Digital Commons Network^™

Quantitative Surface-Enhanced Raman Spectroscopy For Antiretroviral Drug Monitoring: Novel Quality Index And Distributional Approaches In Aqueous And Plasma Matrices, Marguerite Rose Butler

Chemistry & Biochemistry Theses & Dissertations

Surface-enhanced Raman spectroscopy (SERS) offers high sensitivity for molecular detection but is limited for quantitative applications by spatial heterogeneity in signal enhancement on dried colloidal substrates. This Dissertation addresses these limitations through the development and evaluation of novel quantitative methods applied to the antiretroviral drugs tenofovir and emtricitabine.

A quality index (Qi) metric was developed to rank individual SERS spectra within each well based on analyte peak prominence relative to local baseline. SERS spectra were acquired from evaporated silver colloid deposits on aluminum well plates using a custom raster-scanning Raman system. Calibration curves were constructed using the top-ranked spectra (Top-Qi …

Motivation And Constraints In Recreation Participation Among Children And Adults With Disabilities, Monica Klock

Human Movement Studies & Special Education Theses & Dissertations

This dissertation investigated how motivation and constraints relate to participation in outdoor and community recreation among children with disabilities and adults who are blind or visually impaired. Although outdoor recreation is associated with important physical, psychological, and social benefits, people with disabilities continue to participate at lower rates than their peers without disabilities, and prior work shows that barriers extend well beyond physical access to include structural, interpersonal, and intrapersonal constraints. Drawing on the Constraint–Negotiation Model (CNM) and social cognitive theory, this dissertation addressed gaps in multivariate research and life-course perspectives by examining whether and how motivations, perceived constraints, and …

Variability In Nutrient And Enterococcus Concentrations In Tidal Floodwater Across Watersheds With Different Land Uses, Alyssa Bucci

OES Theses and Dissertations

Tidal flooding is an increasingly pressing hazard in coastal Virginia due to sea level rise and land subsidence. The Hampton Roads region of Virginia has the second-highest rate of relative sea level rise in the United States and experiences frequent tidal flooding, but the water quality impacts of this flooding on the Chesapeake Bay are not being accounted for. High concentrations of dissolved nutrients and Enterococcus bacteria (a fecal indicator) have been observed in tidal floodwater of the Lafayette River, a tributary of the James River and the lower Chesapeake Bay. This study investigates variability in dissolved nutrient and Enterococcus …

Exploring Literacy Preparedness And Academic Experiences Of First-Year Community College Students, Alexandra Ranieri

Educational Leadership & Workforce Development Theses & Dissertations

Community colleges enroll students with diverse levels of academic preparation, yet placement into college-level coursework often relies heavily on high school grade point average (GPA), which may not fully reflect students' literacy preparedness. Although research has linked literacy proficiency to academic success, little is known about how first-year community college students experience literacy preparedness during the transition to college. The purpose of this qualitative case study was to examine the literacy preparedness of first-year community college students and explore how their reading abilities aligned with their early academic experiences. Guided by the Reading Systems Framework (Perfetti & Stafura, 2014), the …

Residual Stress Informed Reconstruction And Failure Analysis Of Manufacturing Induced Composite Meso-Structure, Mohammad Nazmus Saquib

Mechanical & Aerospace Engineering Theses & Dissertations

A physics informed, AI-augmented framework is developed to enable digital twins of molded composite materials by linking manufacturing induced residual stresses to a local meso-structure. By reconstructing and explicitly modeling these architectures, the framework reveals how processing driven meso-structural variability governs stiffness, damage evolution, and failure. The work focuses on two technologically important systems: prepreg platelet molded composites (PPMC), characterized by inherently stochastic platelet architectures, and 2/2 twill glass fiber/PA6 organosheets, whose periodic but locally variable weave geometry influences mechanical response. For PPMC, the Residual Stress Informed Microstructure Reconstruction (ResIMiR) framework is introduced, combining thermoelastic strain fields with deep learning …

Computational And Ai Tools For Understanding Telomere-Associated Cancer Mechanisms, Eleni Adam

Computer Science Theses & Dissertations

Telomeres are the protective caps of the human chromosomes and are critical for genome stability. Dysfunctional telomeres caused by their erosion with age and cell proliferation as well as by defects in their maintenance is a major early event leading to genome changes and cancer. Subtelomeres possess the critical role of regulating adjacent telomeres. Due to their complex repeat structure and high variance from one person to another, these areas have not been analyzed in detail. We present a set of computational and machine learning tools to aid in the understanding of subtelomere structure and its rearrangements in cancer.

Initially, …

Public Participation In Community Redevelopment Agencies: A Mixed Methods Approach To Understanding The Impacts Of Collaboration In Public-Private Partnerships, Shannon Mcbride-Lewis

School of Public Service Theses & Dissertations

Local governments create community redevelopment agencies (CRAs) to enhance economic and redevelopment opportunities within their communities through public-private partnerships funded with tax increment financing (TIF). The use of increment revenue, the complexity of public-private partnerships, and the controversies surrounding CRAs can lead to community concerns and opposition. Collaboratively engaging the public in the development, implementation, and performance of CRA public-private partnerships is one way to improve program and project outcomes by enhancing engagement, equity, and accountability. This study asks does the level of resources (dedicated professional staff, consequential incentives, and TIF contribution) and formal public-private partnership programs of CRAs influence …

Effect Of Rheology Modification On Fiber Orientation And Dispersion In 3d-Printed Ultra-High-Performance Concrete, Haodao Li, Alfred Addai-Nimoh, Seongho Han, Kamal H. Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The extrusion process in 3D concrete printing (3DCP) facilitates horizontal alignment of steel fibers along the printing direction, thus enhancing the load-bearing capacity of printed elements. However, such shear-induced fiber alignment is highly sensitive to rheological properties. This study investigates how variations in dynamic yield stress (τd) and plastic viscosity (μ), influence the extrudability, fiber orientation and dispersion, and anisotropic mechanical behavior of ultra-high-performance concrete (UHPC). Five viscosity-modifying agent (VMA) types were incorporated at two content levels to modify the rheology of printable UHPC. Results showed that moderate VMA additions improved printability, whereas excessive contents markedly increased τd and μ; …

Reframing Soil Freezing As An Unsaturated Process, Antai Dong, Xiong Zhang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Soil freezing and frost heave are inherently unsaturated soil phenomena. However, most existing numerical models are based on saturated soil mechanics or assume full saturation. This simplification introduces conceptual inconsistencies, requires modifications that violate fundamentals in soil mechanics and fluid mechanics, and often leads to the use of self-conflicting soil properties. To overcome these limitations, this study develops a physically consistent, fully coupled thermohydraulic model for soil freezing grounded in modern unsaturated soil mechanics. A soil freezing characteristic surface (SFCS) is introduced to represent unfrozen water content in partially frozen soils as a function of both suction and temperature. Recognizing …

Carroll County Extension Update August 2026, Mikayla Cerney

UNH Cooperative Extension

No abstract provided.

Mechanism Of Hypothiocyanous Acid Reductase, Morgan L. Fowler

Masters Theses

Hypothiocyanous acid reductase (Har) is a flavin-dependent enzyme that is effective in protecting bacteria from hypothiocyanous acid. HOSCN is an antimicrobial oxidant that is excreted by the mammalian innate immune system during inflammation, targeting and attacking thiols in pathogens. To combat HOSCN, bacteria have developed defense systems, including hypothiocyanous acid reductase. The catalytic mechanism by which Har interacts with its substrates, HOSCN and NADH, is undetermined and requires exploration.

In this study, we characterized the reductive and oxidative half-reactions of E. coli Har (EcHar). We first investigated and characterized wild-type EcHar, showing that Har is extremely efficient in reacting with …

High-Throughput Characterization Of Creep In Additively Manufactured 316l Stainless Steel, Raushan Kumar Singh

All Graduate Theses and Dissertations, Fall 2023 to Present

Advanced materials are widely used in industries such as nuclear energy, aerospace, and automotive engineering, where components are exposed to extreme temperatures and stresses over long periods of time. As new materials continue to emerge, researchers need efficient ways to evaluate their mechanical performance so they can be used safely and effectively. Among several mechanical challenges, creep is a major concern in these conditions. Creep is a type of mechanical failure in which materials gradually deform when exposed to high temperatures and constant load. Conventional methods for evaluating creep typically involve testing a single specimen at a time, which can …

Investigating The Role Of Patient-Provider Interaction Quality And Illness Interference In Patients' Basic Psychological Need Fulfillment And Subjective Well-Being, Rebecca Erin Elwood

All Graduate Theses and Dissertations, Fall 2023 to Present

Patient-provider communication occurs between patients and medical professionals. This type of communication is experienced by most U.S. adults yearly, and it can lead to positive health outcomes. The purpose of this study was to examine the role of this type of communication in patient’s lives overall. Specifically, the study considered if good quality patient-provider communication is associated with people feeling an overall sense of autonomy, competence, relatedness, and an overall positive experience of their life. It also considered how much symptoms or treatment of health issues impact people’s lives. Data in the study was collected through an online survey with …

Viability Assessment Of Bovine Embryos: A Public Dataset And Deep Learning Baselines, Erfan Khayyati

All Graduate Theses and Dissertations, Fall 2023 to Present

Improving the success rates of cattle breeding is essential for sustainable agriculture, global food security, and high-quality livestock production. Currently, determining whether a lab-grown bovine embryo is healthy enough for a successful pregnancy requires highly trained experts to manually evaluate days of continuous time-lapse video footage. This process is not only incredibly time-consuming but also highly subjective; human reviewers often suffer from visual fatigue when tracking subtle, microscopic cellular changes over a seven-day period, leading to significant disagreement among even top experts on an embryo’s true potential. Furthermore, assessing bovine embryos is notoriously difficult due to their dark, lipid-dense cellular …

Thermal Rating And Prediction Of Roadway-Embedded Power Electronics For Dynamic Wireless Power Transfer, Forrest D. Nichols

All Graduate Theses and Dissertations, Fall 2023 to Present

Electric vehicles can be charged while driving through wireless charging coils buried in the road surface. To avoid running expensive cables from roadside equipment to each charging pad, the electronics that control the power transfer can also be buried in the road. However, burying these circuit boards removes the ability to cool them with fans or flowing air, so the heat generated during operation must escape naturally into the surrounding road material. If the boards get too hot, components fail—a problem that has already been observed in prototype systems.

Predicting how hot each component on a circuit board will get …

Secure Agricultural Futures: Re-Defining And -Imagining Agricultural Water Landscapes In The Us West, Britta L. Schumacher

All Graduate Theses and Dissertations, Fall 2023 to Present

Aridity is swiftly becoming the US West’s new normal. As agricultural communities adjust to persistent growing-season scarcity, they find their livelihoods under increasing threat. This points to the urgency of finding paths toward more secure water futures. A piece of this future puzzle includes water (re-)distribution – taking excess from one place and delivering it to another in need. To begin thinking about (re-)distribution, this dissertation engages with three mixed-methods and multiscale studies. The first study pairs county-level data across the 11 westernmost US states with survey data collected from individual producers in Utah to assess past and current trends …

Spatial Prediction Under Uncertainty: Methodological And Computational Advances In Bayesian Maximum Entropy, Kinspride K. Duah

All Graduate Theses and Dissertations, Fall 2023 to Present

Environmental decisions such as infrastructure design, water management, and snow load estimation depend on spatial data that are often incomplete or uncertain. In many cases, measurements are not exact values but ranges, reflecting limitations in data collection methods. Traditional mapping techniques typically simplify these uncertain measurements, which can lead to less accurate predictions. This dissertation introduces improved statistical tools for making spatial predictions when data are uncertain or partially known. By utilizing a framework called Bayesian Maximum Entropy (BME), this research demonstrates how exact measurements and range-based data can be combined in a mathematically consistent way. The work demonstrates that …

Sensitivity Analysis Of A Low-Power Wireless Capacitive Charging System To Inform Thermal Limitations And Battery Size Reduction Potential For Electric Passenger Vehicles, Karmen Teuscher

All Graduate Theses and Dissertations, Fall 2023 to Present

The purpose of using electric vehicles instead of internal combustion engine vehicles that burn gas is to reduce pollutants in the air and potential environmental impacts such as climate change. EVs produce much less air pollutants than ICEVs but manufacturing the EV batteries and the repeated recharging still contributes to the overall air pollution.

Capacitive power transfer systems can wirelessly charge vehicles through the road as they drive along highways or stop at traffic lights. If vehicles charge as they drive, an opportunity opens to reduce the size of the battery while maintaining the same driving range. Reducing the size …

Agronomic And Economic Evaluation Of Alternative Forage Crops Under Irrigation Technologies And Deficit Irrigation, Shikha Sharma

All Graduate Theses and Dissertations, Fall 2023 to Present

Water is becoming more limited in the western United States, including Utah, so farmers need forage crops that can produce well while using less irrigation water. This study examined how different forage crops respond to reduced irrigation and different irrigation application methods, and whether some crops can provide better economic returns under limited water conditions.

Field studies were conducted at three Utah locations, Cedar City, Logan, and Vernal, from 2020 to 2024. The alternative forage crops included teff, sorghum-sudangrass (sudex), and forage rye. For economic comparison, conventional forage crops included alfalfa, corn, and three-way small grains. Four to five irrigation …

The Impact Of Ai On The Landscape Design Process, Jacob Owen Huff

All Graduate Theses and Dissertations, Fall 2023 to Present

Artificial intelligence (AI) is becoming more common in design fields, including landscape architecture. For example, AI has been used to visually analyze park aesthetics and generate landscape design concepts (Jahani et al., 2022; Senem et al., 2023; Ploennigs & Berger, 2023). This study explores how AI, specifically an image-generation tool called Midjourney, affects the design process for landscape architecture students.

Students completed two design projects—one using AI-generated images and one using traditional, non-AI precedent images. Their final designs were evaluated by professional landscape architects who did not know which designs had been influenced by AI. Students also completed surveys about …

Advancing Management Strategies For Two Promising Mason Bee Species (Osmia Ribifloris And Osmia Bruneri) For Berry Pollination, Miranda L. Jones

All Graduate Theses and Dissertations, Fall 2023 to Present

Bee management can broadly refer to human manipulation of one or multiple parts of a bee’s lifecycle. Managing honey bees, commonly referred to as beekeeping, is responsible for providing most pollination for global food crops. However, using more than one bee species for crop pollination can have many benefits. Benefits include better crop pollination and insurance in case one bee species underperforms or its population collapses. Some bees within the genus Osmia are already widely managed for crop pollination because their developmental lifecycle allows bee managers to readily deploy pollinating bees in sync with varying crop blooms, and for certain …

Asynchronous Intervention For Students With Disabilities On Career Awareness, Erica Rood

All Graduate Theses and Dissertations, Fall 2023 to Present

Historically, students with disabilities have fewer opportunities to prepare for post-high school life, and this is especially true when it comes to getting a job. This is also true for those students with complex support needs (i.e., autism spectrum disorder, intellectual disability, other health impairment). One way to help individuals with disabilities have greater success after high school is to teach them about different careers.

This study was for high school students with disabilities who have complex support needs. It focused on helping them learn about different careers through online modules. The study looked at whether this type of learning …

Does Acceptance Matter? The Moderating Role Of Acceptance Of Pornography Use In Sexual And Relationship Satisfaction, Alexandra L. Gillespie

All Graduate Theses and Dissertations, Fall 2023 to Present

With more or the general population reporting regular pornography use there has been an increase in interest in the consequences of regular use, especially for romantic relationships. Previously completed research has shown that there are likely other explanations for why pornography use is related to both positive and negative outcomes. This study examines how acceptance might change the influence the relationship between frequency of use and relationship and sexual satisfaction for individuals. This relationship may yield greater understanding of why some individuals report benefits and others report negative effects of pornography use. Findings indicated that for men their level of …

Pavlovian Conditioning And Self-Control: From Laboratory To Classroom Application, Saba Mahmoudi

All Graduate Theses and Dissertations, Fall 2023 to Present

Impulsive choice, the preference for a smaller-sooner reward (SSR) over a larger-later reward (LLR), is associated with various challenging behaviors (e.g., gambling and substance-used disorders). Many interventions can reduce impulsive choice but those that produce long-lasting effects typically require long training durations or are difficult to implement in applied settings. This dissertation evaluated a novel Pavlovian training approach designed to promote self-control. In Experiment 1, procedures from Mahmoudi and Madden (2024) were replicated in the laboratory with the addition of a truly random control group. The study also assessed whether presenting the conditioned stimulus (CS) before a choice would increase …

Method Validation Of The Cdc Bottle Bioassay And A Historical Record Of Polycyclic Aromatic Hydrocarbons In Glacier National Park, Evah F. Peard

All Graduate Theses and Dissertations, Fall 2023 to Present

Certain contaminants can persist in the environment for long periods of time, build up within living tissues, travel far from their origin, and harm both ecosystems and organisms. This thesis focuses on two types of contaminants: insecticides and polycyclic aromatic hydrocarbons (PAHs). Insecticides are manufactured to control pests while PAHs are found in oil and gas products and can be produced by industry, vehicle engines, and wildfires. Understanding how harmful these contaminants are and where they end up in the environment is critical for protecting environmental health.

First, I evaluated a widely used test developed by the Centers for Disease …

Improving Teacher Adherence To Greeting And Attendance Routines Through Performance And Graphed Feedback, Caitlin Huppi

All Graduate Theses and Dissertations, Fall 2023 to Present

Schools establish expectations for teachers to create safe, organized, and welcoming environments, but teachers may not consistently follow these expectations throughout the school year. This study examined whether brief feedback could help four high school teachers more consistently greet students and scan IDs for attendance during passing periods. Teachers received graphs showing their performance and brief weekly feedback. All four teachers increased greeting behavior, and three increased attendance scanning. Teachers also rated the intervention as acceptable, feasible, and helpful. These findings suggest that brief feedback may be a practical way for school leaders to support consistent teacher implementation of school-wide …

The Use Of A Novel Decision Making Tool To Support Educators' Use Of Classroom Management Practices, Emma C. Preston

All Graduate Theses and Dissertations, Fall 2023 to Present

We examined the impacts of a novel classroom management evaluation tool that includes a decision-making feature to involve teachers in the selection of a strategy to improve their utilization of classroom management strategies titled the Behavioral Observation and Teacher Support System (BOTSS). We evaluated teacher praise-to-corrective statement ratios and teacher opportunities to respond, as well as student disruptive behavior and teacher social validity. We found that two independent observers scored teacher behavior similarly using the BOTSS, and that the BOTSS process produced moderate effects on teacher behavior. We did not observe an impact on student disruptive behavior. Teachers reported positively …

Bridging The Gap: Exploring The Development Of Science Self-Efficacy Among Students With Learning Disabilities, Aria Hadley-Hulet

All Graduate Theses and Dissertations, Fall 2023 to Present

Students with learning disabilities are often overlooked in efforts to broaden participation in STEM. This multi-paper dissertation investigates science self-efficacy among this population through the lenses of the social model of disability and self-efficacy theory. An integrative review reveals consistently lower academic self-efficacy among students with learning disabilities and a lack of research examining their science self-efficacy specifically. Quantitative analysis of national data shows lower science self-efficacy overall, yet no differences among students enrolled in advanced science courses. A mixed-methods study further demonstrates that in inclusive school environments characterized by asset-based teacher beliefs and normalized accommodations, science self-efficacy differences disappear. …

Investigation Of Yy Production Methods For Invasive Channel Catfish Ictalurus Punctatus Population Management, Andrew M. Wisniewski

All Graduate Theses and Dissertations, Fall 2023 to Present

Aquatic invasive species are one of the leading causes of native fish declines in the Southwestern United States. Channel Catfish Ictalurus punctatus were introduced into the Colorado River Basin, including the San Juan River, New Mexico, Colorado, and Utah for fishery enhancement during the 20th century. This introduction has contributed to the decline of native species and despite intensive mechanical removal efforts, the Channel Catfish population has persisted in the San Juan River. The Trojan Sex Chromosome approach is a promising eradication strategy that proposes the production and release of Trojan sex chromosome carriers (YY) to skew a targeted population’s …

Understanding And Predicting Precipitation Characteristics In The United States Through Machine Learning, Numerical Modeling And Measurements, Cody Luther Ratterman

All Graduate Theses and Dissertations, Fall 2023 to Present

Precipitation is one of the most important yet uncertain variables in the climate system. It varies dramatically in terms of timing, accumulation, rate, and phase, depending on location, season, circulation patterns, and atmospheric conditions. Precipitation forecasts, especially snowfall, are essential to supporting drought mitigation and water management in the Intermountain West. Because rainfall and snowfall lead to opposite effects on snowpack, accurately partitioning rain and snow is important to estimate snowpack levels, winter recreation, mountain ecosystems and runoff. The research findings in this dissertation have advanced the understanding and prediction of precipitation and snowpack in the U.S. by addressing the …