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Articles 151 - 180 of 5710
Full-Text Articles in Engineering Science and Materials
Mechanical Properties And Crystallization Of Polybutylene Terephthalate Reinforced With Glass Flakes And Aluminum Powder, Nattakarn Hongsriphan, Pajaera Patanathabutr
Mechanical Properties And Crystallization Of Polybutylene Terephthalate Reinforced With Glass Flakes And Aluminum Powder, Nattakarn Hongsriphan, Pajaera Patanathabutr
Journal of Metals, Materials and Minerals
This research investigated mechanical properties and crystallization of poly(butylene terephthalate) composites by adding glass flakes (GF) and aluminum particles (Al). The concentration of the GF was 3 wt% or 5 wt%, and the Al was 0.5 wt% or 1.0 wt%. The stress-strain curves of the PBT-based composites showed yielding and necking. The PBT/GF/Al composites with GF/Al ratios of 3/0.5 wt/wt%, 3/1.0 wt/wt%, 5/0.5 wt/wt%, and 5/1.0 wt/wt% had Young’s moduli of 11.44%, 11.70%, 16.81%, and 19.31% higher than that of neat PBT, respectively. In the presence of Al at 1.0 wt%, the flexural modulus of the PBT/GF/Al composites increased to …
Synthesis, Structure, And Electrochemical Properties Of The Ni(Oh)2/Nimoo4 Composite On The Rgo/Nf Template For Hybrid Battery-Supercapacitor Electrodes, Retno Asih, Haniffudin Nurdiansah, Rogabe Sianipar, Ida Ayu Gayatri, Lukman Noerochim, Diah Susanti, Isao Watanabe, Darminto Darminto
Synthesis, Structure, And Electrochemical Properties Of The Ni(Oh)2/Nimoo4 Composite On The Rgo/Nf Template For Hybrid Battery-Supercapacitor Electrodes, Retno Asih, Haniffudin Nurdiansah, Rogabe Sianipar, Ida Ayu Gayatri, Lukman Noerochim, Diah Susanti, Isao Watanabe, Darminto Darminto
Journal of Metals, Materials and Minerals
The growing demand for renewable and sustainable energy has intensified research on advanced energy-storage systems that can deliver both high energy and power densities. In this study, a Ni(OH)2/ NiMoO4 composite on a reduced graphene oxide/nickel foam (rGO/NF) template was synthesized through a hydrothermal and electrodeposition route to construct a hybrid battery-supercapacitor electrode. The unique hierarchical design combines the pseudocapacitive activity of Ni(OH)2/NiMoO4 with the excellent conductivity of rGO and the high surface area of NF, enabling efficient electron and ion transport. Structural and morphological analyses confirm the successful formation of the Ni(OH)2/NiMoO4/rGO/NF architecture. The electrode exhibits a specific capacitance …
Development Of Poly(Lactic Acid)/Ethylene-Propylene-Diene Monomer/Cellulose Composites Using Cellulose Extracted From Hemp Biomass For Plastic Packaging Applications, Supanicha Alapon, Natthanich Thongmee, Wikoramet Teeka, Pattara Somnuake, Sirirat Wacharawichanant
Development Of Poly(Lactic Acid)/Ethylene-Propylene-Diene Monomer/Cellulose Composites Using Cellulose Extracted From Hemp Biomass For Plastic Packaging Applications, Supanicha Alapon, Natthanich Thongmee, Wikoramet Teeka, Pattara Somnuake, Sirirat Wacharawichanant
Journal of Metals, Materials and Minerals
Poly(lactic acid)/ethylene-propylene-diene monomer (EPDM)/cellulose composites using cellulose derived from hemp biomass (CHB) were investigated in this research. Morphology, chemical structures, functional groups, and crystallinity of CHB were characterized, observing a size of 135 ± 32 μm from SEM images with high purity and crystallinity from FT-IR and XRD spectroscopy. The optimized CHB was incorporated at 1 phr, 3 phr, and 5 phr into PLA/EPDM blends at 90/10 w/w. The polymer composites were prepared using an internal mixer, and samples were produced by compression molding for mechanical and thermal testing. The results indicated that the EPDM phase dispersed as droplets in …
Effect Of Cu Content On Microstructure, Morphology, And Antibacterial Properties Of Ti-Cu Alloy Thin Films, Chittra Kedkaew, Phalakorn Khwansungnoen, Tanattha Rattana
Effect Of Cu Content On Microstructure, Morphology, And Antibacterial Properties Of Ti-Cu Alloy Thin Films, Chittra Kedkaew, Phalakorn Khwansungnoen, Tanattha Rattana
Journal of Metals, Materials and Minerals
Ti-Cu alloy thin films exhibit considerable potential for the development of advanced antibacterial surfaces, particularly for biomedical applications. In this research, Ti-Cu binary alloy thin films with a wide range of Cu content from 25.8 at% to 77.8 at% were deposited using magnetron co-sputtering with pure Ti and Cu as the targets. The composition of Cu in the films can be controlled by the applied power of Cu targets. This study investigated the effect of Cu content on the microstructural, morphological, and antibacterial properties using X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Atomic force microscopy (AFM), X-ray photoelectron …
Contributions Of Carbon Content And Cooling Rate On Phase Transformations And Mechanical Properties Of Sintered Fe-1.5cr-0.2mo-Xc Alloys, Mantana Yaruan, Wantana Koetniyom, Thanyaporn Yotkaew, Nattaya Tosangthum, Ruangdaj Tongsri
Contributions Of Carbon Content And Cooling Rate On Phase Transformations And Mechanical Properties Of Sintered Fe-1.5cr-0.2mo-Xc Alloys, Mantana Yaruan, Wantana Koetniyom, Thanyaporn Yotkaew, Nattaya Tosangthum, Ruangdaj Tongsri
Journal of Metals, Materials and Minerals
Microstructural development in sintered Fe-1.5Cr-0.2Mo-xC alloys, produced under different cooling rates of 0.1℃∙s‒1 and 5.4℃∙s‒1, was investigated. It was found that, in slowly sintered Fe-1.5Cr-0.2Mo-xC alloys, the microstructure changed from hypoeutectoid to eutectoid and to hypereutectoid steel microstructural features with increasing carbon content. Under the fast-cooling rate of 5.4℃∙s‒1, the microstructural change with respect to the increase of carbon content involved the competition between the formation of ferrite + carbide mixture and that of martensite-austenite constituent. The increase of tensile strength of slowly cooled sintered Fe-1.5Cr-0.2Mo-xC alloys with increasing carbon content was attributed to …
Effect Of Garnet Incorporation On The Functional Properties Of Sunscreens, Parinya Chakartnarodom, Kanyarat Munmani, Sureerat Polsilapa, Duangrudee Chaysuwan, Wichit Prakaypan, Passakorn Sonprasarn, Edward Laitila, Nuntaporn Kongkajun
Effect Of Garnet Incorporation On The Functional Properties Of Sunscreens, Parinya Chakartnarodom, Kanyarat Munmani, Sureerat Polsilapa, Duangrudee Chaysuwan, Wichit Prakaypan, Passakorn Sonprasarn, Edward Laitila, Nuntaporn Kongkajun
Journal of Metals, Materials and Minerals
Garnet, a silicate mineral, was investigated as a replacement for the TiO2-based compound in sunscreen formulations. Samples containing garnet were evaluated for color shade, viscosity, sun protection factor (SPF), and water resistance. Substituting the TiO2-based compound with garnet reduced both viscosity and SPF but markedly enhanced water resistance. This improvement is attributed to the physical reinforcement provided by garnet particles, which strengthen the sunscreen film and reduce wash-off under water exposure. Garnet incorporation also altered the product’s appearance from white to a darker brownish-beige tone, improving visual compatibility with a wider range of skin tones.
Effects Of Welding Currents On Microstructure And Corrosion Behaviors Of Inconel 625 Cladding On 2.25cr-1mo Steel By Hot-Wire Tig, Supparat Saeheng, Hein Zaw Oo, Prapas Muangjunburee
Effects Of Welding Currents On Microstructure And Corrosion Behaviors Of Inconel 625 Cladding On 2.25cr-1mo Steel By Hot-Wire Tig, Supparat Saeheng, Hein Zaw Oo, Prapas Muangjunburee
Journal of Metals, Materials and Minerals
Hot-wire tungsten inert gas (HW-TIG) cladding has been applied to the steam turbine rotor welding repair. This study investigated the effects of welding currents on microstructure, hardness, and corrosion behavior. The experiments were conducted using four different welding currents applied to bead-on-plate Inconel 625 welds on a 2.25Cr-1Mo steel substrate as the steam turbine rotor material. The selected welding currents were 125 A, 150 A, 175 A, and 200 A. The percentages of weld dilution for different welding currents were also evaluated. Higher welding currents increased weld dilution, weld bead width, and HAZ size. As the welding current increased, the …
Properties And Printability Of Polylactic Acid Films : An Effect Of Polyglutamate Coated Natto As A Bio-Plasticizer, Natrata Thitinardwong, Thira Chavarnakul, Kawee Srikulkit
Properties And Printability Of Polylactic Acid Films : An Effect Of Polyglutamate Coated Natto As A Bio-Plasticizer, Natrata Thitinardwong, Thira Chavarnakul, Kawee Srikulkit
Journal of Metals, Materials and Minerals
Polylactic acid (PLA) film, a biodegradable alternative to petroleum-based plastics, has gained significant attention for sustainable packaging applications. However, its limited screen-printability remains a barrier to broader commercial use. This study aims to enhance the screen-printability of PLA film by incorporating a polyglutamate coated natto (designated as Nat-M). PLA/Nat-M films having 1%, 3%, and 5% Nat-M were prepared and evaluated for their key performance indicators, including ink adhesion (ASTM D3359), tone reproduction accuracy, and printing resolution. The screen-printing resolution was optimized between 400 DPI and 500 DPI (dots per inch) to achieve optimal tone reproduction and edge sharpness. Additionally, ink …
A Top-Electrode-Based Liquid-Solid Triboelectric Nanogenerator For Energy Harvesting And Ethanol Detection, Subrat Bhol, Nakul Charan Sahu, Sunit Gaurav Mohanty, Vicky Raj Maddala, Basanta Kumar Panigrahi, Premkumar Bhosale
A Top-Electrode-Based Liquid-Solid Triboelectric Nanogenerator For Energy Harvesting And Ethanol Detection, Subrat Bhol, Nakul Charan Sahu, Sunit Gaurav Mohanty, Vicky Raj Maddala, Basanta Kumar Panigrahi, Premkumar Bhosale
Journal of Metals, Materials and Minerals
Liquid-solid triboelectric nanogenerators (LS-TENGs) offer a promising avenue for self-powered energy harvesting and sensing by exploiting contact electrification at fluid-dielectric interfaces, where droplet dynamics drive charge separation for electrical output without external power. In this work, a top-electrode LS-TENG was fabricated using a polytetrafluoroethylene (PTFE) film on a PMMA substrate with deionised water droplets, achieving an open-circuit voltage of ‒3.4 V, short-circuit current of 3.6 μA, and peak power of 1.48 nW at 100 MΩ under optimised conditions of 2 cm drop height, 45° tilt, and 50 μL volume. Performance scaled with droplet kinetics and volume due to enhanced contact …
Strategic Optimization Of Plasticizers, Fillers, And Blend Ratios For Enhanced Performance Of Dynamically Cured Epoxidized Natural Rubber (Enr)/Polypropylene (Pp) Thermoplastic Vulcanizates, Azizon Kaesaman, Anuwat Worlee, Charoen Nakason
Strategic Optimization Of Plasticizers, Fillers, And Blend Ratios For Enhanced Performance Of Dynamically Cured Epoxidized Natural Rubber (Enr)/Polypropylene (Pp) Thermoplastic Vulcanizates, Azizon Kaesaman, Anuwat Worlee, Charoen Nakason
Journal of Metals, Materials and Minerals
This study introduces an innovative methodology for optimizing oil, plasticizer, filler, and blend proportions in epoxidized natural rubber with 20 mol% epoxide (ENR-20) and polypropylene (PP) thermoplastic vulcanizates (TPVs), aiming to achieve superior rheological, mechanical, morphological, and thermal performance. By leveraging paraffinic oil, epoxidized soybean oil, and phthalate-based plasticizers, the research investigates their influence on tensile strength, elasticity, and processability. Among the oils and plasticizers evaluated, paraffinic oil demonstrated the most effective plasticizing performance, offering superior flexibility and elasticity. Various paraffinic oil loadings (15 phr, 25 phr, 30 phr, 35 phr, 40 phr, 45 phr, 50 phr, and 75 phr) …
Impact Of Chromium Substitution On Structural And Magnetic Properties Of Mnbi-Based Melt-Spun Ribbons, Anh Kha Vuong, Triet Minh Dang, Truong Xuan Nguyen, Duy Anh Vo Nguyen, Hai Van Pham, Nam Hoai Nguyen, Nam Hong Pham, Oanh Kim Thi Vuong, Tan Nhut Nguyen Le, Tuan Van Dinh, Nam Thanh Tran Nguyen, Nhan Thi Tran, Trung Quoc Nguyen, Nhan Thi Tran, Trung Quoc Nguyen, Lu Wei, Vuong Van Nguyen
Impact Of Chromium Substitution On Structural And Magnetic Properties Of Mnbi-Based Melt-Spun Ribbons, Anh Kha Vuong, Triet Minh Dang, Truong Xuan Nguyen, Duy Anh Vo Nguyen, Hai Van Pham, Nam Hoai Nguyen, Nam Hong Pham, Oanh Kim Thi Vuong, Tan Nhut Nguyen Le, Tuan Van Dinh, Nam Thanh Tran Nguyen, Nhan Thi Tran, Trung Quoc Nguyen, Nhan Thi Tran, Trung Quoc Nguyen, Lu Wei, Vuong Van Nguyen
Journal of Metals, Materials and Minerals
MnBi-based magnetic materials and magnets are of significant interest due to their magnetism without rare earth elements and their ability to replace Nd-Fe-B in high-temperature magnet applications due to its unique feature of enhancing coercivity in the range of 100℃ to 250℃, enabling their energy product (BH)max comparable to NdFeB magnets despite their moderate spontaneous magnetization Msp. To adjust the magnetic properties of MnBi magnets, various elements have been doped to regulate magnetic interactions among the atoms, which subsequently alters Msp and the magneto-crystalline anisotropy energy. In this work, we investigate the effects of chromium doping on the magnetic properties …
Cold Sintering-Assisted Low Temperature Fabrication Of Dense Ba5 Nb4 O15 Ceramics, Usa Sukkha, Apichayaporn Teandam, Phakkhananan Pakawanit, Phitsamai Kamonpha, Wanwilai Vittayakorn, Phieraya Pulphol, Naratip Vittayakorn
Cold Sintering-Assisted Low Temperature Fabrication Of Dense Ba5 Nb4 O15 Ceramics, Usa Sukkha, Apichayaporn Teandam, Phakkhananan Pakawanit, Phitsamai Kamonpha, Wanwilai Vittayakorn, Phieraya Pulphol, Naratip Vittayakorn
Journal of Metals, Materials and Minerals
This study presents a novel approach for fabricating Ba5Nb4O15 (BNO) ceramics at low sintering temperatures via the cold sintering process (CSP), using Ba(OH)2∙8H2O (BOH) as a transient liquid phase. CSP was performed under an external pressure of 10 MPa with a sintering temperature range of 150℃ to 300℃. Optimally, BNO-BOH ceramics achieved a relative density of 93.7 ± 0.43% when sintered at 250℃ for 1 h. Scanning electron microscopy (SEM) suggested that particle densification occurred via a dissolution-precipitation process, which filled pores and formed necks between particles. The study demonstrates that the residual liquid content is crucial for ceramic densification. …
Fabrication Of A Chitosan‒Fe3o4/Activated Carbon/Tio2 Nanocomposite As A Pb(Ii) Heavy Metal Adsorbent, Berliantty Warim Putri, Arif Hidayat, Lya Rizka Herawati, Poppy Puspitasari, Nandang Mufti, Yap Wing Fen, Muhammad Safwan Abdul Aziz, Tahta Amrillah, Ahmad Taufiq
Fabrication Of A Chitosan‒Fe3o4/Activated Carbon/Tio2 Nanocomposite As A Pb(Ii) Heavy Metal Adsorbent, Berliantty Warim Putri, Arif Hidayat, Lya Rizka Herawati, Poppy Puspitasari, Nandang Mufti, Yap Wing Fen, Muhammad Safwan Abdul Aziz, Tahta Amrillah, Ahmad Taufiq
Journal of Metals, Materials and Minerals
Nowadays, water pollution by heavy metal Pb(II) is a significant issue in many countries, including Indonesia. To overcome this problem, a suitable and efficient waste treatment method is necessary. Therefore, in this work, Fe3O4/AC/TiO2 nanocomposite modified with chitosan (CS) for the treatment of Pb (II) waste were investigated. CS was used due to its OH and NH2 functional groups, which enable the formation of a new hybrid nanocomposite that can be used repeatedly. To reduce production costs, environmentally friendly, raw natural materials, such as iron sand, coconut shells, and shrimp shells, were employed. The XRD characterization results indicate that the …
Advanced Hemp-Based Hybrid Composites: A Study On The Influence Of Various Nanofillers On Mechanical And Morphological Properties, Velmurugan Ganesan, Jasgurpreet Singh Chohan, Muthukumar V., Nagaraj M., Lakshmi Narayana S.
Advanced Hemp-Based Hybrid Composites: A Study On The Influence Of Various Nanofillers On Mechanical And Morphological Properties, Velmurugan Ganesan, Jasgurpreet Singh Chohan, Muthukumar V., Nagaraj M., Lakshmi Narayana S.
Journal of Metals, Materials and Minerals
This study investigates the mechanical and microstructural attributes of epoxy composites with hemp fiber reinforcements and incorporated aluminum oxide (Al2O3), silicon dioxide (SiO2), and magnesium oxide (MgO) nanoparticles at different weight fractions of 0.5 wt%, 1.0 wt%, and 1.5 wt%. Nano-fillers remarkably improved the composite performance, as indicated by tensile and flexural tests conducted by ASTM D3039 and ASTM D790 standards. The composite containing 1.5 wt% Al2O3 outperformed other nano filled composites with a tensile strength of 64 MPa and tensile modulus of 3.6 GPa, versus 52 MPa and 3.0 GPa for the unfilled hemp/epoxy composite. In parallel, flexural strength …
Sintering Behavior And Mechanical Properties Of Ha-Ysz-Ti Composite Sintered By Spark Plasma Sintering, Seyed Mohsen Fatemi, Iman Mobasherpour, Leila Nikzad, Mansour Razavi
Sintering Behavior And Mechanical Properties Of Ha-Ysz-Ti Composite Sintered By Spark Plasma Sintering, Seyed Mohsen Fatemi, Iman Mobasherpour, Leila Nikzad, Mansour Razavi
Journal of Metals, Materials and Minerals
This research is aimed to determine the best composition of composite fabricated by Spark Plasma Sintering (SPS) to produce a suitable substituent for bone. The applied powder was prepared by the SPS method and comprises hydroxyapatite (HA), yttria-stabilized zirconia (YSZ), and titanium (Ti). Different percentages of components were used to fabricate the composite samples. X-ray diffraction was used to determine the structural phase of the sintered samples while field emission scanning electron microscopy (FE-SEM) was employed for microstructural analysis of the specimens. The behavior of the samples was investigated during sintering. The gas release, displacements, and porosity percentage of the …
Antibacterial Characterization Of Ciprofloxacin-Doped Electrospun Of Low Molecular Weight Polyethylene Oxide (Peo) And Sodium Alginate (Naalg) Nanofibers, Phuphinee Niyomchon, Treesukon Treebupachatsakul, Kasama Srirussamee
Antibacterial Characterization Of Ciprofloxacin-Doped Electrospun Of Low Molecular Weight Polyethylene Oxide (Peo) And Sodium Alginate (Naalg) Nanofibers, Phuphinee Niyomchon, Treesukon Treebupachatsakul, Kasama Srirussamee
Journal of Metals, Materials and Minerals
Producing nanofibers using the electrospinning technique is a developed method that is widely used and of significant interest nowadays. This technique can be applied using various types of polymers. This research aimed to investigate the antibacterial PEO-NaAlg nanofiber fabrication. The fiber fabrication was examined under various viscosities of electrospinning solution. The electrospun nanofiber fabrication focuses on blending polyethylene oxide (PEO) with a molecular weight of 200-300 kDa, mixed with sodium alginate (NaAlg) of three different viscosities: 150 cP, 300 cP, and 730 cP to study how the viscosity of the solution affects the morphology of electrospun nanofibers. The PEO-NaAlg electrospun …
Effects Of Various Heat Treatment Cycles On Mechanical Properties And Wear Resistance Of 65mn Carbon Steel, Amir Abbas Mojahedi, Seyed Abdolkarim Sajjadi, Fatemehsadat Sayyedan
Effects Of Various Heat Treatment Cycles On Mechanical Properties And Wear Resistance Of 65mn Carbon Steel, Amir Abbas Mojahedi, Seyed Abdolkarim Sajjadi, Fatemehsadat Sayyedan
Journal of Metals, Materials and Minerals
The aim of the present study is to investigate the effect of various heat treatment cycles on mechanical properties and wear resistance of 65Mn carbon steel. For this purpose, five different heat treatment cycles including normalizing, austenitizing, quenching, and tempering were performed at different austenitization temperatures and tempering times. Subsequently, effects of the parameters on tensile strength, toughness, hardness, and wear resistance of the heat-treated samples were investigated. X-ray diffraction (XRD) and scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS) were employed to analyze microstructure of heat-treated samples. To study the wear resistance of the samples after …
Two-Step Sputtering For Depositing Smooth And Thin Zno Films On Non-Heated, Non-Epiready Pet Substrates, Nattaya Tajina Yossapong, Annop Klamchuen, Kittipong Tantisantisom, Ekkaphop Ketsombun, Taworn Intaro, Sakuntam Sanorpim, Warakorn Yanwachirakul
Two-Step Sputtering For Depositing Smooth And Thin Zno Films On Non-Heated, Non-Epiready Pet Substrates, Nattaya Tajina Yossapong, Annop Klamchuen, Kittipong Tantisantisom, Ekkaphop Ketsombun, Taworn Intaro, Sakuntam Sanorpim, Warakorn Yanwachirakul
Journal of Metals, Materials and Minerals
Highly crystalline, smooth-surface, and thin zinc oxide (ZnO) films have been successfully deposited on flexible polyethylene terephthalate (PET) substrates using an optimized two-step RF magnetron sputtering technique at ambient temperature. The PET used in this study was a commercially available overhead projector film, which was not epiready-grade and had a lower melting point (~150℃). This issue made high-quality deposition more challenging. In the first step, a thin ZnO buffer layer was deposited at low RF power to provide a smooth and thermally stable surface. This layer served as both a structural template and a thermal barrier during the subsequent high-power …
Sodium Alginate/Aloe Vera/Mangosteen Peel Extraction Hydrogel Composite Films With Anti-Staphylococcal Properties As A Promising Alternative Material In Biomedical Applications, Pruss Chimwai, Poonyarat Apikarnsakulchai, Tirawit Jindaratanaporn, Witsanu Liangaumnuay, Thitima La-Ongthitirat, Purin Somnuake, Pattara Somnuake
Sodium Alginate/Aloe Vera/Mangosteen Peel Extraction Hydrogel Composite Films With Anti-Staphylococcal Properties As A Promising Alternative Material In Biomedical Applications, Pruss Chimwai, Poonyarat Apikarnsakulchai, Tirawit Jindaratanaporn, Witsanu Liangaumnuay, Thitima La-Ongthitirat, Purin Somnuake, Pattara Somnuake
Journal of Metals, Materials and Minerals
This study focuses on the development of alternative biodegradable hydrogel films from sodium alginate as a matrix and curing into a hydrogel by CaCl2. Thus, the aloe vera (AV) and the crude extract of mangosteen peels (MPE) were additionally blended. The polymer films were prepared using the casting film process, and their morphology, functional groups, water absorption, antibacterial, thermal, and mechanical properties were characterized using SEM, FTIR, water swelling test, disk diffusion method, DSC-TGA, and UTM. The results demonstrated the heterogeneity between the composites and the polymer matrix, and a lower polarity from the decreased %water swelling from 45% to …
Li5feo4 As A Cathode Prelithiation Additive : Doping Engineering And First-Principles Research, Zixiang Li, Zile Zou, Jialan Li, Chennan Ma, Jiarun Li, Xiaoyu Liu, Jin Yi, Jianhui Li
Li5feo4 As A Cathode Prelithiation Additive : Doping Engineering And First-Principles Research, Zixiang Li, Zile Zou, Jialan Li, Chennan Ma, Jiarun Li, Xiaoyu Liu, Jin Yi, Jianhui Li
Journal of Metals, Materials and Minerals
During the initial charge-discharge cycle, irreversible loss of active lithium (~ 5% to 15%) severely affects the battery energy density and shortens cycle life of lithium‑ion batteries (LIBs). Prelithiation strategy has gradually become an effective approach to compensate for the irreversible loss of active lithium. Lithium ferrate (Li5FeO4, LFO) is considered to be a promising cathode prelithiation additive due to its high theoretical capacity (867 mAh·g‒1), suitable delithiation potential (3.5 V to 4.1 V), and competitive raw material. However, the application of LFO is limited by the its properties including poor air stability, low electronic conductivity, and incomplete delithiation. Currently, …
Synergistic Adsorption–Photocatalysis Of Activated Carbon/Titanium Dioxide Composite Derived From Rice Husk Ash Under Ultraviolet-C Irradiation, Bang-Tam Thi Dao, Do Trung Nguyen, Nhien Hon Le, Chi-Nhan Ha-Thuc
Synergistic Adsorption–Photocatalysis Of Activated Carbon/Titanium Dioxide Composite Derived From Rice Husk Ash Under Ultraviolet-C Irradiation, Bang-Tam Thi Dao, Do Trung Nguyen, Nhien Hon Le, Chi-Nhan Ha-Thuc
Journal of Metals, Materials and Minerals
Rice husk ash (RHA), an abundant biomass residue, was employed as a sustainable precursor for synthesizing activated carbon (AC) and its TiO2-based photocatalyst composite. AC was produced via ultrasonication-assisted NaOH activation of KOH-impregnated biochar, yielding a highly porous material with a large surface area. Titanium dioxide nanoparticles were synthesized from titanium (IV) isopropoxide (TTIP) and subsequently immobilized onto AC to form the AC/TiO2 composite. Structural and textural analyses (XRD, FT-IR, BET, SEM–EDS) confirmed the presence of anatase TiO2 uniformly distributed within the AC framework while preserving its porous architecture. The photocatalytic activity of the composite was assessed using Basic Blue …
Role Of Alkali And Alkaline-Earth Doped In Zeolite A-Derived From Industrial Waste Toward Direct Ethanol Dehydrogenation To Acetaldehyde, Darunee Sukchit, Malee Prajuabsuk, Chan Inntam, Saisamorn Lumlong, Bongkochawan Pakamwong, Auradee Punkvang, Duangkamol Gleeson, Pantita Trongjitraksa, Paramasivam Shanmugam, Supakorn Boonyuen, Niramol Juntarachat, Sasijuta Wattanarach, Parjaree Thavorniti, Bunjerd Jongsomjit, Pornpan Pungpo
Role Of Alkali And Alkaline-Earth Doped In Zeolite A-Derived From Industrial Waste Toward Direct Ethanol Dehydrogenation To Acetaldehyde, Darunee Sukchit, Malee Prajuabsuk, Chan Inntam, Saisamorn Lumlong, Bongkochawan Pakamwong, Auradee Punkvang, Duangkamol Gleeson, Pantita Trongjitraksa, Paramasivam Shanmugam, Supakorn Boonyuen, Niramol Juntarachat, Sasijuta Wattanarach, Parjaree Thavorniti, Bunjerd Jongsomjit, Pornpan Pungpo
Journal of Metals, Materials and Minerals
In this study, a sustainable catalytic route for converting ethanol into value-added acetaldehyde was developed using alkali- and alkaline earth-modified zeolite A synthesized from sugarcane bagasse ash (SCBA). Zeolite A was first prepared via alkaline fusion followed by hydrothermal crystallization and subsequently doped with 1 wt% K+ or Ca2+ using incipient wetness impregnation. Comprehensive physicochemical characterization (X-ray fluorescence (XRF), X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX), Fourier transform infrared spectroscopy (FTIR), nitrogen physisorption (N2 physisorption), ammonia temperature-programmed desorption (NH3-TPD), and carbon dioxide temperature-programmed desorption (CO2-TPD)) confirmed the formation of a highly crystalline LTA framework with tunable …
Graphene-Based Materials From Liquid Phase Exfoliation Of Graphite Using Mangosteen-Peel Extract : Experiments And Molecular Simulation, Piyaphat Thepphot, Narissara Karakate, Panu Danwanichakul
Graphene-Based Materials From Liquid Phase Exfoliation Of Graphite Using Mangosteen-Peel Extract : Experiments And Molecular Simulation, Piyaphat Thepphot, Narissara Karakate, Panu Danwanichakul
Journal of Metals, Materials and Minerals
The conventional Hummers method for graphene production requires large quantities of hazardous chemicals, causing environmental impacts and sustainability concerns. This study investigated mangosteen-peel extract as a natural alternative in liquid phase exfoliation of graphite, exploiting the structural similarity between condensed tannins and graphite, which enables π−π interactions. Four exfoliation processes were studied: shear force via a homogenizer (9,500 rpm and 14,000 rpm for 41 min), sonication using an ultrasound bath (200 W and 400 kHz) for 2 h and 3 h at 50℃ and their sequential combinations. The results confirmed successful graphite exfoliation yielding samples with I2D/IG ratios of 0.51 …
Sustainable Lightweight Foams From Hazardous Aluminum Dross, Chayapat Weerapakdee, Makoto Nanko, Yen-Ling Kuo, Sukasem Watcharamaisakul, Kaito Suzuki, Seiryu Suzuki, Siriwan Chokkha
Sustainable Lightweight Foams From Hazardous Aluminum Dross, Chayapat Weerapakdee, Makoto Nanko, Yen-Ling Kuo, Sukasem Watcharamaisakul, Kaito Suzuki, Seiryu Suzuki, Siriwan Chokkha
Journal of Metals, Materials and Minerals
Aluminum dross is a hazardous byproduct from aluminum industry that causes environmental problems and high disposal cost. This work presents a sustainable route to upcycle secondary aluminum dross into lightweight ceramic foams for insulating refractory applications. Secondary aluminum dross powder was blended with polyethylene (PE) pore-forming agents (30 vol% to 70 vol%) and polyvinyl alcohol (PVA) binder added as a 7.5 wt% aqueous solution (binder contents: 1 vol% and 3 vol%), followed by pressing and sintering at 1400℃. Increasing PE systematically reduced bulk density and increased open porosity. At 70 vol% PE, the foams reached a bulk density of 0.94 …
Magnetocaloric Effect Of Gdtbdyerpr Rare-Earth High-Entropy Alloy, Yu Liu, Lei Gao, Jun Peng, Haitao Guo
Magnetocaloric Effect Of Gdtbdyerpr Rare-Earth High-Entropy Alloy, Yu Liu, Lei Gao, Jun Peng, Haitao Guo
Journal of Metals, Materials and Minerals
In this study, a GdTbDyErPr rare-earth high-entropy alloy (RE HEA) was successfully synthesized and its magnetic properties and magnetocaloric effect (MCE) were systematically investigated. The results indicate that the as-cast GdTbDyErPr RE HEA exhibits a single-phase hexagonal close-packed (HCP) structure with lattice parameters of a = 3.609 Å and c = 5.734 Å. Based on large parameter Ω, high mixing entropy (ΔSmix), and small parameters δ and εi, it can be inferred that the GdTbDyErPr alloy forms a disordered solid solution. The GdTbDyErPr RE HEA undergoes a first-order magnetic transition near about 143 K. The parameters |∆ |, RC, and …
Investigating The Effects Of Lamno. On The Morphology, Structural And Optical Properties Of Epoxy-Based Plastic Scintillators, Yeni Febrianti, Airine Hijrah Handayani, Marzuki Naibaho, Phahul Zhemas Zul Nehan, Zulkarnain -, Arbi Dimyati, Budhy Kurniawan
Investigating The Effects Of Lamno. On The Morphology, Structural And Optical Properties Of Epoxy-Based Plastic Scintillators, Yeni Febrianti, Airine Hijrah Handayani, Marzuki Naibaho, Phahul Zhemas Zul Nehan, Zulkarnain -, Arbi Dimyati, Budhy Kurniawan
Journal of Metals, Materials and Minerals
Plastic scintillators are widely used in radiation detection due to their low cost, fast response, and ease of fabrication, although their performace is often limited by low density, low atomic number, make them less efficient for applications requiring high-energy radiation. In this study, LaMnO3 was synthesized using the hydrothermal method and employed as a dopant to enhance the optical and scintillation properties of epoxy-based plastic scintillators. Structural, morphological, and optical characterizations of LaMnO3 were carried out using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), energy-dispersive spectroscopy (EDS), UV-Vis and photoluminescence (PL) spectroscopy. The results confirm that …
Effect Of Mgo On Crawling And Physical Properties In Ceramic Glazes, Thongpanchang Timclub, Pathitta Anuraksombat, Thatree Muangkaew, Niti Yongvanich
Effect Of Mgo On Crawling And Physical Properties In Ceramic Glazes, Thongpanchang Timclub, Pathitta Anuraksombat, Thatree Muangkaew, Niti Yongvanich
Journal of Metals, Materials and Minerals
This study attempted to seek and verify the scientific aspects responsible for crawling in ceramic glazes. The selected additive was magnesium oxide (MgO). The glazes were applied on porcelain biscuits and fired between 1100℃ and 1300℃. The degree of crawling was enhanced with increasing amount of MgO, which was accompanied by formation of forsterite (Mg2SiO4) as a major phase. Complete island separation was achieved with 10 wt% MgO with good wettability and shiny surface. The morphology of the glaze demonstrated this phase as small crystals within the glaze layer. Addition of MgO resulted in a continuous decrease in the thermal …
Enhancing Aqueous Solubility Of A Psoralen Derivative Via Cyclodextrin Inclusion Complexation : In Silico And In Vitro Study, Gulzaib Basharat, Saba Ali, Pattharamon Chaikhun, Choosak Jaroenrit, Kuakarun Krusong, Thanthapatra Bunchuay, Tanatorn Khotavivattana, Thanyada Rungrotmongkol
Enhancing Aqueous Solubility Of A Psoralen Derivative Via Cyclodextrin Inclusion Complexation : In Silico And In Vitro Study, Gulzaib Basharat, Saba Ali, Pattharamon Chaikhun, Choosak Jaroenrit, Kuakarun Krusong, Thanthapatra Bunchuay, Tanatorn Khotavivattana, Thanyada Rungrotmongkol
Journal of Metals, Materials and Minerals
N-(4-Bromobenzoyl)-8-methoxypsoralen-4-amine (BNB) is a psoralen derivative with potent cytotoxic activity against breast cancer cells but with limited pharmaceutical application and therapeutic potential due to its extremely low aqueous solubility. To overcome this limitation, β-cyclodextrin (βCD) and its derivatives dimethyl-βCD (DMβCD), hydroxypropyl-βCD (HPβCD), and sulfobutylether-βCD (SBEβCD) were investigated as carriers to enhance BNB's aqueous solubility via cyclodextrin inclusion complexation. A combined computational–experimental strategy was employed, integrating molecular docking, 500-ns all-atom molecular dynamics simulations in quintuplicate runs (2.5 µs in total), and experimental validation by phase solubility analysis, scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). Docking and simulations revealed …
The Performance Of The Heat Affected Zone Of 9% Ni Steel Narrow Gap Joint Performed By The Gmaw Process With Rotating Electrode, Jorge Carlos Ferreira Jorge, Jeferson Frederico Monteiro Costa, Matheus Campolina Mendes, Luís Felipe Guimarães De Souza, Hiron Akira Yamada Magalhães, Leonardo Sales Araújo
The Performance Of The Heat Affected Zone Of 9% Ni Steel Narrow Gap Joint Performed By The Gmaw Process With Rotating Electrode, Jorge Carlos Ferreira Jorge, Jeferson Frederico Monteiro Costa, Matheus Campolina Mendes, Luís Felipe Guimarães De Souza, Hiron Akira Yamada Magalhães, Leonardo Sales Araújo
Journal of Metals, Materials and Minerals
This work investigates the mechanical properties and microstructural evolution of the heat-affected zone of 9% Ni steel narrow-gap welded joints produced by the GMAW process with a rotating electrode, since no literature on this subject is available. This process is an innovation of the GMAW process, which permits narrow gap welding because the circular motion of the electrode overcomes the main issue of the sidewall's lack of fusion observed in the conventional process. However, the rotation movement of the electric arc imposes a higher peak temperature at the heat affected zone, which can negatively affect the mechanical properties. The joints …
Synthesis And Characterization Of New Graft Copolymers Based On Ozonized Polyethylene: Comparative Approach Between Mass And Solution Grafting, Mostapha Karaoui, Samira Kharchouf, Houda El Yakoubi, Kaouthar Boumane, Mohammed Assouag
Synthesis And Characterization Of New Graft Copolymers Based On Ozonized Polyethylene: Comparative Approach Between Mass And Solution Grafting, Mostapha Karaoui, Samira Kharchouf, Houda El Yakoubi, Kaouthar Boumane, Mohammed Assouag
Journal of Metals, Materials and Minerals
New graft copolymers were developed from low-density polyethylene (LDPE) and high-density polyethylene (HDPE) following an initial ozonation step to introduce reactive functional groups onto the polymer backbone. Among the two polymers, LDPE demonstrated superior susceptibility to ozonation, making it the preferred substrate for subsequent grafting. Grafting was then performed primarily on ozonized LDPE using various functional monomers, including acrylic acid (AA), 4-vinylpyridine (4VP), acrylonitrile (AN), chloromethylstyrene (CMS), as well as copolymers such as AA–vinylphosphonic acid (AA-co-VPA) and AN–vinylphosphonic acid (AN-co-VPA). Grafting was carried out using both solution and melt techniques. The resulting materials were characterized by elemental analysis and Fourier …