Mechanics of Materials Commons^™

Impacting Testing Of High Temperature Ceramics Through The Use Of A Vitiated Heater For Hot And Cold Fire Collisions, Adrian Trejo

Open Access Theses & Dissertations

Material testing is a crucial step during the design process as particular materials serve as safety and life saving conditions. In this study, a MoSi2 is chosen as the target specimen to undergo impact under high temperatures. An impact apparatus is designed and constructed for the purpose of propelling alumina particles at high velocities. A nozzle using compressed nitrogen gas is used to fire the particle at the desired velocities. Due to the possibility of thermal shock occurring at higher temperatures, a separate nozzle utilizing vitiation heating is designed to fire the particle at equally higher temperatures to prove the …

Failure Analysis And Materials Characterization Of Hip Implants, Amanda Marie Bastidos

Open Access Theses & Dissertations

This research focused on the microstructural characterization and failure analysis of hip implant components. The main hip components analyzed were the femoral heads and the ultra-high molecular weight polyethylene (UHMWPE) liners. Previous research has shown that hip implants tend to fail by the PE liners due to adhesive and abrasive wear, delamination, and third body particles (metals, ceramics, and PE). The methods and procedures for analyzing the said failures consisted of non-destructive and destructive evaluations. Non-destructive evaluations included of techniques such as visual characterization and dye penetrant inspection (DPI)-which displayed macroscopic surface details and presented initial clues as to the …

Observed Superspin-Glass Behavior In Ni0.5zn0.5fe2o4 Nanoparticles, Antony Adair

Open Access Theses & Dissertations

In this investigation we seek to identify the magnetic behavior of Ni0.5Zn0.5Fe2O4 nanoparticles though AC-susceptibility and DC-magnetization measurements. Powder x-ray diffraction was performed to determine the purity and average diameter ( ~ 9nm) of the particles. Aditionally, structure was confirmed by comparison through the International Centre for Diffraction Data's Powder Diffraction File [52] (PDF # 08-0234).

Zero-field cooled and field cooled DC magnetization measurements (bifurcation and blocking temperature), as well as M(H) hysteresis (below and above the blocking temperature) lead us to initially suggest that the material may in fact be superparamagnetic. However, further investigation of the real AC susceptibility …

Temperature-Induced Phenomena In Systems Of Magnetic Nanoparticles, Abdul Wazed Bhuiya

Open Access Theses & Dissertations

Magnetic nanoparticle ensembles have received a lot of attention, stemming in part from their current and potential applications in biomedicine and in the development of high-density magnetic storage media. Key to the functionality of these systems are microscopic structures and mechanisms that make them exhibit unique properties and behave differently from their bulk counterparts.

We studied microscopic structures and processes that dictate macroscopic properties, behavior and functionality of magnetic nanoparticle ensembles. As the temperature T strongly influences the magnetic behavior of these systems, we studied temperature dependent magnetic properties using AC-susceptibility and DC-magnetization measurements carried out over a broad range …

Microstructural Characterization And Heat Treatment Of A-286 Turbine Buckets, Christopher Michael Bradley

Open Access Theses & Dissertations

A-286 is an iron-based superalloy used extensively in land-based gas turbines for 2nd stage (low pressure) buckets and 1st and 2nd stage wheels. Although A-286 may appear to some as just another austenitic stainless steel, its elevated temperature properties are attributed to ' precipitate structures, effective distributions of alloy carbides in the forms of M23C6, M6C and MC, and solid solution strengthening. Unfortunately over the course of these components service lives microstructural degradation develops in the form of η-phase formation. The presence of η-phase, especially in large quantities, can have a negative effect on stress rupture properties. Resistance to creep …

Spectroscopic Characterizations Of Organic/Inorganic Nanocomposites, Jayesh Rasikalal Govani

Open Access Theses & Dissertations

Inorganic potassium dihydrogen phosphate (KDP) is widely known for its value as a nonlinear optical material. In this study, pure and l-arginine-doped KDP single crystals were grown by the slow solvent evaporation technique and further subjected to infrared absorption and Raman studies for the confirmation of chemical group functionalization and possible bonding between the organic and inorganic materials. The appearance in the infrared absorption spectra of additional vibrational lines, which mostly originate from disturbed N-H, C-H, and C-N bonds of the l-arginine-doped salt, confirm the interaction between KDP and the organic material. This affirmation is supported by more evidence from …

Effects Of Build Orientation, Aging, And Pre-Conditioning On Mechanical Properties For Stereolithography-Manufactured Astm Type I Specimens Using A Design Of Experiments Approach, Karina Puebla

Open Access Theses & Dissertations

With industry's growing focus on the rapid manufacturing (RM) of end-use products, rapid prototyping (RP) or layered manufacturing (LM) machines that were originally designed to build prototypes may now be required to build functional end-use products. To successfully accomplish the transition, the available materials utilized in RP must provide the performance required for RM. The specific technology used must also be capable of producing repeatable and reproducible parts in regards to mechanical and dimensional properties.

A design of experiments approach was performed to determine the effects of build orientation, aging, and pre-conditioning on the mechanical properties. To perform the investigations, …

Computational Modeling Studies Of The Structures And Properties Of Organotin(Iv) And Stannyl-Thioether Systems With Comparisons To X-Ray Crystallography, Michelle R. Stem Joseph

Open Access Theses & Dissertations

Controlling the toxic effects of organotin(IV) compounds involves engineering the structure of the molecules to optimize their properties. Molecular engineering, coupled with improved capabilities to generate reliable computational optimization models (COMs), will enable researchers to have greater success at harnessing the highly specific cytotoxicity of organotins. For example, as the thio_n ligand phenyl groups were replaced with Cl atoms, the S-Sn intramolecularity was strengthened, the bond distance decreased, and the stannyl tetrahedral structure was deformed from its triphenyl conformation. With each substitution, conformation deformations lowered the damaging bioactivity levels of thio_n. Bonding various ligands to organotin(IV) compounds …

High Temperature Oxidation Behavior Of Nb-20mo-15si-5b-20cr Alloy, Julieta Angelica Ventura

Open Access Theses & Dissertations

Materials for high temperature applications, such as jet engines, gas turbines and turbine blades, require a balanced combination of physical and chemical properties to withstand the aggressive environments in which they are utilized. Some of the properties required are high strength, low density, high melting point and good oxidation resistance at elevated temperatures [1-3]. For this reason, the microstructure and oxidation behavior of the Nb-20Mo-15Si-5B-20Cr alloy (at.%) has been studied as a potential candidate to replace Nickel-based alloys currently used in the aerospace industry.

Short term oxidation (STO) and long term oxidation (LTO) studies have been performed in air for …

Exploring Poly(Ethylene Glycol) As A Suitable Material For Peripheral Nerve Regeneration Scaffolds Manufactured By Stereolithography, Nubia Zuverza

Open Access Theses & Dissertations

One of the challenges in tissue engineering is to have spatial and temporal control over the biological elements within a scaffold used to guide regeneration for example of transected nerves. Some of the physical and chemical characteristics to regulate include incorporation of bioactive domains and release of chemical signals. This study presents the use of stereolithography (SL) to incorporate localized domains for cell adhesion in addition to include releasable nerve growth factor (NGF) in the process of building poly(ethylene glycol)diacrylate (PEGda) hydrogel scaffolds. Besides providing sites for cell attachment, an ideal nerve guidance conduit (NGC) should be able to release …

Convergence, Adaptive Refinement, And Scaling In 1d Peridynamics, Florin Bobaru Ph.D., Mijia Yabg Ph.D., Leonardo F. Alves M.S., Stewart A. Silling Ph.D., Ebrahim Askari Ph.D., Jifeng Xu Ph.D.

Department of Engineering Mechanics: Faculty Publications

We introduce here adaptive refinement algorithms for the non-local method peridynamics, which was proposed (in J. Mech. Phys. Solids 2000; 48:175–209) as a reformulation of classical elasticity for discontinuities and long-range forces. We use scaling of the micromodulus and horizon and discuss the particular features of adaptivity in peridynamics for which multiscale modeling and grid refinement are closely connected. We discuss three types of numerical convergence for peridynamics and obtain uniform convergence to the classical solutions of static and dynamic elasticity problems in 1D in the limit of the horizon going to zero. Continuous micromoduli lead to optimal rates of …

Comparison Of Fuzzy Clustering Methods And Their Applications To Geophysics Data, David J. Miller, Carl A. Nelson, Molly Boeka Cannon, Kenneth P. Cannon

Department of Mechanical and Materials Engineering: Faculty Publications

Fuzzy clustering algorithms are helpful when there exists a dataset with subgroupings of points having indistinct boundaries and overlap between the clusters. Traditional methods have been extensively studied and used on real-world data, but require users to have some knowledge of the outcome a priori in order to determine howmany clusters to look for. Additionally, iterative algorithms choose the optimal number of clusters based on one of several performance measures. In this study, the authors compare the performance of three algorithms (fuzzy c-means, Gustafson-Kessel, and an iterative version of Gustafson-Kessel) when clustering a traditional data set as well as real-world …

Experimental Investigation Of A Novel Blast Wave Mitigation Device, Zhenbi Su, Wen Peng, Zhaoyan Zhang, George Gogos, Reed Skaggs, Bryan Cheeseman, Chian Fong Yen

Department of Mechanical and Materials Engineering: Faculty Publications

A novel blast wave mitigation device was investigated experimentally in this paper. The device consists of a pistoncylinder assembly. A shock wave is induced within the cylinder when a blast wave impacts on the piston. The shock wave propagates inside the device and is reflected repeatedly. The shock wave propagation process inside the device lengthens the duration of the force on the base of the device to several orders of magnitude of the duration of the blast wave, while it decreases the maximum pressure over an order of magnitude. Two types of experiments were carried out to study the blast …

A Novel Method Characterizing The Impact Response Of Functionally Graded Plates, Reid A. Larson

Theses and Dissertations

Functionally graded material (FGM) plates are advanced composites with properties that vary continuously through the thickness of the plate. Metal-ceramic FGM plates have been proposed for use in thermal protection systems where a metal-rich interior surface of the plate gradually transitions to a ceramic-rich exterior surface of the plate. The ability of FGMs to resist impact loads must be demonstrated before using them in high-temperature environments in service. This dissertation presents a novel technique by which the impact response of FGM plates is characterized for low-velocity, low- to medium-energy impact loads. An experiment was designed where strain histories in FGM …

The Role Of Silicon Content On Environmental Degradations Of T91 Steels, Ajit K. Roy, D. Maitra, Pankaj Kumar

Mechanical Engineering Faculty Research

T91 grade steels showed a gradual enhancement in tensile ductility at ambient temperature due to an increase in Si content from 0.5 to 2.0 weight percent (wt.%). However, the ultimate tensile strength was reduced only above 1.5 wt.% Si. The corrosion potential became more active in an acidic solution with increasing temperature. The cracking susceptibility in a similar environment under a slow-strain-rate (SSR) condition was enhanced at higher temperatures showing reduced ductility, time to failure, and true failure stress. Cathodic potentials applied to the test specimens in SSR testing caused an enhanced cracking tendency at 30 and 60°C, suggesting hydrogen …

Tensile Deformation Of A Nickel-Base Alloy At Elevated Temperatures, Ajit K. Roy, Anand Venkatesh, Vikram Marthandam

Mechanical Engineering Faculty Research

The results of tensile testing involving Waspaloy indicate that the failure strain was gradually reduced at temperatures ranging between ambient and 300 °C. Further, serrations were observed in the engineering stress versus strain diagrams in the temperature range of 300-600 °C. The reduced failure strain and the formation of serrations in these temperature regimes could be the result of dynamic strain aging of this alloy. The extent of work hardening due to plastic deformation was reduced at temperatures above 300 °C. A combination of ductile and intergranular brittle failures was seen at temperatures above 600 °C. γ′ was detected at …

Development Of Low Temperature Alpha Alumina Coatings By Ac Magnetron Sputtering, Andrew Cloud

Mechanical Engineering Undergraduate Honors Theses

Alpha-phase aluminum oxide thin films were created using an Isoflux ICM-10 dual target inverted cylindrical magnetron sputtering system using mid-frequency AC power supplies. Alpha alumina films were deposited at a magnetron power of 6 kW, 50% oxygen partial pressure by volume, and -35 V DC bias. Film thickness, substrate material, and position and orientation within the deposition chamber were varied. To ensure the deposition conditions are suitable for alloys, the substrate temperature was measured using temperature indicating liquids. The experimental results, supported by Explicit Euler numerical analysis, revealed a steady state temperature of ~480°C at 6kW. Transmission electron microscopy (TEM) …

The Effect Of Elevated Temperature On The Fretting Fatigue Behavior Of Nickel Alloy In-100, John F. Ownby

Theses and Dissertations

This thesis studied the effect of elevated temperature (600 C) on the fretting fatigue behavior of IN-100. First, fretting and plain fatigue S-N curves were determined over a large range of applied stress at an identical stress ratio of 0.03 at 600 C and for fretting tests, with a constant contact load. The partial slip condition was verified by using hysteresis between shear force and axial stress techniques. The contact width and the crack initiation location were observed for all of the fretting specimens. The contact widths were consistent with expected values and the crack initiation location was at the …

An Experimental Technique For Developing Intermediate Strain Rates In Ductile Metals, Hugh E. Gardenier Iv

Theses and Dissertations

Quantifying the strain-rate sensitive dynamic properties of structural materials is an important area of research in the solid mechanics field. Property evaluation is typically accomplished using dynamic tests which involve rapid loading or impact of specimens. In these tests, inertial forces and wave propagation make it difficult to accurately record the material response to a loading condition at an equivalent location. Furthermore, these tests typically generate high strain rates (in excess of 10³ s⁻¹) and an experimental method for generating rates of strain in the intermediate strain rate regime which is relatively simple, low cost, and reliable …

Investigation Into Fretting Fatigue Under Cyclic Contact Load And In Conjuction With Fatigue Of Titanium Alloy, Abdulla A. Al-Noaimi

Theses and Dissertations

Fretting fatigue is the surface damage that occurs at the interface between two components that are undergoing a small amplitude oscillatory movements. It results in a reduction of the material life comparing to the plain fatigue. Most of the previous works were accomplished under a constant applied contact load and a little effort has been done under a variable contact load, while none of these studies have taken the phase difference between the axial and the contact load. The primary goal of this study is to investigate the effect of phase difference between axial and contact loads on fretting fatigue …

Control Of The Nanoscale Crystallinity And Phase Separation In Polymer Solar Cells, Chih-Wei Chu, Hoichang Yang, Wei-Jen Hou, Jinsong Huang, Gang Li, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Grazing-incidence x-ray diffraction and atomic force microscopy were performed on bulk heterojunction regioregular poly(3-hexylthiophene) (RR-P3HT) [6,6]-phenyl-C₇₁-butyric acid methyl esters spin-cast films with different film processing conditions to correlate the crystalline nanostructure of P3HT with the corresponding solar cell performance. The increase in long wavelength absorption for solvent annealed films is related to highly conjugated crystal structure of RR-P3HT phase-separated in the active layer. Upon thermal annealing, the solvent annealed 50-nm-thick device shows high solar cell performance with fill factor up to 73% and power conversion efficiency of 3.80%.

Stereolithography Of Poly(Ethylene Glycol) Hydrogels With Application In Tissue Engineering As Peripheral Nerve Regeneration Scaffolds, Karina Arcaute

Open Access Theses & Dissertations

In recent years, rapid prototyping (RP) technologies initially developed to create prototypes prior to production for the automotive, aerospace, and other industries, have found applications in tissue engineering (TE). Several different RP technologies are being used to fabricate biocompatible 3D structures with controlled micro- and macro-scale characteristics. The focus of this research was to explore the capabilities of the RP technology, stereolithography (SL), for creating complex, 3D scaffolds with applications in TE using a photocrosslinkable biopolymer, poly(ethylene glycol) (PEG). The primary objective was to create an implantable multi-lumen nerve guidance conduit (NGC) for the regeneration of peripheral nerves.

Studies of …

A Study Of The Interaction Of Thioindigo Dye, With Several Inorganic Host Materials, Alejandra Ramirez

Open Access Theses & Dissertations

Maya Blue has been the focus of numerous studies and is believed to be a mixture of palygorskite clay and indigo dye.^1,2 Several derivatives of this pigment have been developed with intriguing properties. For instance, the dye thioindigo reacts with the palygorskite clay to exhibit a broad range of colors from red to blue under UV-Vis excitation. Based on FT-Raman and computer simulation, previous work performed in our group could relate indigo and thioindigo interaction to the aluminum sites in the framework. super>3,4

The work performed with other inorganic host materials such as, layer structures and zeolites have …

A Finite Element Study Of Piezoelectric Thin Films On Substrates, Bo Liu

Theses and Dissertations

The overall goal of this work has been mainly to advance the understanding of the degradation in the response of piezoelectric thin films after they are deposited on substrates. To have better understanding of the difference in the response between free standing piezoelectric films and those deposited on a substrate, we calculated the normalized "effective" piezoelectric coefficients for BT/MgO, PZT/STO and ZnO/STO respectively. We also studied the impact on the effective coefficients due to the components of the bulk material's piezoelectric coefficients. After studying the clamping effects of the substrate, lattice mismatch, stiffness of the films and the substrates, we …

Modelagem Da Vida De Fadiga E Do Acúmulo De Deformações Permanentes Em Pavimentos Asfálticos Por Meio De Um Modelo De Dano Contínuo, Victor Ferreira Teixeira, Flavio V. Souza, Jorge Barbosa Soares

Department of Mechanical and Materials Engineering: Faculty Publications

: It is known that the conditions of the Brazilian roadways have an enormous impact over the national economy. In face of this problem, there is a need for new methodologies for pavement analyses and design that can more accurately predict pavement distresses. Among the main methods currently used, one can find purely empirical methods and mechanistic-empirical methods which make use of the pavement structure response. The evolution of numerical methods such as the Finite Element Method (FEM) or the Boundary Element Method (BEM) has made the mechanistic-empirical methods more popular for pavement analysis applications. This work shows a mechanistic …

An Experimental Technique For The Evaluation Of Strain Dependent Material Properties Of Hard Coatings, Shad A. Reed, Anthony N. Palazotto, William P. Baker

Faculty Publications

A novel vibration experiment consisting of a free-free boundary condition, an electromagnetic excitation source, a vacuum chamber, and a laser vibrometer based surface measurement system has been developed that permits high levels of excitation on highly damped specimens with a minimal amount of unwanted systematic error. While some of the aspects of this experiment are not unique, when combined with a processing technique that accounts for the nonlinearities present in the system, this experiment permits, accurate measurement of strain dependent stiffness and damping properties of hard coatings at high strain levels. This procedure has been demonstrated using a titanium beam …

Cyclic Creep And Recovery Behavior Of Nextel™ 720/Alumina Ceramic Matrix Composite At 1200° C In Air And Steam Environments, Bridgett A. Whiting

Theses and Dissertations

The cyclic creep and recovery behaviors of the N720/Al₂O₃ composite were investigated in this research. The ceramic matrix composite (CMC) contains a porous alumina matrix with laminated, woven mullite/alumina (Nextel^TM 720) fibers. The composite does not have an interface between the fiber and matrix. The CMC relies on the porous nature for flaw tolerance. The objective of this study the influences of monotonic creep and cyclic creep loading histories on the creep lifetime, creep strain rate, accumulated creep strain as well as on the recovery of creep strain at near zero stress. The cyclic creep and …

Numerical Simulation Of Waves And Fronts In Inhomogeneous Solids, A. Berezovski, M. Berezovski, J. Engelbrecht, G. A. Maugin

Publications

Dynamic response of inhomogeneous materials exhibits new effects, which often do not exist in homogeneous media. It is quite natural that most of studies of wave and front propagation in inhomogeneous materials are associated with numerical simulations. To develop a numerical algorithm and to perform the numerical simulations of moving fronts we need to formulate a kinetic law of progress relating the driving force and the velocity of the discontinuity. The velocity of discontinuity is determined by means of the non-equilibrium jump relations at the front. The obtained numerical method generalizes the wave-propagation algorithm to the case of moving discontinuities …

Effects Of Prior Aging At 191°C On Creep Response Of Im7/Bmi 5250-4, Robert A. Salvia

Theses and Dissertations

The creep behavior of IM7/BMI 5250-4 with fiber orientations of [± 45] and [0/90] that were aged in air at 191 °C for up to 1000 hours was evaluated. The total weight loss during the aging process was also evaluated. Weight loss due to aging was 0.64% for the [0/90] fiber orientation and 0.72% for the [± 45] fiber orientation. Tensile tests to failure were conducted to establish tensile properties. The [0/90] specimens have a much higher stiffness and Ultimate Tensile Strength (UTS) values than the [± 45] specimens. The tensile tests of the aged specimens revealed that the Ultimate …

Effects Of Prior Aging On The Creep Response Of Carbon Fiber Reinforced Pmr-15 Neat Resin At 288°C In An Air Environment, Christopher A. Back

Theses and Dissertations

The mechanical response of carbon fiber reinforced PMR-15 neat resin with a ± 45 fiber orientation was investigated at 288 °C. Mechanical testing was performed on unaged specimens and specimens that were aged up to 1000 hours in an air environment. Tensile tests were performed to determine Young's modulus of elasticity and Ultimate Tensile Strength. Creep tests were performed at creep stress levels of 30 and 60 MPa. Creep periods of at least 25 h in duration were followed by recovery at zero stress. Duration of the recovery period was at least twice the time of the creep period. Oxidation …