Digital Commons Network^™

Minimizing Cr-Evaporation From Balance Of Plant Components By Utilizing Cost-Effective Alumina-Forming Austenitic Steels, Lingfeng Zhou

Graduate Theses, Dissertations, and Problem Reports (ETD)

A solid oxide fuel cell (SOFC) is a clean and efficient energy conversion device. The development of intermediate-temperature SOFCs has made it preferable to use metallic interconnects (MICs) to greatly reduce the cost and significantly increase the efficiency compared to ceramic interconnect materials. However, gaseous chromium species will evaporate from the chromium-containing layer formed on the surface of commonly used MICs and balance of plant (BoP) components. Volatile chromium species have been shown to form solid deposits which poison the cathodes of SOFCs, causing drastic cell performance degradation and thereby limiting commercialization. In order to alleviate the Cr poisoning and …

Examining Evolutionary Rate In Xiphosura, Samantha B. Ocon

Graduate Theses, Dissertations, and Problem Reports (ETD)

Horseshoe crabs, a group of aquatic chelicerate arthropods of the class Xiphosura, are strongly linked with the concept of “living fossils” – a term colloquially used to refer to clades that display a consistently low rate of morphological evolution through time. The concept of living fossils has been hotly debated, as it is considered to simplify or obscure millennia of evolutionary change. Recent methodological and computational advances in the paleobiological sciences have allowed for the investigation of these claims. Xiphosura are a model taxon for this type of investigative study because they exhibit a complex evolutionary history, despite their reputation …

Freeze! The Impact Of A Guided Imagery Intervention On Looming Vulnerability And Subclinical Contamination-Ocd Symptoms, Amber Lynn Billingsley

Graduate Theses, Dissertations, and Problem Reports (ETD)

Looming vulnerability (LV) refers to the tendency to appraise and perceive potential threats as dynamic and increasing in risk. Research suggests that contamination-fearful individuals may have an increased tendency to interpret contamination as growing or spreading (i.e., “looming”), which may hinder habituation to contamination and play a role in the maintenance of contamination-OCD symptoms. Studies have shown that engaging in imagery in which one mentally freezes contamination in place decreases state levels of fear, though little is known about its longer-term effects (e.g., after one week). The present study aimed to experimentally manipulate LV using freeze imagery in a subclinical …

Embodied Energy Geographies: An Exploration Of Fracked Landscapes In The Ohio River Valley, Rachael L. Hood

Graduate Theses, Dissertations, and Problem Reports (ETD)

Methane gas production has boomed across the United States as a result of the development of fracking technology and its associated infrastructures, including pipelines. This production has provoked resistance over a litany of environmental and social concerns at both global and local scales. These concerns are compounded by a history of extractive economies and degradation in the Marcellus shale region of Appalachia and the Ohio River Valley. To date, there has been limited research at the intersection of extractive industry and emotional geography, especially around pipelines. This research draws on feminist, emotional, and energy geographies and uses semi-structured interviews and …

Examining The Pulmonary Response To Repeated Vishniacozyma Victoriae Exposure And Its Association With Allergic Airway Disease, Rachael Erin Rush

Graduate Theses, Dissertations, and Problem Reports (ETD)

Allergic airway diseases such as asthma continue to increase in incidence in industrialized nations like the United States. These diseases are complex inflammatory processes involving numerous cells and mediators and are strongly influenced by fungal exposures. Recent developments in fungal detection methods have highlighted the contribution of Basidiomycota yeast species in indoor environments such as Vishniacozyma (syn. Cryptococcus) victoriae. However, despite the high levels of this yeast detected in indoor environments, very little is known about it or its role in respiratory morbidity. V. victoriae is phylogenetically similar to pathogenic Cryptococcus neoformans but lacks a capsule and is …

Examining The Relationship Among Perceived Academic Climate, Belongingness, And Engineering Identity, Sumaia Ali Raisa

Graduate Theses, Dissertations, and Problem Reports (ETD)

An attempt to cultivate an inclusive learning environment in engineering is trending as a response to women's underrepresentation and a lower retention rate than men undergraduates. This study was situated in such an undergraduate engineering program where interventions were embedded in the course curriculum focusing on cultivating an inclusive engineering identity. Following a sociocultural perspective, the present study aimed to examine the relation of engineering identity with perceived academic climate, sense of belonging, and gender among two engineering cohorts (before covid and during covid context). A total of 482 first-year engineering undergraduates' survey responses were analyzed in this study using …

Designing And Achieving Airness: Theatrical Lighting Design Of Airness By Chelsea Marcantel, Colleen Marie Doherty

Graduate Theses, Dissertations, and Problem Reports (ETD)

This is the account of the lighting design process for Airness by Chelsea Marcantel. This show was designed using all my learned skills and the equipment available. This account will take the reader through an analysis of the play, the design process, research, technical process, and it concludes with a self-evaluation. This thesis is supported by outside sources, images, and documentation.

Chemical Characterization Of Clastic Cave Sediments And Insights Into Particle Transport And Storage In Karst Aquifers, Jill L. Riddell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Chemical characterization of clastic cave sediments and insights into particle transport and storage in karst aquifers

Jill L. Riddell

Cave sediments can be divided into two groups: precipitates and clastics. Precipitates are speleothems, or lithologic or mineral features that are chemically precipitated in the cave environment. Clastic cave sediments are frequently described by depositional facies, sorting, and particle size (Bosch and White, 2004). Robust analytical chemical analyses of these sediments to quantify their physical and chemical components is rarely performed although some chemical characterization of mineralogy and paleomagnetism has become prevalent in recent years (Chess et al., 2010; Sasowsky …

Overstepping: U.S. Immigration Judges And The Power To Develop The Record, Jayanth K. Krishnan

Articles by Maurer Faculty

In 1952, Congress established a new federal position to be filled by “special inquiry officers” charged with overseeing deportation cases. These immigration judges—as they eventually came to be called—were assigned to work within the executive branch, namely, the Department of Justice, and they were to be answerable ultimately to a political appointee, the attorney general. Importantly, they received specific statutory authority allowing them to “develop the record” during an immigration case. This power enabled immigration judges to assemble evidence and call, “interrogate, examine, and cross‑examine . . . any witnesses.”

Given that many immigrants who appear in immigration court do …

Optimization And Analytics Of Decarbonized Forest And Biomass Supply Chains, Xufeng Zhang

Graduate Theses, Dissertations, and Problem Reports (ETD)

First, a data-driven holistic analysis framework was developed to aid the industrial development of forest biomass for bioenergy to promote the regional bioeconomy. Leveraging the existing but fragmented multi-source data, four components of industrial bioenergy development were integrated into the framework including spatial statistical analysis of biomass feedstock and bioenergy production, machine learning-based suitability assessment, bioenergy plant sites identification and ranking, and socio-economic impacts assessment. A case study was conducted for forest biomass to pellet fuel in the U.S. Mid-Atlantic region. Our results indicate that the great potential of forest biomass with high variation at the county level is primarily …

The Impact Of Perceived Daily Racism And Racial Identity Development On Body Dissatisfaction Among Asian American Female College Students, Mary E. Burkhart Polk

Graduate Theses, Dissertations, and Problem Reports (ETD)

Eating disorders pose a significant health problem for a diverse group of people. However, knowledge regarding their origins and appropriate treatments has not expanded, more specifically for Asian Americans. This study aimed to increase the knowledge surrounding an essential component of disordered eating, body dissatisfaction, and potential factors in its development. Specifically, the impact of experiences of daily racism and racial identity development on body dissatisfaction among Asian American college women were examined. Using a non-experimental, quantitative survey design, this study assessed the relationship between perceived daily racism and the racial identity schema Internalization on the endorsement of body dissatisfaction …

Athlete Attachment Style With Coaches As A Predictor Of Athlete Disordered Eating And Body Image Anxiety, Taylor Allen

Graduate Theses, Dissertations, and Problem Reports (ETD)

The coach-athlete relationship has been established as an important and significant relationship within athletes’ lives (Davis & Jowett, 2010; Jowett, 2008). There is also literature that demonstrates the impact of the sport culture environment and the quality of the coach-athlete relationship on disordered eating and body image anxiety in athletes (Galli et al., 2011; Petrie & Greenleaf, 2012; Reel et al., 2010; Shanmugam et al., 2013). However, much of the current literature does not examine this significant coach-athlete relationship from an attachment framework. Current literature supports the significance of the coach-athlete relationship and more recent research supports viewing coaches as …

Behaviors, Contextual Influences, And Consequences: Relationships That Affect Student Decision-Making Of Academic Misconduct In College, Justine A L Burnett

Graduate Theses, Dissertations, and Problem Reports (ETD)

Academic misconduct on college campuses is not a new challenge for higher education institutions but an old problem that has changed considerably. Student demonstrations of academic misconduct behaviors have evolved, making it difficult for institutions to consistently keep well-informed on how students cheat to effectively respond to violations of academic integrity policies. This study investigates the relationships between misbehaviors, their associated consequences, and influences to prevent, respond to, and reduce academic misconduct at a large research-intensive university.

This quantitative study uses institutional academic misconduct reports between 2017 and 2020 and student surveys to examine significant relationships in the decision-making process …

Does U.S. Federal Employment Law Now Cover Caste Discrimination Based On Untouchability?: If All Else Fails There Is The Possible Application Of Bostock V. Clayton County, Kevin D. Brown, Lalit Khandare, Annapurna Waughray, Kenneth G. Dau-Schmidt, Theodore M. Shaw

Articles by Maurer Faculty

This article discusses the issue of whether a victim of caste discrimination based on untouchability can assert a claim of intentional employment discrimination under Title VII or Section 1981. This article contends that there are legitimate arguments that this form of discrimination is a form of religious discrimination under Title VII. The question of whether caste discrimination is a form of race or national origin discrimination under Title VII or Section 1981 depends upon how the courts apply these definitions to caste discrimination based on untouchability. There are legitimate arguments that this form of discrimination is recognized within the concept …

Organized For Service: The Hicks Classification System And The Evolution Of Law School Curriculum, John L. Moreland

Articles by Maurer Faculty

This article traces the origins and development of the Hicks Classification System, an in-house organizational scheme used by the Yale Law Library from the late 1930s to the 1990s. It explores the relationship between the Hicks Classification System and the changing pedagogical methods of the law school curriculum during the early part of the 20th century. It provides a brief biographical sketch of Frederick C. Hicks, creator of the scheme, the need for a legal classification system, a detailed analysis of Hicks’s scheme, its finding aids, and a discussion of the inherent cultural biases in the system.

Targeting Vulnerabilities In Cell State And Calcium Signaling For The Treatment Of Lung Cancer, Clark Jones

Graduate Theses, Dissertations, and Problem Reports (ETD)

Lung cancer remains the deadliest of all cancers due to the high mutational burden associated with the disease. Combating mutational drivers and drug resistance proves to be essential in the development of novel therapies to improve patient outcomes. A first-in-class cyclic peptide known as MTI-101 has been shown to induce necrotic cell death in a caspase independent manner. MTI-101 was derived from the linear peptide known as HYD1 that was found in a high throughput screen to block cell adhesion with the extracellular matrix. The compound was further optimized and cyclized to the currently used MTI-101 that was found to …

Analysis Of Forensically Relevant Evidence Using Electrochemistry, Spectroscopy, And Mass Spectrometry Tools, Colby Edward Ott

Graduate Theses, Dissertations, and Problem Reports (ETD)

Forensic science relies on the use of multiple techniques in the assessment of evidence to increase the accuracy and reliability of the results. However, with the rapidly changing drug landscape due to the introduction of novel psychoactive substances, many traditional screening methods are no longer sensitive or selective enough for use. Additionally, many screening methods such as chemical color tests are prone to false positive and negative results and are subjective. Therefore, the goal of this dissertation was to develop a novel analytical scheme that can provide a more efficient, rapid, and sensitive method that will facilitate adoption in the …

Reinforcement Learning For Process Control: Applications To Energy Systems, Elijah Ballard Hedrick

Graduate Theses, Dissertations, and Problem Reports (ETD)

Reinforcement learning (RL) is a machine learning method that has recently seen significant research activity owing to its successes in the areas of robotics and gameplaying (Silver et al., 2017). However, significant challenges exist in the extension of these control methods to process control problems, where state and input signals are nearly always continuous and more stringent performance guarantees are required. The goal of this work is to explore ways that modern RL algorithms can be adapted to handle process control problems; avenues for this work include using RL with existing controllers such as model predictive control (MPC) and adapting …

Impact Of Haemonchus Contortus On Feed Efficiency And Feeding Behavior Of Katahdin And Suffolk Lambs, Camren L. Maierle

Graduate Theses, Dissertations, and Problem Reports (ETD)

Nutritional impact of internal parasitism, specifically Haemonchus contortus (Hc), is a significant contributor to production losses in small ruminants. Both chronic and subclinical infections generate millions of dollars of losses worldwide. Understanding the nutritional impact of Hc on lamb performance is crucial in determining the additional nutrient requirements of infected individuals. The aim of this study was to evaluate nutritional impact of Hc on infected Katahdin lambs with extensive genetic selection for parasite resistance and susceptible Suffolk lambs. Growth, feeding behavior, and feed efficiency (RFI. F:G) were evaluated during artificial Hc infection. Katahdin ewes from the Virginia …

Small Mammal Communities Of Restored And Natural Wetlands In West Virginia, Krista Noe

Graduate Theses, Dissertations, and Problem Reports (ETD)

Wetland restoration is commonly practiced as part of conservation programs or wetland mitigation, which attempts to offset human-created losses of natural wetlands. However, because of the intrinsic and human-derived value of wetlands, it is critical to determine whether these wetlands truly act similarly to natural wetlands. One role of wetlands is to provide habitat for a diverse array of wildlife species. Small mammals are often overlooked taxa in wetland restoration efforts. However, they are essential to the wetland system because they influence vegetation and are prey for higher trophic level wildlife. I discuss considerations of restored wetlands, wildlife responses to …

Development Of Machine Learning Algorithm To Identify High-Emitters From On-Road Data For Heavy-Duty (Hd) Vehicles, Filiz Kazan

Graduate Theses, Dissertations, and Problem Reports (ETD)

The process of on-road, heavy-duty engine family certification is regulated by the United States Environmental Protection Agency (US EPA). Currently, the US EPA 2010 emissions standards require the threshold from the Federal Testing Procedure (FTP) engine dynamometer cycle to be at or below a brake-specific NO_x (bs-NO_x) value of 0.20 g/bhp-hr for heavy-duty (HD) engines. The engine manufacturers are also required to conduct in-use portable emission measurement system (PEMS) testing to prove their products' compliance. The selected vehicles are required to satisfy not-to-exceed (NTE) analysis under normal driving conditions in the heavy-duty in-use testing (HDIUT) program. California …

Investigating The Mitochondrial Protein Mitoneet In C. Elegans Models Of Aging And Alzheimer's Disease, Jacob Ryan Boos

Graduate Theses, Dissertations, and Problem Reports (ETD)

Oxidative stress is an imbalance between reactive oxygen species production and elimination, favoring the former. Reactive oxygen species serve as important signaling molecules for physiological homeostasis. However, when produced in excess, these once important signaling molecules become detrimental, disrupting cellular functions, and ultimately leading to cell death. In aging, reactive oxygen species production is increased, accompanied with reductions in oxidative stress resistance, increasing the risk for developing age-related diseases including cardiovascular disease, cancer, stroke, and neurodegenerative diseases. The outer mitochondrial membrane iron-sulfur cluster containing protein mitoNEET (CISD1; gene CISD1) has shown to be a mediator of mitochondrial function and …

Machine Learning Approach To Health Risk Determination, Levi Butcher Cole

Graduate Theses, Dissertations, and Problem Reports (ETD)

In the United States, cardiovascular disease is the leading cause of death for both men and women. The factors that contribute to heart disease are well known but it is still an ever-evolving field of research. The possible benefits to being able to determine an individual’s Health Risk could provide the early insights needed to combat cardiovascular disease. However, two major problems within this area are the public availability of a dataset and the label imbalances for the dataset. In this thesis, we present a framework for exploring health risk using a combination of the NHANES dataset and open-source machine …

Low-Temperature Hot Corrosion Of Boilers In The Coal-Fired Power Plant, Artem Gavrilev

Graduate Theses, Dissertations, and Problem Reports (ETD)

Hot corrosion of materials has remained a relevant topic since its introduction in the second half of the 20th century as gas turbine engines suffered severe corrosion during operation over seawater. Hot corrosion is observed in a multitude of high temperature components, such as gas turbines, power plants, refineries, fluidized bed combustion systems, pipelines, and industrial waste incinerators.

Hot corrosion experiments in the laboratory have been conducted under constant temperatures of interest, while in the actual working conditions of coal-fired power plants, boiler tubes are cooled down via water cooling from a relatively high fireside temperature, e.g., 1000°C. To investigate …

“The Virus Of Liberty”: John Perry Barlow, Internet Law, And Grateful Dead Studies, Joseph A. Tomain

Articles by Maurer Faculty

In 2019, the Duke Law and Technology Review published a special issue titled, "The Past and Future of the Internet: A Symposium for John Perry Barlow." This essay examines the legal scholarship in the Barlow symposium and frames it in the interdisciplinary terms of Grateful Dead studies. Part I focuses on the two Barlow essays that formed the basis of the symposium. Part II connects issues raised by the Barlow symposium to Grateful Dead studies. The essay concludes that Barlow's legacy should inspire others to engage both the cultural and political paths with “groundless hope,” because protecting the “inexplicable pleasures …

Classifying Blood Glucose Levels Through Noninvasive Features, Rishi Reddy

Graduate Theses, Dissertations, and Problem Reports (ETD)

Blood glucose monitoring is a key process in the prevention and management of certain chronic diseases, such as diabetes. Currently, glucose monitoring for those interested in their blood glucose levels are confronted with options that are primarily invasive and relatively costly. A growing topic of note is the development of non-invasive monitoring methods for blood glucose. This development holds a significant promise for improvement to the quality of life of a significant portion of the population and is overall met with great enthusiasm from the scientific community as well as commercial interest. This work aims to develop a potential pipeline …

Vaping During Pregnancy: Effects On Vascular And Behavioral Outcomes In Offspring, Eiman A. Aboaziza

Graduate Theses, Dissertations, and Problem Reports (ETD)

Electronic cigarette (e-cig) use is increasing due to aggressive marketing, tempting flavors, and seemingly higher acceptability in the community (lesser perceived social stigma) despite unproven claims of safety. In an alarming trend, pregnant women smokers have turned to novel “modified risk” products, such as e-cigs, in response to heavy marketing of e-cigs as safer alternatives to cigarettes and a tool to help quit smoking. This is despite proven detrimental effects of nicotine on a growing fetus, and scarcity of information regarding toxicity of e-liquid (with and without nicotine) on child development. Moreover, rampant e-cig use among youth (nearly 4 million …

Evaluate The Efficacy Of A Mixture Of Peroxyacetic Acid And H2o2 Against The Survival And Cross-Contamination Of The Salmonella Surrogate Enterococcus Faecium On Tomatoes During Triple-Wash, Corey Waitman Coe

Graduate Theses, Dissertations, and Problem Reports (ETD)

Triple-wash with a mixture of peroxyacetic acid and H2O2 (SaniDate-5.0) during post-harvest processing of fresh produce has been recommended by West Virginia Small Farm Center to improve microbial safety. It has been well recognized that the washing of produce is more important for preventing cross-contamination than reducing foodborne pathogens. Furthermore, it may help improve public confidence in that the produce they obtain from locally grown farmers is safe for their consumption. determine the efficacy of SaniDate-5.0 for reducing the survival and preventing cross-contamination of the Salmonella surrogate Enterococcus faecium on tomatoes during triple-wash.

E. faecium ATCC-8459 (resistant to 100-ppm nalidixic-acid) …

Multifunctional Organoboron Compounds And Boralactonate Salts, Randika T. Abeysinghe

Graduate Theses, Dissertations, and Problem Reports (ETD)

Organoboron compounds have gathered an important significance within the chemistry community on account of their wide range of applications in synthesis, catalysis, and medicinal chemistry. Even though the uses of boron compounds in drug discovery have been overlooked until the last several decades, boronic acid containing molecules have garnered increased attention due to the unique chemical properties of the boron center. Boron-functionalized ��-aryl propionic acid non-steroidal anti-inflammatory drug derivatives (bora-NSAIDs) can be accessed via copper(I)-catalyzed alkene boracarboxylation, using CO2 and B2pin2. To explore and expand the current synthetic and future medicinal chemistry applications of these bora-NSAIDs, methods …

Invisible Confidence: Developing An Innovative Leotard For Urinary And Menstrual Protection, Desiree' Nicole Childers

Graduate Theses, Dissertations, and Problem Reports (ETD)

Invisible Confidence: Developing an Innovative Leotard for Urinary and Menstrual Protection

The focus of this thesis project is to develop a multifaceted study, related to leotards in competitive gymnastics and dance with regards to design and construction, use of absorbent fabrics, and product development and marketing. The research for developing this design will include: the exploration into the anesthetic design of the gymnastics leotard, along with the mechanical properties of fabric in the area of absorption and durability, as well as how the construction might affect these aspects, and will explore the steps towards the development and marketing of these …