, aviation, and other necessary fields due to its lightweight and tweakable properties. However, corrosion is inevitable on metals and alloys, and that causes millions of dollars of revenue loss every year. Therefore, we propose to research fabricating coating to prevent corrosion on Al-alloy. This study uses an iron-based metal-organic framework (MOF) and polyurethane (PU) based composite coating to prevent corrosion on the Al-alloy. The makeup of the composite material is changed by varying the percentage of MOF. In addition, a binder is also used to enhance the homogenization between …
