Engineering Science and Materials Commons^™

High-Voltage Solid-State Lithium Batteries: A Review Of Electrolyte Design, Interface Engineering, And Future Perspectives, Cheng Yang, Zi-Xin Liang, Ming-Yun Zhang, Ming-Zhe Chen, Kai Zhang, Li-Min Zhou

Journal of Electrochemistry

Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance. The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte, which is expected to be commercialized in the future. However, in high voltage conditions (> 4.3 V), the decomposition of electrolyte components, structural degradation, and interface side reactions significantly reduce battery performance and hinder its further development. This review summarizes the latest research progress …

Development Trends And Priority Research Fields Of Electrochemical Discipline In The 15th Five Year Plan Period, Lin Zhuang, Wen-Bin Cai, Heng-Xing Ji, Qing Li, Gong-Wei Wang, Sen Xin, Qing Zhao, Fang-Yi Cheng, Yu-Guo Guo, Lan-Qun Mao, Yang Tian, Fei Wu, Li-Min Zhang, Yan Xiang, Jin-Song Hu, Rui Cao, Li Xiao, Hua-Bing Tao, Wei Xing, Dong-Ping Zhan, Hong-Gang Liao, Mei-Ling Xiao, Bin Ren, Zhang-Quan Peng, Rui Wen, Xiang Wang, Yue-Feng Song, Hou-Fu Lv, Bao-Yu Xia, Guo-Xiong Wang, Jun Cheng, Zhi-Pan Liu, Min Zhou, Bing Huang, Cun-Pu Li, Yu-Qin Zou, Shuang-Yin Wang, Hai-Bo Lin, Zi-Dong Wei

Journal of Electrochemistry

In fulfillment of the national science-and-technology development agenda, the Department of Chemical Sciences of the National Natural Science Foundation of China (NSFC) convened the Strategic Symposium on the Fifteenth Five-Year (2026–2030) Development Plan for Electrochemistry held in Xiamen on 29 August, 2025—the culminating year of the Fourteenth Five-Year (2021–2025) Development Plan. More than forty leading experts in the field of electrochemistry participated with spanning nine thematic fronts: Interfacial Electrocatalysis, Interfacial Electrochemistry for Energy Storage, Bioelectrochemistry, Electrochemistry of Hydrogen Energy, Electrochemical Micro-/Nano-Manufacturing, Operando Electrochemical Characterization, Electro-Thermal Coupling Catalysis, Theoretical and Computational Electrochemistry, and Electrochemical Synthesis. The forum assembled China’s foremost electrochemical …

Techno-Economic Analysis Of Hybrid Pv-Wind-Diesel Generator Swarm Grid For Rural Electrification In Tanzania, Ibrahim Mwammenywa

Tanzania Journal of Engineering and Technology (TJET)

Remote, rural, and off-grid communities, particularly in Sub-Saharan Africa (SSA), face significant challenges in securing reliable and affordable electricity. While solutions such as solar home systems (SHSs) and diesel generators (DGs) have been adopted by some individuals, their deployment is often not optimized to meet the full load demand. This study addresses this challenge by proposing a hybrid swarm grid (HSG) design that integrates photovoltaic (PV), wind energy, and diesel generators (DGs). Utilizing MATLAB/Simulink and HOMER, the HSG is modeled and optimized for a typical SSA village, incorporating real-world variables such as load demand profiles, solar irradiance, and wind patterns. …

Investigating The Harmonic Content Of A Pwm Inverter With Varying Modulation Index, Peter Makolo

Tanzania Journal of Engineering and Technology (TJET)

Photovoltaic energy is a clean and endless vital renewable energy. In order to generate electricity from solar energy an inverter is required to transform the direct current into alternating current. Also, with the emerging of new ultra-high voltage direct current transmission technology, the rectification and inverters play a great role. Most three-phase two-level inverters draw harmonics that cause heat dissipation, waveform distortions hence affect the electrical loads. Knowing that Total Harmonic Distortion content of voltage source inverter is important and must be within the allowable range. Several schemes are suggested to mitigate the distortion in order to produce as much …

Extraction Of Aluminum From Lunar Regolith Through Molten Salt Electrolysis, Jacob N. Ortega, Todd P. Sander, Jeffrey D. Smith, Fateme Rezaei, David J. Bayless, William Schonberg, Daniel S. Stutts, Frank D. Han

Materials Science and Engineering Faculty Research & Creative Works

This paper presents the methodology, development, and results of an end-to-end regolith-to-metal concept for producing aluminum in-situ on the lunar surface, namely, the Lunar In-Situ Aluminum Production through Molten Salt Electrolysis (LISAP-MSE) method. Using electrolytic reduction, aluminum oxide (i.e., alumina) can be reduced into aluminum and oxygen via electrolysis in a molten salt bath. A steady supply of hydrogen chloride could allow this in-situ resource utilization (ISRU) method to supply several necessary materials consumed in the electrolytic reduction step of the process to produce bulk aluminum metal, oxygen, water, and silica from anorthite abundant in lunar highland regions. In this …

Characterization Of The Fatigue Threshold Behavior Of Uhmwpe, Bethany B. Smith, Anurag Roy, Robert O. Ritchie, Lisa A. Pruitt

Faculty Journal Articles

Ultra-high-molecular-weight-polyethylene (UHMWPE) has been the material of choice for bearings in total joint replacements (TJRs) for decades as a result of its excellent wear resistance, chemical inertness, energetic toughness, low friction, and biocompatibility. Utilization of this polymer in orthopedic devices requires oxidation, wear, and fatigue resistance. Balancing these important properties by tailoring processing techniques and modulating microstructural features has been an ongoing endeavor in the field. Research into the clinical applications of UHMWPE has primarily focused on the challenges of wear and oxidation while studies into the realm of fatigue have been more limited. Literature gaps exist in fully understanding …

Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts, Ling Zhang, Wang-Yang Wu, Qiu-Yue Hu, Shi-Dan Yang, Li Li, Rui-Jin Liao, Zi-Dong Wei

Journal of Electrochemistry

The unavailability of high-performance and cost-effective electrocatalysts has impeded the large-scale deployment of alkaline water electrolyzers. Professor Zidong Wei’s group has focused on resolving critical challenges in industrial alkaline electrolysis, particularly elucidating hydrogen and oxygen evolution reaction (HER/OER) mechanisms while addressing the persistent activity-stability trade-off. This review summarizes their decade-long progress in developing advanced electrodes, analyzing the origins of sluggish alkaline HER kinetics and OER stability limitations. Professor Wei proposes a unifying “12345 Principle” as an optimization framework. For HER electrocatalysts, they have identified that metal/metal oxide interfaces create synergistic “chimney effect” and “local electric field enhancement effect”, enhancing selective …

Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance, Yu-Rong Liu, Miao Zhang, Yan-Hui Yu, Ya-Lin Liu, Jing Li, Xiao-Dong Shi, Zhen-Ye Kang, Dao-Xiong Wu, Peng Rao, Ying Liang, Xin-Long Tian

Journal of Electrochemistry

Development of robust electrocatalyst for oxygen reduction reaction (ORR) in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries (SZABs). Herein, constructing a local electric field coupled with chloride ions (Cl⁻) fixation strategy in dual single-atom catalysts (DSACs) was proposed, and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte, with a high half-wave potential (E_1/2) of 0.868 V and a good maximum power density (Pmax) of 182 mW·cm⁻² in the assembled SZABs, much higher than those of the Pt/C catalyst (E_1/2: 0.846 V; Pmax: 150 mW·cm^{−2 …}

Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries, Rong-Qi Liu, Wen-Shuo Shang, Jin-Tao Zhang

Journal of Electrochemistry

Zinc-iodine (Zn-I₂) batteries have emerged as a compelling candidate for large-scale energy storage, driven by the growing demand for safe, cost-effective, and sustainable alternatives to conventional systems. Benefiting from the inherent advantages of aqueous electrolytes and zinc metal anodes, including high ionic conductivity, low flammability, natural abundance, and high volumetric capacity, Zn-I₂ batteries offer significant potential for grid-level deployment. This review provides a comprehensive overview of recent progress in three critical domains: positive-electrode engineering, zinc anode stabilization, and in situ characterization methods. On the cathode side, anchoring iodine to conductive matrices effectively mitigates polyiodide shuttling and enhances …

Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping, Chang Lan, Jing-Sen Bai, Xin Guan, Shuo Wang, Nan-Shu Zhang, Yu-Qing Cheng, Jin-Jing Tao, Yu-Yi Chu, Mei-Ling Xiao, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

The weak adsorption energy of oxygen-containing intermediates on Co center leads to a considerable performance disparity between Co-N-C and costly Pt benchmark in catalyzing oxygen reduction reaction (ORR). In this work, we strategically engineer the active site structure of Co-N-C via B substitution, which is accomplished by the pyrolysis of ammonium borate. During this process, the in-situ generated NH₃ gas plays a critical role in creating surface defects and boron atoms substituting nitrogen atoms in the carbon structure. The well-designed CoB₁N₃ active site endows Co with higher charge density and stronger adsorption energy toward oxygen species, …

Influence On Shot Peening And Blast Polishing For Rotating Bending Fatigue Strength Of Vacuum Carburized Steel With Circumferential Notch, Yuji Kobayashi, Hayato Taniguchi, Kiyotaka Masaki

15th International Conference on Shot Peening

In order to improve fuel efficiency in automobiles, weight reduction is necessary as well as improving engine efficiency. For transmission gears, thickness reduction is necessary for weight reduction. When the thickness is reduced, the cross-sectional area becomes smaller, and the load stress increases. Therefore, higher fatigue strength is required. Most gears carry out carburizing. Shot peening is often used to improve the fatigue strength of carburized heat-treated parts. After shot peening, compressive residual stress is introduced, but at the same time, surface roughness is increased. Therefore, the processing conditions of shot peening are very important. Blast polishing is a processing …

Investigations On The Fatigue Strength Of Threads Produced By Different Fabrication Techniques, Philippe Du Maire, Jürgen Hoffmeister, Andreas Öchsner, Michael Johlitz

15th International Conference on Shot Peening

The increasing importance of sustainability in engineering demands the development of long-lasting, high-performance components that reduce material and energy consumption over time. This study investigates how different thread manufacturing processes, i.e., cutting, rolling, and deep rolling, affect the fatigue strength of bolts made from 42CrMo4+QT steel. Cylindrical specimens with M12 threads were subjected to cyclic tensile loading with constant mean stress. Fatigue strength was evaluated using the staircase method, and supporting analyses included X-ray diffraction for residual stress, and full width half maximum examination and Vickers microhardness measurements. Results show that thread rolling significantly improves fatigue strength, achieving 113.8 MPa …

Numerical Assessment Of Shot Peening Contribution To The Fatigue Strength Of Gear Tooth Root, Gurutz Cortabitarte Laucirica, Xuban Telleria, Iñigo Llavori, Ibai Ulacia, Miren Larrañaga, Jon Ander Esnaola

15th International Conference on Shot Peening

Gears are commonly treated with shot peening (SP) and/or case hardening to enhance fatigue resistance. However, their effects are often conservatively assessed using standardized methods, which can limit their optimal application in industrial components. Particularly, the effect of SP over case-hardened gears remains insufficiently explored. Therefore, the present study evaluates the contribution of SP on single tooth bending fatigue (STBF) strength of raw and case-hardened spur gears, commonly used in automotive and heavy machinery industries. In the study four conditions are addressed: (i) untreated, (ii) case-hardened, (iii) shot-peened, and (iv) case-hardened and shot-peened. First, the residual stress field of the …

Enhancing The Fatigue Strength Of Am Materials Via Mechanical Surface Treatment, Fabian Keil, Jan Schubnell, Sascha Fliegener, Alexander Heiss

15th International Conference on Shot Peening

Additive manufacturing (AM) processes, while enabling the production of intricate geometries, frequently result in suboptimal surface quality, which can significantly restrict the fatigue strength of components when compared to those manufactured using traditional methods. This study explores the effectiveness of mechanical surface treatment (MST) techniques, specifically shot peening and deep rolling, in enhancing the fatigue performance of additively manufactured AlSi10Mg and 316L alloys. A combination of experimental investigations and finite element simulations was employed to evaluate the influence of these treatments on surface integrity, microstructure, and fatigue life. The results reveal that both MST approaches lead to substantial improvements in …

Expansion Of Laser Peening Application With A High-Power Microchip Laser On A Robotic Arm, Yuji Sano, Yoshio Mizuta, Satoshi Tamaki, Tomonao Hosokai, Tomoharu Kato, Yoshihiro Sakino, Volker Schneidau, Sebastian Holz, Jörg Behler

15th International Conference on Shot Peening

Laser peening (LP) introduces compressive residual stress (RS) onto the surface of metallic materials using nanosecond laser pulses irradiated through a water layer, thereby effectively suppressing fatigue crack initiation. However, conventional LP systems require large, stationary setups, restricting their use to indoor environments. To overcome this limitation, a portable LP device featuring a finger-sized microchip laser mounted on a collaborative robot arm has been developed. Equipped with a compact power supply and a water circulation/recovery system, the device can operate on-site with minimal setup. Successful processing across various materials has confirmed both compressive RS induction and fatigue life extension. Notably, …

Effects Of Laser Peening On Fatigue Properties Of Welded Aluminum Thin Plates, Kiyotaka Masaki, Yoshio Mizuta, Satoshi Tamaki, Yuji Sano

15th International Conference on Shot Peening

To improve the fatigue properties of welded aluminum alloy thin plates used in transportation machinery, handheld laser peening (HH-LP) was applied to 2 mm-thick A5083-O specimens prepared by bead-on TIG welding. Conventional laser peening often causes warping in thin plates, but the HH-LP treatment using low-energy laser pulses avoids this problem. The HH-LP treatment introduced compressive residual stresses of over 200 MPa on the heat-affected zone (HAZ) of the welded specimens. Fatigue tests under plane bending conditions revealed that the HH-LP treatment significantly improved the fatigue strength of the welded specimens, achieving a level comparable to that of the base …

Nonlinear Analytical Models Of The Seismically Isolated ``Frame-Boiler'' System With Cantilever-Type Hysteresis Dampers, Aleksandr Mikhailovich Anushchenko, Dmitrii Evgenievich Bondarev, Aleksandr Yurievich Schukin

Journal of Sustainable Construction Materials and Technologies

This study shows results of development of the ``frame-boiler'' system with hysteresis dampers analytical model. Hysteresis dampers are used as boiler antiseismic bracing. It is noted that simplified analytical models are necessary at the stage of preliminary iterative calculations, when a CAE-modeling is impractical due to significant time costs. The authors have proposed 2 options of analytical models: 2-mass model and 3-mass model. The differential equations of motion for each model are written below. The results of the calculation for seismic impacts are compared with the finite element model. It is shown that 3-mass model gives good match of results …

Advancing Sustainable Structural Solutions: Hemp Fiber-Reinforced Polymer (Hfrp) Reinforcement Bars For Concrete Applications Through Material Selection, Simulation, And Pathways For Future Development, Thomas Cadenazzi, Busra Keles

Journal of Sustainable Construction Materials and Technologies

This paper investigates innovative Hemp Fiber-Reinforced Polymer (HFRP) rebars as a sustainable alternative to conventional Carbon Steel (CS) and Glass Fiber-Reinforced Polymer (GFRP) rebars used as reinforcement in concrete structures. The feasibility of HFRP rebars is assessed, focusing on mechanical properties and sustainability advantages. A virtual tensile test on a modeled M19 HFRP rebar, conducted using Autodesk's Fusion 360, demonstrates tensile strength comparable to CS 235 and greater environmental sustainability than GFRP, despite a slight reduction in stiffness. The study also considers the potential of graphene fiber integration to enhance mechanical properties, underscoring HFRP's adaptability. Findings suggest that HFRP rebars, …

Comparative Analysis Of Life Cycle Assessment Of Traditional And Contemporary Timber Buildings, Sadık Akşar, Gökçe Tuna

Journal of Sustainable Construction Materials and Technologies

Wood has long been used as a primary building material, but with the Industrial Revolution and the spread of multi-story structures, its structural limitations became evident. In the 21st century, engineered timber products have reintroduced wood as a sustainable alternative, offering advantages such as lightness, rapid assembly, and recyclability. At the same time, buildings are responsible for significant environmental impacts, making assessment methods essential. Life Cycle Assessment (LCA) is one of the most widely used tools for evaluating these impacts across all stages of a building’s life cycle. This study applies LCA to timber construction systems, focusing on both traditional …

Sustainable Paving Block Development: Utilizing Rejected Coal As Filler And Assessing Its Impact On Paving Block’S Properties, Siti Nikmatin, Allen Kurniawan, Heriansyah Putra, Rima Fitria Adiati, Riawan Ma’Ruf, Dwi Arso Yedi Irwanto

Journal of Sustainable Construction Materials and Technologies

This study investigated the potential use of rejected coal as a fine aggregate filler in paving block production. Comprehensive characterization of the rejected coal was conducted, including toxicity, physical, chemical, and mineralogical analyses of the coal. The results showed that the rejected coal met environmental safety standards (TCLP) and had suitable properties as an aggregate. Paving blocks were produced by incorporating different proportions of rejected coal fillers and were tested for compressive strength, water absorption, and density. The optimal mix with 35% rejected coal filler as a replacement of stone ash achieved a compressive strength of 14.61 MPa, water absorption …

Numerical Comparative Study Of The Thermal Performance And Load-Bearing Capacity Of Hollow Clay Bricks Used In Construction In Libya, Osama Lawej, Mahmoud Ahmed, Ismael Ehtiwesh

Journal of Sustainable Construction Materials and Technologies

The optimization of structural and thermal performance in building components is a key challenge in sustainable construction, particularly in hot climate regions like Libya. Hollow clay bricks are widely used due to their local availability and affordability; however, their internal geometry is often not optimized for thermal resistance or mechanical integrity. This study addresses this gap by numerically investigating the effect of cavity geometry on the load-bearing capacity and thermal insulation performance of hollow clay bricks. Three configurations were analyzed, including two commercial designs from the Libyan market and a newly proposed arched cavity design. Finite Element Method (FEM) simulations …

Developing A Modular Circular Wall Over-Clad System For Facade Thermal Upgrade In Deep Energy Retrofit, Patrick Daly

Journal of Sustainable Construction Materials and Technologies

The EU has implemented several policy and legislative initiatives aimed at decarbonisation and circularity transition of the Built Environment including a strategy for large scale renovation of the building / housing stock. Modularised construction solutions are argued to be a potential acceleration pathway toward this objective. Yet there remains issues and challenges in implementing such strategies in a complex and heterogeneous stock and sector. This research investigates this decarbonisation pathway, examining the feasibility and potential of applying a modularised construction over-clad system, based on advanced circularity, in the deep energy retrofit of social housing. The research is based on a …

Effect Of Gelam Wood And Rice Husk Composition With Molding Pressure On The Combustion Performance Of Biopellets, Rachmat Subagyo, Rudi Siswanto, Ma’Ruf Ma’Ruf, Mastiadi Tamjidillah, Abdul Ghofur, Femiana Gapsari, M. Zainul Rusdi, Azie Aprianto, Wardoyo Wardoyo, Naila Salsabila

Journal of Mechanical Engineering Science and Technology (JMEST)

This study investigates the effects of gelam wood (Melaleuca leucadendron) and rice husk composition in biopellet production, focusing on compaction pressures of 60, 80, and 100 kg/cm². Five biomass ratios (G100–RH0, G80–RH20, G60–RH40, G50–RH50, G0–RH100) were tested for moisture, ash, fixed carbon, volatile matter, calorific value, ignition time, burning rate, and combustion temperature. Results showed that moisture content ranged from 0.98% (G0–RH100, 60 kg/cm²) to 12.28% (G100–RH0, 80 kg/cm²), while ash content varied between 2.47% (G100–RH0, 60 kg/cm²) and 20.93% (G0–RH100, 80 kg/cm²). The highest calorific value reached 3968 cal/g (G100–RH0, 60–80 kg/cm²), though below the SNI 8675:2018 minimum of …

Experimental And Numerical Investigation On The Effect Of Projectile Mass And Apex Angle On Penetration Depth Into Sandy Soils, Abdul-Rahman K. Osman, Ahmed Elshesheny Dr, Mohamed S. Zahran Dr, Nabil M. Nagy Prof.

Journal of Engineering Research

Projectile penetration in granular soils remains a critical concern in defense engineering and ballistics research. This study presents an experimental and numerical investigation of rigid cone-tip projectile penetration into very dense sand, examining the influence of apex angle and projectile weight on penetration depth. Laboratory experiments were conducted using metallic projectiles with apex angles of 10°, 30°, 60°, and 90° and weights of 2.445, 3.87, 5.33, and 6.81 kg, dropped from a height of 4.295 m into a 500×500×500 mm wooden tank filled with sand to 400 mm height at 95% relative density. Through systematic testing, two empirical correlation …

A Polar Turbulence Invariant Map With Applicability To Realisable Machine Learning Turbulence Models, James G. Wnek, Christopher Schrock, Eric M. Wolf, Mitch Wolff

Mechanical and Materials Engineering Faculty Publications

Invariant maps are a useful tool for turbulence modelling, and the rapid growth of machine learning-based turbulence modelling research has led to renewed interest in them. They allow different turbulent states to be visualised in an interpretable manner and provide a mathematical framework to analyse or enforce realisability. Current invariant maps, however, are limited in machine learning models by the need for costly coordinate transformations and eigendecomposition at each point in the flow field. This paper introduces a new polar invariant map based on an angle that parametrises the relationship of the principal anisotropic stresses, and a scalar that describes …

Detecting Electrical Submersible Pump (Esp) Failures And Estimating Run Life Using Artificial Neural Networks, Mostafa Ahmed Sobhy

Theses and Dissertations

Electric Submersible Pumps (ESPs) are one of the important artificial lift methods for sustaining production in mature and high-water-cut wells; but may suffer frequent failures due to mechanical, electrical, hydraulic, chemical, and operational failures. These failures can yield substantial deferred production and intervention costs. Plenty of ESP installations are fitted with downhole sensors. Yet, it is observed that the current industry practice underutilizes the wealth of available sensor and operational data and lacks standardized, explainable failure-type identification and classification.

In this thesis, a comprehensive Machine Learning (ML) and Deep Learning (DL) framework was introduced for ESPs that simultaneously estimates remaining …

Tensile Creep Of A Hybrid Polymer-Matrix/Ceramic-Matrix Composite At Elevated Temperature, Waleed S. Alshehri

Theses and Dissertations

Advanced aerospace systems require structural materials that can perform reliably in high-temperature environments for long durations. The performance of standard polymer matrix composites (PMCs) in these conditions is often limited by their susceptibility to time-dependent deformation, such as creep. The objective of this research is to characterize the high-temperature creep behavior of a novel unitized material system comprising a polymer matrix composite (PMC) and a ceramic matrix composite (CMC) co-cured together. The PMC part consists of the polyimide matrix reinforced with laminated carbon fibers woven in an eight harness satin weave (8HSW). The CMC part consists of a zirconia-based ceramic …

A Green Concrete Mixture Using Rice Husk As Partially Cement Replacement, Khloud Khalid Eldamshiry, Zeina Salama, Amany Micheal, Rania Rushdy Moussa, Ayatallah Raafat

Architectural Engineering

Egypt's agricultural waste production has increased significantly in recent decades, leading to improper disposal methods and environmental pollution. Rice husks are the most common agricultural solid waste in Egypt, contributing to "black clouds" and causing health issues. On the other hand, Cement, a crucial component of construction materials, generates unsound residues and greenhouse gas emissions. Green concrete with rice husks could be a profitable solution for environmentally sound construction, reducing cement consumption and increasing the durability and integrity of new materials. This study investigates the use untreated rice husk fibres with a concrete mixture, avoiding burning and contributing to environmental …

Design And Optimization Of Anode Catalysts For Direct Ethanol Fuel Cells: Advances And Challenges In C-C Bond Activation And Selective Modulation Of The C1 Pathway, Kai-Chi Qin, Meng-Tian Huo, Yu Liang, Si-Yuan Zhu, Zi-Hao Xing, Jin-Fa Chang

Journal of Electrochemistry

Direct ethanol fuel cells (DEFCs) are a promising alternative to conventional energy sources, offering high energy density, environmental sustainability, and operational safety. Compared to methanol fuel cells, DEFCs exhibit lower toxicity and a more mature preparation process. Unlike hydrogen fuel cells, DEFCs provide superior storage and transport feasibility, as well as cost-effectiveness, significantly enhancing their commercial viability. However, the stable C–C bond in ethanol creates a high activation energy barrier, often resulting in incomplete electrooxidation. Current commercial platinum (Pt)- and palladium (Pd)-based catalysts demonstrate low C–C bond cleavage efficiency (

Effect Of Saccharin On Crystallization Behavior Of Electroless Cobalt Plating, Yu-Xin Luo, Jing-Jing Wang, Lu Wang, Zi-Yi Yan, Yi Ma, Xin Bo, Jing-Shuang Dang, Zeng-Lin Wang

Journal of Electrochemistry

In the process of electroless cobalt plating, the saccharin additive can significantly change the surface morphology, texture orientation, and conductivity of the cobalt coating layer. When the amount of saccharin was 3 mg·L^–1, the cobalt coating transformed from disordered large grains to a honeycomb structure, with a preferred orientation of (002) facet on hexagonal close-packed (HCP) cobalt crystals. The resistivity of the cobalt film decreased to 14.4 μΩ·cm, and further decreased to 10.7 μΩ·cm after the annealing treatment. When the concentration of saccharin was increased, the grain size was gradually refined and a “stone forest” structure was observed, …