Engineering Science and Materials Commons^™

An Experimental Technique For Developing Intermediate Strain Rates In Ductile Metals, Hugh E. Gardenier Iv

Theses and Dissertations

Quantifying the strain-rate sensitive dynamic properties of structural materials is an important area of research in the solid mechanics field. Property evaluation is typically accomplished using dynamic tests which involve rapid loading or impact of specimens. In these tests, inertial forces and wave propagation make it difficult to accurately record the material response to a loading condition at an equivalent location. Furthermore, these tests typically generate high strain rates (in excess of 10³ s⁻¹) and an experimental method for generating rates of strain in the intermediate strain rate regime which is relatively simple, low cost, and reliable …

Investigation Into Fretting Fatigue Under Cyclic Contact Load And In Conjuction With Fatigue Of Titanium Alloy, Abdulla A. Al-Noaimi

Theses and Dissertations

Fretting fatigue is the surface damage that occurs at the interface between two components that are undergoing a small amplitude oscillatory movements. It results in a reduction of the material life comparing to the plain fatigue. Most of the previous works were accomplished under a constant applied contact load and a little effort has been done under a variable contact load, while none of these studies have taken the phase difference between the axial and the contact load. The primary goal of this study is to investigate the effect of phase difference between axial and contact loads on fretting fatigue …

Cu Doping Lifepo4 And Its Electrochemical Performance, Ming-Sen Zheng, Shan-Ke Liu, Shi-Gang Sun, Quan-Feng Dong

Journal of Electrochemistry

LiFePO₄ and LiFePO₄ doped with Cu²⁺ ions were synthesized by solid-state reactions.The structure of LiFePO₄ and the Fe valence were analyzed by the XRD(X-ray diffraction) and XPS(X-ray photoelectron spectroscopy) respectively.The Cu doping position in LiFePO₄ is discussed.It has found that the volume of LiFePO₄ by doping Cu²⁺ ions is reduced.The minim Cu²⁺ ions doping does not almost change the binding energy of Fe₂p_1/2 in LiFePO_4.According to the experiment results,we conclude that most of the Cu²⁺ ions substitute the Fe²⁺ ions in LiFePO₄ when a …

A Study On Supercapacitor Based On Aligned Carbon Nanotubes, Xiao-Yan Ye, Yan-Zhi Wang, Hai-Yan Song, Zhuo Sun, Pin-Gang He, Yu-Zhi Fang

Journal of Electrochemistry

Large scale vertically aligned carbon nanotubes(ACNTs) with uniform length and diameter were prepared by the pyrolysis of iron(Ⅱ) phthalocyanine at low pressure.The ACNTs were activated by electrolyte-activation,acid-activation or electrochemical activation.The performance of the capacitor based on activated ACNTs was characterized by cyclic voltammograms which was of rectangular shape,impedence spectroscopy in which the phase is above 80° and the result specific capacitance was 16～32 F/g,which suggest that the ACNTs are the promising material for the supercapacitor.

Preparation And Electrochemical Performance Of Ordered Mesoporous Titanium Phosphate As Cathode Material For Li-Ion Battery, Qiong Wang, Attia Adel, Zhi-Cong Shi, Yong Yang

Journal of Electrochemistry

Ordered porous titanium phosphate materials were prepared by using the surfactant template combined with the sol-gel method. The samples were characterized by small angle X-ray diffraction(SA-XRD) method, N₂ adsorption/desorption techniques,high resolution transmission electron microscopy(HRTEM) and element analysis. It is found that the calcination temperature is a big influence on the porous structure, and electrochemical performance of the titanium phosphate materials, and the mesoporous titanium phosphate showed good performance in the electrochemical test, the first discharge capacity is 94 mAh/g at the current density of 150 mA/g. On the other hand, the no porous material with a low capacity of …

Synthesis Of Adipic Acid From Cyclohexanol By Electrochemical Oxidation Using Cr2O72-/Cr3+ As Indirect Oxidant, Zhen-Hai Liang, Yu-Qing Cui, Hong-Yan Sun

Journal of Electrochemistry

Adipic acid was synthesized by electro-oxidation of cyclohexanol taking Cr₂O₇^2-/Cr³⁺ as indirect oxidant.The best technological conditions were optimized by orthogonal experiment.The optimum condition are as follows: the temperature is 35 ℃,ratio of crude material is n(cyclohexanol)∶n(Cr₂O₇^2-)=0.4∶1 and concentration of H₂SO₄ is 4 mol·L^-1.Under these conditions,the yield of adipic acid can reach 70.29%.Moreover,The effects of concentration of Ag₂SO₄,(NH₄)₂SO₄,H₂SO₄and current density on the formation of Cr₂O₇^2-were also …

Mechanism Of The Cathode Reduction Of Ti(Ⅳ) In Molten Na3Alf6-Alf3, Hai-Bin Sun, Xiu-Rong Zuo, Zhi-Guo Zhong, Xue-Hui Hu

Journal of Electrochemistry

The mechanism of TiO₂ electrode process has been investigated by cyclic voltammetry and chronopotentiometry on the tungsten filament in molten Na₃AlF₆-AlF₃ salts at 990 ℃.The experimental results showed that electrochemical reduction of Ti(Ⅳ) precede were two steps,firstly Ti(Ⅳ) was reduced to Ti(Ⅱ),then Ti(Ⅱ) was reduced to Ti,namely: Ti(Ⅳ)→Ti(Ⅱ)→Ti.

Interfacial Electrochemical Behavior Of Fibrinogen On Pt Electrode, Song-Mei Chen, Jian-Zhang Zhou, Zhong-Hua Lin, Dong-Mei Zeng, Nan Huang, Guo-Jiang Wan

Journal of Electrochemistry

The interfacial electrochemical behaviors of fibrinogen on Pt electrode in phosphate buffered solution(PBS) was investigated by using cyclic voltammetry and electrochemical in-situ FTIR spectroscopy.The cyclic voltammetry results demonstrated that the fibrinogen adsorb on Pt electrode and impede the interfacial charge transfer of hydrogen ion reaction process as well as of oxygen reduction process,which is increased with higher scan rate.The cyclic voltammetry spectra of platinum absorbed with fibrinogen in K₃[Fe(CN)₆] and K₄[Fe(CN)₆]·3H₂O solutions shows that the fibrinogen can partly decrease the oxidation and reduction current peaks.There is no specific anodic and …

Molten Salt Treatment Of Mno2 And Investigation On Supercapacitor Properties, Ye Chen, Zun-Bo Zhang, Wei Zhang, Liang Liu, Zhi-Min Liu

Journal of Electrochemistry

The MnO₂ prepared by solid phase method is treated by KCl-NaCl-LiCl molten salt system.The XRD patterns indicated that the crystal structures of MnO₂ sample have had the α-MnO₂ and γ-MnO₂ phase,the crystallinity of sample is increased after treated by molten salt.The electrochemical properties were tested by cyclic voltammetry,constant current charge/discharge and AC impedance.The result shows that the supercapacitor performance of the treated material has improved.The specific discharge capacitance of the treated sample are 129.07 F·g^-1,increased by 27.88% compared to 100.94 F·g^-1 of untreated sample.Long cycle life and high coulombic efficiency were also demonstrated …

Potentiometric Response Of Glucose On Mno2-GoX Carbon Paste Electrode, Cai-Juan Wang, Xiao-Ya Hu

Journal of Electrochemistry

A novel carbon paste electrode(CPE) modified with MnO₂ and glucose oxidase(GO_x), is reported. Different factors, such as the effect of supporting electrolyte, pH of solutions,various paste glues, the amount of MnO₂ and temperature, which may influence the determination of H₂O₂ and glucose were tested to optimize. Based on above, potentiometric determination of glucose was achieved in neutral solution and at 35 ℃, the electrode gave a response of 36.12～34.62 mV/pG lucose between 2.0×10^-5 mol·L-1 and 5.2×10^-3 mol·L^-1 with a detection limit of 3.3×10^-6 mol·L^-1. Moreover, this kind …

Square Wave Stripping Voltammetric Behaviors Of Rutin On Glassy Carbon Electrode And Its Application, Jun Hua, Xiao-Ying He, Fang Liao, Qing-Tao Zhu

Journal of Electrochemistry

The electrochemical behaviors of rutin(Rt) at glassy carbon electrode were studied by square wave stripping voltammeter in the presence of 0.1mol·L^-1HAc-NaAc buffer solution(pH=3.0).The sensitive oxidation peak of rutin was observed and which potential peak is 0.46V(vs.SCE).The experimental parameters,such as pH value,deposition potential and deposition time were investigated and selected.The peak currents were proportional to the concentration of rutin in range of 5.0×10^-8 mol·L^-1~1.0×10^-6mol·L^-1,and the linear regression coefficient equaled 0.99799,the detection limit was 1.1×10-8 mol·L^-1.This method was applied to the determination of rutin content in tablet with satisfactory results.

Corrosion Electrochemical Behavior Of Az31 And Az61 Magnesium Alloys In Simulated Sea Water, Ling-Jie Li, Sheng-Hai Yu, Jing-Lei Lei, Chuan-Pu Liu, Sheng-Tao Zhang, Fu-Sheng Pan

Journal of Electrochemistry

Tafel polarization curves and electrochemical impedance spectroscopy(EIS) techniques were employed to investigate the corrosion electrochemical behavior of AZ31 and AZ61 magnesium alloys.Scanning electron microscopy(SEM) was used to observe the alloy microstructure and corrosion morphology.The variation of the bulk corrosive medium pH with immersion time was recorded during the exposure of the alloys to simulated sea water.Results show that AZ61 magnesium alloy exhibits much better anti-corrosion ability than AZ31 magnesium alloy.The different corrosion behavior between the two magnesium alloys is correlated with their different content of Al alloying element.The higher content of Al in AZ61 alloy leads to the homogenerous microstructure …

The Determination Of Vitamin C By Bromophenol Blue Modified Glassy Carbon Electrode, Shu-Lin Zhang, Min-Jiao Li, Yi Luo, Xiao-Bo Wang

Journal of Electrochemistry

The content of ascorbic acid of(vitamin C) was analyzed by using fast cyclic voltamment with bromophenol blue(BPB) modififed GC-electrode,and which experimental conditions were optimiged.The results showed that the BPB modified GC-electrode had the good stability and anti-jamming faculty for analysing the content of ascorbic acid.A linear relationship between the peak current and concentration of vitamin C in the range of 0.0050~0.1500 g·L^-1 was obtained,which related coefficient and the detection limit are-0.9991 and 0.0010 g·L^-1,respeclively.The method has satisfactory results.

Effects Of Oxidation Methods On The Stability Of Coooh Conductive Network In Foam Nickel Electrodes, Xiao-Feng Li, Yan-Wei Wei, Hui-Chao Dong

Journal of Electrochemistry

Two kinds of the cobalt oxyhydroxide conductive networks in foam nickel electrodes were prepared by different methods i.e.the electrochemical-oxidation(EO) and chemical-oxidation(CO) and which redox behaviors were studied by using cyclic voltammetry and X-ray diffraction measurements.The results show that the CoOOH(CO) has better redox reversibility than CoOOH(EO) and the structure of the former can be kept when nickel electrodes are subjected to a negative potential.Thus,98.7% capacity retention is demonstrated on nickel/metal-hydride batteries with CoOOH(CO) conductive network after being imposed over-discharge state storage;on the contrary,only 83.3% capacity retention is found on the batteries with CoOOH(EO) conductive network.

The Influence Of The Sputtering Power On The Structural And Electrochemical Properties Of Tin Oxide Films, Min-Zhen Cai, Jie Song, Ming-Sen Zheng, Qi-Hui Wu, Sun-Tao Wu, Quan-Feng Dong

Journal of Electrochemistry

Tin oxide films were deposited on silicon substrates at room temperature using the radio frequency(RF) magnetron sputtering with different sputtering power.The influence of sputtering power upon the crystal structure,surface morphology and electrochemical properties of tin oxide films were then investigated.The XRD and SEM results illustrate that the phase of tin oxide thin films changed from amorphous to crystalline and the grain size augments with the increase of the sputtering power.The constant current charge and discharge cycle tests imply that the initial irreversible capacity loss of Li/tin oxide batteries increase and which capacity decrease as the sputtering power increases.The sputtering power …

Effect Of Au At Different States On Electrocatalytic Performance Of Pd Catalyst For Oxidation Of Formic Acid, Xin Wang, Ya-Wen Tang, Tian-Hong Lu

Journal of Electrochemistry

Using liquid-reduction or complex-redution method,four catalysts,i.e,the Au/C,Pd/C,Pd-Au/C-T and Pd-Au/C-H were preparated and which electroanalytic activities and stabilities for the oxidation of formic acid were compares.It was found that the Au/C catalyst has no electrocatalytic activity,and the Pd/C catalyst possesses the good electrocatalytic performance for the oxidation of formic acid.The addition of Au into the Pd/C catalyst can increase the electrocatalytic activity and stability.Especially,the electrocatalytic activity and stability of the Pd-Au/C-T catalyst with the alloy of Pd and Au are better than that of the of the Pd-Au/C-H catalyst,in which,Pd and Au do not form the alloy.The investigation of its reason …

In Situ Measurement Of Chloride Concentration And Ph Distribution In The Crevice During The Crevice Corrosion Of Copper Electronic Board, Min Zhang, Xiang-Dong Zhuo, Chang-Jian Lin

Journal of Electrochemistry

Although the crevice corrosion of metals had been extensively studied in the past years,it remained lack of direct experimental information of the micro chemical environments and electrochemical conditions inside the corroding crevice.The distribution of chloride concentration and local pH in the occluded area are the most crucial factors in development of crevice corrosion.The array probes in one dimension of Ag/AgCl and IrO₂ array were developed in this work to in situ follow the distribution of chloride concentration and local pH in the occluded area during the crevice corrosion propagation.Based on a designed simulated crevice corrosion system in 0.5mol/L NaCl …

Synthesis Of 2,2′-Dichlorohydrazobenzene Using An Ion Exchange Membrane, Chao Zhang, Pei-Jin Li

Journal of Electrochemistry

Using an ion exchange membrane as a separator,the 2,2′-Dichlorohydrazobenzene is synthesized by the electrolytic reduction of o-chloronetrobenzene.The effects of electrode activation condition,current density,electrolyte temperature on electrolytic reduction are discussed.It was found that the optimum reaction temperature is 80 ℃.When the electrolyte concentration was 30% NaOH at the anode and 10% NaOH at the cathode,current density is 4.2A/dm²,the current efficiency reached 73% and yield is 83%.

Me-Em 2008 Annual Report, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical and Aerospace Engineering Annual Reports

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High Cycle Fatigue Of Aa6082 And Aa6063 Aluminum Extrusions , Nicholas E. Nanninga

Dissertations, Master's Theses and Master's Reports - Open

The high cycle fatigue behavior of hollow extruded AA6082 and AA6063 aluminum extrusions has been studied. Hollow extruded aluminum profiles can be processed into intricate shapes, and may be suitable replacements for fatigue critical automotive applications requiring reduced weight. There are several features inherent in hollow aluminum extrusions, such as seam welds, charge welds, microstructural variations and die lines. The effects of such extrusion variables on high cycle fatigue properties were studied by taking specimens from an actual car bumper extrusion. It appears that extrusion die lines create large anisotropy differences in fatigue properties, while welds themselves have little effect …

Comparison Of Vacuum Glazing Thermal Performance Predicted Using Two- And Three-Dimensional Models And Their Experimental Validation, Brian Norton, Philip Eames, Yueping Fang, Trevor Hyde, Neil Hewitt

Conference Papers

The thermal performance of vacuum glazing was predicted using two dimensional (2-D) finite element and three dimensional (3-D) finite volume models. In the 2-D model, the vacuum space, including the pillar arrays, was represented by a material whose effective thermal conductivity was determined from the specified vacuum space width, the heat conduction through the pillar array and the calculated radiation heat transfer between the two interior glass surfaces within the vacuum gap. In the 3-D model, the support pillar array was incorporated and modeled within the glazing unit directly. The difference in predicted overall heat transfer coefficients between the two …

Control Of The Nanoscale Crystallinity And Phase Separation In Polymer Solar Cells, Chih-Wei Chu, Hoichang Yang, Wei-Jen Hou, Jinsong Huang, Gang Li, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Grazing-incidence x-ray diffraction and atomic force microscopy were performed on bulk heterojunction regioregular poly(3-hexylthiophene) (RR-P3HT) [6,6]-phenyl-C₇₁-butyric acid methyl esters spin-cast films with different film processing conditions to correlate the crystalline nanostructure of P3HT with the corresponding solar cell performance. The increase in long wavelength absorption for solvent annealed films is related to highly conjugated crystal structure of RR-P3HT phase-separated in the active layer. Upon thermal annealing, the solvent annealed 50-nm-thick device shows high solar cell performance with fill factor up to 73% and power conversion efficiency of 3.80%.

Stereolithography Of Poly(Ethylene Glycol) Hydrogels With Application In Tissue Engineering As Peripheral Nerve Regeneration Scaffolds, Karina Arcaute

Open Access Theses & Dissertations

In recent years, rapid prototyping (RP) technologies initially developed to create prototypes prior to production for the automotive, aerospace, and other industries, have found applications in tissue engineering (TE). Several different RP technologies are being used to fabricate biocompatible 3D structures with controlled micro- and macro-scale characteristics. The focus of this research was to explore the capabilities of the RP technology, stereolithography (SL), for creating complex, 3D scaffolds with applications in TE using a photocrosslinkable biopolymer, poly(ethylene glycol) (PEG). The primary objective was to create an implantable multi-lumen nerve guidance conduit (NGC) for the regeneration of peripheral nerves.

Studies of …

A Study Of The Interaction Of Thioindigo Dye, With Several Inorganic Host Materials, Alejandra Ramirez

Open Access Theses & Dissertations

Maya Blue has been the focus of numerous studies and is believed to be a mixture of palygorskite clay and indigo dye.^1,2 Several derivatives of this pigment have been developed with intriguing properties. For instance, the dye thioindigo reacts with the palygorskite clay to exhibit a broad range of colors from red to blue under UV-Vis excitation. Based on FT-Raman and computer simulation, previous work performed in our group could relate indigo and thioindigo interaction to the aluminum sites in the framework. super>3,4

The work performed with other inorganic host materials such as, layer structures and zeolites have …

A Unified Methodology Of Maintenance Management For Repairable Systems Based On Optimal Stopping Theory, Hongye Wang

LSU Doctoral Dissertations

This dissertation focuses on the study of maintenance management for repairable systems based on optimal stopping theory. From reliability engineering’s point of view, all systems are subject to deterioration with age and usage. System deterioration can take various forms, including wear, fatigue, fracture, cracking, breaking, corrosion, erosion and instability, any of which may ultimately cause the system to fail to perform its required function. Consequently, controlling system deterioration through maintenance and thus controlling the risk of system failure becomes beneficial or even necessary. Decision makers constantly face two fundamental problems with respect to system maintenance. One is whether or when …

Electrochemical Fabrication Of Auco Nanostructures, Maoshi Guan

LSU Doctoral Dissertations

Electrodeposited Au/CoAu multilayered nanowires are materials with alternating layers of Au and CoAu in a wire where the layer thickness and wire diameter are nanometer size. They can be used for different applications. For example, the wires may exhibit giant magnetoresistance (GMR), a change in the materials resistance with a magnetic field, having applications as a sensor material for microdevices. If Co is etched from CoAu nanowires, rough, porous gold nanostructures will be left behind, which could be used as novel catalysts. In this study, the electrodeposition of Au/CoAu multilayered nanowires and nanotubes in nanoporous templates was explored from a …

Moderately-Rapid Assessment Of Alkaline Desiccation Environmental Systems, David Alan Bates

LSU Doctoral Dissertations

A moderately-rapid assessment tool was developed to analyze the waterless desiccation compost toilet investigated in a rural Mexican setting. Over 100 social factors were identified along with the applicable technical factors that influenced the low acceptability of the toilets. A 4-point rating scale was developed to increase the ability and speed of analyzing both the social and technical data. The treatment process was an alkaline-desiccation process with mean pH values of 8.2 ± sd 1.1 and water content of 18.3% ± sd 9.9, which resulted in mean fecal coliform values of 15.0 MPN/g ± sd 31.8, drastically lower than the …

Internal Cooling In Ribbed Rectangular (Ar=4:1) Passages At High Rotation Numbers And Improvement In Finning Strategies, Fuguo Zhou

LSU Doctoral Dissertations

Experimental studies have been performed on two-pass rectangular internal coolant channels with aspect ratio AR 4:1 with high rotation numbers. Three passages are investigated: smooth, 90 deg ribbed and 45 deg ribbed. A maximum Reynolds number of 150,000 and a maximum rotation number of 0.6 are achieved in the study. These maximum parameter values are considerably higher than those previously reported for the 4:1 AR geometry, and provide data for parameter ranges that may be representative of certain modern turbine blades. Heat transfer behaviors with rotation in the three passages are presented. Rotation effects, density effects and buoyancy effects are …

Stochastic Demand Forecast And Inventory Management Of A Seasonal Product A Supply Chain System, Mohammad Anwar Ashek Rahman

LSU Doctoral Dissertations

Estimation of seasonal demand prior to an active demand season is essential in supply chain management. The business cycle of the seasonal demand is divided into two stages: stage-1, the slow-demand period, and stage-2, the peak-demand period. The focus here is to determine an appropriate demand forecast for the peak-demand period. In the first set of forecasting model, a standard gamma and an inverse gamma prior distribution are used to forecast demand. The parameters of the prior model are estimated and updated based on current observation using Bayesian technique. The forecasts are derived for both complete and incomplete datasets. The …

Degradation And Water Quality Dynamics Of Sugarcane Residue In South Louisiana, Jose Roberto Deras

LSU Doctoral Dissertations

PURPOSE: This research was conducted to assess methods to manage the residue blanket to avoid open field burning in sugarcane. Experiments were conducted in the state of Louisiana to evaluate methods to asses and potentially reduce water quality issues. METHODS: Concentrations and frequencies of biological compost tea were sprayed on sugarcane combine-harvester residue blanket to increase degradation rate and reduce potential for runoff water to transport nutrients and sediments that may impair water bodies, while sustaining suitable sugarcane yield. Carbon dioxide evolution rate (mg CO2-C) and CO2 fluxes were measured in laboratory and in open field conditions; as an index …