Power and Energy Commons^™

Lithium Storage Performance Of High Capacity Material Si@CPzs In Lithium Ion Batteries, Qing-Nuan Zhang, Fang-Fang Zhang, Hong-Xia Li, Bing-Jun Yang, Xiao-Cheng Li, Juan Yang

Journal of Electrochemistry

Carbon layers with different thicknesses were introduced into the surfaces of silicon (Si) nanoparticles by sol-gel method using poly (cyclotriphosphazene-co-4, 4'-sulfonyldiphenol) as the carbon source. Technologies of X-ray diffraction, thermo-gravimetric analysis, Brunauer-Emmett-Teller and transmission electron microscopy were employed to analyze the structures and components of the as-prepared Si@C_PZS composites. Electrochemical performance of Si@C_PZS with different carbon thicknesses was studied. The results showed that Si@C_PZS with carbon thickness of 10 nm possessed the best performance. Its capacity remained 940 mAh·g^-1 after 290 cycles under 500 mA·g^-1. As the addictive, the graphite-based anode contained 30% of …

Preparations Of Nickel-Iron Hydroxide/Sulfide And Their Electrocatalytic Performances For Overall Water Splitting, Hang-Shuo Lu, Xiao-Bo He, Feng-Xiang Yin, Guo-Ru Li

Journal of Electrochemistry

The Ni-Fe/Ti oxygen evolution electrode was prepared by electrodeposition on a titanium mesh substrate. Then, the as prepared Ni-Fe/Ti electrode was used to derive the Ni-Fe-S/Ti hydrogen evolution electrode through solid phase sulfuration. The effects of the molar ratio of Ni²⁺ to Fe³⁺ in the electrolyte and the amount of thiourea on the structures and electrochemical performances of Ni-Fe/Ti and Ni-Fe-S/Ti electrodes were investigated. The results show that the oxygen evolution performance of Ni-Fe/Ti electrode was first increased and then decreased with the increase of nickel ion content in the electrolyte. The Ni9Fe1/Ti electrode exhibited the best oxygen …

Atomic Force Microscopic Characterization Of Solid Electrolyte Interphase In Lithium Ion Batteries, Qing-Yu Dong, Yan-Li Chu, Yan-Bin Shen, Li-Wei Chen

Journal of Electrochemistry

In recent years, the rapid growing in the electric vehicle market has raised higher requirement on the lithium-ion batteries (LIBs) performance towards energy density and safety. However, considering the successful development of LIBs techniques in the past 30 years, there is little room left for improving the LIBs performance on the aspects related to the electrode materials, battery structure design and production processes. It is important to pursue more comprehensive fundamental understanding in the entire system and working principle of LIBs. Solid electrolyte interphase (SEI), existing between the electrode material and the electrolyte, has been proved to be an important …

Electrochemical Preparations And Applications Of Nano-Catalysts With High-Index Facets, Chi Xiao, Na Tian, Zhi-You Zhou, Shi-Gang Sun

Journal of Electrochemistry

The performance of catalysts highly depends on their surface structure and composition. Nanocrystals bounded by high-index facets usually exhibit high catalytic activity due to their high-density low-coordinated step atoms with high reactivity. In this paper, we have reviewed the preparations of noble metals (e.g., Pt, Pd and Rh) nanocatalysts with high-index facets by electrochemical square-wave potential method developed in our group. The square-wave potential method includes a nucleation procedure to generate nuclei, followed by a square-wave potential procedure for a certain period of time for the growth of nuclei into nanocrystals. The formation mechanism of high-index facets is also discussed. …

Research Progresses In Polymeric Proton Exchange Membranes For Fuel Cells, Xu-Po Liu, Yun-Feng Zhang, Shao-Feng Deng, De-Li Wang, Han-Song Cheng

Journal of Electrochemistry

Proton exchange membrane (PEM) is one of the key components in PEM fuel cells, which possesses the function of separating the cathode and anode, affording proton transport channels and preventing fuel permeability. The property of PEM significantly influences the performance and service life of fuel cells. Nowadays, the commercially used Nafion membranes have the shortcomings of serious fuel permeability, low proton conductivity at elevated temperature and high price, which limits the rapid development of PEM fuel cells. Therefore, it seems to be urgent to develop novel PEMs with low cost and good comprehensive properties. Polymeric proton exchange membrane is an …

Research Progresses In Ni-Co-Mn/Al Ternary Concentration Gradient Cathode Materials For Li-Ion Batteries, Chun-Fang Zhang, Wen-Gao Zhao, Shi-Yao Zheng, Yi-Xiao Li, Zheng-Liang Gong, Zhong-Ru Zhang, Yong Yang

Journal of Electrochemistry

Nickel-rich ternary materials with large reversible capacity as well as high operating voltage are considered as the most promising candidate for next generation lithium-ion batteries (LIBs). However, the inferior cycle stability and thermal stability have limited their widely commercial applications. Concentration gradient design of Ni-Co-Mn/Al ternary concentration gradient materials have been extensively studied in the past decade, which can ensure high cycle capacity while maintaining excellent cycle stability. In this paper, the latest research progresses in Ni-Co-Mn/Al ternary concentration gradient materials for LIBs are reviewed. Firstly, we summarize the different synthesis methods of ternary concentration-gradient materials, especially focusing on the …

Effect Of Nitrogen Content In Catalyst Precursor On Activity Of Fen/C Catalyst For Oxygen Reduction Reaction, Zhi Yang, Ya-Yun Shen, E Zhou, Cheng-Ling Wei, Hao-Li Qin, Juan Tian

Journal of Electrochemistry

Non-noble metal catalysts with high activity and low cost have attracted increasing interest as potential catalysts for oxygen reduction reaction (ORR) to replace Pt-based catalysts. In this paper, the effect of nitrogen content in catalyst precursor on ORR activity of FeN/C catalyst was investigated by X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) surface area and pore size distribution measurements, transmission electron microscope (TEM), thermogravimetric analysis (TGA), and rotating disk electrode (RDE) techniques. The results show that the most active catalyst was obtained by pyrolysis in argon at 1050 °C with a catalyst precursor containing 20wt% 1,10-phenanthroline, 1wt% Fe and Black Pearl 2000. …

Challenges In The Activity And Stability Of Pt-Based Catalysts Toward Orr, Tuo Zhao, Er-Gui Luo, Xian Wang, Jun-Jie Ge, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

The development of highly efficient oxygen reduction reaction (ORR) catalysts is the key to the commercialization of fuel cells, where the sluggish ORR reaction rate needs to be overcome by adjusting the intermediates adsorption energies on the catalytic surfaces. To-date, platinum (Pt)-based materials are the-state-of-the-art catalysts in terms of both activity and stability in ORR, making them the preferred choice for commercial applications. However, the high cost of Pt-based catalysts limits their widespread use, leading to massive effects paid in reducing Pt loading, improving catalyst activity and stability. This article illustrates the challenges in the ORR reaction and introduces the …

Preparation And Electrocatalytic Performance Of Nico2O4/Ni Foam For Hydrogen Peroxide Electrooxidation, Wei-Wei Chen, Fei-Fan Zhang, Jia-Liang Du, Yi Wang, Chun-Lin Zhao, Kai Zhu, Dian-Xue Cao, Gui-Ling Wang

Journal of Electrochemistry

The electrodes of Ni foam supported NiCo₂O₄ nanowires were prepared by hydrothermal method, followed by a thermal treatment in air, and were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It was found that the NiCo₂O₄ nanowires had a diameter of about 50 nm with a length up to 3 ~ 5 μm. The catalytic performances of the Ni foam supported NiCo₂O₄ nanowires for H₂O₂ electrooxidation were studied by cyclic voltammetry and chronoamperometry. The results show that the Ni foam supported NiCo …

Evaluation Of Capacitive Deionization Desalination Technology For Irrigation, Ziad Khalifa, Moustafa Elshafei Prof, Abdalrahman Amer, Eng, Ashraf Seleym Dr, Tamer Samir Eng

Chemical Engineering

Desalination of brackish groundwater has great potential to alleviate the problem of the limited water resources in Egypt. In this paper, we studied the desalination of brackish water for irrigation purposes using capacitive deionization (CDI) technology. We investigated a modular unit for use in greenhouses (GH). A GH for the production of tomato requires about 3.2 m3/d of water. The target CDI unit has a production capacity of 32 m3/d for irrigation of 10 greenhouses from brackish water. The paper provides an extensive simulation study to illustrate the influence of various design parameters and to unveil the CDI technology pros …

Short-Term Electricity Price Forecasting In Deregulated Electricity Market Based On Enhanced Artificial Intelligence Techniques, Pourdaryaei Alireza

Student Works (2020-2029)

Electricity price forecasting is considered as one of prime factors for operation, planning and scheduling of price-setter market participants. However, possessing time variant, non-linear and non-stationary behaviors make the electricity price a complex signal. The main challenge in this area is providing highly accurate and efficient day-ahead price forecasting. A suitable feature selection technique, which is able to model the interacting features and nonlinearities of the forecast processes, is still required although researches have been performed for day-ahead forecasting. In this research, a hybrid electricity price forecasting methodology is proposed using two-stage feature selection method and optimization using adaptive neuro-fuzzy …

Residential Thermal Storage And Cooling, Joao Marcelo Rocha Belmonte, Jacob Anderson, Andrew Clarke, Daphne Forester, Bianca Hardtke, Josh Hartman, Marc D. Compere

Sustainability Conference

No abstract provided.

Dual-Axis Solar Tracker, Bryan Kennedy

All Undergraduate Projects

Renewable energies, and fuels that are not fossil fuel-based, are one of the prolific topics of debate in modern society. With climate change now becoming a primary focus for scientists and innovators of today, one of the areas for the largest amount of potential and growth is that of the capturing and utilization of Solar Energy. This method involves using a mechanical system to track the progression of the sun as it traverses the sky throughout the day. A dual-axis solar tracker such as the one designed and built for this project, can follow the sun both azimuthally and in …

Computational Assessment Of Aortic Valve Function And Mechanics Under Hypertension, Saurav Kadel

Browse all Theses and Dissertations

Calcific aortic valve disease (CAVD), the most common valvular heart disorder, is associated with complications such as stroke, heart attack, aortic aneurysm, left ventricular hypertrophy, and ultimately death. While hypertension has been identified as a major risk factor for CAVD, the mechanisms by which it may promote calcification are still unknown. Given the sensitivity of valvular tissue to mechanical stress alterations, the hemodynamic abnormalities linked to hypertension may play a role in the development of CAVD. Further, the effects of hypertension on the left ventricular functionality and coronary flow resistance remain largely uninvestigated. Hence, the objectives of this thesis were …

Microgrid-Enabled Reactive Power Support To Enhance Grid Economics, Sarhan Hasan

Electronic Theses and Dissertations

Reactive power plays an essential role in voltage control and stability in electric power systems. Various Volt/VAR techniques are utilized in electric power systems to maintain the voltage profile within defined acceptable limits and accordingly provide reliability and stability. Reactive power has been commonly generated through large-scale synchronous generators or distributed capacitor banks to provide proper transmission and distribution level system management, however, reactive power can be further used as an effective means to reduce total system operation cost. In this dissertation, an optimal reactive power model is proposed to determine the optimal nodal reactive powers that result in the …

Deep Reinforcement Learning For The Optimization Of Building Energy Control And Management, Jun Hao

Electronic Theses and Dissertations

Most of the current game-theoretic demand-side management methods focus primarily on the scheduling of home appliances, and the related numerical experiments are analyzed under various scenarios to achieve the corresponding Nash-equilibrium (NE) and optimal results. However, not much work is conducted for academic or commercial buildings. The methods for optimizing academic-buildings are distinct from the optimal methods for home appliances. In my study, we address a novel methodology to control the operation of heating, ventilation, and air conditioning system (HVAC).

We assume that each building in our campus is equipped with smart meter and communication system which is envisioned in …

Experimental Investigation Of Low-Voltage Silicon Carbide (Sic) Semiconductor Devices For Power Conversion Applications, Saleh Salem H. Alharbi

Electronic Theses and Dissertations

Enhancing the performance and efficiency of power converter systems requires fast-switching power devices with considerably low switching and conduction losses. Silicon (Si) semiconductor devices are the essential components in electronic converter designs, and their behaviors and switching characteristics determine the system’s overall performance and efficiency. These conventional Si devices are nearing to hit their physical and operational limits in meeting power converter requirements with respect to high temperature and large voltage conditions. However, silicon carbide (SiC) power devices enable greater converter efficiency and better power density, particularly under hard switching frequencies and high output voltages due to their outstanding material …

Real-Time Detection Of Demand Manipulation Attacks On A Power Grid, Srinidhi Madabhushi

Electronic Theses and Dissertations

An increased usage in IoT devices across the globe has posed a threat to the power grid. When an attacker has access to multiple IoT devices within the same geographical location, they can possibly disrupt the power grid by regulating a botnet of high-wattage IoT devices. Based on the time and situation of the attack, an adversary needs access to a fixed number of IoT devices to synchronously switch on/off all of them, resulting in an imbalance between the supply and demand. When the frequency of the power generators drops below a threshold value, it can lead to the generators …

Power System Frequency Control And Stability Analysis With Increasing Renewable Energy Penetration Level, Weihang Yan

Electronic Theses and Dissertations

With the ever-increasing penetration level of renewable energy generation units and the replacement of traditional synchronous generators, the issues associated with the deteriorated performance of power system frequency regulation and potential grid frequency instability become more significant. In this dissertation, the inertial control algorithms are investigated and analyzed for power electronics converter in a renewable energy generation unit. The concept and design of Virtual Synchronous Generator are comprehensively discussed, such that the small-signal stability and frequency stability of power systems with high renewable energy penetration level can be enhanced. Moreover, both nonlinear dynamic model and small-signal linearization of Virtual Synchronous …

Aggregated Der Management In Advanced Distribution Grids, Mohsen Mahoor

Electronic Theses and Dissertations

Evolution of modern power systems are more distinct in distribution grids, where the growing integration of microgrids as well as distributed energy resources (DERs), including renewable energy resources, electric vehicles (EVs), and energy storage, poses new challenges and opportunities to grid management and operation. Rapid growth of distribution automation as well as equipment monitoring technologies in the distribution grids further offer new opportunities for distribution asset management. The idea of aggregated DERs is proposed as a remedy to streamline management and operation of advanced distribution grids, as discussed under three subjects in this dissertation. The first subject matter focuses on …