Power and Energy Commons^™

Air Piston Approach To Wave Power Generation, Arun Ramadass

Theses

Scientists have calculated that, by tapping just 0.2% of the energy produced by the world's oceans we can provide for all the worlds current energy needs. It is generally accepted that a combination of traditional energy production methods, (oil, coal, gas, nuclear) mixed with a combination of renewable energy production approaches is the future in providing for an increasingly energy hungry world. Wind, solar and biomass have moved into the public arena only in the last few years.

The proposed patented device (US Patent No.: 7,468,563) Ocean Wave Energy Converter harnesses the energy of ocean waves by continually raising and …

A High Performance Sulfur/Carbon Xerogel Composite In Lithium Sulfur Battery Application, Chong Wang, Jia-Jia Chen, Qiu-Jie She, Qian Zhang, Yi-Ning Shi, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

Sulfur/carbon composite was synthesized by the thermal method with the carbon xerogel as the conductive framework. The property of composite was characterd by XRD and SEM. It shown that the composite with the particle size below 10 μm had the same morphology as the carbon xerogel and the sulfur was absorbed in the pores in non-crystalline. The discharge capacity of the composites were 1311 mAh/g and 1107. 1 mAh/g at 0. 1C and 0. 2 C rates,respetively. And a retention capacity was about 800 mAh/g after 30 cylcyes.

Nano/Micro-Structured Electrode Materials For Lithium-Ion Batteries, Yu-Guo Guo, Zhong-Li Wang, Xing-Long Wu, Wei-Ming Zhang, Li-Jun Wan

Journal of Electrochemistry

Nanostructured materials are currently of interest as high performance anodes and cathodes for rechargeable lithium-ion batteries because of their novel nano-size effects and significantly enhanced kinetics. This review paper describes some recent developments in this field,addressing the size effects,morphology effects,as well as the functions of carbon coating layers toward lithium storage. Several"kinetically stabilized"nano/microstructured electrode materials and high-rate electrode materials with mixed-conducting networks based on the work of the authors are highlighted for illustration.

Electrocatalytic Oxidation Of Hcooh At Au(Core)-Pd(Shell)-Pt(Cluster) Nanocubes, Qing-Ning Jiang, Huan Li, Ning Yang, Ping-Ping Fang, Feng-Ru Fan, Zhong-Qun Tian

Journal of Electrochemistry

Gold nanocubes were synthesized by a two-step seed-mediated growth method. The Aucore-Pdshell and Au_core-Pd_shell-Pt_cluster nanocubes with controllable shell thickness of Pd and cluster coverage of Pt were synthesized by simply changing the amount ratio of H₂PdCl₄ or H₂PtCl₆. The samples were characterized by scanning electron microscope (SEM) , transmission electron microscopc (TEM) and cyclic voltammetry (CV). CV was then used to make a systematic study on the dependence of the electrocatalytic properties on the shell thickness of Au_core-Pd_shell and Pt coverage of Au_core-Pd …

Prerapation And Supercapacitor Property Of Mesoporous Carbon Nanofibers, Yong-Wen Wang, Ming-Bo Zheng, Jian Cao, Jie-Ming Cao, Guang-Bin Ji, Jie Tao

Journal of Electrochemistry

Two different mesoporous carbon nanofibers with large mesopore or core-shell structure were prepared by using the resol/F127 mixture to fill the AAO template. The morphology and structural parameters of the samples were characterized by SEM,TEM,and N₂ adsorption-desorption analysis. The supercapacitive behaviors of the electrodes were tested by cyclic voltammetry and galvanostatic charge-discharge. The results show that the specific capacitances of mesoporous carbon nanofibers increased obviously and the fine supercapacitive performances were achieved at high scan rate or large current density.

Optimization Of Membrane Electrode Assembly In Air-Breathing Direct Methanol Fuel Cell, Liang Ma, Wei-Wei Cai, Jing Zhang, Liang Liang, Jian-Hui Liao, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

The structure and performance of MEA were optimized by tailoring the catalyst layer,cathodic microporous layer (MPL) ,anodic MPL and membrane,with the considerations of unique characteristics of airbreathing direct methanol fuel cell (DMFC) such as methanol crossover and cathode flooding. It was found that high catalyst loading could suppress the methanol crossover effectively,but too high catalyst loading can lead to high mass transport resistance. Hydrophobic anodic MPL with 30% (by mass) PTFE could facilitate the CO₂ bubble detachment,which decreased the methanol concentration gradient and suppressed the methanol crossover accordingly. When Nafion 115 was used as membrane,methanol crossover was severe,while Nafion …

High-Rate Cyclic Properties Of Hollow Carbon Hemisphere As Anode Materials For Lithium Ion Batteries, Guang-Hui Zhang, Zao-Xue Yan, Hong-Li Zou, Pei-Kang Shen

Journal of Electrochemistry

High surface area hollow carbon hemispheres (HCHs) covered with hard carbon layers have been synthesized by using polystyrene spheres (PSs) as templates under hydrothermal method combined with the intermittent microwave heating (IMH) method. The morphologies of the materials are characterized by SEM and TEM. The electrochemical properties of the HCHs are tested. Comparing with graphite and mesocarbon microbeads (MCMB) ,the HCHs show higher capacity and excellent cyclic life performance.

Research On Electrochemical Performance Of Lithium-Ion Battery Cathode Material Lini(1/3)Co(1/3)Mn(1/3)O2 In Aqueous Lino3 Solution, Jun Zheng, Xin Jia, Chong Wang, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

The cathode material of LiNi_1/3Co_1/3Mn_1/3O₂ synthesized by sol-gel method shows excellent high rate performance, and high output power density during discharge process. A well-ordered layered α-NaFeO₂ structure was confirmed by XRD and a primary particle size of about 500 nm was indicated by SEM. Galvanostatic charge-discharge test indicates that LiNi_1/3Co_1/3Mn_1/3O₂ in 2 mol·L^-1 LiNO₃ aqueous solution with pH 12 reached a ca-pacity of 147 mAh/g while charged and discharged at 2C. The capacities were 64, 33, 16 mAh/g with 80C (14.4 A/g), 150C …

Fabrication Of Electrochemically Activated Glassy Carbon/Bismuth Film Electrodes For Sensitive Analysis Of Pb(2+) And Cd(2+), Kang Shi, Wen-Jing Wang, Kun Hu

Journal of Electrochemistry

The application of electrochemically activated glassy carbon (GC) in the in-situ preparing of bismuth film electrodes (BiFEs) to analyze Pb^{2 +} and Cd^{2 +} was investigated. The glassy carbon electrodes were electrochemically activated by either potentiostic or cyclic polarization in 1 mol·L^-1 NaOH solution. Experimental results show that employment of HCl solution as the analytical solution not only can reproducibly renew the electrochemically activated GC electrode surface with an electrochemical clear procedure, but also can greatly enhance the sensitivity of BiFes method for analysis of Pb^{2 +} and Cd^{2 +}. The test range thus …

Synthesis Of Cosalen Composite In Apo-5 And Its Electrocatalytic Behaviour For Reaction Of Dioxygen Reduction, Rong Zhang, Li-Hua Tang, Bin-Bin Fan, Jing-Hong Ma, Rui-Feng Li

Journal of Electrochemistry

CoAPO-5 molecular sieve was hydrothermally synthesized. The Cobalt ions in CoAPO-5 were coordinated with the SALEN ligend diffusing into the channels of the molecular sieve to form CoSALEN complexes. The electrochemical behaviors and electrocatalysis for dioxygen reduction of the CoSALEN complex immobilized in APO-5 modified glassy carbon electrodes (GCEs) have been investigated by cyclic voltammetry (CV) and chronoamperometry (CA) in differrent pH aqueous solutions. The results showed that the PS/CoSALEN/APO-5 /GC modified electrode is of the high electrocatalytic activity towards dioxygen reduction in pH 6. 86 buffer solution with a reduced overpotential of 447 mV lower than bare GC electrode. …

Failure Reaction Mechanism Of Internal Short-Circuit For Lithium-Ion Batteries, He Li, Shen-Jun Yu, Zhi-Kui Chen, Guang-Chuan Liang

Journal of Electrochemistry

In this work, the battery impact testing machine has been used to study the failure progress of internal short-circuit (ISC) for lithium ion batteries. The reaction mechanisms between cathode/anode and electrolyte in the battery at different temperatures were characterized by differential scanning calorimetry (DSC), gas chromatography/mass spectrometry (GC/MS) and X-ray diffraction (XRD). The experimental results show that the ISC failure of the battery was mainly due to the reaction between cathode Li_0.5CoO₂ and electrolyte. The decomposition and oxygen evolution reactions of cathode occurred when the temperature reached a certain value. At the same time a fierce oxidation …

Influence Of Ions Dimension On The Electric Field Activation Of Micro-Crystallite Carbon, Gang-Wei Sun, Wen-Hua Song, Guo Cheng, Wen-Ming Qiao, Li-Cheng Ling

Journal of Electrochemistry

Micro-crystallite carbon (CC) was synthesized by KOH activation of carbonized petroleum coke precursors. The porous properties structure and crystallite structure were characterized by N₂ adsorption-desorption, X-ray diffraction (XRD) measurements. The capacitive behavior of CC was investigated in the electrolyte of Et₄NBF₄/PC, Et₄NBF₄/AN, Bu₄NBF₄/PC and Bu₄NBF₄/AN, respectively. Results showed that the lower potential of electric field activation (EFA) was obtained in the solvent of AN than in PC, which was ascribed to the fact that smaller solvated ions dimension in AN facilitating the intercalation …

Hydrogen Evolution Reaction Activtity Of Ni-Ru-Ir Oxide Cathode Coating, Yin-Hui Fu, Xue-Ming Li, Wu-Lin Li, Jun Zhang

Journal of Electrochemistry

The Ni-Ru-Ir electrode coating was fabricated by thermal decomposition and oxidation. Electrochemical properties of Ni-Ru-Ir electrode coating and pure nickel cathode in the 30% NaOH solutions at 90 ℃(conditions of the industrial electrolysis) ,have been investigated by cyclic voltammetry,Tafel curves and chronoamperometry. The results show that the Ni-Ru-Ir oxide electrode coating exhibited high catalytic activity. At the current density of 0. 3 A·cm^-2,the lowest hydrogen evolution overpotential of Ni-Ru-Ir oxide electrode coating was about 300 mV lower than Ni. The roughness and excharge current density of Ni-Ru-Ir electrode coating were 32 and 4 times,respectively,larger than those of pure …

Synthesis And Electrochemical Properties Of Li3V2(Po4)3/C Cathode Materials For Lithium Ion Battery, Li-Ying Liu, Hai-Yan Zhang, Lian Chen, Yu-Chun Zhai

Journal of Electrochemistry

Cathode material Li₃V₂(PO₄) ₃ /C for Lithium-ion battery was synthesized by combination of ball milling and baking. Physical and electrochemical performances of as-prepared materials were characterized through XRD,EIS and galvanostatic cell cycling. The results show that the products were monoclinic Li₃ V₂ (PO₄) ₃ with well-developed crystal structure. At 0. 1C,0. 25C and 0. 5C,the initial discharge capacities were 150. 6,134. 1 and 107. 1 mAh·g^-1 ,respectively. Capacity retention rates were 87. 3% after 130 cycles at 0. 25C and 87. 2% after 105 cycles at 0. 5C. Charge-discharge …

Nano-Sized Au On Nickel Foam As Cathode Of Alkaline Al-H2O2 Semi Fuel Cell, Shu-Li Chen, Bang-An Lu, Yao Liu, Gui-Ling Wang, Dian-Xue Cao

Journal of Electrochemistry

Nano-sized Au particles were deposited on a nickel foam substrate by a fast spontaneous deposition method using AuCl₃ as the source of Au. The effects of AuCl₃ concentration and deposition time on the size and distribution of Au particles,and the performance of the obtained Au/Ni electrode as the cathode of Al-H₂O₂ semi fuel cell were investigated. It was found that after the nickel foam was immersed in a 2 mmol·L^-1 AuCl₃ solution for 60 s,Au particles with diameters smaller than 100 nm were deposited on its surfaces and cover the surface completely. The …

2010 Spring Engr333 Project Final Report, Eric Ledy, Rachel Jelgerhuis, Jasper Gondhi, Michael Gondhi, Steve Brink, John Mantel, Kyle Harvey, Jim Vanleeuwen, Jacob Speelman, Mitch Brummel, Tyler Van Dongen, Nathan Van Heukelum, Lynette Hromada, Jen Meneely, Matthew Brouwer, Marc Eberlein, Steve Demaagd, Tim Opperwall, Andrew Dejong, Joel Love, Alex Boelkins, Amanda Hollinger, Betsy Huyser, Jason Dornbos, Jason Handlogten, Justin Karsten, Matt Milan

ENGR 333

Calvin is developing plans for a new data center to provide business continuity and quick recovery in the event of a disaster. The new data center will not replace the existing data center; rather, it will provide redundancy for the operations of the campus. Because of the energy demands of data centers, there is a worldwide push for energy efficiency. So-called “green data centers” provide the same functionality as a normal data center with reduced energy usage and reduced energy costs. Calvin, like most organizations, must weigh the long-term economic benefits of energy efficiency projects against higher initial cost. The …

2010 Spring Engr333 Poster 1, Eric Ledy, Rachel Jelgerhuis, Jasper Gondhi, Michael Gondhi, Steve Brink, John Mantel, Kyle Harvey, Jim Venleeuwen, Jacob Speelman, Mitch Brummel, Tyler Van Dongen, Nathan Van Heukelum, Lynette Hromada, Jen Meneely, Matthew Brouwer, Marc Eberlein, Steve Demaagd, Tim Opperwall, Andrew Dejong, Joel Love, Alex Boelkins, Amanda Hollinger, Betsy Huyser, Jason Dornbos, Jason Handlogten, Justin Karsten, Matt Milan

ENGR 333

Calvin is developing plans for a new data center to provide business continuity and quick recovery in the event of a disaster. The new data center will not replace the existing data center; rather, it will provide redundancy for the operations of the campus. This new data center will be placed in the Spoelhof Complex. Because of the energy demands of data centers, there is a worldwide push for energy efficiency. So-called “green data centers” provide the same functionality as a normal data center with reduced energy usage and reduced energy costs. Calvin, like most organizations, must weigh the long-term …

2010 Spring Engr333 Poster 2, Eric Ledy, Rachel Jelgerhuis, Jasper Gondhi, Michael Gondhi, Steve Brink, John Mantel, Kyle Harvey, Jim Vanleeuwen, Jacob Speelman, Mitch Brummel, Tyler Van Dongen, Nathan Van Heukelum, Lynette Hromada, Jen Meneely, Matthew Brouwer, Marc Eberlein, Steve Demaagd, Tim Opperwall, Andrew Dejong, Joel Love, Alex Boelkins, Amanda Hollinger, Betsy Huyser, Jason Dornbos, Jason Handlogten, Justin Karsten, Matt Milan

ENGR 333

The new redundant data center requires that Network Operations Center personnel are able to monitor certain conditions within the data center for the safety of the server equipment. Server equipment will fail if it gets too hot or if the surrounding environment becomes too humid, therefore the baseline instrumentation design must monitor both temperature and humidity in the data center. The system must also be capable of remotely alerting NOC personnel when there is a problem.

2010 Spring Engr333 Project Seminar Presentation, Eric Ledy, Rachel Jelgerhuis, Jasper Gondhi, Michael Gondhi, Steve Brink, John Mantel, Kyle Harvey, Jim Vanleeuwen, Jacob Speelman, Mitch Brummel, Tyler Van Dongen, Nathan Van Heukelum, Lynette Hromada, Jen Meneely, Matthew Brouwer, Marc Eberlein, Steve Demaagd, Tim Opperwall, Andrew Dejong, Joel Love, Alex Boelkins, Amanda Hollinger, Betsy Huyser, Jason Dornbos, Jason Handlogten, Justin Karsten, Matt Milan

ENGR 333

File for student presentation, given by students in the Spring 2010 class of ENGR333.

Maintenance Optimization For Substations With Aging Equipment, Haifeng Ge

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

Today’s electric utilities are confronted with a myriad of challenges that include aging infrastructure, enhanced expectation of reliability, reduced cost, and coping effectively with uncertainties and changing regulation requirements. Utilities rely on Asset Management programs to manage inspections and maintenance activities in order to control equipment conditions. However, development of strategies to make sound decisions in order to effectively improve equipment and system reliability while meeting constraints such as a maintenance budget is a challenge.

The primary objective of this dissertation is to develop models and algorithms to study the impact of maintenance toward equipment/system reliability and economic cost, and …