Comparative Study Of Nanoporous Pt, Ptru And Ptruir Catalysts Using Electrochemical Ftir Spectroscopy,
2010
Department of Chemistry, Lakehead University, 955 Oliver Road, Thunder Bay, Ontario P7B 5E1, Canada;
Comparative Study Of Nanoporous Pt, Ptru And Ptruir Catalysts Using Electrochemical Ftir Spectroscopy, M. Amussen Robert, Holt-Hindle Peter, Nigro Samantha, Aicheng Chen
Journal of Electrochemistry
In recent years much effort has been put towards developing efficient Pt-based electrocatalysts for applications in fuel cells. With the rising cost of precious metals such as Pt,the need to enhance the activity and to decrease the load of catalysts is prominent. Herein we report on the synthesis and comparative study of nanoporous Pt,PtRu and PtRuIr electrocatalysts. The nanoporous electrodes were fabricated using a hydrothermal method and characterized by scanning electron microscopy (SEM) ,energy dispersive spectroscopy (EDS) ,X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) . The electrocatalytic activity of the fabricated nanopo- rous materials was evaluated using both CO …
In Situ Surface-Enhanced Raman Scattering Spectroscopic Study Of Sulfur Adsorption On Polycrystalline Platinum Electrode Surface,
2010
Department of Chemistry, Georgetown University, 37th & 0 Streets, NW, Washington, DC 20057, USA
In Situ Surface-Enhanced Raman Scattering Spectroscopic Study Of Sulfur Adsorption On Polycrystalline Platinum Electrode Surface, Bolian Xu, In-Su Park, Ying Li, De-Jun Chen, Yuye J. Tong
Journal of Electrochemistry
The paper reports the first in situ surface enhanced Raman scattering (SERS) spectroelectrochemistry study of sulfur adsorption and electro-oxidation on highly roughened polycrystalline Pt surface in both acidic and basic supporting electrolytes. The SERS spectra were taken at a constant electrode potential after accumulative electro-oxidation CVs of the Pt electrode with pre-adsorbed sulfur species and at different electrode potentials that were varied stepwise of the Pt electrode immersed in sulfur-containing electrolytes without pre-adsorbed sulfur species. In both cases,a dominant vibrational band at 299 cm-1 in acidic electrolyte but at 310 cm-1 in basic electrolyte was observed,which was assigned …
Studies Of Oxidation Processes Of Adsorbed And Solution Co On Pt(110) Electrode By Cyclic Voltammetry And In Situ Ftirs,
2010
Xiamen University
Studies Of Oxidation Processes Of Adsorbed And Solution Co On Pt(110) Electrode By Cyclic Voltammetry And In Situ Ftirs, Li Tian, Jun-Tao Li, Jin-Yu Ye, Chun-Hua Zhen, Shi-Gang Sun
Journal of Electrochemistry
The oxidation processes of adsorbed CO (COad) and solution phase CO (COsol) on Pt(110) electrode were investigated by cyclic voltammetry and in-situ FTIR spectroscopy. It has revealed that in comparison with COad on Pt(110) in a CO-free solution,the oxidation current peak of COsol in a CO-saturated solution is positively shifted ca. 168 mV,and the peak current density has been increased by 6. 70 times. Linear adsorbed CO (COL) is determined by in-situ FTIR spectroscopy as the main species,which is uniformly distributed on Pt (110) surface. In a CO-free solution,the onset potential of COL is measured by in-situ FTIRS ca. 0. …
Tracking Simultaneous Time-Varying Power Harmonic Distortions Using Filter Banks,
2010
Universidade Federal de Juiz de Fora
Tracking Simultaneous Time-Varying Power Harmonic Distortions Using Filter Banks, Carlos A. Duque, Paulo M. Silveira, Thomas L. Baldwin, Paulo F. Ribeiro
University Faculty Publications and Creative Works
Although it is well known that the Fourier analysis is only accurately applicable to steady-state waveforms, it is a widely used tool to study and monitor time-varying signals, such as are commonplace in electrical power systems. The disadvantages of the Fourier analysis, such as frequency spillover or problems due to sampling (data window) truncation can often be minimized by various windowing techniques, but they nevertheless exist. This paper demonstrates that it is possible to track and visualize amplitude and time-varying power systems harmonics, without frequency spillover caused by classical time-frequency techniques. This new tool allows for a clear visualization of …
Modular Electronic Load,
2010
California Polytechnic State University - San Luis Obispo
Modular Electronic Load, Jason March
Electrical Engineering
This project entails the design and development of a modular electronic load. The cost and simplicity of the design are considered such that it can be reproduced in-house to replace whenever possible resistor box for load testing of any analog circuits but more specifically power electronic circuits.
The design process as well as the hardware development is explained in details in this report. Results from hardware testing are also provided.
Enhanced Cal Poly Super System Simulink Model,
2010
California Polytechnic State University, San Luis Obispo
Enhanced Cal Poly Super System Simulink Model, Matthew Ogden Mcfarland
Master's Theses
The Cal Poly Sustainable Power for Electrical Resources (SuPER) project is a solar power DC distribution system designed to autonomously manage and supply the energy needs of a single family off-the-grid home. The following thesis describes the improvement and re-design of a MATLAB Simulink model for the Cal Poly SuPER system. This model includes a photovoltaic (PV) array, a lead-acid gel battery with temperature effects, a wind turbine model, a re-designed DC-DC converter, a DC microgrid, and multiple loads. This thesis will also include several control algorithms such as a temperature controlled thermoelectric (T.E.) cooler, intelligent load switching, and an …
Asynchronous Mips Processors: Educational Simulations,
2010
California Polytechnic State University, San Luis Obispo
Asynchronous Mips Processors: Educational Simulations, Robert L. Webb
Master's Theses
The system clock has been omnipresent in most mainstream chip designs. While simplifying many design problems the clock has caused the problems of clock skew, high power consumption, electromagnetic interference, and worst-case performance. In recent years, as the timing constraints of synchronous designs have been squeezed ever tighter, the efficiencies of asynchronous designs have become more attractive. By removing the clock, these issues can be mitigated. How- ever, asynchronous designs are generally more complex and difficult to debug. In this paper I discuss the advantages of asynchronous processors and the specifics of some asynchronous designs, outline the roadblocks to asynchronous …
Further Developments On The Geothermal System Scoping Model,
2010
National Renewable Energy Laboratory
Further Developments On The Geothermal System Scoping Model, Mark Antkowiak, Rosemary Sargent, Jesse W. Geiger
Publications (E)
The fields of well construction and engineering, power plant construction and engineering, and reservoir engineering often proceed independently of one another. Yet the subsystems of a geothermal plant with which each of these fields is concerned need to be integrated in order to create a viable geothermal power system and make enhanced (or engineered) geothermal systems (EGS) a technical and an economic reality. Furthermore, each of these subsystems need to be examined in the context of the overall power system to aid with plant construction, and–more salient to the U.S. Department of Energy–to help determine best investment of research dollars. …
The Generation Of Domestic Electricity Load Profiles Through Markov Chain Modelling,
2010
Technological University Dublin
The Generation Of Domestic Electricity Load Profiles Through Markov Chain Modelling, Aidan Duffy, Fintan Mcloughlin, Michael Conlon
Conference Papers
Micro-generation technologies such as photovoltaics and micro-wind power are becoming increasing popular among homeowners, mainly a result of policy support mechanisms helping to improve cost competiveness as compared to traditional fossil fuel generation. National government strategies to reduce electricity demand generated from fossil fuels and to meet European Union 20/20 targets is driving this change. However, the real performance of these technologies in a domestic setting is not often known as high time resolution models for domestic electricity load profiles are not readily available. As a result, projections in terms of reducing electricity demand and financial paybacks for these micro-generation …
Validated Real-Time Energy Models For Small-Scale Grid-Connected Pv-Systems,
2010
Technological University Dublin
Validated Real-Time Energy Models For Small-Scale Grid-Connected Pv-Systems, Lacour Ayompe, Aidan Duffy, Sarah Mccormack, Michael Conlon
Articles
This paper presents validated real-time energy models for small-scale grid-connected PV-systems suitable for domestic application. The models were used to predict real-time AC power output from a PV system in Dublin, Ireland using 30-min intervals of measured performance data between April 2009 and March 2010. Statistical analysis of the predicted results and measured data highlight possible sources of errors and the limitations and/or adequacy of existing models, to describe the temperature and efficiency of PV-cells and consequently, the accuracy of power prediction models. PV-system AC output power predictions using empirical models for PV-cell temperature and efficiency prediction showed lower percentage …
Simulation Of Temperature Distributions In Tissue Upon Laser Pulse Irradiation Including Water Mass Transfer,
2010
Old Dominion University
Simulation Of Temperature Distributions In Tissue Upon Laser Pulse Irradiation Including Water Mass Transfer, Deepthi Nagulapally
Electrical & Computer Engineering Theses & Dissertations
Lasers, due to their unique characteristics, have tremendous applications in the medical field. Generally all laser applications in hie-medicine involve the propagation of laser energy through tissue. Energy is deposited giving rise to many physical, hie-chemical, and mechanical effects. Among these are dynamical changes in the local temperature distributions within the tissue. Analysis of the temperature changes requires the creation of an appropriate optical transmission and heat flow model that incorporates user specified laser parameters. Here, a numerical simulation model was developed to study both steady state and time dependent temperature distributions due to pulsed laser radiation within user specified …
A Comparison Of Induction Motor Starting Methods Being Powered By A Diesel-Generator Set,
2010
University of Nebraska-Lincoln
A Comparison Of Induction Motor Starting Methods Being Powered By A Diesel-Generator Set, Adam John Wigington
Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research
Starting induction motors on isolated or weak systems is a highly dynamic process that can cause motor and load damage as well as electrical network fluctuations. Mechanical damage is associated with the high starting current drawn by a ramping induction motor. In order to compensate the load increase, the voltage of the electrical system decreases. Different starting methods can be applied to the electrical system to reduce these and other starting method issues. The purpose of this thesis is to build accurate and usable simulation models that can aid the designer in making the choice of an appropriate motor starting …
The Applications And Limitations Of Printable Batteries,
2010
California Polytechnic State University - San Luis Obispo
The Applications And Limitations Of Printable Batteries, Matthew Delmanowski
Graphic Communication
This study focuses on the potential applications for printed batteries and how they could affect the printing industry. It also analyzes the main problems associated with manufacturing this technology and what needs to be done to overcome these issues. To find the answers to these questions, two methods of research were used. The first was through the elite and specialized interviewing of Dr. Scott Williams of Rochester Institute of Technology and Professor Nancy Cullins from Cal Poly. The second form of research was a common, yet useful, method called secondary research. This entailed looking at recent written research papers about …
Simulation Of Cal Poly Super System Simulink Model Using Insolation Variation,
2010
California Polytechnic State University - San Luis Obispo
Simulation Of Cal Poly Super System Simulink Model Using Insolation Variation, Jacob Kory
Electrical Engineering
This senior project focuses on simulation of the Cal Poly SuPER system using an insolation model. First, local and historical weather data is examined to determine the range of limits that the model will utilize. Then, the insolation model is constructed to fit into the existing SuPER model. The overall system is tested under a variety of insolation values to determine system performance of motor and static loads. Based on these simulations, several factors of the current model are discovered that limit the power consumption profile under off-peak load conditions. Finally, recommendations on improvements to the model are discussed
Distributed Generation: Issues Concerning A Changing Power Grid Paradigm,
2010
California Polytechnic State University, San Luis Obispo
Distributed Generation: Issues Concerning A Changing Power Grid Paradigm, Scott G.M. Therien
Master's Theses
Distributed generation is becoming increasingly prevalent on power grids around the world. Conventional designs and grid operations are not always sufficient for handling the implementation of distributed generation units; the new generation may result in undesirable operating conditions, or system failure. This paper investigates the primary issues involved with the implementation of distributed generation and maintaining the integrity of the power grid. The issues addressed include power flow, system protections, voltage regulation, intermittency, harmonics, and islanding. A case study is also presented to illustrate how these issues can be addressed when designing distributed generation installation on an existent distribution system. …
Optimization Of P3ht-Pcbm Polymer Solar Cells Through Device Simulation And Manufacturing,
2010
California Polytechnic State University - San Luis Obispo
Optimization Of P3ht-Pcbm Polymer Solar Cells Through Device Simulation And Manufacturing, James Boom
Computer Engineering
Given a good model and implementation of that model, computer simulation can be used to reduce the time and material costs of research. To this end I worked with other students to manufacture, test and simulate the single layer P3HT-PCBM solar cell. Using the data collected from this project, future work can then be done with the project's simulator to further optimize these types of solar cell devices.
Power Losses Associated With Stand-By Chargers,
2010
California Poly
Power Losses Associated With Stand-By Chargers, Robert Peralta
Electrical Engineering
Many average households across the United States may not realize how much power is saved by simply removing the plug from the receptacle when not being used. A misconception with stand-by/portable chargers is; if a device is not connected to the charger, but the charger is still connected to the wall, then the charger will not consume power. That statement is false. The following report will demonstrate how much power is lost in an average household. When a reference is made to an average house, I will refer to a 4 bedroom single family home. The house will have an …
Electric Bicycle System,
2010
California Polytechnic State University - San Luis Obispo
Electric Bicycle System, Robert Cong, Rodney Martinez, Mark Casilang, Peter Vong
Electrical Engineering
The Electric Bicycle System is a systems project that incorporates three different ways of charging a lithium-ion battery: the 120VAC wall outlet, regenerative braking, and solar power; which is used to power an electric hub motor running a bicycle. The purpose of the project is to show that it is possible and relatively simple, to build an electric bicycle by oneself. This project can be broken down into five separate categories: the lithium-ion battery, the DC-DC boost converter, the solar panel, the motor, and the motor controller. Each of these will be built upon and improved further by future students, …
Transmission Line Forecast Study,
2010
California Polytechnic State University - San Luis Obispo
Transmission Line Forecast Study, Ryan Garoogian
Electrical Engineering
Load forecasting is the procedure to predict future loading conditions on a power system. Using simulation software such as ETAP you are able to predict abnormal voltage conditions, overloading of certain equipment, as well as determine protective equipment from short circuit studies. This study consisted of a 115kV loop network with multiple loading busses and one infinite bus. There was no separate generation other than the infinite bus. As load increased from forecasting to the future voltage dropped. To restore voltage levels capacitors were added at strategic points in the system to boost the voltage back up. Preparing yourself for …
High Voltage Switched-Mode Power Supply For Three-Phase Ac Aircraft Systems,
2010
California Polytechnic State University - San Luis Obispo
High Voltage Switched-Mode Power Supply For Three-Phase Ac Aircraft Systems, John Brewer Jr., Kamaljit Bagha
Electrical Engineering
The purpose of this senior project was to design and fabricate a proof-of-concept Three-Phase Sinusoidal Switched-Mode Inverter with a power output capability of 10 kW and nominal operating frequency of 400 Hz for AC aircraft system applications. This senior project report includes a thorough discussion and presentation of the inverter system background, requirements, design, construction, and testing processes.
