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Shock Wave And Vortex Ring Dynamics From Explosively Driven Shock Tunnels, Rachel Louise Bauer Jan 2025

Shock Wave And Vortex Ring Dynamics From Explosively Driven Shock Tunnels, Rachel Louise Bauer

Doctoral Dissertations

"Blast and shock tubes are frequently used to create shock waves to study their effects and impacts on structures, humans, and personal protective equipment. These tubes are also found in other industries including wind tunnels for aerodynamic testing, jet engines for propulsion research, spacecraft reentry simulations, and industrial applications such as material testing and high-velocity impact studies. Despite their widespread use, there is no standard design, with variations in geometry, size, and energy sources. Current research only evaluates the peak pressure of the shock wave produced and does not consider the effects of changing the size or geometry of the …


The Evolving Use Of Strategic Planning Tools In The Manufacturing Environment: Implications For Quality 4.0 And Beyond, Richard Lee Wilson Jan 2025

The Evolving Use Of Strategic Planning Tools In The Manufacturing Environment: Implications For Quality 4.0 And Beyond, Richard Lee Wilson

Doctoral Dissertations

"Having a strong strategic plan is critical for success for any business no matter the size of the organization, the product or service they provide, or the industry they serve. There are many methods businesses use to develop their strategic plans. One such method is known as Hoshin Kanri, which has been in use for decades. However, recent years have seen an increase in artificial intelligence, big data, data analytics, and other technology tools to create cyber physical systems on the manufacturing floor. The increase in technology in manufacturing to integrate cyber systems with physical systems spawned a new industrial …


Leveraging Deep Learning Models And Social Media Data For Enhanced Situation Awareness In Disaster Management, Ademola Abdulganiyu Adesokan Jan 2025

Leveraging Deep Learning Models And Social Media Data For Enhanced Situation Awareness In Disaster Management, Ademola Abdulganiyu Adesokan

Doctoral Dissertations

"In recent years, social media has become a crucial source of real-time data for disaster management, supporting emergency responses when traditional channels like 911 are overcrowded and overwhelmed. It offers authorities valuable data for developing effective strategies, especially when swift actions are essential to save lives. However, the informal language, ambiguous meanings, and irrelevant content on social media pose challenges to accurate classification and hinder the efficient extraction of disaster-relevant information, leading to inefficiencies in emergency response efforts.

This research focuses on seven key questions: i) How can we detect, classify, and analyze hate and offensive tweet emotions during large-scale …


Transport And Plugging Behavior Of Co2-Resistant Preformed Particle Gels In High Conductive Channels For Conformance Control, Adel Alotibi Jan 2025

Transport And Plugging Behavior Of Co2-Resistant Preformed Particle Gels In High Conductive Channels For Conformance Control, Adel Alotibi

Doctoral Dissertations

"Improving oil recovery is essential with rising global oil demand and declining production in mature fields. CO2 flooding has been widely applied as a major Enhanced Oil Recovery (EOR) method due to its effectiveness in boosting oil recovery while enabling safe carbon storage in the subsurface. However, in fractured and highly heterogeneous reservoirs, CO2 often flows through paths of least resistance, leading to early breakthrough or quick excessive CO2 production and leaving substantial oil in unswept zones or areas. Traditional in-situ polymer gels have been applied to control CO2 flooding conformance, their performance has been varied, …


Development And Testing Of Irradiation-Tolerant High-Entropy Alloys, Matthew John Luebbe Jan 2025

Development And Testing Of Irradiation-Tolerant High-Entropy Alloys, Matthew John Luebbe

Doctoral Dissertations

"High entropy alloys (HEAs) are a novel class of alloys made of multiple principal elements in near equal proportions. They have been observed to possess an array of useful engineering properties, such as good ductility and fracture toughness, high temperature strength, oxidation and corrosion resistance and irradiation resistance. This makes them promising candidates for harsh environments, especially nuclear reactors. These properties could potentially realize advanced Gen IV nuclear reactor designs. However, most HEA compositions contain Co, which activates under irradiation, generating safety and waste management concerns. This work studies three compositions of Co-free HEAs whose strength and microstructures are evaluated …


Investigation Of Shockwave Behavior To Inform Helmet Design Using Schlieren Imagery And Free-Field Blasts, Cody Jh Thomas Jan 2025

Investigation Of Shockwave Behavior To Inform Helmet Design Using Schlieren Imagery And Free-Field Blasts, Cody Jh Thomas

Doctoral Dissertations

"Ballistic resistance of military helmet designs is a prioritized feature to protect warfighters from traumatic brain injury. However, injuries from shock-based threats have not been optimized for warfighter protection and have resulted in the prevalence of blast-induced traumatic brain injury (bTBI). Research gaps were identified in understanding the under wash effect using free field blasts and schlieren imagery. Thus, the following were investigated: (1) overpressure changes on a warfighter’s head due to directionality from a blast, (2) shock wave dampening effects of viscoelastic materials in helmets, and (3) geometric effects of a helmet brim design in the reduction of bTBI. …


Polybenzodiazine Aerogels: All-Nitrogen Analogues Of Polybenzoxazines - Synthesis, Characterization, And Their Application In Carbon Dioxide Capture, Vaibhav Edlabadkar Jan 2025

Polybenzodiazine Aerogels: All-Nitrogen Analogues Of Polybenzoxazines - Synthesis, Characterization, And Their Application In Carbon Dioxide Capture, Vaibhav Edlabadkar

Doctoral Dissertations

"The rapidly risen concentration of carbon dioxide in the atmosphere over recent years contributed to global warming and ocean acidification. Carbon capture is viewed as an essential tool from keeping atmospheric CO2 levels from rising further. This thesis focuses on the development of new materials for high capacity and selective adsorption of CO2. One such material was based on a newly synthesized tetrahydroquinazoline (THQ), which was designed as an all-nitrogen analogue of main-stream benzoxazine monomers. THQ solutions in DMF gelled at 100 °C via HCl-catalyzed ring opening polymerization to polybenzodiazine (PBDAZ) wet gels, which were dried in …


Mitigating Frost Heave And Thaw Weakening In Roads Using Wicking Geotextile, Javad Galinmoghadam Jan 2025

Mitigating Frost Heave And Thaw Weakening In Roads Using Wicking Geotextile, Javad Galinmoghadam

Doctoral Dissertations

"Excess water is known to be the primary cause of soil and foundation problems. In cold regions, water-related problems are exacerbated by seasonal freezing and thawing cycles. Frost heave and thaw weakening is the leading cause of premature pavement failure and consume considerable budgets of the Department of Transportations in cold regions. The first step to designing mitigation measures is the ability to predict frost heave under different conditions. This study aims to introduce a new method for quantifying frost heave using a prediction model based on the state surface approach. This proposed model addressed many inconsistencies and limitations of …


Advancing Refuge Alternatives In Mine Emergencies Using Advanced Numerical Simulation, Kutay Emre Karadeniz Jan 2025

Advancing Refuge Alternatives In Mine Emergencies Using Advanced Numerical Simulation, Kutay Emre Karadeniz

Doctoral Dissertations

"Incidents and emergencies within underground coal mines can result in severe injuries or even loss of life, particularly due to the hazardous nature of mine explosions. One of the options for the miners to protect themselves from these hazards is to be sheltered in a refuge alternative (RA). However, the literature lacks an analysis of survivability constraints and the structural integrity of RAs when exposed to geomechanical changes and the ability to withstand the impact of coal mine explosions. In this study, based on the utilization and survivability constraints, basic human requirements and the required physical specifications of RAs during …


Vibration Modeling Of Rectangular Plates And Application To Solar Cell Dust Mitigation, Jeremiah John Rittenhouse Jan 2025

Vibration Modeling Of Rectangular Plates And Application To Solar Cell Dust Mitigation, Jeremiah John Rittenhouse

Doctoral Dissertations

"Many engineering structures can be modeled as rectangular plates, including solar cells. Carefully controlled plate vibration can be useful to solve an engineering problem, such as lunar dust accumulation on solar cells, which blocks light and reduces power generation. For this application, plate vibration at resonance is studied and used experimentally to eject lunar dust from a solar cell.

Piezoelectric actuator placement on the inactive side of a solar cell to induce vibration dust mitigation from the active side of the cell is presented in this work. Three solar cell prototypes were created and tested for efficacy, resulting in an …


New Topologies For High Voltage Gain Dc-Dc Power Electronic Converters – Theoretical Analysis And Experimental Validation, Saeed Habibi Jan 2025

New Topologies For High Voltage Gain Dc-Dc Power Electronic Converters – Theoretical Analysis And Experimental Validation, Saeed Habibi

Doctoral Dissertations

"This dissertation is focused on developing and analyzing new high voltage gain DC-DC power electronic converters. The proposed converters in this dissertation are suitable candidates for connecting low voltage sources such as photovoltaic (PV) panels or fuel cell (FC) stacks to a DC microgrid or DC link of an inverter. The proposed converters provide desired characteristics such as high voltage gain at a low or medium duty cycle values, low voltage stress on power semiconductors, and continuous input current. Initially, the research introduces three novel converter topologies: First, two quadratic converters based on the combination of a three-winding coupled inductor …


Additive Manufacturing Of Multifunctional Materials And Composites, John Michael Pappas Jan 2025

Additive Manufacturing Of Multifunctional Materials And Composites, John Michael Pappas

Doctoral Dissertations

"This research focused on developing fundamental knowledge of process-material interactions for additive manufacturing of multifunctional materials that are highly desirable in high-tech industries for potential weight and space savings. Multifunctional materials are very sensitive to defects, which severely hinder performance. Thus, defect formation was systematically studied to develop strategies and methodologies to efficiently fabricate high-performance materials and composites. Blown-powder-based laser additive manufacturing of transparent spinel ceramics was investigated to reduce porosity and cracking, defects that hindered transparency and mechanical properties. A systematic study of processing parameters revealed that laser power and powder flow rate had the largest effects on defect …


Photoionization Of Spin-Polarized Rydberg Atoms Out Of A Continuous Wave Optical Dipole Trap, Kevin Lee Romans Jan 2025

Photoionization Of Spin-Polarized Rydberg Atoms Out Of A Continuous Wave Optical Dipole Trap, Kevin Lee Romans

Doctoral Dissertations

"Recent research has demonstrated the need for a fully differential experiment on the photoionization of 6Li Rydberg atoms in a continuous wave (cw) laser field, as this would provide a new path forward for studying never before accessible atom-light interactions. Rydberg atoms are back in the focus of intense research due to their peculiar properties, which make them interesting candidates for quantum optics and information applications. In this work, we study the ionization of such Rydberg atoms, due to their interaction with a trapping laser field, by utilizing a reaction microscope (ReMi) capable of measuring photoelectron momentum distributions with …


Exploring The Feasibility Of Innovative Integration Of Phase Change Materials For Thermo-Adaptive Asphalt Pavements, Farshad Saberi Kerahroudi Jan 2025

Exploring The Feasibility Of Innovative Integration Of Phase Change Materials For Thermo-Adaptive Asphalt Pavements, Farshad Saberi Kerahroudi

Doctoral Dissertations

"Current research examined the feasibility and efficiency of employing phase change materials (PCMs) in asphalt pavement materials to result in thermo-adaptive asphalt pavement. The PCM was introduced to the asphalt materials in three different scales, including asphalt binder, asphalt mastic, and asphalt mixture. After investigating asphalt at different scales, mix blending method was found as the easiest method without any complexity to mix asphalt binder with PCM. The testing results could reveal an improvement in the high temperature performance of asphalt binder without sacrificing the low temperature performance with the presence of PCM and Gilsonite. Also, introducing PCM to asphalt …


Parallel Algorithms For Large Scale Dynamic Graph Analysis, Arindam Khanda Jan 2025

Parallel Algorithms For Large Scale Dynamic Graph Analysis, Arindam Khanda

Doctoral Dissertations

A complex system of interacting entities in contemporary scenarios, be it biological, technological, or social, can be represented using graphs. Dynamic graphs, unlike their static counterparts, are ones in which the underlying topology changes over time. These networks act as a model for numerous systems, from transportation to social interactions, capturing the ever-evolving nature of real-world phenomena. However, the inherent temporality of these networks presents a unique set of challenges and the traditional static graph algorithms often fall short in efficiency and applicability. In our research, we delve into the complexities presented by large dynamic networks and suggest various methodologies …


Characterizations Of Eco-Friendly Class C Fly Ash-Based Alkali-Activated Mixtures For Various 3d-Printing Techniques, Fareh Abudawaba Jan 2025

Characterizations Of Eco-Friendly Class C Fly Ash-Based Alkali-Activated Mixtures For Various 3d-Printing Techniques, Fareh Abudawaba

Doctoral Dissertations

This study explored the potential of using high-calcium class C fly ash (FA) as the main precursor for synthesizing alkali-activated mortar (AAM) suitable for 3D-printed concrete (3DPC) applications. The objective was to broaden the selection of AAMs, designed to suit various printing techniques, including continuous mixing and pumping, large batch mixing, and set-on-demand processes. The study began by assessing the fresh properties of various mixtures, utilizing tests such as open time (OT), initial setting time (IST), immediate axial deformation, and penetration test (PT), to determine the mixtures' extrudability and buildability. The study optimized mixtures with a broad spectrum of cycle …


Thermal Hydraulics Investigation Of A Horizontal Dual Channel Setup Representing Micro Nuclear Reactors Using Integrated Advanced Measurement Techniques, Zeyad Zeitoun Jan 2025

Thermal Hydraulics Investigation Of A Horizontal Dual Channel Setup Representing Micro Nuclear Reactors Using Integrated Advanced Measurement Techniques, Zeyad Zeitoun

Doctoral Dissertations

The urgency to reduce greenhouse gas emissions has spotlighted nuclear energy as a carbon-free solution. Despite its promise, nuclear safety concerns, highlighted by the 2011 Fukushima disaster, necessitate advancements in reactor technology. The United States has prioritized the development of safer, prismatic micronuclear reactors for the coming decade, focusing on the safe operation of these facilities. These reactors' design addresses potential hazards, particularly in loss of flow accident scenarios, making the understanding of natural circulation gas flow dynamics critical. Experiments on a horizontal dual-channel plenum-to-plenum facility (P2PF) were conducted to closely mimic the conditions within prismatic micronuclear reactors. This study …


Investigation Of The Transport And Plugging Behavior Of Preformed Particle Gels (Ppgs) In Fractures For Conformance Control In Carbonate Reservoirs, Abdulaziz A. Almakimi Jan 2025

Investigation Of The Transport And Plugging Behavior Of Preformed Particle Gels (Ppgs) In Fractures For Conformance Control In Carbonate Reservoirs, Abdulaziz A. Almakimi

Doctoral Dissertations

This study aims to systematically evaluate the performance of preformed particle gels (PPGs) in fractured carbonates mainly through a series of core flooding experiments. Carbonate reservoirs exhibit unique features of heterogeneity and pore geometry, while (PPGs) are known for their plugging efficiency, deformability, and dehydratable nature. The main goal of gel injection in fractured reservoirs is to place a gel pack appropriately into the fracture, diverting injected fluid to the oil-bearing matrix and reducing excessive water production. However, considerable dehydration of (PPGs) is possible at the adjacent matrix and within the fracture, which could lead to a filter-cake formation and/or …


Experimental Investgation Of Core Fluid And Heat Transfer Of Pwr By Using Advanced Measurments Techniques, Saud Aldawood Jan 2025

Experimental Investgation Of Core Fluid And Heat Transfer Of Pwr By Using Advanced Measurments Techniques, Saud Aldawood

Doctoral Dissertations

This comprehensive study investigates the thermal-hydraulic mechanisms and convective heat transfer characteristics within (PWRs), with a focus on (SMRs) under both single-phase and two-phase bubbly flow conditions. Specifically, the research investigates the complex bubble dynamics in two-phase flow rod bundles, which are crucial for understanding reactor behavior during loss-of-coolant accidents (LOCA). Employing an advanced experimental setup developed at the (mFReel) at MST, this work measures critical parameters such as void fraction, bubble passage frequency, bubble velocity, bubble chord length, and interfacial area concentration (IAC) using a four-tip optical probe across various locations in the rod bundle. The findings reveal that …


Provenance Of The Uppermost Carboniferous–Lower Triassic Sandstones, Bogda Mountains, Nw China: Implications On The Late Paleozoic Tectonic History Of The Southern Central Asian Orogenic Belt, Sixuan Wu Jan 2025

Provenance Of The Uppermost Carboniferous–Lower Triassic Sandstones, Bogda Mountains, Nw China: Implications On The Late Paleozoic Tectonic History Of The Southern Central Asian Orogenic Belt, Sixuan Wu

Doctoral Dissertations

"The Permian-Triassic period represents a significant but insufficiently understood tectonic transition stage in the southern Central Asian Orogenic Belt (CAOB) between the Paleozoic continental amalgamation and Cenozoic orogenic reactivation. This study integrates fieldwork, petrographic, and detrital zircon geochronological data to document the trend of depositional environments, framework grain compositions, and dates of detrital zircon grains of the uppermost Carboniferous–Lower Triassic sandstones from three study areas in Bogda Mountains, the greater Turpan-Junggar basin, NW China, to decipher the spatial and temporal changes in the provenance lithology and area and reconstruct the unroofing history of the southern CAOB.

In the first part …


Nano-Micro Engineering For Advanced Energy Devices, Tazdik Patwary Plateau Jan 2025

Nano-Micro Engineering For Advanced Energy Devices, Tazdik Patwary Plateau

Doctoral Dissertations

The development of advanced materials and manufacturing techniques for energy storage devices is continuously growing. The research emphasizes micro-engineering, nano-engineering, and advanced materials science, with the goal of enhancing the performance and scalability of manufacturing methods of different materials processing with a view of achieving sustainability. In the micro-engineering domain, novel methods for fabricating thick electrodes with short diffusion paths are introduced, enabling higher mass loading and improved battery performance. Additionally, innovative strategies for optimizing the performance of carbon nanofibers (CNFs) as anode materials in LIBs are explored in the nano-engineering domain. These studies address key challenges such as inter-bonding …


A Comprehensive Analysis Of Climate Resilience Strategies For Small Island Developing States, Ashley-Ann Davis Jan 2025

A Comprehensive Analysis Of Climate Resilience Strategies For Small Island Developing States, Ashley-Ann Davis

Doctoral Dissertations

Small Island Developing States (SIDS) face unique and disproportionate challenges in their efforts to achieve climate resilience due to their geographic vulnerabilities, limited resources, and systemic economic and social constraints. This dissertation provides a comprehensive analysis of climate resilience strategies tailored to SIDS, addressing critical systemic issues and exploring interdisciplinary solutions. It synthesizes findings across four interconnected studies, including an analysis of disaster preparedness and response mechanisms in developing countries to identify gaps and opportunities for improving resilience in extreme events. The research investigates economic factors influencing energy portfolio transitions in the Caribbean, emphasizing the complexities of renewable energy adoption. …


Power Supply Induced Jitter Analysis In High-Speed Drivers, Yifan Ding Jan 2025

Power Supply Induced Jitter Analysis In High-Speed Drivers, Yifan Ding

Doctoral Dissertations

The Input/Output Buffer Information Specification (IBIS) model faces challenges in accurately simulating power-supply-induced jitter (PSIJ), particularly under nonlinear and time-varying power noise conditions with pre-driver stages. This work introduces advancements in IBIS model modification algorithms to enhance PSIJ simulation accuracy for high-speed drivers.

First, a correction coefficient-based approach was developed to adjust switching coefficients K_pu and K_pd using pre-driver DC jitter sensitivity, significantly improving model robustness under DC and AC power noise. However, its effectiveness diminished under large noise amplitudes due to coefficient shape dominance.

To address this, a simplified algorithm bypassed correction coefficient, directly correlating switching transitions with jitter …


Ceramic Dielectrics For High Temperature Capacitor Applications, Alan Daniel Devoe Jan 2025

Ceramic Dielectrics For High Temperature Capacitor Applications, Alan Daniel Devoe

Doctoral Dissertations

Technical progress in microelectronics is allowing operation in environments that were previously considered impossible. Building complete electronic circuits for applications above 450 degrees C, such as the planned NASA missions to Venus, require a variety of active and passive components, including multilayer ceramic capacitors (MLCC).

This study explores calcium zirconate CaZrO3 and magnesium oxide MgO based dielectric compositions for MLCC applications that are capable of operating at extreme temperatures between 450 degrees C and 600 degrees C. Both materials were characterized with respect to impurities, dopants, crystal structure and microstructural development. Dielectric properties were measured to determine permittivity, dissipation factor, …


Implication And Applications Of Machine Learning On Biomedical Images, Jason Hagerty Jan 2025

Implication And Applications Of Machine Learning On Biomedical Images, Jason Hagerty

Doctoral Dissertations

Medical imaging ranges in modality including computer tomography imaging, x-ray imaging, digital microscopy, and macro-focus dermoscopy images. The latter two modalities are the focus of the presented work.

To perform a diagnostic evaluation on the captured dermoscopy image, it begins with what is usually a labor-intensive operation that requires an expert to perform the initial segmentation for localizing a region of interest (ROI). Once that ROI is obtained, a physician with years of training and experience will observe biological markers that can be used to visually differentiate whether a lesion is benign or malignant. A similar process is used for …


Quantum And Classical Phase Transitions In Disordered Systems, Gaurav Ramesh Khairnar Jan 2025

Quantum And Classical Phase Transitions In Disordered Systems, Gaurav Ramesh Khairnar

Doctoral Dissertations

This work examines the effects of quenched disorder on classical and quantum phase transitions. There are countless examples of phase transitions in nature. Here, we study phase transitions in condensed matter with the help of simple models that focus on the essential unifying features of the problems. We are particularly interested in investigating how the presence of disorder changes the behavior of the system in the vicinity of a phase transition.

Here, we discuss three closely related problems regarding phase transitions. First we consider the behavior of highly diluted magnets with varying dilution levels in order to explain the unusual …


Experimental Study Of Defects In Coaxial Wire-Based Laser Metal Deposition, Remy Mathenia Jan 2025

Experimental Study Of Defects In Coaxial Wire-Based Laser Metal Deposition, Remy Mathenia

Doctoral Dissertations

This work seeks to improve the usability and capability of coaxial wire-based laser metal deposition (LMD) through the experimental study of process parameters on output geometry, directional effects, and defect formation. Wire-based LMD is a directed energy deposition (DED) strategy that uses a focused laser heat source to melt and fuse metal wire as it is deposited. This process is used to build parts layer-by-layer until a desired geometry is accomplished. LMD enables the creation of complex components at a high build rate with low material and energy waste. This work focuses on the deposition of titanium wire in the …


Evaluating And Relaxing The Limits On Flexural Reinforcement Ratio Of Masonry Shear Walls, Tousif Mahmood Jan 2025

Evaluating And Relaxing The Limits On Flexural Reinforcement Ratio Of Masonry Shear Walls, Tousif Mahmood

Doctoral Dissertations

Reinforced masonry shear walls (RMSWs), essential for lateral and out-of-plane load-resisting systems in modern construction are constrained by TMS 402/602 code limits on reinforcement ratios ("ρ" _"max" ) and axial compressive stresses (≤10% of masonry compressive strength, f_m^'), undermining masonry’s inherent compression capacity under high axial loads. This dissertation investigates the seismic performance of reinforced masonry shear walls (RMSWs) subjected to high axial compressive stresses (10–20% of f_m^'), with a focus on walls violating the maximum reinforcement ratio ("ρ" _"max") and axial load limits of TMS 402-22. Through experimental testing of 30 large-scale fully grouted (FG) and partially grouted (PG) …


On The Importance Of Novel Adsorption Processes And Structured Adsorbents For Biogas Upgrading And Storage, Kyle Newport Jan 2025

On The Importance Of Novel Adsorption Processes And Structured Adsorbents For Biogas Upgrading And Storage, Kyle Newport

Doctoral Dissertations

The current adsorption processes investigated for biogas upgrading encounter severe challenges with regards to both adsorbents and processes, which necessitate the design and development of novel approaches to effectively separate carbon dioxide from methane and, hence, produce pipeline-grade renewable natural gas (RNG) as a fuel. These key challenges include (i) moderate CO2/CH4 selectivity, (ii) relatively long cycle times, (iii) high regeneration energy requirements, (iv) high-pressure drop, and (v) short adsorbent lifetime. The current biogas upgrading processes typically rely on pressure swing adsorption (PSA) or temperature swing adsorption (TSA). While PSA cycles are fast, the system requires large amounts of energy …


Development Of Catalytic Membranes And Composites For Energy Storage Devices And Nonenzymatic Biosensors, Harish Singh Jan 2025

Development Of Catalytic Membranes And Composites For Energy Storage Devices And Nonenzymatic Biosensors, Harish Singh

Doctoral Dissertations

The excessive use of fossil fuels has led to their rapid depletion, causing an energy crisis and environmental issues. Consequently, there's a growing focus on sustainable energy conversion. Electrocatalysts are pivotal in this development, particularly for fuel cells and solar fuel generators, necessitating high-efficiency, cost-effective catalysts for large-scale adoption. Transition metal chalcogenides have emerged as promising electrocatalysts due to their high efficiency, electrochemical tunability, and abundant active sites. This work is divided in two parts. In Part A, we have investigated transition metal chalcogenide and few atom clusters FACs as electrocatalysts for oxygen evolution and reduction, highlighting their structure-property relationships …