Environmental Chemistry Commons^™

A Kinetic Analysis Of Bleaching Synthetic Indigo In Solution, Emily Fry

[Archive] Belmont University Research Symposium (BURS)

Indigo's ability to dye a wide variety of fabric types gives it a prominent place in the textile industry. As a vat dye, indigo must be reduced to leuco-indigo to dissolve in water and dye fabric. It is common practice in the textile industry to bleach indigo-dyed denim to alter the final appearance of the garment. This research aims to determine the kinetic order of this bleaching process, using hydrogen peroxide as a bleaching agent for synthetic indigo. Vat solutions of synthetic indigo were made using fructose as the reducing agent and sodium hydroxide to create a reducing environment. Four …

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Indoor Air Quality Through The Lens Of Outdoor Atmospheric Chemistry, Jonathan P.D. Abbatt, Douglas B. Collins

Faculty Contributions to Books

Outdoor atmospheric chemistry and air quality have been the topic of research that intensified in earnest around the mid-20^th century, while indoor air quality research has only been a key focus of chemical researchers over the last 30 years. Examining practices and approaches employed in the outdoor atmospheric chemistry research enterprise provides an additional viewpoint from which we can chart new paths to increase scientific understanding of indoor chemistry. This chapter explores our understanding of primary chemical sources, homogeneous and multiphase reactivity, gas-surface partitioning, and the coupling between the chemistry and dynamics of indoor air through the lens of …

Marcadores Moleculares Subrogados A La Repelencia Al Agua En Suelos Afectados Por El Fuego, Nicasio T. Jiménez-Morillo, Gonzalo Almendros, Nuno Guiomar, Ana Z. Miller, Cristina Barrocas-Dias, José M. De La Rosa, Patrick G. Hatcher, José A. González-Pérez

Chemistry & Biochemistry Faculty Publications

Soil water repellency (SWR) is often attributed to the accumulation of hydrophobic organic compounds, mainly lipids. Nonetheless, lipid extraction not always suppress SWR and unextractable soil constituents may be related with residual SWR. Burnt (B) and unburnt (UB) soils (Doñana National Park, Huelva) under two vegetations (cork oak and heather) and two soil fractions, coarse (1–2 mm) and fine (

The Significance Of A New 11,000-Year Volcanic Record From The South Pole And Inferences From Comparisons With Other Volcanic Records, Derek Lee Brandis

Electronic Theses and Dissertations

Snow accumulation at the polar regions of the planet preserves chemical substances from the atmosphere creating natural archives. Records of the atmospheric environment including atmospheric chemical composition and the climate can be reconstructed from ice cores from the polar ice sheets. Sulfur emitted by explosive volcanic eruptions is preserved as sulfate in polar snow and can be used to reconstruct the record of volcanic eruptions. Since large volcanic eruptions impact the environment and climate, records of volcanic eruptions from ice cores can help us to study and understand climate change and model the future climate environment. A 1750-m ice core …

The Photo-Transformation Of Free Methionine In The Presence Of Surrogate And Standard Isolate Dissolved Organic Matter Under Sunlit Irradiation, Benjamin J. Mohrhardt

Dissertations, Master's Theses and Master's Reports

Sulfur (S)-containing amino acids are key sources of carbon, nitrogen, and sulfur involved in protein synthesis, protein function, and providing energy for microbial growth. Dissolved free and combined methionine is one of two S-containing amino acids incorporated into proteins and has been attributed to their stability and function. The oxidation of methionine has received considerable attention given its ubiquitous presence in most biological systems and has been associated with losses in protein function and pathological disorders. In natural waters, methionine is rapidly and selectively taken up by microorganisms to achieve cellular requirements of carbon, nitrogen, and sulfur. The abiotic transformation …

Spatial Geochemical Changes In Central And East Texas Soils Over Time Resulting From Human Decomposition, Isabela Marisol Overturf

CMC Senior Theses

Human decomposition is studied to aid forensic investigations and better understand the impact of cemeteries on urban resources like soil and groundwater. The purpose of this study was to identify changes in soil geochemistry at and around a human grave to search for lateral nutrient movement and possibly identify new patterns in elemental concentrations that could be used in estimating post-mortem intervals (PMIs). At the Forensic Anthropology Research Facility (FARF) at Texas State San Marcos, soil samples were collected from a shallow grave over the course of 54 days to conduct analysis for organic matter content, texture, pH, and bulk …

Soil Literature Research Project, Kathryn Currey

Natural Sciences Student Research Presentations

TOPIC OVERVIEW : TOXINS IN SOILS AND HEALTH OF HUMANS

• Soil contamination happens all the time as a result of various causes, that can be purposeful or accidental (Soil Science Society of America, np). Some common examples of ways that soil is contaminated is through mining, waste disposal and oil drilling, (Misachi, John).

• Soil contamination and a large presence of toxins present in soils from across the world has harmed our planet, the animals and the humans on it (Soil Science Society of America, np).

• For this project I am going to discuss toxins due to soil …

Soil Health, Laini Flessner

Natural Sciences Student Research Presentations

My literature research topic looks at the remediation of soil, specifically through phytoremediation. Phytoremediation is a method of decontaminating soil by using plants that filter out or degrade pollutants (Rahim and Koh 2).

Soils Project, Teagan Wuethrich

Natural Sciences Student Research Presentations

With the mass production of plastic materials throughout the world there is not only significant impacts towards marine life, but also terrestrial environments because of plastic pollution. These plastic products are non-biodegradable and only break down into tiny microscopic pieces of plastic. These microscopic plastics pollute the grounds and soils us humans depend on.

Soils Project, Corinne Wolf

Natural Sciences Student Research Presentations

There are several well known impacts of climate change on our planet, such rising sea levels or warming temperatures. However, I wanted to explore a way in which climate change could potentially impact soils.

Soil & Forensic Analysis, Devan Bianchini

Natural Sciences Student Research Presentations

What is forensic analysis?

• Work done by forensic scientists to analyze evidence found at crime scenes and outside evidence tied to a crime (“Forensic Science”)
• An analysis method used to aid law enforcement in criminal investigations and in a court room to prove whether a criminal suspect is innocent or guilty of committing a crime (“Forensic Science”)

How can soil be used in forensic analysis?

• By forensic scientists in trace evidence examination (“Forensic Science”), a method of forensic analysis examining microscopic traces of evidence, such as soil particles found at or on evidence from a crime scene (“Trace Evidence Analysis”) …

Soil Health, Laszlo Meredith

Natural Sciences Student Research Presentations

No abstract provided.

Soils Project, Kelsie Pitcher

Natural Sciences Student Research Presentations

My primary research article discussed the importance of soil damping. The research question is "What's the importance of soil damping for tall buildings?" (Gómez et al. 1). This is a process that can create stability (Gómez et al.). Soil damping can prevent weakening of structures overtime caused by severe weather conditions. (Gómez et 3). Soil damping is a form of energy dissipation allowing the structure to be more stable when experiencing things like high winds and intense weather conditions (Gómez et al. 5).

Soil Contamination Due To Nuclear Testing, Animesh Jha

Natural Sciences Student Research Presentations

Why this topic:

• Nuclear contamination has long term effects (cdc.gov)
• Australia and the U.S. took land from indigenous peoples to conduct nuclear tests (Rapaport, Hughes)
• Give idea of whether indigenous peoples can return to their lands safely

Stratospheric Aerosol Composition Observed By The Atmospheric Chemistry Experiment Following The 2019 Raikoke Eruption, Chris D. Boone, Peter F. Bernath, Keith Labelle, Jeff Crouse

Chemistry & Biochemistry Faculty Publications

Infrared aerosol spectra derived from Atmospheric Chemistry Experiment measurements following the June 2019 Raikoke volcanic eruption are used to evaluate the composition of stratospheric aerosols in the Arctic. A blanket of aerosols, spanning an altitude range from the tropopause (8–11 km) to 20 km, persisted in the stratosphere over northern latitudes for many months. The aerosols within this blanket were almost exclusively sulfates. The percentage of sulfuric acid in the aerosols decreased over time, dropping below 50% H₂SO₄ concentration at some altitudes by March 2020. Contrary to previous reports, the aerosol blanket was not comprised of smoke …

Toxic Effects Of Silver Ions On Early Developing Zebrafish Embryos Distinguished From Silver Nanoparticles, Martha S. Johnson, Preeyaporn Songkiatisak, Pavan Kumar Cherukuri, Xiao-Hong Nancy Xu

Chemistry & Biochemistry Faculty Publications

Currently, effects of nanomaterials and their ions, such as silver nanoparticles (Ag NPs) and silver ions (Ag⁺), on living organisms are not yet fully understood. One of the vital questions is whether nanomaterials have distinctive effects on living organisms from any other conventional chemicals (e.g., their ions), owing to their unique physicochemical properties. Due to various experimental protocols, studies of this crucial question have been inconclusive, which hinders rational design of effective regulatory guidelines for safely handling NPs. In this study, we chronically exposed early developing zebrafish embryos (cleavage-stage, 2 hours post-fertilization, hpf) to a dilution series of …

Application Of Chemostratigraphic Methods To Floodplain Alluvial Deposits Within The Big Harris Creek Basin, North Carolina, Samantha N. Sullivan, Jerry R. Miller, Carmen L. Huffman

Chemistry & Biochemistry Faculty Publications

Big Harris Creek, North Carolina, possesses a geomorphic history and alluvial stratigraphic record similar to many drainages in southern Appalachian Piedmont. An approximately 1 km reach of Upper Stick Elliott Creek, a tributary to Big Harris Creek, was used herein to (1) explore the use of chemostratigraphic methods to define and correlate late Holocene alluvial deposits along this relatively uncontaminated rural stream containing legacy sediments (historic, anthropogenically derived deposits), and (2) interpret depositional floodplain processes within small (<10 km²), headwater drainages. The lithofacies within four floodplain sections were described in channel banks and sampled at about 5 cm intervals. …

On The Stratospheric Chemistry Of Midlatitude Wildfire Smoke, Susan Soloman, Kimberlee Dube, Kane Stone, Pengfei Yu, Doug Kinnison, Owen B. Toon, Susan E. Strahan, Karen H. Rosenlof, Robert Portmann, Sean Davis, William Randel, Peter Bernath, Chris Boone, Charles G. Bardeen, Adam Bourassa, Daniel Zawada, Doug Degenstein

Chemistry & Biochemistry Faculty Publications

Massive Australian wildfires lofted smoke directly into the stratosphere in the austral summer of 2019/20. The smoke led to increases in optical extinction throughout the midlatitudes of the southern hemisphere that rivalled substantial volcanic perturbations. Previous studies have assumed that the smoke became coated with sulfuric acid and water and would deplete the ozone layer through heterogeneous chemistry on those surfaces, as is routinely observed following volcanic enhancements of the stratospheric sulfate layer. Here, observations of extinction and reactive nitrogen species from multiple independent satellites that sampled the smoke region are compared to one another and to model calculations. The …

Validation Of The Use Of Clathromorphum Compactum Growth And Skeletal Δ18o As A Proxy For Seawater Conditions, Teagan Mcmahon

Pitzer Senior Theses

Crustose coralline algae (CCA) are important organisms that create benthic habitat in the photic zone of oceans worldwide. CCAs mechanisms of photosynthesis and calcification may, in some cases, make them vulnerable to climate change and ocean acidification. Therefore, CCA are important not only for their ecological role within ecosystems but also for their ability to indicate the effects that ocean acidification and climate change may have on other marine calcifying organisms. Some species of CCA are known to be useful recorders of paleo oceanic conditions. These climate archives and reconstructions of past environmental conditions are important for understanding past changes …