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Articles 78481 - 78510 of 5152514
Full-Text Articles in Entire DC Network
Book Review: Wyche Fowler: A Political Life In Georgia, Congress, And Abroad, Amy Shaw
Book Review: Wyche Fowler: A Political Life In Georgia, Congress, And Abroad, Amy Shaw
Georgia Library Quarterly
No abstract provided.
Supporting Data – Urban Stream, Cardinal Court, Isu, Normal, November 9, 2023 To May 1, 2025, Eric Wade Peterson, Ava Miller
Supporting Data – Urban Stream, Cardinal Court, Isu, Normal, November 9, 2023 To May 1, 2025, Eric Wade Peterson, Ava Miller
Faculty Publications - Geography, Geology, and the Environment
Between November 9, 2023 to May 1, 2025, water samples were collected upstream and downstream along a segment of a stream adjacent to Cardinal Court on the Illinois State University campus. At each location, samples were collected at the surface. In-situ measurements of Dissolved Oxygen, Specific Conductance, and Temperature were recorded with a YSI 85. Anion samples were analyzed using a Ion Chromatograph for fluoride (F-), chloride (Cl-), nitrate as nitrogen (NO3-N), phosphate (PO43-), and sulfate (SO42-). The available dataset provides the recorded field parameters and the analyzed ion concentrations.
Developing Ecosocial Literacy / Transforming Ecosocial Leadership: A Curriculum Research & Development Project, Chris Zorn, Lois A. Yamauchi, Madiha Jamil
Developing Ecosocial Literacy / Transforming Ecosocial Leadership: A Curriculum Research & Development Project, Chris Zorn, Lois A. Yamauchi, Madiha Jamil
IALS Journal
This case study examines the Global Leadership Laboratory (GLL), a yearlong high school leadership course at University Laboratory School in Hawaiʻi. The curriculum integrates transformative learning and contemplative practices to promote student voice, self-awareness, leadership skills, and personal agency. Through interviews, observations, and student artifacts, the study found that reflective journaling, dialogue, contemplative practices, and transformative learning activities supported the development of authentic student voice and perspective transformation, although outcomes varied by classroom conditions and student readiness.
The Social And Cultural Challenges Experienced By Children With Send Through Quasi-Inclusion Practices In Two Mainstream Primary Schools In Postcolonial Guyana, Lidon Lashley, Clevelon Gordon
The Social And Cultural Challenges Experienced By Children With Send Through Quasi-Inclusion Practices In Two Mainstream Primary Schools In Postcolonial Guyana, Lidon Lashley, Clevelon Gordon
IALS Journal
This ethnographic study investigates the sociocultural experiences of 36 children with SEND and two non-SEND peers in two rural mainstream primary schools in Guyana. Through interviews, observations, and situational analysis, the study explores how ableism, colonial legacies, prejudice, poverty, linguistic barriers, and inadequate educational support shape the experiences of children with SEND. Findings reveal persistent stigmatization, discrimination, marginalization, exclusion, and "fated failure" discourses that negatively affect learning, participation, agency, and wellbeing. The study concludes that teachers require greater support, training, and specialist resources to foster genuine inclusion within Guyana's mainstream schools.
Students’ Perceptions At The University Of Puerto Rico Secondary School Regarding Cellphone Use In The School Environmen, Nicolás Ramos, Nydiaam Vilanova
Students’ Perceptions At The University Of Puerto Rico Secondary School Regarding Cellphone Use In The School Environmen, Nicolás Ramos, Nydiaam Vilanova
IALS Journal
This mixed-methods study investigates students’ perceptions of cellphone use at the University of Puerto Rico Secondary School. Data were collected from 133 students through a structured electronic survey examining phone ownership, usage patterns, emotional responses, parental regulation, and opinions regarding cellphone restrictions in schools. Results indicate that most students perceive their cellphone use as appropriate, recognize both educational and social benefits, and oppose complete bans while supporting responsible use and guided autonomy. The findings suggest that schools should emphasize digital citizenship, self-regulation, and balanced technology use rather than punitive restrictions.
Anthelmintic Efficacy Of Rosemary Oil And Its Nanoemulsion Against The Monogenean Parasite, Zeuxapta Seriolae, In Yellowtail Kingfish (Seriola Lalandi), Md Reaz Chaklader, Lindsey Woolley, Hosna Gholipour-Kanani, Masashi Maita, Gavin Partridge
Anthelmintic Efficacy Of Rosemary Oil And Its Nanoemulsion Against The Monogenean Parasite, Zeuxapta Seriolae, In Yellowtail Kingfish (Seriola Lalandi), Md Reaz Chaklader, Lindsey Woolley, Hosna Gholipour-Kanani, Masashi Maita, Gavin Partridge
Fisheries Research Articles
This study evaluated the anthelmintic efficacy of rosemary oil delivered as a nanoemulsion compared with regular rosemary oil against the monogenean parasite Zeuxapta seriolae in yellowtail kingfish (YTK; Seriola lalandi). A 20-day feeding trial tested three dietary treatments: two levels of regular rosemary oil (providing 0.85 and 1.7 g cineole·kg−1 feed) and a rosemary-oil nanoemulsion (providing 0.85 g cineole·kg−1 feed), against a control diet without rosemary oil. Juvenile fish (293 ± 5 g) were pre-exposed to Z. seriolae oncomiracidia before the trial, resulting in an initial mean parasite abundance of 97 ± 4 per fish. At trial completion, plasma …
Bad Bunny’S Super Bowl Performance Generated 892.8% More Social Media Mentions Than Kid Rock’S Halftime Show With Triple The Search Interest, Jin-A Choi, Bond Benton, Yi Lou
Bad Bunny’S Super Bowl Performance Generated 892.8% More Social Media Mentions Than Kid Rock’S Halftime Show With Triple The Search Interest, Jin-A Choi, Bond Benton, Yi Lou
College of Communication and Media Scholarship and Creative Works
A study from Montclair State University faculty in the Joetta Di Bella and Fred C. Sautter III Center for Strategic Communication in the College of Communication and Media analyzed social media reaction to the NFL’s Super Bowl halftime show featuring Bad Bunny and Turning Point USA’s “All-American Halftime Show” featuring Kid Rock. Results suggest significantly higher interest online in Bad Bunny’s performance. Highlights from the study include 892.8% more posts on X about Bad Bunny’s halftime show performance with a 963.6% higher number of posts throughout Super Bowl Sunday. Additionally, there was triple the amount of search interest for “Bad …
Abuse Of Contract: A Proposal For A New Cause Of Action, Miriam A. Cherry
Abuse Of Contract: A Proposal For A New Cause Of Action, Miriam A. Cherry
William & Mary Law Review
With the growth of online commerce and the platform economy, many companies are including provisions in their online terms and conditions that extend far beyond what reasonable consumers would expect. Some terms and conditions purport to bind customers to separate contracts in future transactions that have little to do with the first contract. Other boilerplate purports to cover family members of the customer who created an account. Some retailers have argued that people shopping in their brick-and-mortar stores are subject to terms and conditions because those shoppers had at some point previously created an online account. For example, Disney argued …
Medical Device Dangers: Choosing Ignorance In The Courts And At The Fda, George Horvath
Medical Device Dangers: Choosing Ignorance In The Courts And At The Fda, George Horvath
William & Mary Law Review
Medical devices save lives and improve well-being but have caused as many as 83,000 deaths and 1.7 million injuries in a recent decade. Decisions of critical importance—patients’ decisions whether to have a device implanted, doctors’ decisions about which device to use, insurers’ decisions whether to reimburse for those devices—depend on information about risk that is provided by manufacturers. But producing this information is costly. Injured patients, through private lawsuits under state products liability theories, can incentivize device manufacturers to incur these costs and to produce and disclose information about device risk. Unfortunately, courts are making it increasingly unlikely that this …
Property Law For Positive Externalities: Carving New Sticks For The Bundle, J.B. Ruhl, James Salzman
Property Law For Positive Externalities: Carving New Sticks For The Bundle, J.B. Ruhl, James Salzman
William & Mary Law Review
Property law has long confronted a troubling puzzle: Why does doctrine focus so much on eliminating harms flowing as negative externalities from uses of property—curbing pollution, nuisances, and other harmful land uses—while largely ignoring the potential to encourage positive externalities? Why such a strong focus on preventing bads instead of promoting goods? Using a case of a natural capital resource and the ecosystem services of flood control, water purification, and pollination it provides, this Article explains how and why existing doctrine fails to recognize these benefits as distinct property interests, leading to systematic underinvestment in conservation and service provision. We …
Skrmetti And The Problem Of Incidental Intent, Martin Katz
Skrmetti And The Problem Of Incidental Intent, Martin Katz
William & Mary Law Review
The modern Supreme Court has defined “discriminatory intent” as a strict-liability concept. It does not matter why the government sorts people by a protected characteristic, such as race or sex; it matters only that the government does sort people by such a characteristic. This principle is the key holding of affirmative-action cases, such as Students for Fair Admissions, Inc. v. President & Fellows of Harvard College. Yet, in the recent case United States v. Skrmetti, the Court seemed to focus not on the question of whether the government sorted people by sex (it did), but on the question …
Table Of Contents (V. 67, No. 3)
Interannual Variation In Seed Traits Of Cedrela Species, Guadalupe Galíndez, Ana Álvarez, Diana Ceccato, Victoria Rivero, Gisela Malagrina, Tania Bertuzzi, Pablo Saravia, Stavros Nicolás Sola, Carol C. Baskin, Luis Fornes
Interannual Variation In Seed Traits Of Cedrela Species, Guadalupe Galíndez, Ana Álvarez, Diana Ceccato, Victoria Rivero, Gisela Malagrina, Tania Bertuzzi, Pablo Saravia, Stavros Nicolás Sola, Carol C. Baskin, Luis Fornes
Plant and Soil Sciences Faculty Publications
Climate change is altering temperature and precipitation regimes in Argentina, with potential consequences for regeneration and persistence of forest tree species, emphasizing the importance of ex situ seed conservation. We evaluated interannual variation in seed traits, desiccation tolerance, storage behavior, and longevity of Cedrela balansae C. DC. and C. fissilis Vell. (Meliaceae), two endangered native species of subtropical rainforests in Argentina. Both species produced desiccation-tolerant seeds, independently of collection year, seed traits, or climatic conditions. Depending on the species, seed traits and longevity varied across years and showed strong relationships with temperature and precipitation, particularly during seed development. Cedrela balansae …
Gimyb76, A Meja-Inducible R2r3-Type Transcription Factor, Regulates Licochalcone A Biosynthesis In Licorice (Glycyrrhiza Inflata), Yuping Li, Zhigeng Wu, Jixiang Zhu, Jiangyi Zeng, Yongliang Liu, Jihua Wang, Ling Yuan, Ying Wang, Yongqing Li
Gimyb76, A Meja-Inducible R2r3-Type Transcription Factor, Regulates Licochalcone A Biosynthesis In Licorice (Glycyrrhiza Inflata), Yuping Li, Zhigeng Wu, Jixiang Zhu, Jiangyi Zeng, Yongliang Liu, Jihua Wang, Ling Yuan, Ying Wang, Yongqing Li
Plant and Soil Sciences Faculty Publications
Licochalcone A (LCA) is a characteristic compound in licorice Glycyrrhiza inflata and is widely utilized in pharmaceutical and cosmetic industries. However, the biosynthetic pathway and regulatory mechanisms of LCA remain poorly understood. In this study, we first found the accumulation of LCA is induced by methyl jasmonate (MeJA). Given that MYB transcriptional factors are well-documented as key regulators of flavonoid biosynthesis, we identified a total of 147 GiR2R3-MYB genes in G. inflata, which were classified into 28 subgroups. The chromosome distributions, sequence characteristics, gene structures, duplication events and cis-acting elements were also investigated. Through integrated analysis of GiR2R3-MYBs expression patterns …
Synthetic Microbial Communities Enhance Tobacco Quality By Driving Bacterial Community Succession And Modulating Metabolite Profiles, Kuifu Men, Huaqiang Xuan, Jingrui Chen, Hongliang Li, Xuwei Chen, Yingle Jiao, Xianchao Shang, Yi Xie, Li Zhang, Long Yang, Ling Yuan, Sitakanta Pattanaik, Xin Hou
Synthetic Microbial Communities Enhance Tobacco Quality By Driving Bacterial Community Succession And Modulating Metabolite Profiles, Kuifu Men, Huaqiang Xuan, Jingrui Chen, Hongliang Li, Xuwei Chen, Yingle Jiao, Xianchao Shang, Yi Xie, Li Zhang, Long Yang, Ling Yuan, Sitakanta Pattanaik, Xin Hou
Plant and Soil Sciences Faculty Publications
The fermentation of cigar tobacco leaves (CTLs) is a critical process driven by microbial activity, which directly influences the degradation of macromolecules and the development of distinctive aromas. However, mechanisms for the directional regulation of this process using defined microbial consortia remain underexplored. This study aimed to construct a synthetic microbial community (SynCom) to enhance the fermentation efficiency and quality of cigar tobacco leaves. Bacillus safensis and Bacillus velezensis with high extracellular cellulase, amylase and protease activities were screened out, and synthetic communities were constructed. This microbial community was applied to cigar tobacco leaves (cultivar QX204) during a 42-day fermentation. …
Post-Translational Control Of Biotic Stress-Related Nicotine Biosynthesis By A Map Kinase Signaling Cascade, Yan Zhou, Yongliang Liu, Ruiqing Lyu, Sanjay Kumar Singh, Xueyi Sui, Xin Hou, Sitakanta Pattanaik, Ling Yuan
Post-Translational Control Of Biotic Stress-Related Nicotine Biosynthesis By A Map Kinase Signaling Cascade, Yan Zhou, Yongliang Liu, Ruiqing Lyu, Sanjay Kumar Singh, Xueyi Sui, Xin Hou, Sitakanta Pattanaik, Ling Yuan
Plant and Soil Sciences Faculty Publications
The evolutionarily conserved mitogen-activated protein kinase (MAPK) cascades relay extracellular signals into cells, triggering a variety of cellular responses. We previously revealed NtMPK4 as a positive regulator of nicotine biosynthesis; however, its upstream regulation remains unclear. Here, we characterized a MAPK cascade, comprising NtMEKK1b, NtMPKK2a, and NtMPK4, that promotes nicotine biosynthesis. This signaling module transduces external cues, including jasmonate and pathogen elicitors such as flg22, into post-translational modifications that enhance transcriptional activity and pathway gene expression. NtMPKK2a physically interacts with and phosphorylates NtMPK4 in vivo, confirming its role as an upstream kinase. RNAi-mediated silencing of NtMPKK2a significantly reduced the expression …
Artificial Intelligence, Society 5.0 And Smart City Adaptation Initiatives For Businesses: An Integrated Approach, Ines A. M. Gila, Fernando A. F. Ferreira, Neuza C. M. Q. F. Ferreira, Florentin Smarandache, Momtaj Khanam, Tugrul Unsal Daim
Artificial Intelligence, Society 5.0 And Smart City Adaptation Initiatives For Businesses: An Integrated Approach, Ines A. M. Gila, Fernando A. F. Ferreira, Neuza C. M. Q. F. Ferreira, Florentin Smarandache, Momtaj Khanam, Tugrul Unsal Daim
Engineering and Technology Management Faculty Publications and Presentations
The mass migration of human populations to urban areas has resulted in unprecedented challenges for city services. To address and find solutions for these emerging issues, decision-makers must embrace the smart city and Society 5.0 paradigms, which comprehensively tackle various dimensions of the problem and ensure adaptability to evolving citizen needs. Central to the success of these paradigms is technology, particularly artificial intelligence (AI). AI’s transformative capabilities enable the expansion of services, automation of tasks, efficient operationalization and processing vast amounts of data to address urban challenges, aligning with several sustainable development goals (SDGs) such as sustainable cities and communities …
Information Sharing Within Institutional Investor Networks, Wei Ting Loh
Information Sharing Within Institutional Investor Networks, Wei Ting Loh
Research Collection School Of Accountancy
This study examines whether information sharing occurs within institutional investor networks. I identify networks of institutional investors who share common investments and find that in-network investors earn significantly higher returns than other investors of the same firm, suggesting that valuable private information is shared within these networks. I also find that ownership by investor networks is associated with speedier price discovery and incorporation of more firm-specific news in prices, consistent with information sharing facilitating efficient price formation. In addition, ownership by network investors is associated with higher information risk as reflected in the probability of informed trading and market liquidity. …
The Scoop, Vol. 12 Issue 11, February 2026, Health Sciences Library
The Scoop, Vol. 12 Issue 11, February 2026, Health Sciences Library
Volume 12
Latest news and updates from the Health Sciences Library in our monthly newsletter for February 2026. Please see page 2 for a text-only version of this issue!
How Do Social Isolation And Loneliness Vary By Age?, Jihye Baek, Cal J. Halvorsen
How Do Social Isolation And Loneliness Vary By Age?, Jihye Baek, Cal J. Halvorsen
Harvey A. Friedman Center for Aging
Social isolation and loneliness, which are experienced by many older adults, can negatively impact health and well-being. Although often used interchangeably, social isolation is defined as an objective lack of social ties (e.g., number of close family members or friends) and loneliness as an internal sense of disconnection (e.g., feeling alone even when surrounded by others). Because social relationships, health, and life circumstances change as we age, patterns of social isolation and loneliness may differ by age group. Therefore, this research brief asks, How do patterns of social isolation and loneliness differ across age groups among community-dwelling older adults?
Caregivers' Experiences Of Assessment And Treatment For Their Child With Childhood Apraxia Of Speech: An International Questionnaire Study, Donna Claire Thomas, Maryane Gomez, Angela Muis, Nathan Trezise, Eliza Williamson, Julie Case, Elizabeth Murray, Maria Irene Grigos, Jenya Iuzzini-Seigel, Shelley L. Velleman
Caregivers' Experiences Of Assessment And Treatment For Their Child With Childhood Apraxia Of Speech: An International Questionnaire Study, Donna Claire Thomas, Maryane Gomez, Angela Muis, Nathan Trezise, Eliza Williamson, Julie Case, Elizabeth Murray, Maria Irene Grigos, Jenya Iuzzini-Seigel, Shelley L. Velleman
Speech Pathology and Audiology Faculty Research and Publications
Purpose: The aim of this study was to understand caregivers' preferences and experiences with diagnosis and treatment of childhood apraxia of speech (CAS).
Method: Caregivers of children with CAS completed a 70-item online survey that explored demographics, initial concerns, the CAS diagnostic process, speech therapy goals, and preferred and received speech therapy service delivery (session frequency, length, and context). Quantitative data were analyzed descriptively and with inferential statistics; qualitative data were analyzed using content analysis.
Results: One hundred sixty-one caregivers participated, mostly from the United States, Australia, and Canada. A total of 72% of caregivers had concerns about their child's …
At The Margins Of History, The Body Moves And Knows: Carmen As Myth, Flamenco As A Fugitive Form Of Knowledge Transmission, Inmaculada Zanoguera Garcias
At The Margins Of History, The Body Moves And Knows: Carmen As Myth, Flamenco As A Fugitive Form Of Knowledge Transmission, Inmaculada Zanoguera Garcias
Dissertations, Theses, and Capstone Projects
My research, grounded in decolonial historiography and performance studies, examines how Spain has historically relied on the exoticized Other for the construction of its national identity. At the center of my analyses is Carmen, the eponymous protagonist of French writer Prosper Mérimée’s 1845 novella Carmen. Through this dissertation, I attend to the process through which this fictional character turned into the enduring myth of Carmen—the Orientalized, quintessential Spanish woman—and the consequences that upholding this myth has on the real lives of women, historically and contemporarily. I depart from the assumption that this myth-making process emerged in response to Spain’s inability …
Local Angiotensin Converting Enzyme 2 (Ace2) Enzymatic Activity Modulates Cholinergic Interneuron Function In The Dorsolateral Striatum, Aria R. Walls
Local Angiotensin Converting Enzyme 2 (Ace2) Enzymatic Activity Modulates Cholinergic Interneuron Function In The Dorsolateral Striatum, Aria R. Walls
Dissertations, Theses, and Capstone Projects
The renin angiotensin system (RAS) is an ancestrally ancient peptidergic signaling pathway best known for its role regulating blood pressure in the periphery. However, its presence and importance in the central nervous system has more recently been identified and is less well understood. Previous work shows RAS is expressed in the nigrostriatal pathway of the basal ganglia and has been implicated in basal ganglia disorders including Parkinson’s disease (PD) and levodopa-induced dyskinesia (LID). Interestingly, the canonical and noncanonical arms of the RAS pathway produce opposite effects on PD disease vulnerability and progression. The shift from the neurodegenerative canonical RAS to …
The Rhetorical Agency Of Student-Parents: Assembling, Archiving, And Naming Practices And Interpretations That Transform Worlds, Dhipinder Walia
The Rhetorical Agency Of Student-Parents: Assembling, Archiving, And Naming Practices And Interpretations That Transform Worlds, Dhipinder Walia
Dissertations, Theses, and Capstone Projects
This dissertation is an interdisciplinary project that uses interview data collected from six student-parents attending Bronx Community College during 2024 to 2025. Using rhetorical and critical discourse analysis, this dissertation argues student-parents enact their rhetorical agency to transform their college experience. Specifically, student-parents use their rhetorical agency to interpret time and place in a way that centers their own wellbeing as well as the wellbeing of their children. This dissertation focuses on interpretations and ordinary practices that reimagine what time and place can look and feel like on a college campus. Additionally, student-parents enact their rhetorical agency through ordinary practices …
Distribution Of Power In South Asia: Assessing Sino-Indian Conflict Propensity, Fatima Faisal
Distribution Of Power In South Asia: Assessing Sino-Indian Conflict Propensity, Fatima Faisal
Dissertations, Theses, and Capstone Projects
In international relations, the distribution of power is a key theme impacting the propensity for nations to break into wars; however, the vast academic literature is Eurocentric with a concentration on the United States and the Soviet Union. This paper shifts to the unexplored distribution of power in South Asian with a particular focus of Sino-Indian border conflicts namely the Sino-Indian War (1962), the Nathu La and Cho La clashes (1967), the Arunachal Ambush (1975), Sumdorong Chu standoff (1987), the Armed Confrontation (2013), and the Doklam Standoff (2017), and the Galwan Valley (2020) to determine if the region was more …
Finding Luis: A Creative Nonfiction Account Of Law & Society, Jason M. Leggett
Finding Luis: A Creative Nonfiction Account Of Law & Society, Jason M. Leggett
Dissertations, Theses, and Capstone Projects
This essay explores the contradictions in legal theory and human experience through creative nonfiction. Its main purpose is to argue that a truly just society requires acknowledging the profound influence of individual narratives on the law. This is supported by blending personal narratives, critical analysis, and philosophical inquiry to reveal the gap between codified law and lived realities for marginalized individuals. This unique Legal Poetics methodology employs a series of six vignettes, such as the author's and Luis's shared experiences with traumatic brain injury and the denial of justice, as data. By integrating autoethnography, law as narrative, and performativity theories, …
Monosaccharide Binding To Synthetic Carbohydrate Receptor Microarrays, Milan A. Shlain
Monosaccharide Binding To Synthetic Carbohydrate Receptor Microarrays, Milan A. Shlain
Dissertations, Theses, and Capstone Projects
Chapter 1: A glycan detection platform comprised of synthetic carbohydrate receptors (SCRs) immobilized onto polymer brushes was prepared. SCR043, an alkene-containing SCR, was incorporated into grafted-from polymer brushes using hypersurface photolithography, resulting in microarrays of SCR043-functionalized polymer brushes, where brush height (h) and SCR grafting density (Γ) is controlled precisely at each feature in the array. The influence of h and Γ on the binding to five fluorescently labelled monosaccharides – α-glucose (α-Gluc-FL), α-galactose (α-Gal-FL), α-mannose (α-Man-FL), β-glucose (β-Gluc-FL), and β-galactose (β-Gal-FL) – in aqueous buffer …
Systems Epistemology, Boris Ayala
Systems Epistemology, Boris Ayala
Dissertations, Theses, and Capstone Projects
This dissertation develops a new kind of theory of knowledge, which I call Systems Epistemology (SE). Currently available theories tend to follow the TB+ format according to which knowledge is a true belief plus certain additional properties. Insofar as these theories offer a conceptual gap between the additional properties and truth, however, they are vulnerable to intuitive counterexamples. Building on work by Richard Foley and Stephen Hetherington, SE focuses not on a target belief and the properties it must have to count as knowledge, but rather on the beliefs that surround it and hold it in place. This shift in …
Mind The Gap: Morphological Defectivity And Suffixal Competition In Polish, Szymon E. Zuberek
Mind The Gap: Morphological Defectivity And Suffixal Competition In Polish, Szymon E. Zuberek
Dissertations, Theses, and Capstone Projects
This study investigates morphological defectivity and suffixal competition in the genitive singular of Polish masculine inanimate nouns. Drawing on survey-based grammaticality judgments from native speakers, it examines how respondents select between the suffixes -a and -u or reject both as unacceptable, thereby signaling defectivity. Mixed-effects logistic regressions revealed that defectivity was rare overall but patterned systematically by age, education, and region, with additional baseline variability across lexical items. Suffix choice showed a strong preference for -a, modulated by age, education, and region, with additional baseline variability across lexical items. These findings inform our understanding of paradigm structure, sociolinguistic variation, and …
Mechanistic Studies Of Aerobic Photochemistry: Gold Nanoclusters, Nanoparticles, And Solution-Phase Systems, Serah Essang
Mechanistic Studies Of Aerobic Photochemistry: Gold Nanoclusters, Nanoparticles, And Solution-Phase Systems, Serah Essang
Dissertations, Theses, and Capstone Projects
This thesis comprises five chapters as enumerated below.
Chapter 1 describes our findings on the reactions of Au glutathione nanocluster (Au20SG16) with singlet oxygen (1O2) in D2O. We noticed it underwent a self-photooxidation reaction. Leading us to mechanistic studies using photophysical, photochemical, theoretical, and indirect trapping methods. We found rapid total quenching of singlet oxygen (1O2) by ground-state Au20(SG)16, with evidence for dioxygen insertion into the nanocluster. Supported by analyses with IR, ESI-MS, and density functional theory, we propose the formation of …