Digital Commons Network^™

Functionalized Carbon Nanohoops: Synthesis, Structural Insights, And Pathways To Carbon Nanobelts, Liu Li

Graduate Theses, Dissertations, and Problem Reports (ETD)

The development of structurally defined carbon nanostructures has gained significant attention due to their unique electronic, optical, and mechanical properties. Cycloparaphenylenes (CPPs), also known as carbon nanohoops, and carbon nanobelts (CNBs) represent key molecular segments of carbon nanotubes (CNTs), offering a bottom-up approach to precise nanotube construction. This dissertation focuses on the synthesis, structural characterization, and functionalization of CPPs, as well as the development of novel synthetic pathways for CNBs. A series of functionalized CPPs, including [9]-, [12]-, [15]-, and [18]CPPs, were synthesized using a modular approach involving a Diels-Alder adduct formation followed by a Ni(cod)2/bpymediated macrocyclization reaction. The influence …

Apostrophes And Archimedes, Evan J. Clough

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis explores how digital collage and printmaking can be used to develop images through acts of subjective response, intentional and unintentional acts of appropriation, and parodic re-use and comparison pushed to absurd extremes. It looks at the history of creating art for parodic re-use and examines “Pataphysics”, developed by and for art appropriation of pattern, form, and process. These concepts are explained and related to visual artwork that was made for the thesis exhibition Apostrophes and Archimedes Cast Shadow Puppets. The exhibition invites viewers to experience the phenomenon of observation, automatic transformation, and creation using multiple modalities of exaggerated …

A Limb-Speed-Driven Locomotor Control System And Its Ability To Adapt, Emily Marie Herrick

Graduate Theses, Dissertations, and Problem Reports (ETD)

Despite how simple walking may seem, the locomotor control system is structurally and functionally complex. Its hierarchical organization of supraspinal and spinal networks with forward and feedback pathways has many interactions at multiple levels that are dependent on the dynamics of a high-dimensional musculoskeletal system. Having a comprehensive understanding of sensorimotor integration within a healthy locomotor control system is crucial for understanding changes to the system due to age or neurologic disease and developing effective technologies to recover mobility in those populations. In this dissertation, we address persistent gaps in knowledge pertaining to how the nervous system controls locomotion.

In …

Numerical Investigation Of Pressurized Oxy-Combustion, Lei Li

Graduate Theses, Dissertations, and Problem Reports (ETD)

Pressurized oxy-combustion (POC) is emerging as a promising and transformative technology for carbon capture, utilization, and storage, offering advantages of low cost, low emissions, and high efficiency. POC operates by burning pulverized coal at elevated pressures in a recycled flue gas environment, typically rich in O₂ and CO₂. This study presents a comprehensive numerical investigation into the fundamental behaviors of lab-scale POC reactors, using both two-dimensional (2D) Reynolds-Averaged Navier-Stokes (RANS) simulations and three-dimensional (3D) Large-Eddy Simulations (LES) with the commercial computational fluidized dynamics (CFD) software package ANSYS Fluent.

The primary focus of this work is to understand flame stabilization and …

Searching For The "Tender Places": Shoddy, Knowledge, And Material Culture In The Civil War Era, Robert William Novak

Graduate Theses, Dissertations, and Problem Reports (ETD)

In the American Civil War era, shoddy was difficult to understand. It was simultaneously seen as evidence of advancing western civilization as well as a disgusting amalgamation of refuse and disease that threatened those who touched it. Made from shredding woolen rags and tailors’ clippings, the recycled woolen fibers could by applied in myriad woolen blends that came to dominate the ready-made clothing industry that developed through the first half of the nineteenth century. Its application could soften coarse blends and refine the appearance of cheap cloth. When the American Civil War erupted in 1861, however, shoddy came to define …

Expanding The Vibrating Sharp-Edge Spray Ionization Toolkit For Oligonucleotide Characterization, Sultan Mahmud

Graduate Theses, Dissertations, and Problem Reports (ETD)

A gentle or soft Ionization process is a critical component in native mass spectrometry (MS) to lift the biomolecules from the bulk solution into the gas phase environment of the mass spectrometer preserving their shape, topology and non-covalent interactions. Electrospray ionization (ESI) facilitates structural preservation of proteins, nucleic acids and their complexes and as a result it has been extensively used in native MS. However, in negative ion mode, ESI is somewhat limited in sensitivity due to corona discharge effect resulting from the requirement of a high amount of voltage. This often disrupts the ESI process and may not preserve …

The Effects Of The Implementation Of State-Sponsored Free Community College Programs On Enrollment And Net Price, Kristafer Lee Adkins

Graduate Theses, Dissertations, and Problem Reports (ETD)

State-sponsored, free community college programs have been implemented with the goal of increasing access to higher education, especially for financially disadvantaged students. This study seeks to determine the impact of the implementation of the Tennessee Promise and the Oregon Promise on enrollment and net price by student family income level using a difference-in-differences methodology comparing in-state, public, two-year institutional outcomes with: in-state, public four-year institutions; national, public, two-year institutions; and, public, two-year institutions in states that border Tennessee/Oregon. Enrollment was, on average, found to have increased between 44 and 167 students at Tennessee public, two-year institutions for all students with …

Forensic Characterization And Comparison Of Modern Nail Polish Products By Their Physical Features And Chemical Composition, Madison Meredith Lindung

Graduate Theses, Dissertations, and Problem Reports (ETD)

Nail polish can serve as valuable evidence in forensic investigations as it is often found on the hands and feet of individuals. Nail polish can break off and transfer easily during self-defense actions or forceful contact, such as in cases of kidnapping, sexual assault, or homicide. These residues can provide clues about who was at the scene, as well as where, when, and how the event evolved. However, compared to other types of paints commonly analyzed in forensic laboratories, limited forensic research has been conducted on the chemical composition and discrimination capabilities of popular nail products. The lack of information …

The Economics Of Crime And Reform: Essays On Alcohol Taxation, Cannabis Legalization, And Felon Enfranchisement., Georgios Marios Bantis

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation comprises three independent yet thematically connected essays that explore the effects of public policy on crime and municipal finance. The first chapter examines the relationship between alcohol taxation and crime, assessing how changes in excise tax policies influence criminal activity. The second chapter investigates the fiscal implications of felon enfranchisement, analyzing how the restoration of voting rights to individuals with felony convictions affects municipal public finance. The third chapter evaluates the impact of cannabis legalization on crime, focusing on whether and how legalization alters crime patterns. Each chapter is structured as a stand-alone research paper. A general introduction …

Social Support And Negative Affective Outcomes Among Older Adults: Does Valuing Autonomy Matter?, Erika Anne Fenstermacher

Graduate Theses, Dissertations, and Problem Reports (ETD)

While not a normal part of aging, depression is a concerning psychiatric condition in late life. Depression is a significant predictor of suicide and the highest rates of suicide occur in middle aged and older adult men. One factor that may protect against depression and suicidal behavior among older adults is social support. Social support has been demonstrated as a significant factor in health and well-being. Perceived social support has consistently been linked to beneficial outcomes, however, received support has mixed results with some studies even finding received support to be harmful. For individuals who highly value autonomy, it may …

Co-Transmission Is Co-Opted For The Coordination Of Auditory Sensory Integration, Marryn M. Bennett

Graduate Theses, Dissertations, and Problem Reports (ETD)

Corollary discharge circuits (CDCs) are conserved mechanisms for sensory modulation during species specific behavioral programs. Many behaviors require multiplexed differential sensory modulation for proper execution. Co-transmission of fast and slow neurotransmitters allows for distinct modulation of different downstream targets within one sensorimotor circuit. However, studying co-transmission within the context of modulatory circuits like CDCs requires complete knowledge of behavioral circuits and precise tools for individually determining the implications of each transmitter on its targets. In this dissertation, I used a conserved set of corollary discharge interneurons in Drosophila melanogaster as a model to study the intricacies of sensory modulation through …

Autonomous Vehicle Supported Mobility Services For Rural Areas, Alvira Ahmed Tasnim

Graduate Theses, Dissertations, and Problem Reports (ETD)

Autonomous Vehicles (AVs) are emerging as a promising mobility solution to address growing transportation demands, particularly unmet traffic demand in rural areas where conventional transit systems often fall short. Rural areas face unique mobility challenges due to dispersed populations, limited infrastructure, and low/no transit coverage. Existing transit services tend to concentrate around dense urban cores, leaving low-demand areas outside underserved. This spatial undercoverage leads to significant mobility gaps for rural residents. This study examines the potential of AV-based ride-sharing services to address these mobility needs by providing flexible, demand-responsive mobility services where fixed-route transit services are either economically or operationally …

Using Probabilistic Risk Assessment In Drilling R&D Projects, Jacob Matthew Smith

Graduate Theses, Dissertations, and Problem Reports (ETD)

Well drilling, since its inception, has always carried an intrinsic quantity of risk. Economically, the evolution of data analytics and the tools available to operators provide the opportunity to transform the lessons learned from previous well drilling endeavors into bottom line improvements. Additionally, methods for forecasting and risk management of potential trouble areas have significantly advanced due to the abundance of empirical data from prior drilling operations. Probabilistic Risk Assessment is a viable method through which risk can be tracked and mitigated in project management. Coupled with this data, the usage of Probabilistic Risk Assessment (PRA) provides a quantified, trackable …

Vital Rates And Nest Site Selection Of Merriam’S Wild Turkeys (Meleagris Gallopavo Merriami) In South-Central, South Dakota, Luke N. Mccray

Graduate Theses, Dissertations, and Problem Reports (ETD)

Wild turkeys (Meleagris gallopavo) are an economically and culturally significantly game species throughout much of the United States. Within South Dakota, spring turkey hunting generates approximately $20 million in expenditures annually to local economies. Merriam’s wild turkeys (Meleagris gallopavo meriami) were reintroduced to the Missouri River Breaks of Gregory County, South Dakota, USA, between the 1950s and 1980s, and was one of the most successful reintroductions in the state. However, a recent decline in gobbler harvest suggests a potential decline in this population. To estimate survival and reproduction and evaluate nest site selection, we captured 121 …

An Evidence-Based Practice Initiative To Improve Blood Pressure Control, Teresa D. Hines

Graduate Theses, Dissertations, and Problem Reports (ETD)

Introduction/Background: High blood pressure (HBP) is a significant public health concern. It affects millions of adults in the United States (US) and half of the adult population in the Appalachia regions. High blood pressure is a known risk factor for cardiovascular disease (CVD), which is the leading cause of morbidity and mortality Appalachia. Complications associated with high blood pressure result in substantial economic burdens for patients and their families, healthcare systems, and national economies. High blood pressure is a significant health issue in West Virginia (WV), with an estimated 602,000 people suffering from HBP.

Purpose: The purpose of this …

Analysis Of Shotshell Breech Face Impressions Using A Computer-Based Algorithm, Carly Renee Smith

Graduate Theses, Dissertations, and Problem Reports (ETD)

Forensic firearm analysis involves the comparison of test fires from a suspect firearm to an unknown sample, typically collected from a crime scene. Test fires and the unknown sample are examined for agreement in class characteristics and sufficient agreement in individual characteristics using a comparison microscope. The forensic analysis of firearms has been challenged both in court and by governmental organizations for its subjective nature and the inability to accurately report error rates.

To combat these challenges, the National Institute of Standards and Technology (NIST) has proposed using computer-based algorithms, such as Congruent Matching Cells (CMC). These CMC algorithm calculates …

Demonstrating The Potential Of Biophilic Design, Sustainable Site Initiatives, And Regenerative Landscape Design To Transform Neglected And Underutilized Spaces Into Vibrant, Eco-Friendly Hubs In Mckeesport Pennsylvania., Chinweuba Stephen Kikanme

Graduate Theses, Dissertations, and Problem Reports (ETD)

McKeesport is a city located along Monongahela and Youghiogheny rivers in Allegheny County, Pennsylvania, about 13 miles southeast of Pittsburgh. It is part of the River metropolitan area. McKeesport, once a thriving center of steel production, is now facing significant challenges associated with industrial decline, urban blight, flood hazard, population decline, brownfield sites and environmental degradation. However, the transformation of neglected spaces within the city into sustainable and vibrant urban hubs offers a powerful opportunity for revitalization. By incorporating natural elements such as green roofs, urban agriculture, and native plant restoration, this project seeks to create spaces that not only …

P23h Rhodopsin Accumulation Disrupts Synaptic Protein Levels In Rod Photoreceptors, Samantha Thompson

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rod photoreceptors are specialized neurons located in the retina, the neural tissue that lines the back of the eye. Rod photoreceptors are necessary for dim light and peripheral vision through the photoactivation rhodopsin (Rho). Rho is synthesized in the inner segment of rods before being unidirectionally trafficked to the outer segment. In diseases such as retinitis pigmentosa (RP), Rho trafficking can be disrupted, leading to progressive rod cell death. In many cases of RP, Rho is mislocalized to the rod photoreceptor synapse (“spherule”). The impact of Rho mislocalization on spherule structure and protein organization is poorly understood. We hypothesize that …

From Bobcat To Bursts: Multi-Messenger Constraints On Supermassive Black Holes And Binaries, Jessica Sydnor

Graduate Theses, Dissertations, and Problem Reports (ETD)

Supermassive black hole binaries (SMBHBs) are a natural consequence of hierarchical galaxy formation and evolution. When galaxies merge, their central supermassive black holes (SMBHs) are expected to form bound pairs that evolve from kiloparsec to sub-parsec separations under the influence of dynamical friction, stellar scattering, and gas dynamics. Ultimately, these SMBHs reach the regime where gravitational wave emission dominates and drives the final inspiral and coalescence. Understanding the formation, evolution, and observational signatures of SMBHBs is critical to advancing multi-messenger astrophysics, particularly in the era of pulsar timing arrays (PTAs) and the upcoming Laser Interferometer Space Antenna (LISA), which opens …

Introduction Of Polar Functional Groups To Pyridinedipyrrolide Zirconium Photosensitizers Through Post-Synthetic Modifications, Marisa Nicole Tordella

Graduate Theses, Dissertations, and Problem Reports (ETD)

Photosensitizers are vital components to applications such as photoredox catalysis, photodynamic therapy, and various avenues of solar energy production. The abilities of transition metal photosensitizers containing precious metals have been well studied over the years. However, because of the growing scarcity of these metals, there has been a shift in finding more earth abundant alternatives. To help fill this gap in the literature, the Milsmann group has developed and studied the photophysical properties of Zr(IV) complexes with various ligand systems. Due to the electron deficient metal center, these complexes exhibit ligand-to-metal charge transfer (LMCT), unlike the metal-to-ligand charge transfer commonly …

Three Essays On Environmental Regulation And Economic Revitalization In Energy Rich Regions, Young Gwan Lee

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation consists of three essays that investigate the environmental and regulatory dimensions of unconventional oil and gas (UOG) development and place-based policy in the United States. The research examines how energy production activities interact with water resource management, regulatory compliance behavior, and regional economic resilience. By integrating empirical modeling, quasi-experimental methods, and policy evaluation, the dissertation provides new insights into how environmental risks and economic tradeoffs are shaped by regulatory constraints, strategic behavior of regulated entities, and government interventions in extractive regions. Managing produced water from unconventional oil and gas (UOG) production is a growing environmental challenge, particularly as …

Investigation Of Spalling Effects On The Brittle Behavior Of Rectangular Pillars In Underground Stone Mines, Yolver Yesid Jimenez Ibanez

Graduate Theses, Dissertations, and Problem Reports (ETD)

Recent catastrophic collapses in U.S. limestone mines have exposed the limitations of traditional empirical design formulas for brittle rock masses. These events, especially those involving slender pillars, underscore that traditional methods often fail to account for progressive, spalling-dominated failure, highlighting a crucial gap in our understanding. This research addresses this issue by conducting a comprehensive investigation into the mechanics of spalling in rectangular stone mine pillars, utilizing advanced three-dimensional numerical modeling with FLAC3D combined with LiDAR-based geometric modeling.

The stability of a pillar is governed by a complex interaction between the in-situ stress field, rock mass properties, and pillar geometry. …

Investigating The Physiological, Metabolomic, And Transcriptomic Changes In Response To Telomerase Deletion In Saccharomyces Cerevisiae, Taizina Momtareen

Graduate Theses, Dissertations, and Problem Reports (ETD)

Telomerase is an enzyme found in rapidly dividing cells that maintains chromosome ends and prevents the loss of genetic information during cell division. When telomerase is inactive, cells gradually lose their telomeres and eventually stop dividing. In yeast, a rare subset of cells can bypass this growth arrest by switching to a recombination-based mechanism to maintain telomeres. Therefore, yeast provides a powerful system to study this adaptation, as telomerase-deficient strains can generate 'survivors' that mimic the Alternative Lengthening of Telomeres (ALT) pathway observed in some human tumors. In this work, my goal was to examine how a telomerase-null (TLC1 …

Investigating The Biology, Hypovirulence, And Pathogenicity Of Three Canker-Causing Phytopathogenic Fungi In The Cryphonectriaceae And Cytosporaceae On American Chestnut (Castanea Dentata) And Oaks (Quercus Spp.) In The Eastern U.S., Danielle N. Mikolajewski

Graduate Theses, Dissertations, and Problem Reports (ETD)

American chestnut (Castanea dentata) and various oak species (Quercus spp.) are impacted by several economically important canker pathogens in the fungal order Diaporthales, namely Cryphonectria parasitica and Endothia gyrosa (Cryphonectriaceae). Cytospora canker caused by several closely related fungi in the fungal genera Cytospora and Valsa (Cytosporaceae) have also been implicated in causing canker diseases of Quercus and Castanea in Asia, Europe and North America. The impacts of C. parasitica on American chestnut have been exhaustively studied and it’s impacts on various oak hosts have also been broadly investigated and reported. Endothia gyrosa has …

Rare Earth Element Recovery From Acid Mine Drainage Using Ion Exchange And Selective Precipitation Processes, Paubla Andrea Gallego Lopez

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rare earth elements (REEs) are used in high-tech applications due to their electromagnetic and optical properties. As global demand for REEs surges, the limitation of primary mineral deposits has increased interest in alternative sources. One such source is acid mine drainage (AMD), which, although typically low in REE concentration, offers a promising avenue for recovery. Among the emerging recovery methods, ion exchange has shown promise due to its effectiveness at low concentrations and lower operational cost than conventional techniques such as acid leaching and solvent extraction.

This research focused on developing a recovery process by combining ion exchange with selective …

Characterization Of A Descending Neuron That Modulates Flight Performance And Provides Input Onto A Flight-Related Predictive Motor Circuit, Andisheh Balouchi

Graduate Theses, Dissertations, and Problem Reports (ETD)

Descending neurons (DNs) play a critical role in sensorimotor integration by relaying motor information to the ventral nerve cord (VNC). Within the VNC, local interneurons, other DNs, and ascending neurons (ANs) make circuits with sensory and motor neurons to modify flies’ behavior. One important AN pair in Drosophila Melanogaster is mesothoracic ascending histaminergic neurons (MsAHNs), which are known to convey predictive wing motor signals to the brain. DNg32 is the primary upstream synaptic partner of MsAHNs, integrating DNg32 input with other inputs to generate predictive motor signals. The goals of this study were to 1) map the synaptic connectivity of …

Simulated Slot Machine Gambling In Relation To Sign-Tracking, Polina Krom

Graduate Theses, Dissertations, and Problem Reports (ETD)

The propensity to attribute incentive salience to reward-related cues, or sign-tracking (ST) has been linked to addiction in animal models and some initial human data. The current study explores the role of sign-tracking (ST), as a potential risk factor for problematic slot machine gambling, which abundantly features audiovisual reward-related cues, henceforth sensory features. A sample of healthy participants without gambling problems (n = 30) completed a Pavlovian-to-Instrumental Transfer (PIT) paradigm to assess ST propensity and played on a realistic slot machine simulator consisting of two versions: with sensory features (SF+) and without (SF-). Each game version had fixed bet sizes, …

Not Far Enough: The West Virginia Human Rights Commission And The Civil Rights Movement, David Solomon

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis investigates the West Virginia Human Rights Commission and its action surrounding the Civil Rights Movement. The Commission represented the liberal ideals that led white moderates to be potent allies of the Civil Rights Movement. Throughout the years following its inception, the Commission investigated and documented many instances of Jim Crow that were crushing Black communities in West Virginia. However, the limits of its liberal approach prevented it from creating solutions that would address the power structures that supported discrimination in West Virginia. By the late 1960s, Black frustrations with the lack of meaningful change boiled over into riots …

The Effect Of Carrier Type And Material Used On Results Of 1,1,1,2-Tetrafluoroethane Application To Teeth, Jonathon Logan Williams Dds

Graduate Theses, Dissertations, and Problem Reports (ETD)

Introduction: The formulation of a pulpal diagnosis is crucial to prescribe appropriate treatment recommendations for endodontics. The application of a cold stimulus to the tooth’s surface utilizing the refrigerant 1,1,1,2-Tetrafluoroethane (R-134a) is a common way to obtain a pulpal diagnosis. Cotton as a form of applicator is used to absorb the R-134a and create a temperature change in the pulp. There is limited research if there is a better material than cotton to generate this cold response. No studies to date have been found to determine if a sponge as an applicator would generate a more significant cold response than …

The Effect Of Alternative Work Regimes On Recruiter Productivity, Keith Sean Cogdell

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation examines the impact of different work regimes, onsite, remote, and hybrid, on recruiter productivity within the staffing industry. As workforce models evolve, organizations encounter challenges in determining how these structural changes influence employee performance. Existing studies are often cross-sectional and rely heavily on self-reported data, limiting their capacity to capture long-term trends and contextual factors. To address this issue, the present research utilizes a longitudinal design with five years of recruiter-level performance data from a national staffing firm, which includes over 27,000 observations. Using Self-Determination Theory (SDT) as a framework, the study investigates how intrinsic motivation mediated by …